VACUUM ELECTRON TUBE WITH PLANAR CATHODE BASED ON NANOTUBES OR NANOWIRES
20180012723 · 2018-01-11
Inventors
Cpc classification
H01J35/065
ELECTRICITY
H01J21/105
ELECTRICITY
H01J1/312
ELECTRICITY
International classification
Abstract
A vacuum electron tube comprises at least one electron-emitting cathode and at least one anode arranged in a vacuum chamber, the cathode having a planar structure comprising a substrate comprising a conductive material, a plurality of nanotube or nanowire elements electrically insulated from the substrate, the longitudinal axis of the nanotube or nanowire elements substantially parallel to the plane of the substrate, and at least one first connector electrically linked to at least one nanotube or nanowire element so as to be able to apply a first electrical potential to the nanowire or nanotube element.
Claims
1. A vacuum electron tube comprising at least one electron-emitting cathode and at least one anode arranged in a vacuum chamber, the cathode having a planar structure comprising a substrate comprising a conductive material, a plurality of nanotube or nanowire elements electrically insulated from the substrate, the longitudinal axis of said nanotube or nanowire elements being substantially parallel to the plane of the substrate, and at least one first connector electrically linked to at least one nanotube or nanowire element so as to be able to apply a first electrical potential to the nanowire or nanotube element.
2. The vacuum electron tube according to claim 1, wherein the nanotube or nanowire elements are substantially parallel to one another.
3. The vacuum electron tube according to claim 1, wherein which the first connector comprises a substantially planar contact element arranged on an insulating layer and linked to a first end of said nanotube or nanowire element.
4. The vacuum electron tube according to claim 1, wherein the cathode further comprises a first control means linked to the first connector and to the substrate, and configured to apply a bias voltage between the substrate and the nanotube element so that the nanotube or nanowire element emits electrons through its surface by tunnel effect.
5. The vacuum electron tube according to claim 4, wherein the bias voltage lies between 100 V and 1000 V.
6. The vacuum electron tube according to claim 1, wherein the nanotube or nanowire elements have a radius of between 1 nm and 100 nm.
7. The vacuum electron tube according to claim 1, wherein the cathode comprises a second electrical connector linked electrically to at least one nanotube or nanowire element so as to be able to apply a second electrical potential to the nanotube or nanowire element.
8. The vacuum electron tube according to claim 7, wherein the first and the second connectors respectively comprise a first and a second substantially planar contact elements arranged on an insulating layer and respectively linked to a first and a second ends of said nanotube or nanowire element.
9. The vacuum electron tube according to claim 7, wherein the cathode comprises at least one nanotube or nanowire element linked simultaneously to the first connector and to the second connector.
10. The vacuum electron tube according to claim 1, wherein the cathode further comprises means for heating the nanotube or nanowire element.
11. The vacuum electron tube according to claim 9, wherein the cathode comprises a second control means linked to the first and to the second connectors and configured to apply a heating voltage to said nanotube or nanowire element via the first and the second electrical potentials, so as to generate an electric current in said nanotube or nanowire element, such that the nanotube or nanowire element emits electrons through its surface by thermoionic effect.
12. The vacuum electron tube according to claim 11, wherein the heating voltage lies between 0.1 V and 10 V.
13. The vacuum electron tube according to claim 1, wherein the nanotube or nanowire elements are partially buried in a burying insulating layer.
14. The vacuum electron tube according to claim 4, wherein the cathode is divided into a plurality of zones, the nanotube or nanowire elements of each zone being linked to a different first electrical connector, such that the bias voltages applied to each zone are independent and reconfigurable.
15. The tube according to claim 1, wherein the nanotube or nanowire elements are conductors.
16. The vacuum electron tube according to claim 4, wherein the nanotube or nanowire elements are semiconductors and wherein the bias voltage is greater than a threshold voltage, the nanowire or nanotube element then constituting a channel of a capacitor of MOS type, so as to generate free carriers in the nanowire or nanotube element.
17. The vacuum electron tube according to claim 16, wherein the cathode further comprises a light source configured to illuminate the nanotube or nanowire element so as to generate free carriers in said nanowire or nanotube element by photogeneration.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0046] Other features, aims and advantages of the present invention will become apparent on reading the following detailed description and in light of the attached drawings given as nonlimiting examples and in which:
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DETAILED DESCRIPTION
[0072] A vacuum tube is proposed here based on nanotube or nanowire elements arranged according to a planar geometry, whereas all of the prior art has always sought to use the tip effect associated with the form of the nanotube/nanowire cathodes to produce vacuum-tube cathodes.
[0073] The vacuum electron tube 70 according to the invention is illustrated in
[0074] The vacuum electron tube 70 comprises at least one electron-emitting cathode C and at least one anode A arranged in a vacuum chamber E. The specific feature of the invention lies in the original structure of the cathode, the rest of the tube being dimensioned according to the prior art.
[0075] The at least one cathode C of the tube 70 has a planar structure comprising a substrate Sb comprising a conductive material, that is to say a material exhibiting an electrical behaviour similar to a metal, and a plurality of nanotube or nanowire elements NT electrically insulated from the substrate.
[0076] According to an embodiment illustrated in
[0077] Nanotubes and nanowires are known to those skilled in the art. Nanotubes and nanowires are elements whose diameter is less than 100 nanometers and whose length is from 1 to several tens of microns. The nanotube is a mostly hollow structure whereas the nanowire is a solid structure. The two types of nanoelement are globally called NT and are compatible with a cathode of the vacuum tube according to the invention.
[0078] Typically, the substrate is of doped silicon, doped silicon carbide, or any other conductive material compatible with the fabrication of the cathode.
[0079] The cathode further comprises at least one first connector CE1 linked electrically to at least one nanotube or nanowire element so as to be able to apply a first electrical potential to the element NT. The first connector CE1 thus allows electrical access to the elements NT. Because of the complexity of the fabrication technology, the elements NT of the cathode are not necessarily all connected. Hereinbelow, we will focus only on the elements NT actually linked electrically to the connector CE1.
[0080] Because of the planar structure, the (connected) elements NT of the cathode C in operation emit electrons from the surface S thereof. There are two variants each inducing a specific configuration of the cathode C according to the invention, according to the physical effect causing the emission of electrons. A first variant is based on the tunnel effect, a second variant is based on the thermoionic effect, the two variants being able to be combined, allowing an increased emission of electrons. These two variants are described in detail later.
[0081] The planar structure of the elements NT offers numerous advantages. It makes it possible to produce the generic device illustrated in
[0082] Furthermore, the fabrication of the elements NT according to the invention is performed from known technological building blocks, and does not require any growth of PECVD (plasma DC) type as in the case of the vertical carbon nanotubes, which releases the constraints on the materials that can be used and on the potential designs significantly. It is in particular possible to produce surface insulations (not currently compatible with PECVD growth) which makes it possible to obtain a higher level of robustness compared to the current “gated cathode” designs.
[0083] The elements NT can be produced by in-situ growth on a plate (catalyst localization methods for example) or by ex-situ growth methods with mounting. The two methods have advantages and drawbacks:
[0084] In-situ: no need for mounting, possible localization of the nanowires/nanotubes. But this method is more restricted and it is difficult to select the nanowires/nanotubes after the event.
[0085] Ex-situ: access to a much greater panel of growth methods than in-situ growth. This approach offers greater flexibility of implementation and of adaptation of the method to the material needs. Furthermore, it is possible to select nanomaterials of similar diameter to reduce the parameter for the field emission. Material quality control is also simplified. Finally, the commercial availability of a wide range of materials offers an advantageous design flexibility. This method does however present the drawback of requiring a step of mounting and of controlling the density to ensure the target spacing W between 2 nanowires/nanotubes.
[0086] The production of horizontal nanowires on substrate by etching is a theme widely studied for the requirements of microelectronics. The notions of size reduction and of size dispersion are in particular the focus of these studies. Several strategies have been successfully developed for addressing this issue (optical lithography DUV/EUV; electron beam lithography; “spacer lithography”; etc.). It should be noted that the production of these nanowires/nanotubes according to the invention is very similar to the gate production in the CMOS technologies which gates these days are achieving sizes of the order of 10 nm on the industrial scale.
[0087] Preferentially, for better operation, the nanotube or nanowire elements NT are substantially parallel to one another, and the average distance W between each element is controlled. An average distance between elements NT of the order of the thickness of the insulation is preferred. The parallel alignment ensures a greater integration compactness and therefore a greater number of active emitters per surface area unit, which potentially increases the current emitted by the structure.
[0088] According to a preferred embodiment illustrated in
[0089] According to an embodiment also illustrated in
[0090] Typically, the insulating layer Is used in the fabrication of the nanotubes has been removed (sacrificial layer) under the nanotube part, these nanotubes then being moored to the substrate by the planar contact C1, which for its part is insulated from the substrate by the insulating layer Is. Thus, in this variant, the insulation is obtained for the planar contact C1 by a physical sacrificial layer Is and for the elements NT by the vacuum Vac.
[0091] There is thus no longer any NT/insulation/vacuum interface, but only an NT/vacuum interface. The thermal insulation of the NTs is increased. Furthermore, the emission surface is increased, the bottom half-surface being able to participate in the current emitted (subject to an assurance that the external field E0 makes it possible to recover the electrons emitted by this bottom half-surface).
[0092] According to a first preferred variant illustrated in
[0093] For that, the cathode C of the tube 70 comprises a first control means MC1 linked to the first connector CE1, biased at the voltage V1, and to the substrate Sb, and configured to apply a bias voltage V.sub.NW between the substrate and the nanotube element. If V.sub.Sb is the potential of the substrate, then:
V.sub.NW=V1−V.sub.sb
[0094] To obtain field emission, it is essential for the potential difference V.sub.NW to be negative. The substrate can for example be linked to the ground.
[0095] The front-face contact with the elements NT via CE1 is in effect electrically insulated from the conductive substrate Sb.
[0096] For good insulation, a “thick” insulating layer Is with a thickness h of between 100 nm and 10 μm is preferable.
[0097] The bias voltage V.sub.NW is therefore established between the elements NT and the substrate. This bias voltage and the external macroscopic field E0 combined induce a surface field E.sub.S on the element NT. In effect, the nanoelement/insulation/substrate system forms a capacitor which allows the generation of a large number of negative charges which are concentrated on the small surface S of the nanotube, as illustrated in
[0098] It should be noted that the external macroscopic field applied E0 is basically necessary for the needs of the vacuum electron tube (notably to direct the electrons emitted in the tube).
[0099] The extraction of the electrons is performed by tunnel effect, and the electrons are emitted radially in all directions. The external field E0 makes the electrons take a trajectory 100 that is globally at right angles to the substrate, as illustrated in
[0100] Compared to a conventional approach with emitters 1D preferentially at right angles to the substrate VACNT, there is an analogy between the height/radius of the VACNTs and the height h set by the thickness of insulation, radius of the planar nanowire/nanotube NT. Thus, compared to the emitters 1D and to the problem of dispersion of these two parameters in the fabrication explained in the state of the art section, the present invention offers the following advantages.
[0101] Regarding the height of the emitters, the horizontal emitter elements NT all have exactly the same height h, unlike in the conventional approaches (typically +/−1 μm on the vertical nanotubes, for typical heights of 5 to 10 μm), which de facto considerably reduces the issue of the dispersion of this parameter, which is solved extremely simply through the use of a homogeneous insulating layer Is produced with conventional microelectronics means.
[0102] Regarding the nanotube radius, it is possible to apply methods known furthermore to produce nanowires/nanotubes exhibiting low radius dispersions. Furthermore, the nanomaterials thus produced can be selected by various methods to reduce as much as possible the dispersion of the radius factor (a thing that is impossible if considering growth on substrate). A radius dispersion of +/−2 nm is typically achievable (compared to +/−20 nm for VACNTs).
[0103] Thus, in a cathode according to the prior art, because of the dispersion of the height and the radius of the vertical nanotubes, there are few nanotubes which effectively emit electrons, which induces a strong current per emitter, a strong current constituting a greater probability of destruction.
[0104] In the cathode C according to the invention, because of a smaller dispersion, there is less current per emitter, and therefore the cathode is more robust.
[0105] Furthermore, the cathode C is such that when the bias voltage V.sub.NW is low or zero, the field effect is negligible: the vacuum tube 70 operates in “Normally off” mode, which is an element of dependability sought after in certain medical X-ray tube applications.
[0106] It should also be noted that, compared to the emitters of 1D type, the tip effect of the planar nanoelements according to the invention is produced in two dimensions, and the potential electron emission surfaces are therefore significantly greater. In effect, for a 1D microtip, the surface is of the order of ˜r.sup.2; whereas, for a planar nanotube it is of the order of L.r (L length of the nanowire, r radius of the nanowire) for a similar emitter density. This gain in emission surface is advantageous for targeting strong overall currents.
[0107] To obtain a tip effect and extraction by tunnel effect, preferentially the nanotube or nanowire elements NT have a radius r of between 1 nm and 100 nm.
[0108] To obtain an emission by field effect (tunnel effect) of a nanotube/nanowire element NT, the surface electrical field Es should lie between 0.5 V/nm and 5 V/nm. This range of values conditions the dimensioning of the cathode through the relationship:
With:
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[0115] Typically E0 is of the order of 0.01 V/nm and the term V.sub.NW/(h/ε.sub.r) is of the order of 0.1 V/nm. The term V.sub.NW/(h/ε.sub.r) is large compared to E0, and it is this first term which contributes in the first instance to the obtaining of the field Es.
[0116] The fact that E0 is not used in the extraction of the electrons, that is to say that there is independence between generation/extraction (via V.sub.NW) and acceleration (via E0) of the electrons is an enormous advantage for X-ray tubes.
[0117] According to the prior art, when the field E0 is changed, the emission current is changed.
[0118] In the cathode according to the invention, it is the bias voltage which conditions the value of the emission current, not, or very little, the external field E0. It is thus possible in an X-ray tube according to the invention to produce an image with emission currents that are identical for different energies.
[0119] Thus, typical tunnel effect fields of a few Volts/nm are obtained on the surface S of the nanowires/nanotubes NT.
[0120] Other design rules make it possible to improve the electron emission: [0121] Typically the distance W between two emitters NT is greater than or equal to h/2. [0122] Typically h/r is greater than or equal to 100: for example, h=1 to 5 μm and r=2 to 10 nm. [0123] Typically, the acceptable bias between top contacts and substrate is at least of the order of E0*h/εr (i.e. a few tens of volts).
[0124] According to a preferred variant illustrated in
[0125] Advantageously, the cathode comprises at least one element NT linked simultaneously to the first connector CE1 and to the second connector CE2, in order to render the cathode according to the invention compatible with the use of the thermoionic effect (see later).
[0126] In this configuration, different potentials are applied to the two ends of the nanoelement, which, with a conductive substrate, is possible only with the presence of an insulation between the nanoelement and the substrate.
[0127] Preferentially, to simplify the fabrication, the cathode C comprises several nanotube or nanowire elements NT connected to the same first connector and/or to the same second connector.
[0128] Preferentially, the connector CE2 comprises a planar contact element C2 (typically metal, of a material standard in microelectronics: aluminium, titanium, gold, tungsten, etc.), arranged on an insulating layer Is and linked to a second end E2 of the element NT as illustrated in
[0129] Thus, on the insulation, a series of electrical contact elements are linked to one another. The contacts are preferentially locally parallel and placed at a distance L. Between the electrodes there are the nanowires/nanotubes NT such that at least one of their ends is connected to one of the electrical contacts. The characteristic distance between two nanowires/nanotubes is denoted W.
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[0131] For the cathode C according to the invention having the structure of
V1=V2.
[0132] For a controlled emission, preferentially the distance W between the elements NT is substantially constant and controlled. In effect, it is preferable to observe an average distance of the order of the insulation thickness, the constancy in the value of the distance W being the ideal case. That makes it possible to maximize the number of effective emitters per unit of surface area and therefore increase the associated emission current. The emitters are called upon in the same way which maximizes the associated emission current and increases the lifetime/robustness of the cathode.
[0133] With such a geometry, densities of 50 000 to 100 000 per mm.sup.2 are obtained (“fill factor” less than 1 due to the integration of the contact relays on the front face). Each element NT has an emissive surface of the order of 7000 nm.sup.2 (useful emission of the half-surface S).
[0134] The nominal emission currents per emitter (of the order of 200 nA) are acceptable by the nanowires/nanotubes.
[0135] According to another variant, the cathode C according to the invention emits electrons by thermoionic effect, by heating the element NT. Thus, the cathode C further comprises means for heating the nanotube or nanowire element NT. For that, it is not necessary to specifically dimension the elements NT, there is no constraint on the height h of the insulating layer Is or on the radius r of the elements NT. It is suitable in this case to use a material with low work function for the nanoelements, such as tungsten or molybdenum.
[0136] A preferred means for heating the nanotube/nanowire is to pass a current into the latter. For that, at least one nanotube or nanowire element NT must be linked simultaneously to the first connector CE1 and to the second connector CE2.
[0137] According to an embodiment in
[0138] The following applies: Vch=V1−V2
[0139] An electric current I is thus generated in the nanotube/nanowire element NT.
[0140] The two connectors CE1 and CE2 must be separated spatially sufficiently on the nanotube to allow the current to circulate.
[0141] For a variant of the invention in which only the thermoionic effect is used (no bias voltage V.sub.NW or specific dimensioning), it is suitable to heat the element NT to a heating temperature greater than or equal to 1000° Celsius.
[0142] When the thermoionic effect combines with/complements the tunnel effect (see later), a heating temperature greater than 600° Celsius is sufficient.
[0143] Preferentially, the heating voltage Vch lies between 0.1 V and 10 V.
[0144] Thus, a cathode configured according to the invention comprises at least one control means (MC1 and/or MC2) linked to the first connector CE1 and configured to apply a potential difference such that the cathode emits electrons from its surface S. The potential difference being applied:
[0145] first control means MC1: between the element NT (V1 via CE1) and the substrate Sb (potential of the substrate VSb) for an electron emission by tunnel effect (bias voltage V.sub.Nw=V1−VSb),
[0146] second control means MC2: to the element NT itself (V1 via CE1 and V2 via CE2) for an emission by thermoionic effect (heating voltage Vch=V1−V2).
[0147] The bias voltage and the heating voltage being able to be applied simultaneously to benefit from the two effects.
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[0149] According to one embodiment, the cathode according to the invention combines the two physical electron emission effects, tunnel effect and thermoionic effect, as illustrated according to the principle in
[0150] The presence of a vacuum—insulation—nanowire/nanotube interface is likely to induce a local exacerbation of the field. Since this interface is located “under” the nanowire, it is preferable to reduce this effect because it can lead to a local electron injection in the insulation and undesirable charge effects. For that, according to an embodiment illustrated in
[0151] According to a variant, the layer Isent is the insulating layer arranged on the substrate Sb.
[0152] According to a preferred variant, the layer Isent consists of at least one additional layer deposited on the insulating layer Is. In effect, this partial burying can provoke an electron emission in the insulation, which induces local charge effects, these effects “screening” the action of the substrate. Preferentially, local encapsulation in a material exhibiting a strong dielectric permittivity (called “high-k” material), such as HfO.sub.2, with ε.sub.HfO2=24, is performed to act on the permittivity effect and thus minimize the field of the nanowire at the junction with the insulation while maximizing the field on the free part of the nanowire. According to an embodiment, the burying layer Isent is a multilayer made up of a plurality of sublayers. The structure of the field lines is thus better controlled and the undesirable exacerbation effects are limited. Furthermore, it is possible to act on the permittivity/dielectric strength parameters of the different layers to optimize the applicable voltages in the structure.
[0153] Advantageously, approximately half of the nanoelement is buried in the layer Isent.
[0154] However, the incorporation of a material with strong permittivity, even in a thin layer, can significantly modify the effective height, and this aspect should be taken into account in the dimensioning of the thickness h of the layer Is.
[0155] According to another variant illustrated in
[0156] According to the prior art, the spatial modulation of the emission zone is produced by juxtaposing several cathodes alongside one another.
[0157] An advantage of the pixelation of a cathode is that it is possible, for imaging applications, initially to identify a zone of interest by illuminating using a wide emission zone, then, once the zone of interest has been detected, peform an illumination of the zone of interest with an emission zone of smaller dimensions allowing increased resolution.
[0158] According to a variant illustrated in
[0159] Preferentially, the nanotubes/nanoelements NT are made of conductive material, such as carbon, doped ZnO, doped silicon, silver, copper, tungsten, etc.
[0160] According to another embodiment, the nanotube/nanowire elements are semiconductors, for example made of Si, SiGe or GaN, so as to induce the presence by field effect and/or by illumination, which makes it possible to have increased control of the electron emission.
[0161] The nanowire or nanotube element then constitutes a channel of a capacitor of MOS type. The generation of carriers works when the bias voltage V.sub.NW is greater than a threshold voltage Vth.
[0162] In the case of a photogeneration of the carriers, the tube 70 further comprises a light source configured to illuminate the nanotube or nanowire element; the free carriers are then generated by photogeneration.
[0163] Semiconductor nanoelements NT can be used to generate electrons by tunnel effect and/or by thermoionic effect.
[0164] By way of illustration,
[0165] In a second step illustrated in
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[0167] Then, the contacts are produced by lift-off on the mat previously produced, as illustrated in