HIGH-FREQUENCY POWER SOURCE UV LAMP MONITOR AND TOTAL ORGANIC CARBON METER USING THE SAME

Abstract

Provided is a high-frequency power source UV lamp monitor capable of easily confirming lighting of a UV lamp built in a housing having a hermetically sealed structure. The monitor is attached to a high-frequency power UV lamp 20 that emits ultraviolet light by supplying high-frequency energy from a high-frequency power source 19 via a feeder, and is configured to include a detection circuit having a core member attached around the feeder in a ring shape and made of a magnetically permeable material, an induction circuit wound around the core member to extract a high-frequency induction current, and a detection element connected to the induction circuit.

Claims

1. A high-frequency power source UV lamp monitor attached to a high-frequency power source UV lamp, the UV lamp monitor being configured to emits ultraviolet light in response to high-frequency energy supplied from a high-frequency power source via a feeder, the high-frequency power source UV lamp monitor comprising: a detection circuit including a core member attached around the feeder in a ring shape and made of a magnetically permeable material, an induction circuit wound around the core member to extract a high-frequency induction current, and a detection element connected to the induction circuit.

2. The high-frequency power source UV lamp monitor as recited in claim 1, wherein the detection element is an LED.

3. A total organic carbon analyzer provided with a sample oxidizing portion for oxidizing carbon contained in a sample solution by irradiation with ultraviolet rays to convert the carbon into carbon dioxide, wherein the sample oxidizing portion uses a high-frequency power source UV lamp for emitting ultraviolet rays by supplying high-frequency energy from a high-frequency power source via a feeder, and is provided with a high-frequency power source UV lamp monitor for confirming lighting of the high-frequency power source UV lamp, and wherein the high-frequency power source UV lamp monitor comprises a detection circuit including a core member attached around the feeder in a ring shape and made of a magnetically permeable material, an induction circuit wound around the core member to extract a high-frequency induction current, and a detection element connected to the induction circuit.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0020] FIG. 1 is a configuration diagram showing a TOC analyzer using a high-frequency power source UV lamp monitor according to the present invention.

[0021] FIG. 2 is a diagram showing a configuration of a sample oxidizing portion of FIG. 1.

[0022] FIG. 3A is a wiring diagram of a high-frequency power source UV lamp and a monitor in the sample oxidizing portion of FIG. 1.

[0023] FIG. 3B is a wiring diagram showing a modified embodiment of the detector in FIG. 3A.

EMBODIMENTS FOR CARRYING OUT THE INVENTION

[0024] Hereinafter, an embodiment in which a high-frequency power source UV lamp monitor according to the present invention is applied to a TOC analyzer will be described with reference to the attached drawings. FIG. 1 is a configuration diagram showing the TOC analyzer for on-line measurement using a high-frequency power source UV lamp monitor according to an embodiment of the present invention. FIG. 2 is a diagram showing a configuration of a sample oxidizing portion in the TOC analyzer of FIG. 1, and FIG. 3A is a diagram showing wiring of a high-frequency power source UV lamp and a high-frequency power source UV lamp monitor included in the sample oxidizing portion.

[0025] In the TOC analyzer in this embodiment, a total carbon (TC) and an inorganic carbon (IC) in a sample solution are measured, and the difference is calculated. That is, the total organic carbon (TOC) concentration can be obtained by the following equation (1).

TOC=TCIC(1)

[0026] As shown in FIG. 1, the TOC analyzer 10 is provided with a flow path L to which a sample solution is supplied from a sample introduction port 11 for on-line measurement, a sample oxidizing portion 12 provided in the middle of the flow path L, a conductivity cell 13 for detecting the concentration of carbon dioxide by a conductivity sensor, and a liquid feed pump 14, such as, e.g., a tube pump, for feeding a sample solution and passing it through the flow path L.

[0027] Hereinafter, for convenience of description, a flow path extending from the sample introduction port 11 to the sample oxidizing portion 12 is defined as a flow path L1, a flow path in the sample oxidizing portion 12 is a flow path L2, a flow path extending from the sample oxidizing portion 12 to the conductivity cell 13 is defined as a flow path L3, and a flow path in the the conductivity cell 13 is defined as a flow path L4.

[0028] The sample oxidizing portion 12 has a built-in excimer UV lamp (high-frequency power source UV lamp) 20 connected to a high-frequency power source 19.

[0029] As shown in FIG. 2, the excimer UV lamp 20 has a double tube structure, and the inner tube 21 thereof is served as a part of a flow path L (i.e., a flow path L2) for oxidizing a sample solution and delivering it to the conductivity cell 13. A rare gas (e.g., xenon) is sealed in the outer tube 22. Electrodes 22c and 22d are provided on the inner wall 22a and the outer wall 22b of the outer tube 22, respectively, and the electrodes 22c and 22d are connected to a high-frequency power source 19 of 10 kHz to 1,000 kHz via a feeder 23. For example, it is configured such that when a high-frequency power of 100 kHz is applied from the high-frequency power source 19, ultraviolet rays generated by dielectric barrier discharge are irradiated toward the inner tube 21.

[0030] The excimer UV lamp 20 is accommodated in a hermetically sealed container 24 so that ultraviolet rays and air containing harmful ozone do not leak from the inside of the hermetically sealed container 24 to the outside.

[0031] Further, a detection circuit 30 for performing lighting confirmation is attached to a portion located outside the hermetically sealed container 24 in the feeder 23 connecting the high-frequency power source 19 and the excimer UV lamp 20. The detection circuit 30 is composed of a core member (toroidal core or ferrite core) 31 made of a magnetically permeable material and attached to the outer periphery of the feeder 23 in a ring shape, an induction circuit 32 wound around the core member 31 in a coil shape to extract a high-frequency induction current, and an LED (detection element) 33 connected to the induction circuit 32. The induction circuit 32 is also provided with a rectifying diode 34 and a protective resistor 35 for rectification and protection of the LED 33.

[0032] When the measurement is performed using such a TOC analyzer 10, first, in a state in which the excimer UV lamp 20 is turned off, the sample solution is continuously sucked into the flow path L by the liquid feed pump 14 at a constant flow rate, and the entire flow path L (flow paths L1 to L4) is filled with the sample solution. At this time, since a sample solution not irradiated with ultraviolet rays, that is, a unoxidized sample solution, is flowing through the conductivity cell 13 (flow path L4), the amount of carbon dioxide in the sample solution at this time is detected by the conductivity cell 13 as a signal of inorganic carbon (IC).

[0033] Subsequently, the liquid feed pump 14 is stopped and the excimer UV lamp 20 is turned on. In this state, ultraviolet irradiation is performed for about one minute. As a result, the total carbon (TC) of the sample solution staying in the inner tube 21 (flow path L2) of the sample oxidizing portion 12 is oxidized to be converted into carbon dioxide.

[0034] Thereafter, when the excimer UV lamp 20 is turned off and suction of the sample solution is resumed at a constant flow rate by the liquid feed pump 14, the sample solution (unoxidized sample solution) in the flow path L3 between the sample oxidizing portion 12 and the conductivity cell 13 flows for a while in the conductivity cell 13, and then the sample solution oxidized in the sample oxidizing portion 12 (flow path L2) reaches the conductivity cell 13. The amount of carbon dioxide at this time is detected as the total carbon (TC).

[0035] More specifically, when the sample solution is sucked at a constant flow rate, the time from the completion time T1 of passing the unoxidized sample solution in the flow path L3 to the completion time T2 of passing the sample solution oxidized in the flow path L2 in the conductivity cell is substantially determined by the relationship between the volumes of the flow paths L2 and L3. Therefore, the amount of carbon dioxide is continuously detected with the conductivity cell 13 until at least a period including before and after centering the period from the time T1 to the time T2 elapses, and the peak value of the detection signal of the conductivity cell 13 detected during that period is acquired as a signal of the total carbon (TC).

[0036] Then, the total organic carbon (TOC) concentration is calculated from the values of the inorganic carbon (IC) and the total carbon (TC) obtained immediately before based on the equation (1). Thus, the first measurement is completed.

[0037] Subsequently, when the sample solution is continuously sucked by the liquid feed pump 14 even after completion of the first measurement, all the flow paths L (L1 to L4) including the conductivity cell 13 are filled with the replaced unoxidized sample solution.

[0038] Therefore, by repeating the above measurement flow, it is possible to continuously perform the second and subsequent measurement of the total organic carbon (TOC) concentration.

[0039] Next, the lighting confirmation flow of the excimer UV lamp 20, which is a feature of the present invention, will be described.

[0040] When measuring the total carbon (TC) concentration, the sample solution is made to be retained in the inner tube 21 (flow path L2) of the sample oxidizing portion 12 and high-frequency power is supplied from the high-frequency power source 19 to excite the excimer UV lamp 20 to start discharge. Thus, by the action of the ultraviolet rays irradiated from the excimer UV lamp 20, an oxidation reaction occurs in the total carbon (TC) in the sample solution, and the total carbon (TC) is converted into carbon dioxide.

[0041] However, in cases where ultraviolet rays are not irradiated due to a failure or malfunction of the excimer UV lamp 20, the measurement of the total carbon (TC) concentration is performed without the oxidation reaction being performed, and an erroneous measurement result is shown, so that the user needs to confirm the lighting of the excimer UV lamp 20 using the detection circuit 30 before the measurement.

[0042] That is, in the ultraviolet irradiation in the sample oxidizing portion 12, high-frequency energy is supplied from the high-frequency power source 19 to the excimer UV lamp 20 via the feeder 23, so electromagnetic waves are generated around the feeder 23 by the high-frequency energy in the feeder 23. The generated electromagnetic waves are extracted as a high-frequency induction current by the core member 31 attached to the feeder 23 at a position outside the hermetically sealed container 24 and having high magnetic permeability and the induction circuit 32. When the high-frequency induction current flows to the LED 33 via the rectifying diode 34 connected to the induction circuit 32, the LED 33 emits light. Therefore, the lighting of the excimer UV lamp 20 can be confirmed by the lighting of the LED 33.

[0043] Although an embodiment of the present invention has been specifically described above, the present invention is not necessarily limited to the above-described embodiment, and it is needless to say that the present invention can be appropriately modified and changed within the scope not departing from the spirit of the present invention. Hereinafter, a modified embodiment thereof will be described.

[0044] The detection circuit 30 may be any other detection circuit as long as it is a circuit for extracting and detecting an induced current. An example is shown in FIG. 3B. In the detector 30 of FIG. 3B, the reference numeral 35 denotes a protective resistor, the reference numeral 36 denotes a capacitor for AC passage, and the reference numeral 37 denotes a protective diode.

[0045] In the embodiment described above, the resistor element may be used as a detection element to detect a voltage signal. In this case, the detected voltage signal may be compared with a threshold voltage set in advance to judge whether or not lighting is on, and when it is equal to or larger than the threshold value, it is judged that lighting is on, and when it is less than the threshold value, it is judged that lighting is off, and the judgment results may be notified by a detection means, such as, e.g., a buzzer.

[0046] Further, in the excimer UV lamp 20 used in the above embodiment, since the sample solution passes through the inner tube 21 (flow path L2), it is enough that only the inner tube 21 is irradiated with ultraviolet rays. Therefore, by forming the outer peripheral surface of the outer tube 22 with a material which does not allow transmission of ultraviolet rays, or by adhering or covering the outer tube 22 with a material which does not allow transmission of ultraviolet rays, it is possible to safely use the outer tube 22 without using the hermetically sealed container 24 while eliminating the problems of external irradiation of ultraviolet rays or harmful ozone generation.

INDUSTRIAL APPLICABILITY

[0047] The present invention can be used as a lamp monitor of a UV lamp used in a TOC analyzer.

DESCRIPTION OF SYMBOLS

[0048] 10: TOC analyzer (total organic carbon analyzer) [0049] 11: sample introduction port [0050] 12: sample oxidizing portion [0051] 13: conductivity cell [0052] 19: high-frequency power source [0053] 20: excimer UV lamp (high-frequency power source UV lamp) [0054] 21: inner tube [0055] 22: outer tube [0056] 22c, 22d: electrode [0057] 23: feeder [0058] 24: hermetically sealed housing [0059] 30: detection circuit [0060] 31: core member [0061] 32: induction circuit [0062] 33: LED (detection element) [0063] 34: rectifying diode [0064] 35: protective resistance [0065] 36: capacitor [0066] 37: protective diode