Radial flow reactor

11707723 · 2023-07-25

    Inventors

    Cpc classification

    International classification

    Abstract

    The present disclosure relates to a radial flow reactor including a pair of beds configured to produce a product by processing a raw material supplied thereto. A substance being produced or the product is movable between the pair of beds before the product is moved to a separate reservoir. The ratio of the area of an outlet with respect to the area of an inlet in each of the pair of beds is adjusted such that, when the substance being produced or the product is introduced into the outlet of one bed of the pair of beds from the other bed of the pair of beds, limited processing efficiency caused by the limited area of the outlet in each of the pair of beds is overcome.

    Claims

    1. A radial flow reactor comprising: a first bed and a second bed, each comprising a cylindrical body, an annular reaction region provided along a central axis within the body, a first flow path provided between an inner surface of the body and the reaction region, and a second flow path provided between the central axis of the body and the reaction region, wherein an inlet of the reactor is connected to the first flow path of the first bed, the first flow path of the first bed is not connected to the first flow path of the second bed, the second flow path of the first bed and the second flow path of the second bed are connected to each other, and an outlet of the reactor is connected to the first flow path of the second bed, wherein, when a raw material is introduced into the inlet of the reactor, the raw material sequentially passes through the first flow path of the first bed, the reaction region of the first bed, the second flow path of the first bed, the second flow path of the second bed, the reaction region of the second bed, and the first flow path of the second bed, thereby forming a product, and the product is discharged through the outlet of the reactor, and wherein a ratio of an area of the outlet with respect to an area of the n inlet in the entire reactor including the first bed and the second bed is adjusted by configuring the first flow path of the first bed and the first flow path of the second bed to correspond to each other equally.

    2. The radial flow reactor of claim 1, wherein the ratio of the area of the outlet with respect to the area of the inlet in the entire reactor including the first bed and the second bed ranges from 0.7 to 1.7.

    3. The radial flow reactor of claim 1, wherein the raw material is air, and the product is oxygen, and the entire reactor including the first bed and the second bed is used as a portion of a pressure swing adsorption oxygen generator or a vacuum pressure swing adsorption oxygen generator.

    4. The radial flow reactor of claim 1, wherein an area gradient of an internal flow in the entire reactor including the first bed and the second bed has a shape of custom character when the inlet is on a top edge and the outlet is on a bottom edge.

    5. A radial flow reactor comprising: a pair of beds configured to produce a product by processing a raw material supplied thereto, wherein: a substance being produced or the product is movable between the pair of beds before the product is moved to a separate reservoir, a ratio of an area of an outlet with respect to an area of an inlet in each of the pair of beds is adjusted in order to overcome limited processing efficiency caused by the limited area of the outlet in each of the pair of beds, when the substance being produced or the product is introduced into the outlet of one bed of the pair of beds from the other bed of the pair of beds; wherein each bed of the pair of beds, comprises a first bed and a second bed, wherein each of the first bed and the second bed comprises a cylindrical body, an annular reaction region provided along a central axis within the body, a first flow path provided between an inner surface of the body and the reaction region, and a second flow path provided between the central axis of the body and the reaction region, and wherein, in each bed of the pair of beds, the inlet of the bed is connected to the first flow path of the first bed, the first flow path of the first bed is not connected to the first flow path of the second bed, the second flow path of the first bed and the second flow path of the second bed are connected each other, and the outlet of the bed is connected to the first flow path of the second bed, and when a raw material is introduced into the inlet of the bed, the raw material sequentially passes through the first flow path of the first bed, the reaction region of the first bed, the second flow path of the first bed, the second flow path of the second bed, the reaction region of the second bed, and the first flow path of the second bed, thereby forming the substance being produced or the product, and the substance being produced or the product is discharged through the outlet of the bed.

    6. The radial flow reactor of claim 5, wherein, when the raw material is supplied first to one bed of the pair of beds, the product is discharged through the other bed of the pair of beds, and continuously, when the raw material is supplied to the other bed, from which the product has been discharged, the product is discharged through the one bed to which the raw material has been supplied.

    7. The radial flow reactor of claim 6, wherein, when the inlet of the bed of the pair of beds, to which the raw material is supplied, is on a bottom edge and the outlet of the bed is on a top edge, an inner area gradient of the bed of the pair of beds, to which the raw material is supplied, has a shape of custom character after the raw material is introduced and before the substance being produced or the product moves to the bed of the pair of beds, from which the product is discharged.

    8. The radial flow reactor of claim 7, wherein the first bed and the second bed are connected in series, thereby forming an inner area gradient having a shape of custom character when the inlet of the bed of the pair of beds, to which the raw material is supplied, is on the bottom edge and the outlet of the bed is on the top edge.

    9. The radial flow reactor of claim 5, wherein, in each of the pair of beds, the ratio of the area of the outlet with respect to the area of the inlet in the entire bed including the first bed and the second bed ranges from 0.7 to 1.7.

    10. The radial flow reactor of claim 5, wherein the first bed and the second bed have different shapes and sizes and are made of different materials.

    11. The radial flow reactor of claim 5, wherein the raw material is air, and the product is oxygen, and the pair of beds is used as a portion of a pressure swing adsorption oxygen generator or a vacuum pressure swing adsorption oxygen generator.

    Description

    BRIEF DESCRIPTION OF THE DRAWINGS

    (1) The above and other features of the present disclosure will now be described in detail with reference to certain exemplary examples thereof illustrated in the accompanying drawings which are given herein below by way of illustration only, and thus are not limitative of the present disclosure, and wherein:

    (2) FIG. 1 is a schematic view illustrating a general process of producing a product using a conventional radial flow reactor;

    (3) FIG. 2 is a longitudinal cross-sectional view of the conventional radial flow reactor;

    (4) FIG. 3 illustrates a modeling result from which the difference of the area between the inlet and the outlet of the conventional radial flow reactor may be reviewed;

    (5) FIG. 4 is a longitudinal cross-sectional view illustrating a bed included in the first embodiment of the radial flow reactor according to the present disclosure;

    (6) FIG. 5 is a longitudinal cross-sectional view illustrating beds included in the second embodiment of the radial flow reactor according to the present disclosure;

    (7) FIG. 6 is a longitudinal cross-sectional view illustrating a modified example of the beds included in the second embodiment of the radial flow reactor according to the present disclosure;

    (8) FIG. 7 is a longitudinal cross-sectional view illustrating another modified example of the beds included in the second embodiment of the radial flow reactor according to the present disclosure;

    (9) FIG. 8 illustrates a modeling result from which the difference of the area between the inlet and the outlet of the radial flow reactor according to the present disclosure may be reviewed;

    (10) FIG. 9 is a schematic view illustrating an example of a volume adjusting unit included in the radial flow reactor according to the present disclosure;

    (11) FIG. 10 is a schematic view illustrating another example of the volume adjusting unit included in the radial flow reactor according to the present disclosure.

    DETAILED DESCRIPTION

    (12) Hereinafter, various embodiments of the present disclosure will be described with reference to the accompanying drawings. However, the accompanying drawings are presented only to aid the description of various features of the present disclosure, but those skilled in the art to which the present disclosure pertains will appreciate that the scope of the present disclosure is not limited to the scope of the accompanying drawings.

    (13) In addition, in describing various embodiments of the present disclosure, the same names and reference numerals will be used for components having the same functions, but it should be understood in advance that the names and reference numerals are not completely the same as those of the related art.

    (14) In addition, terms used in various embodiments of the present disclosure are used only to describe specific embodiments and are not intended to limit the present disclosure. A singular form may include a plural form unless the context clearly dictates otherwise. It will be understood that terms “comprise”, “have”, etc., when used in various embodiments of the present disclosure, are intended to specify the presence of stated features, integers, steps, operations, components, parts, or any entities including any thereof, but do not preclude the possibility of the presence or addition of one or more other features, integers, steps, operations, components, parts, or combinations thereof.

    (15) First, a first embodiment of a radial flow reactor 100 according to the present disclosure will be described in detail with reference to FIGS. 4 and 9 to 10.

    (16) Here, FIG. 4 is a longitudinal cross-sectional view illustrating a bed included in the first embodiment of the radial flow reactor according to the present disclosure. FIG. 9 is a schematic view illustrating an example of a volume adjusting unit included in the radial flow reactor according to the present disclosure. FIG. 10 is a schematic view illustrating another example of the volume adjusting unit included in the radial flow reactor according to the present disclosure.

    (17) The first embodiment of the radial flow reactor 100 according to the present disclosure including beds having a structure as illustrated in FIG. 4 includes a first bed 110 into which a raw material is introduced and a second bed 120 in which a continuous reaction subsequent to a reaction in the first bed 110 occurs. The first embodiment of the radial flow reactor 100 according to the present disclosure having this configuration may be provided with a pair of beds including the first bed 110 and the second bed 120, as will be described later.

    (18) Here, each of the first bed 110 and the second bed 120 may include a first flow path 112 or 122 provided along the inner surface of its body in the height direction, a second flow path 114 or 124 provided along the central axis in the height direction, and a reaction region 130 provided between the first flow path 112 or 122 and the second flow path 114 or 124.

    (19) In each of the first bed 110 and the second bed 120 configured as above, as a raw material passes through the reaction region 130 while moving from the first flow path 112 or 122 to the second flow path 114 or 124 or from the second flow path 114 or 124 to the first flow path 112 or 122, a substance being produced or a product may be produced.

    (20) Here, the substance being produced or the product may be oxygen, nitrogen, or hydrogen having a high level of purity, and each of the reaction regions 130 may include a variety of substances as an active material, in addition to a catalyst, an absorbent, or the like.

    (21) That is, each of the reaction regions 130 may be configured to generate oxygen having a high level of purity using air as a raw material so as to be used to configure a pressure swing adsorption gas generating apparatus or a vacuum pressure swing adsorption gas generating apparatus, so that the radial flow reactor 100 according to the present disclosure may be used as a portion of an oxygen generating apparatus.

    (22) In the first embodiment of the radial flow reactor 100 according to the present disclosure including the first bed 110 and the second bed 120 as described above, the first bed 110 and the second bed 120 may be connected in series, thereby forming an overall inner area gradient having the shape of custom character.

    (23) Here, in the inner area gradient formed in the shape of custom character, a bottom edge refers to a side on which an inlet through which the raw material is supplied is positioned, while a top edge refers to a side on which an outlet through which the substance being produced or the product is discharged is positioned. The bottom edge and the top edge may not have symmetric shapes, and left and right sides may have curved shapes with various inclinations.

    (24) The first embodiment of the radial flow reactor 100 according to the present disclosure including a pair of beds including the first bed 110 and the second bed 120 and having the overall inner area gradient in the shape of custom character, as described above, is configured such that the substance being produced or the product is movable between the pair of beds before the product is moved to a separate reservoir. Thus, it does not have limited processing efficiency caused by the limited area of the outlet of any one of the pair of beds, as described above in the background art section.

    (25) This is because flow directions, heights, widths, etc. for the first bed 110 and the second bed 120 of each of the pair of beds may be in advance modeled and set, so that the area ratio of the outlet to the inlet of the entirety of the reactor including the first bed 110 and the second bed 120 may be adjusted.

    (26) Here, if the area of the outlet is wide enough to be capable of corresponding to the area of the inlet, the area ratio of the outlet to the inlet of the entirety of the reactor may be included in the scope of the present disclosure. Advantageously, in the entirety of the reactor, the area of the outlet may be at least 0.7 to 1.7 times the area of the inlet.

    (27) The above numerical limitation of 0.7 to 1.7 times is a limitation intended to explain as an example that the area of the outlet is wide enough to correspond to the area of the inlet. Any numerical value (e.g., a numerical value of about 1.8 times) that may be changed from the above numerical limitation by those skilled in the art will be regarded as falling within the scope of the present disclosure.

    (28) In addition, in a case in which the area of the outlet is 0.7 to 1.7 times the area of the inlet in the entirety of the reactor, it may be assumed that the active material of the reaction regions 130 is deformed into the shape of a cylinder or a prism having a height of 3.5 ft (about 1.07 m). In this case, it is possible to adjust the area of either the inlet or the outlet to be at least 0.9 time the area of the base of the cylinder or the prism. This may be more advantageous in terms of the processing efficiency.

    (29) Since the area of the outlet may be adjusted to be 0.7 to 1.7 times the area of the inlet as described above, it is possible to overcome the limitation in which the processing efficiency is lowered due to the limited outlet area when the substance being produced or the product is introduced through the outlet of one of the pair of beds including the first bed 110 and the second bed 120 from the other of the pair of beds including the first bed 110 and the second bed 120.

    (30) The limitation of the conventional radial flow reactor 10 can be overcome in this manner, since the area ratio of the outlet with respect to the inlet of the entire reactor including the first bed 110 and the second bed 120 can be adjusted as described above. The area ratio of the outlet with respect to the inlet can be adjusted, since each of the pair of beds is comprised of a plurality of beds, such as the first bed 110 and the second bed 120, and the flow directions, the heights, the widths, etc. for the first bed 110 and the second bed 120 can be set.

    (31) In particular, setting the flow directions in the first bed 110 and the second bed 120 may be an important factor in adjusting the area ratio of the outlet with respect to the inlet of the entire reactor, which will be described hereinafter in detail with reference to FIG. 4.

    (32) As illustrated in FIG. 4, there is little difference between a diameter D4 by which the area of the inlet portion of the first bed 110 corresponding to the inlet of the first embodiment of the radial flow reactor 100 according to the present disclosure is determined and a diameter D5 by which the area of the outlet portion of the second bed 120 corresponding to the outlet of the first embodiment of the radial flow reactor 100 according to the present disclosure is determined.

    (33) In addition, the raw material is supplied to the first flow path 112 of the first bed 110 and passes through the reaction region 130 of the first bed 110, and the substance being produced or the product is discharged through the second flow path 114 of the first bed 110. Then, the substance being produced or the product may be introduced into the second flow path 124 of the second bed 120. Thus, when h2 and h3 are adjusted, the ratio of the area of the outlet with respect to the inlet in the first embodiment of the radial flow reactor 100 according to the present disclosure may be adjusted.

    (34) In this configuration, after the raw material is introduced and before the substance being produced or the product is produced and discharged, the overall area gradient inside one bed of the first embodiment of the radial flow reactor 100 according to the present disclosure has the shape of custom character.

    (35) That is, in FIG. 4, the area gradient inside the first bed 110 in which a flow F2 is formed from a flow F1 passing through the reaction region 130 of the first bed 110 has a trapezoidal shape, whereas the area gradient inside the second bed 120 in which a flow F4 is formed from a flow F3 passing through the reaction region 130 of the second bed 120, in which a reaction continuously occurs subsequent to the first bed 110, has an inverted trapezoidal shape. Thus, the overall area gradient inside one bed of the first embodiment of the radial flow reactor 100 according to the present disclosure has the shape of custom character, by which the limitation of the conventional radial flow reactor 10, as described in the background art section, can be overcome.

    (36) Meanwhile, the first bed 110 and the second bed 120 of each of the pair of beds included in the first embodiment of the radial flow reactor 100 according to the present disclosure may further include a volume adjusting unit 140 on top of the respective reaction region 130.

    (37) Here, the volume adjusting unit 140 may have various structures and shapes that can cope with changes in the volume of the reaction region 130 caused by fixation of an active material etc. through repetitive generation of the substance being produced or the product. Although there is any reason for changes in the volume of the reaction region 130, which has not been discovered or known yet, the scope of protection is not limited thereby.

    (38) A more detailed description will be provided as follows with reference to FIGS. 9 to 10.

    (39) First, as illustrated in FIG. 9, the volume adjusting unit 140 may include a bag 142 in which a fluid capable of swelling in response to a change in the volume of the reaction region 130 is contained.

    (40) Here, the bag 142 may be made of a variety of flexible materials allowing the fluid to swell in response to a change in the volume of the reaction region 130. The bag 142 may have a curved shape as illustrated in FIG. 9 but is not necessarily limited thereto.

    (41) In addition, when the bag 142 has the curved shape, the bag 142 may not be properly disposed on top of the reaction region 130. Thus, a separate boundary layer 144 may be provided between the reaction region 130 and the bag 142. The material, shape, or the like of the boundary layer 144 may vary.

    (42) Meanwhile, as illustrated in FIG. 10, the volume adjusting unit 140 may include a flexible gasket 146 configured to be moved upward or downward in response to a change in the volume of the reaction region 130 and weights 148 configured to move the gasket 146 downward and maintain the gasket 146 in equilibrium.

    (43) Here, the equilibrium may include a state in which there is no space between the gasket 146 and the reaction region 130. The equilibrium comprehensively refers to a state in which there is no factor interfering with a reaction even in the case that the reaction continuously occurs.

    (44) In addition, the gasket 146 may be made of a variety of flexible materials capable of moving upward and downward in response to a change in the volume of the reaction region 130. The shape of the gasket 146 is not limited as long as the gasket 146 can accommodate the weights 148 as illustrated in FIG. 10.

    (45) In addition, the shape of the weights 148 is not limited to small spheres as illustrated in FIG. 10, but the weights 148 may have a variety of shapes, if the weights 148 can move the gasket 146 downward and maintain the gasket 146 in equilibrium, e.g., a state in which there is no space between the gasket 146 and the reaction region 130.

    (46) Next, a second embodiment of the radial flow reactor 100 according to the present disclosure will be described in detail with reference to FIGS. 5 to 7.

    (47) Here, FIG. 5 is a longitudinal cross-sectional view illustrating beds included in the second embodiment of the radial flow reactor according to the present disclosure. FIG. 6 is a longitudinal cross-sectional view illustrating a modified example of the beds included in the second embodiment of the radial flow reactor according to the present disclosure. FIG. 7 is a longitudinal cross-sectional view illustrating another modified example of the beds included in the second embodiment of the radial flow reactor according to the present disclosure.

    (48) As illustrated in FIGS. 5 to 7, the second embodiment of the radial flow reactor 100 according to the present disclosure may be configured such that the first bed 110 and the second bed 120 providing the pair of beds included in the radial flow reactor 100 according to the present disclosure are provided as respective bodies connected through a connecting pipe 150, differently from the first embodiment in which the first bed 110 and the second bed 120 are provided in a single body.

    (49) However, although the first bed 110 and the second bed 120 are connected through the connecting pipe 150, the entirety of the first bed 110 and the second bed 120 providing the pair of beds included in the second embodiment of the radial flow reactor 100 according to the present disclosure should be configured such that the area gradient has the shape of custom character.

    (50) In an example, one of the pair of beds included in the second embodiment of the radial flow reactor 100 according to the present disclosure may be configured such that, when a raw material is supplied through the first flow path 112 of the first bed 110 and passes through the reaction region 130 of the first bed 110 and a substance being produced or a product is discharged through the second flow path 114 of the first bed 110, the substance being produced or the product may be introduced through the second flow path 124 of the second bed 120, as illustrated in FIG. 5.

    (51) In the above-described example illustrated in FIG. 5, as illustrated in FIG. 6, the direction of a flow F2 in the second flow path 114 of the first bed 110 and the direction of a flow F3 in the second flow path 124 of the second bed 120 may be inverted by changing the position of the connecting pipe 150. Even in this change, there is no change in the configuration in which, when the substance being produced or the product is discharged through the second flow path 114 of the first bed 110, the substance being produced or the product may be introduced into the second flow path 124 of the second bed 120, and the area gradient of the entirety of the first bed 110 and the second bed 120 may have the shape of custom character.

    (52) Meanwhile as long as the second embodiment of the radial flow reactor 100 according to the present disclosure is configured such that the first bed 110 and the second bed 120 are connected through the connecting, pipe 150, there may be a configuration, as illustrated in FIG. 7, in which, when the raw material is supplied into the second flow path 114 of the first bed 110 and passes through the reaction region 130 of the first bed 110 and the substance being produced or the product is discharged through the first flow path 112 of the first bed 110, the substance being produced or the product may be introduced into the first flow path 122 of the second bed 120.

    (53) In this configuration in which a portion through which the raw material flows and a portion through which the substance being produced or the product flows are in opposite sides, the area gradient of the entirety of the first bed 110 and the second bed 120 has the shape of custom character. Even in this case, when the substance being produced or the product is introduced into the outlet of one of the pair of beds from the other of the pair of beds, the limited processing efficiency caused by the limited area of the outlet of one of the pair of beds can equally be overcome by adjusting the area ratio of the outlet with respect to the inlet. Therefore, it should be understood that the second embodiment of the radial flow reactor 100 according to the present disclosure is within the scope of the present disclosure.

    (54) Meanwhile, also in the second embodiment of the radial flow reactor 100 according to the present disclosure, the volume adjusting unit 140 may also be included. This feature is substantially the same as in the first embodiment and thus a description thereof will be omitted.

    (55) In the first embodiment and the second embodiment of the radial flow reactor 100 according to the present disclosure as described above, a substance being produced or a product is movably produced between the pair of beds before the product is moved to a separate reservoir. To overcome the limited processing efficiency caused by the limited area of the outlet of one of the pair of beds when the substance being produced or the product is introduced into the outlet of one of the pair of beds from the other of the pair of beds, the area ratio of the outlet with respect to the inlet in the entirety may be adjusted irrespective of whether the first bed 110 and the second bed 120 of the pair of beds are directly connected to each other as a single body or are connected to each other through the connecting pipe 150.

    (56) As described above, if the first bed 110 and the second bed 120 are configured such that the area ratio of the outlet with respect to the inlet is adjustable so that the area gradient has the shape of custom character (or custom character in some cases), although the beds are not directly connected as a single body as in the above-described first embodiment or are not connected using the connecting pipe 150 as in the above-described second embodiment, all of such configurations are within the scope of the present disclosure. Even in the case that the first bed 110 and the second bed 120 are variously formed in different shapes, sizes, or materials, all of such configurations are within the scope of the present disclosure.

    (57) The radial flow reactor 100 having this scope of right, according to the present disclosure, has a modeling result illustrated in FIG. 8 as an example, differently from the modeling result illustrated in FIG. 3 as an example in the background art section.

    (58) That is, referring to the modeling result of the conventional radial flow reactor 10 illustrated in FIG. 3, compared to the areas of the inlet and the outlet of the axial flow reactor including an active material formed in a height of 3.5 ft (about 1.07 m), the conventional radial flow reactor 10 including an active material having the same quantity and of the same type has an inlet area ratio of 145% and an outlet area ratio of 93%. The area of the outlet is merely 63% (=93/145×100%) of the area of the inlet.

    (59) That is, in the conventional radial flow reactor 10, the area of the outlet depends on the area of the inlet and thus is quite small. Thus, when a substance being produced or a product is introduced into the outlet of one of the pair of beds from the other of the pair of beds, processing efficiency should be limited due to the limited area of the outlet of each of the pair of beds.

    (60) However, referring to the modeling result of the radial flow reactor 100 according to the present disclosure illustrated in FIG. 8, compared to the areas of the inlet and the outlet of the axial flow reactor including an active material formed in a height of 3.5 ft (about 1.07 m), the radial flow reactor 100 according to the present disclosure including an active material having the same quantity and of the same type has an inlet area ratio of 126% and also has an outlet area ratio of 126%, such that the area of the outlet may be adjusted to be 100% (=126/126×100%) of the area of the inlet. Accordingly, it is possible to overcome the limited processing efficiency caused by the limited area of the outlet.

    (61) Although the foregoing embodiments of the present disclosure have been described hereinabove, it will be apparent to those skilled in the art to which the present disclosure pertains that the present disclosure can be embodied in specific forms other than the foregoing embodiments without departing from the gist or scope of the present disclosure.

    (62) Accordingly, the foregoing embodiments shall be interpreted as being illustrative while not being limitative, and thus, the present disclosure is not limited to the above description and may be changed within the scope of the appended claims and their equivalents.