Generation device and detection device of monopole current, and memory element using a monopole current
10714677 ยท 2020-07-14
Assignee
Inventors
Cpc classification
G01R15/20
PHYSICS
G11C11/161
PHYSICS
International classification
G01R19/00
PHYSICS
Abstract
In order to provide a memory element configured to generate and detect monopole current, in an embodiment provided in the present disclosure is a monopole current generation detection device comprising a ferromagnetic quantum spin-ice layer, a buffer layer made of a material capable of exhibiting a quantum spin-liquid state, and a pair of electrodes disposed in contact with the buffer layer. In this device it is possible to apply a voltage between the pair of electrodes by providing a voltage application means. It is possible to generate a monopole current J.sup.m upon application of the voltage, where the monopole currents through the ferromagnetic quantum spin-ice layer and through another ferromagnetic quantum spin-ice layer that is in contact with the buffer layer on the other side of the ferromagnetic quantum spin-ice layer. Also, the monopole current can be electrically detected by providing a detection circuit to the device. In embodiments of the present disclosure, further provided is a memory element in which a buffer layer is sandwiched by two ferromagnetic quantum spin-ice layers.
Claims
1. A monopole current generation device, comprising: a ferromagnetic quantum spin-ice layer; a buffer layer that is in contact with the ferromagnetic quantum spin-ice layer and is made of a material capable of exhibiting a quantum spin-liquid state; and a pair of electrodes, each of which being separated from each other in one of in-plane orientations of the buffer layer and disposed in contact with the buffer layer, wherein the buffer layer is different in material from the ferromagnetic quantum spin-ice layer.
2. The monopole current generation device of claim 1, wherein a material of the ferromagnetic quantum spin-ice layer is Yb.sub.2Ti.sub.2O.sub.7, and wherein the material of the buffer layer is Pr.sub.2Zr.sub.2O.sub.7, Pr.sub.2Sn.sub.2O.sub.7, or Pr.sub.2Hf.sub.2O.sub.7.
3. The monopole current generation device of claim 1, wherein the monopole current generation device is capable of generating a monopole current that has non-zero curl around the direction upon application of a voltage between the pair of electrodes, the monopole current flowing through the ferromagnetic quantum spin-ice layer and through another ferromagnetic quantum spin-ice layer that is in contact with the buffer layer on the other side of the ferromagnetic quantum spin-ice layer side.
4. A monopole current detection device, comprising: a ferromagnetic quantum spin-ice layer; a buffer layer that is in contact with the ferromagnetic quantum spin-ice layer and is made of a material capable of exhibiting a quantum spin-liquid state; and a pair of electrodes, each of which being separated from each other in one of in-plane orientations of the buffer layer and disposed in contact with the buffer layer.
5. The monopole current detection device of claim 4, wherein a material of the ferromagnetic quantum spin-ice layer is Yb.sub.2Ti.sub.2O.sub.7, and wherein the material of the buffer layer is Pr.sub.2Zr.sub.2O.sub.7, Pr.sub.2Sn.sub.2O.sub.7, or Pr.sub.2Hf.sub.2O.sub.7.
6. A memory element, comprising, in the following order: a first ferromagnetic quantum spin-ice layer; a buffer layer made of a material capable of exhibiting a quantum spin-liquid state; and a second ferromagnetic quantum spin-ice layer, wherein the memory element further comprising a pair of electrodes disposed in contact with the buffer layer, and wherein the buffer layer is different in material from the first ferromagnetic quantum spin-ice layer and from the second ferromagnetic quantum spin-ice layer.
7. The memory element of claim 6, wherein the memory element is configured to read at least one of either the direction or an intensity of magnetization in at least one of the first ferromagnetic quantum spin-ice layer and the second ferromagnetic quantum spin-ice layer.
8. The memory element of claim 6, wherein a material of at least one of the first ferromagnetic quantum spin-ice layer and the second ferromagnetic quantum spin-ice layer is Yb.sub.2Ti.sub.2O.sub.7, and wherein the material of the buffer layer is Pr.sub.2Zr.sub.2O.sub.7, Pr.sub.2Sn.sub.2O.sub.7, or Pr.sub.2Hf.sub.2O.sub.7.
9. The memory element according to claim 6, wherein the memory element holds at least temporarily at least one of direction and an intensity of magnetization in at least one of the first ferromagnetic quantum spin-ice layer and the second ferromagnetic quantum spin-ice layer.
10. The memory element of claim 9, wherein both of the magnetization in the first ferromagnetic quantum spin-ice layer and the magnetization in the second ferromagnetic quantum spin-ice layer are able to be flipped and these magnetizations are oriented antiparallel to each other, and wherein the pair of electrodes is configured to apply a voltage to the buffer layer, the voltage inducing an electric polarization in the buffer layer for reversing both of the magnetization in the first ferromagnetic quantum spin-ice layer and the magnetization in the second ferromagnetic quantum spin-ice layer.
Description
BRIEF DESCRIPTION OF THE SEVERAL VIEWS OF THE DRAWINGS
(1)
(2)
(3)
(4)
DETAILED DESCRIPTION
(5) Hereinafter, embodiments related to a generation device and a detection device of a monopole current device and a memory element according to the present disclosure will be described with reference to the drawings. In the description, common parts or elements throughout the drawings are denoted by the same reference numerals, unless otherwise noted. In addition, each element in the drawings should be understood as not being drawn to scale.
1. Generation Device and Detection Device of a Monopole Current
(6)
(7) In the case the monopole current generation detection device 100 is operated as a monopole current detection device, the detection circuit 160 is electrically connected to the pair of electrodes 142 and 144. The detection circuit 160 includes a capacitor 162 having an extremely large capacitance, a resistor 164, and a voltmeter 166. The amount of transferred electric charges is obtained as the amount of electric charges accumulated in the capacitor 162, or from the product of the voltage difference and the electrostatic capacity.
(8) In the case the monopole current generation detection device 100 is operated for a monopole generation device, a voltage application means 150 serving as a drive circuit is connected to the pair of electrodes 142 and 144. The voltage application means 150 acts as a driving circuitry for producing a potential difference to the buffer layer 120.
(9) The monopole current generation detection device 100 does not include a layer corresponding to a second FM layer 230 in memory elements 200A and 200B, which will be described later with reference to
(10) The generation principle of monopole current using the monopole current generation detection device 100 is as follows. An electric polarization P having a component in one of in-plane orientations (the y direction in the figure) is generated inside the buffer layer 120 upon voltage application by the voltage application means 150. The voltage application means 150 is generally configured to adjust the voltage and its polarity; it is equipped with, for example, a variable voltage source 152 and switches 154A and 154B for inverting the voltage output from it. The magnitude and polarity of the electric polarization P to be generated inside the buffer layer 120 is adjustable. In response to the electric polarization P generated in the buffer layer 120 via the pair of electrodes 142 and 144, monopole currents are generated in the interior of the FM layer 110 and the layer under test 30, the monopole currents being antiparallel to each other having a curl component along the electric polarization P in accordance with the virtual quantum electromagnetism. That is, when the electric polarization P is generated in the buffer layer 120, the typical monopole current J.sup.m is generated as shown in
(11) On the other hand, the detection principle using the monopole current generation detection device 100 is as follows. In the buffer layer 120, an electric polarization P is induced in response to monopole currents generated inside of the FM layer 110 and the layer under test 30 and flowing in antiparallel to each other. The electric current generated by the induced electric polarization is accumulated in the capacitor 162. By measuring the voltage difference across the capacitor 162 by the voltmeter 166, the electric polarization generated in the buffer layer 120 is determined from the electrostatic capacity and variation of the voltage difference. If the relationship between the measured value of the electric polarization and the measured value of the monopole current, described later in connection with the leakage magnetic field measurement, is prepared specifically for the monopole current generation detection device 100 in advance, it is possible to determine direction and intensity of the monopole currents generated in the layer under test 30 from the measured value of the electric polarization.
(12) Materials of layers of the monopole current generation detection device 100 include, typically, a crystal of Yb.sub.2Ti.sub.2O.sub.7 for the FM layer 110 with the thickness in the z direction is about 1 nm, which is formed to have the thickness of about or above 1 nm typically, or around its unit cell size. The buffer layer 120 is typically Pr.sub.2M.sub.2O.sub.7, where M denotes Zn, Sn, Hf, etc. Other materials for the memory elements 200A and 200B, described later, can also be adopted for the corresponding layers of the monopole current generation detection device 100.
2. Memory Element
(13)
2-1. Structure
(14) The memory elements 200A and 200B have a first ferromagnetic quantum spin-ice layer (first FM layer) 210, a buffer layer 220 of a material which can exhibit a quantum spin-liquid phase, and a second ferromagnetic quantum spin-ice layer (second FM layer) 230 in the structure. In the case of the memory element 200A shown in
2-2. Principles of Rewrite and Store Operations
(15) When a monopole current is adopted, the distributions of monopole magnetic charges in the first and second FM layers 210 and 230, i.e., the magnetizations M in these layers, can be reversed (flipped) while their relative relationships are kept unchanged, or while maintaining their antiparallel configuration between the first and second FM layers 210 and 230. Here, the orientation (polarity) of the monopole current J.sup.m in the first and second FM layers 210 and 230 and resulting direction (polarity) of the ferromagnetic magnetization M are determined by a direction (polarity) of the applied electric polarization. The polarity of the voltage required for inverting the magnetization is determined in accordance with the direction of the magnetization. The time integration value of the monopole current is directly reflected in the modulation of magnetization accompanying the reversal operation. Thus, the magnetization flip operation for the first and second FM layers 210 and 230 corresponds to a bit inversion operation of memory contents, or rewrite operation, for the memory element 200A and 200B.
(16) The magnetization M in the first and second FM layers 210 and 230 after the modulation by the monopole current J.sup.m is maintained according to their ferromagnetic property. The magnetization M will be maintained so long as any specific rewrite operation is not performed; thus the magnetizations in the first and second FM layers 210 and 230 serve as a storage mechanism of the memory elements 200A and 200B.
2-3. Performances of Rewrite and Store Operations
(17) The flip operation by way of the monopole current described above can be operated at high speed. Based on theoretical predictions, the time scale for this magnetization flip is determined by the interaction constant of the quantum spin-ice material. To be more specific in terms of a frequency, for a typical existing material that would serve as a candidate for the first and second FM layers 210 and 230 such as Yb.sub.2Ti.sub.2O.sub.7, it is possible to operate at a high speed of about 10 GHz. Therefore, the restriction that may be attributed to its principle will not raise a problem in respect of the speed of the rewrite operation.
(18) Also, the power consumption required for flipping magnetization is extremely small. The amount of power consumption is such that electric polarization can be produced in the buffer layer 220 serving as a quantum spin-liquid. Since the buffer layer 220 is a dielectric substance having a high insulation property, the flipping causes a charging of the capacitor formed by the pair of electrodes 242 and 244, which requires power consumption corresponding to electric power due to the transient current.
2-4. Read Operation of Memory States
(19) The memory states of the memory elements 200A and 200B can be read by any technique that can read, for example, a direction of magnetization in the second FM layer 230 or the direction of the leakage magnetic field formed by the first and second FM layers 210 and 230.
(20) One preferable example of such operations in the memory element 200A is to utilize a magneto-optical Kerr effect, which is a conventional magneto-optical effect. In the magneto-optical Kerr effect, a surface 204, which is an end of the second FM layer 230, is irradiated with polarized light to detect polarity of polarization rotation in the reflected light. A beam arrangement for reading is shown by a dashed line in
(21) One preferable example of the read operations of memory states in the memory element 200B, in addition to the magneto-optical Kerr effect, is one that measures a leakage magnetic field in the vicinity of a surface 206. Based on polarity and magnitude detected by a magnetic detector element 250, such as a magnetic head and a scanning SQUID element that are mechanically scanned as necessary (see NPL5) or the like, it is possible to read the direction and the intensity of magnetization in the second FM layer 230. As described herein, any technique may be employed for reading operation, or bit reading, of memory content.
2-5. Example Materials and Structures
(22) The substrates 202A and 202B are typically a crystal of Yb.sub.2Ti.sub.2O.sub.7 or Eu.sub.2Ti.sub.2O.sub.7 having a pyrochlore structure. The first and second FM layers 210 and 230 are a crystal of Yb.sub.2Ti.sub.2O.sub.7 having a pyrochlore structure, typically. The thickness of the first and second FM layers 210 and 230 in the z direction in the drawings is typically about 1 nm, and about 1 nm or more of the thickness of the unit cell, typically. The buffer layer 220 is a crystal of Pr.sub.2Zr.sub.2O.sub.7, Pr.sub.2Sn.sub.2O.sub.7, or Pr.sub.2Hf.sub.2O.sub.7 having a pyrochlore structure, typically. In addition, Tb.sub.2Ti.sub.2O.sub.7 may also be used for the buffer layer 220 with fine adjustment of its composition. The thickness in the z direction of the buffer layer 220 is suitably selected from a range of several nm or more, typically. As will be apparent to those skilled in the art, these thin films can be formed by an arbitrary method of forming a crystalline thin film. For example, a PLD (pulsed laser deposition) method is one of promising techniques.
(23) When reading the magnetization in the second FM layer 230 by the magneto-optical Kerr effect, the reading wavelength is selected in accordance with the purpose. In the case the memory element 200A is arranged in an array and integrated, the lower limit of its size may depend on the reading wavelength. Typically, if an Al(In, Ga)N solid ultraviolet laser (wavelength: 250 nm) is assumed for one of realistic examples, it would be possible to design the area of the memory element 200A to 0.06 m.sup.2 or so.
(24) On the other hand, when reading a change in the magnetic field generated around there by a conventional magnetic head, it is effective to bring the magnetic head closer to the surface 206 on the side of the memory element. In that case, since the lower limit required for detection for a scale of length regarding the surface 206 is 10-20 nm or so, it is possible for the memory element 200B to adapt itself to a large scale integration by arranging ones on, for example, y-z plane in
(25) At the time of the present application, in order to realize a quantum spin-liquid state reliably for the buffer layer 220, it is necessary to cool the pyrochlore substance down to 0.2 K or less, typically. However, it is promising to employ a thin film substance Ir.sub.2O.sub.4, as another candidate material, where Li is de-intercalated from the iridium spinel Li Ir.sub.2O.sub.4. This is because the temperature scale can be increased up to room temperature for the thin film material Ir.sub.2O.sub.4 (NPL3). Therefore, the operation in the present embodiment can be expected to be applied at a higher temperature. By substituting Ir with another element (for example, Rh) for adjusting the lattice constant, Ir.sub.2O.sub.4 can be adopted not only for the ferromagnetic quantum spin-ice layer, but for the buffer layer, as it can be a quantum spin-liquid.
3. Confirmation of Operational Principle
(26) Next, in order to check the above-described principle the inventors confirmed as to how the monopole current is generated based on the theoretical calculation. The generation of the monopole current is shown through numerical simulations that are supported by theory. In the first place of the procedure, a Hamiltonian is formulated in which pseudo spins, each having a spin quantum number of , exert ferromagnetic interaction in a crystal lattice of a pyrochlore structure for the quantum spin-ice material. Next, an emergent U(1) gauge field generated therein is analyzed based on the mean field theory. The monopole wavefunction is determined by a self-consistent method under appropriate boundary conditions.
(27)
(28) A material of the L and R ferromagnetic quantum spin-ice sections 32 and 36 is any material capable of generating a monopole current, or a crystal of Yb.sub.2Ti.sub.2O.sub.7, typically. As for the size and material of the gap section 34, the gap is made to separate the L and R ferromagnetic quantum spin-ice sections 32 and 36 from each other by a distance that allows the monopole current to tunnel for conduction therethrough and a material serving as a quantum spin-liquid is disposed in the gap section 34 for completing the junction. Also, the operation of the present embodiment can be verified when the gap section 34 is made to be a simple gap.
(29)
4. Variation Examples
(30) The monopole current generation detection device 100 and the memory elements 200A and 200B may be reduced into practice with various modifications. For instance, as described in connection with memory elements 200A and 200B, the arrangement of the substrates is freely selected in the monopole current generation detection device 100. In addition, both the voltage application means 150 and the detection circuit 160 are connected with the pair of electrodes 142 and 144 at the same time for the monopole current generation detection device 100 after necessary modifications in the field of circuit technology are made. It is also possible to arrange the memory elements 200A and 200B differently from those that are depicted in the drawings, for example, the arrangement of the pair of electrodes 242 and 244 connected with the buffer layer 220, according to the implementation necessity, such as facilitating integration.
(31) The embodiments of the present disclosure have been concretely described above. Each of the above-described embodiments, variations and specific examples has been described for the purpose of explaining the disclosure; therefore, the scope of the disclosure of the present application should be determined based on the claims. Also, modifications within the scope of the present disclosure including other combinations of the respective embodiments are also included in the scope of the claims.
INDUSTRIAL APPLICABILITY
(32) The present disclosure utilizes a monopole current of the present disclosure and can be used for any device that utilizes a device or a storage device.
REFERENCE SIGNS LIST
(33) 100 monopole current generation device and detection device (monopole current generation detection device)
(34) 110 ferromagnetic quantum spin-ice layer (FM layer)
(35) 120, 220 buffer layer
(36) 142, 144, 242, 244 pair of electrodes
(37) 150 voltage application means
(38) 152 variable voltage source
(39) 154A, 154B switch
(40) 160 detection circuit
(41) 162 capacitor
(42) 164 resistor
(43) 166 voltmeter
(44) 200A, 200B memory element
(45) 202A, 202B substrate
(46) 204, 206 surface
(47) 210 first ferromagnetic quantum spin-ice layer (first FM layer)
(48) 230 second ferromagnetic quantum spin-ice layer (second FM layer)
(49) 250 magnetic detector element
(50) 30 layer under test
(51) 32, 36 L and R ferromagnetic quantum spin-ice sections
(52) 34 gap section
(53) The various embodiments described above can be combined to provide further embodiments. All of the U.S. patents, U.S. patent application publications, U.S. patent applications, foreign patents, foreign patent applications and non-patent publications referred to in this specification and/or listed in the Application Data Sheet are incorporated herein by reference, in their entirety. Aspects of the embodiments can be modified, if necessary to employ concepts of the various patents, applications and publications to provide yet further embodiments. These and other changes can be made to the embodiments in light of the above-detailed description. In general, in the following claims, the terms used should not be construed to limit the claims to the specific embodiments disclosed in the specification and the claims, but should be construed to include all possible embodiments along with the full scope of equivalents to which such claims are entitled. Accordingly, the claims are not limited by the disclosure.