Membrane surface hydrophobicity through electro-hydrodynamic film patterning

Abstract

A roll-to-roll system for forming a hydrophobic polymer membrane surface includes a heated carrier belt, a repository of polymer material arranged to deposit the polymer material onto the carrier to create a heated polymer, an electrode belt positioned opposite the carrier belt, an electric field generator positioned to generate an electric field between the carrier belt and the electrode belt and to infuse a pattern into the heated polymer to form a patterned polymer film, and a solvent bath to rinse the patterned polymer film. A method of creating a hydrophobic polymer membrane surface includes depositing a polymer material onto a heated carrier, using the carrier, transporting the polymer material past an electrode that acts as an electric field generator, generating an electric field adjacent the carrier, using the electric field to infuse a pattern into the polymer membrane surface, and setting the pattern into the polymer membrane surface.

Claims

1. A roll-to-roll system for forming a hydrophobic polymer membrane surface, comprising: a heated carrier belt; a repository of polymer material arranged to deposit the polymer material onto the carrier to create a heated polymer, wherein the polymer material contains polyelectrolytes; an electrode belt positioned opposite the carrier belt; an electric field generator positioned to generate an electric field between the carrier belt and the electrode belt and to infuse a pattern into the heated polymer to form a patterned polymer film; a first solvent bath to rinse the patterned polymer film; and a second solvent bath to set the pattern in the patterned polymer film.

2. The system of claim 1, wherein the electrode belt is heated.

3. The system of claim 1, wherein the polymer material comprises one of a liquid or a slurry.

4. The system of claim 1, wherein the pattern is one of micro-scale or nano-scale.

5. The system of claim 1, wherein the electrode belt has a pattern on its surface.

6. The system of claim 1, wherein the pattern comprises a periodic pattern of one of pillars or posts.

7. The system of claim 6, wherein the pillars or posts have one of a rectangular, circular, or square cross-section.

8. The system of claim 1, wherein the second solvent bath to set the pattern in the film is selected to gelatinize the polymer to set the pattern.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) FIGS. 1-4 shows examples of patterned polymer films.

(2) FIG. 5 shows an electric field generator for electrohydrodynamic film patterning.

(3) FIG. 6 shows an embodiment of an electrohydrodynamic film patterning system.

(4) FIG. 7 shows a flowchart of an embodiment of a method to electrohydrodynamically pattern a polymer film.

DETAILED DESCRIPTION OF THE EMBODIMENTS

(5) Specifically, the embodiments here propose a technology to form hydrophobic membranes from hydrophilic polymers with charged surfaces in an efficient roll-to-roll process. The polymers that are of interest are termed polyelectrolytes and they include: carboxymethyl cellulose, polystyrene sulfonates, polyacrylic acid, polyaniline, polyallylamine hydrochloride, poly(2-acrylamido-2-methyl-1-propanesulfonic acid), polyaspartic acid, alginates, pectin, carrageen. Hydrophobic membranes can be formed from these polymers directly or from typical membrane polymers containing amounts of these polyelectrolytes as additives.

(6) FIG. 1 shows an example of a patterned polymer film 10. Hydrophobic films have a high contact angle, meaning that drops of solution do not wet the surface. Increasing the surface roughness of the film by patterning, increases the contact angle and therefore the hydrophobicity. The equation used to calculate the theoretical marginal values of the dimension H, b and a, where H is the height of the pillars and/or posts in the pattern, referred to here collectively as posts, b is the gap between the posts, and a is the width of the posts. In the expanded view 12, b is the gap between the posts 14 and 16, and a is the width of post 16. The equation is:

(7) $\frac{b}{a}=\sqrt{-\frac{4\cos {}_i}{\left(\cos {}_i\right)\left(\frac{}{H}\right)}}-1.$

(8) The pattern infused into the polymer film may have nanopatterned roughness, meaning that the roughness patterned into the film is on a nanometer scale, superimposed over a micropatterned roughness. However, even if the patterned roughness is only on the micropatterned scale, the hydrophobicity increases. FIG. 2 shows an embodiment of a post 16. FIG. 3 shows an embodiment of an array of posts such as 17, and FIG. 4 shows a pattern of stripes such as 18.

(9) Current patterning methods include focused ion beam milling for silicon wafers, laser etching metals, XeF.sub.2 gas phase etching and wafer dicing for silicon wafers. Another method of generating patterns is to use electrohydrodynamic (EHD) film patterning (EHD-FP). In one use of EHD-FP, in U.S. Pat. No. 9,348,231, an electric field is used to align liquid forms inside the polymer films such as nanotubes and nanowires and then cure the film.

(10) The alignment results from the application of an electric field from an electric field generator 20, such as that shown in FIG. 5. In FIG. 5, a current source such as 26 generates a field that is applied to a set of electrodes, a positive electrode 22 and a negative electrode 24. When the current is applied, an electric field is generated in the region 28 between the two electrodes.

(11) As used here, rather than to cause liquid forms in the polymer material as in the patent mentioned above, the field is used to form the pattern in the film itself, creating pattern roughness. Control of the field controls the resulting pattern, in one embodiment. In another embodiment, the carrier belt, discussed in more detail in FIG. 3, has a pattern that is infused into the polymer upon the application of the field.

(12) The embodiments here use roll-to-roll processing, which makes them faster, cheaper, and scalable compared to sheet at a time processing or microfabrication. FIG. 6 shows an embodiment of a system 30 to perform EHD-FP, and FIG. 7 shows an embodiment of a method to use the system. A repository 40 deposits a polymer material 42 onto a carrier belt 47 at 60. The polymer material 42 may consist of a polymer mixed with a solvent to allow the material to be easily dispensed. The polymer material may consist of a slurry or a liquid. For processing that is not roll-to-roll, the carrier may consist of something besides a belt, such as a chip carrier or other transport means. The term carrier as used here includes any carrier that can receive the polymer material and transport it.

(13) The carrier 47 is heated by a heater 46. The carrier transports the polymer material at 62 through an electric field generated by the electric field generator 32 at 64 that is arranged adjacent the electrode belt 37. For non-roll-to-roll processing, the electrode field generator may not require the electrode belt. The field generator 32 generates an electric field through which the polymer material travels and forms a pattern 44 at 66.

(14) As mentioned previously, the pattern may be formed on a microscale or a nanoscale with a repeating pattern. The repeating pattern may have pillars and/or posts may have a circular, rectangular or square cross-section. It has been shown that repeated patterns of roughness increase the hydrophobicity.

(15) Once formed in the polymer, the pattern can be set in many different ways. In one embodiment, the now-patterned polymer film may be heated to a higher temperature than originally heated. This may be accomplished by the heater 46, or by the second roller 49. The second temperature is high enough to evaporate any of the solvent in the polymer material. The pattern may be set with the use of a chilling roller 48 or other cooling mechanisms.

(16) Alternative to evaporating the solvent in the polymer material, the patterned polymer film may be rinsed by submersion in a solvent bath 50, along transport rollers 52 and 54. The patterned film may undergo a second solvent bath 56 along rollers 55 and 57 to gelatinize or otherwise set the pattern. In this manner, a roll-to-roll process can implement EHD to pattern films to create a periodic roughness pattern that increases the hydrophobicity of the film.

(17) It will be appreciated that variants of the above-disclosed and other features and functions, or alternatives thereof, may be combined into many other different systems or applications. Various presently unforeseen or unanticipated alternatives, modifications, variations, or improvements therein may be subsequently made by those skilled in the art which are also intended to be encompassed by the following claims.