TRANSFERRING VISCOUS MATERIALS
20230240017 · 2023-07-27
Inventors
Cpc classification
H05K3/046
ELECTRICITY
H05B2203/005
ELECTRICITY
H05K2203/1105
ELECTRICITY
H05K2203/083
ELECTRICITY
H05B2203/019
ELECTRICITY
H05K3/1258
ELECTRICITY
H05K2203/0113
ELECTRICITY
International classification
H05K3/12
ELECTRICITY
Abstract
A method and device are described to transfer a viscous functional material onto a receiving substrate. A plate is provided having a cavity surface that includes a cavity. A plurality of individually addressable resistive heater elements are provided that are in thermal contact with respective zones of the cavity. Viscous functional material is provided in the cavity with a material composition that, when sufficiently heated, generates a gas at an interface between the cavity surface in the cavity and the functional material, to transfer the functional material from the cavity by the gas generation onto the receiving substrate. Respective portions of the viscous functional material in respective zones of the cavity are heated by supplying respective ones of the plurality of individually addressable heater elements with an electric power having a respective time dependent magnitude.
Claims
1. A transfer method of a functional material, onto a receiving substrate, the method comprising: providing a plate having a donor surface that includes at least one donor area that is formed as a cavity in the donor surface and having a plurality of individually addressable resistive heater elements in thermal contact with respective zones of the cavity forming the at least one donor area; filling the cavity forming the at least one donor area with functional material, the functional material being one selected from the group consisting of: an electric conductor, an electric insulator, a thermal conductor and a thermal insulator; and wherein the functional material has a viscosity of at least 50 Pa.Math.s and a material composition that, when sufficiently heated, generates a gas at an interface between the donor surface in the donor area and the functional material, to transfer the functional material from the at least one donor area by the gas generation onto the receiving substrate; and heating respective portions of the viscous functional material in respective zones of the at least one donor area, wherein the heating respective portions of the viscous functional material is by supplying respective ones of the plurality of individually addressable heater elements with an electric power having a respective time dependent magnitude.
2. The transfer method of claim 1, wherein the functional material has a viscosity of at most 1000 Pa.Math.s.
3. The transfer method according to claim 1, wherein the heating is performed in a plurality of heating cycles, wherein during mutually different phases within a heating cycle, of the plurality of heating cycles, a respective one of at least a subset of the plurality of individually addressable heater elements is provided with an electric power, wherein the electric energy provided within a single phase of a heating cycle is below a threshold value at which a transfer of the functional material occurs, and wherein a total amount of electric energy provided in the plurality of heating cycles exceeds the threshold value.
4. The transfer method according to claim 1, wherein the plurality of individually addressable heater elements are arranged in successive zones of the at least one donor area, wherein the heating is performed by sequentially supplying electric power to a respective one of the plurality of individually addressable heater elements, and wherein a non-linear relationship exists between a rank of the individually addressable heater elements in the succession and a point in time at which a supply of electric power is initiated to a particular addressed one of the individually addressable heater elements.
5. The transfer method according to claim 4, wherein the successive zones include at least a first zone, a one but last zone and a last zone, wherein heating the last zone is postponed with a delay period after the heating the one-but last zone.
6. The transfer method according to claim 4, wherein the zones include at least a first zone, a one but first zone, a central zone, a one but last zone and a last zone, wherein the method comprises, in order, performing steps of: ejecting sections of the viscous functional material from the first zone and the last zone by heating associated resistive heater elements, thus allowing sections corresponding to the first zone and the last zone to fold towards each other; pulse-wise heating the heater elements associated with the one but first zone and the one but last zone to gradually release sections of the viscous functional material in the one but first zone and the one but last zone, thus allowing sections corresponding to the one but first zone and the one but last zone to fold towards each other; and ejecting folded functional material, arising from the ejecting and pulse-wise heating, by heating the heater element associated with the central zone.
7. The transfer method according to claim 6, wherein the at least one donor area has a central zone extending over a length in a first direction (X) and has at each longitudinal end a wing extending at both sides of the central zone in a second direction (Y) transverse to the first direction, wherein the wings each extend in the at least a first zone, a one but first zone, the one but last zone and the last zone, wherein the at least one donor area comprises a first portion of viscous functional material, wherein the plate further comprises between the wings, at respective sides of the central zone, a first additional donor area with a first additional portion of viscous functional material, and a second additional donor area with a second additional portion of viscous functional material, wherein the first donor area and the second additional donor area each extend in at least two zones outside the central zone, wherein during operation of the method the first additional portion and the second additional portion of viscous functional material fuse into a continuous electrically conducting strip extending in the second direction on the receiving substrate, wherein the first portion forms an electrically conductive bridge, wherein the functional material present in the wings is folded during the transfer as a respective leg of the bridge arranged at mutually opposite sides of the continuous electrically conducting strip and the functional material present in the central zone forms a body of the bridge extending between the legs and crossing over the electrically strip.
8. The transfer method according to claim 1, wherein the plate and the receiving substrate are moved relative to each other while in the process of transferring functional material from the at least one donor area, a first portion thereof already adheres to the receiving substrate while another portion thereof remains adhered to the plate surface in the donor area.
9. The transfer method of claim 1, wherein the functional material is provided with a solvent and a solid state composition of more than 50 vol % solid state material.
10. The transfer method according to claim 1, wherein the functional material is a conductive material taken from the group consisting of: an electroconductive polymer, a metallized polymer, a solder paste, and a conductive adhesive.
11. A transfer device for transferring of a functional material, onto a receiving substrate, the device comprising: a plate having a donor surface that includes at least one donor area that is formed as a cavity in the donor surface and that is filled with the functional material, the functional material being one selected from the group consisting of: an electric conductor, an electric insulator, a thermal conductor and a thermal insulator, and wherein the functional material has a viscosity of at least 50 Pa.Math.s and a material composition that, when sufficiently heated, generates a gas at an interface between the donor area surface in the donor area and the functional material, to transfer the functional material from the at least one donor area by the gas generation onto the receiving substrate; a plurality of individually addressable resistive heater elements each of the individually addressable resistive heater elements being in thermal contact with a respective zone of the cavity forming the at least one donor area; and control circuitry configured to supply an electric power having a respective time dependent magnitude to respective ones of the plurality of individually addressable resistive heater elements.
12. The transfer device according to claim 11, wherein the functional material has a viscosity of at most 1000 Pa.Math.s.
13. The transfer device according to claim 11, wherein the resistive heater elements are arranged in a heater matrix comprising: a first set of powerlines arranged in a first planar direction of the plate, and a second set of powerlines arranged in a second planar direction transverse to the first planar direction; and wherein respective heater elements are electrically connected to respective pairs of a powerline of the first set and a powerline of the second set.
14. The transfer device according to claim 13, wherein the resistive heater elements are of a material with a negative temperature coefficient or are varistor heater elements.
15. A non-transient computer-readable medium comprising computer-executable instructions that when executed by a programmable processor causes a transfer device, comprising a plate having a donor surface that includes at least one donor area that is formed as a cavity in the donor surface and having a plurality of individually addressable resistive heater elements in thermal contact with respective zones of the cavity forming the at least one donor area, to transfer a functional material, onto a receiving substrate according to a method comprising: filling the cavity forming the at least one donor area with functional material, the functional material being one selected from the group consisting of: an electric conductor, an electric insulator, a thermal conductor and a thermal insulator; and wherein the functional material has a viscosity of at least 50 Pa.Math.s and a material composition that, when sufficiently heated, generates a gas at an interface between the donor surface in the donor area and the functional material, to transfer the functional material from the at least one donor area by the gas generation onto the receiving substrate; and heating respective portions of the viscous functional material in respective zones of the at least one donor area, wherein the heating respective portions of the viscous functional material is by supplying respective ones of the plurality of individually addressable heater elements with an electric power having a respective time dependent magnitude.
16. The transfer device according to claim 11, wherein the control circuitry is configured to supply the electric power in a plurality of heating cycles, wherein the controller, during mutually different phases within a heating cycle, provides a respective one of at least a subset of the plurality of individually addressable heater elements with an electric power, wherein the electric energy provided within a single phase is below a threshold value at which a transfer of the functional material occurs, and the total amount of electric energy provided in the plurality of heating cycles exceeds the threshold value.
17. The transfer device according to claim 11, wherein the transfer device is configured to move the plate and the receiving substrate relative to each other while in the process of transferring functional material from the at least one donor area, a first portion thereof already adheres to the receiving substrate while another portion thereof remains adhered to the plate surface in the donor area.
18. The transfer device according to claim 11, wherein the plurality of individually addressable heater elements are arranged in successive zones of the at least one donor area, wherein the controller is configured to sequentially supply an electric power to a respective one of the plurality of individually addressable heater elements, and wherein a non-linear relationship exists between a rank of the individually addressable heater elements in the succession and a point in time at which a supply of electric power is initiated to a particular addressed one of the individually addressable heater elements.
19. The transfer device according to claim 18, wherein the successive zones include at least a first zone, a one but last zone and a last zone, wherein the controller is configured to postpone initiating a supply of electric power to the heater element heating the last zone with a delay period after having supplied an electric power to the heater element of the one-but last zone.
20. The transfer device according to claim 18, wherein the zones include at least a first zone, a one but first zone, a central zone, a one but last zone and a last zone, the controller being configured to sequentially perform: supplying an electric power to the resistive heater elements of the first and the last zone to eject sections of the viscous functional material therein, thus allowing sections corresponding to the first zone and the last zone to fold towards each other; pulse-wise supplying an electric power to the heater elements associated with the one but first zone and the one but last zone to gradually release sections of the viscous functional material in the one but first zone and the one but last zone, thus allowing sections corresponding to the one but first zone and the one but last zone to fold towards each other; and supplying an electric power to the heater element associated with the central zone to eject folded functional material arising from the supplying an electric power to the resistive heater elements of the first and the last zone and pulse-wise supplying an electric power to the heater elements associated with the one but first zone and the one but last zone.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0026] These and other aspects are described in more detail with reference to the drawing. Therein:
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DETAILED DESCRIPTION OF EMBODIMENTS
[0039] Like reference symbols in the various drawings indicate like elements unless otherwise indicated.
[0040]
In the example shown in
[0041] The individually addressable resistive heater elements 131, 132, 133, 134, 135 are coupled to a control circuitry 14. The control circuitry 14 is configured to supply an electric power C131, C132, C133, C134, C135 having a respective time dependent magnitude to respective ones 131, 132, 133, 134, 135 of the plurality of individually addressable resistive heater elements.
[0042] Some elements are shown in more detail in
[0043] In some embodiments the device may have a predetermined configuration to operate in a predetermined manner.
[0044] In the embodiment shown, the control circuitry 14 is configured to read a record carrier 60 that comprises instructions that specify the time dependent magnitude according to which it is to supply power to the respective resistive heater elements 131-135. Mutually different record carriers may specify mutually different embodiments of methods to be performed with the device 1. Examples thereof are provided below. Also it may be conceived that the device has a proper record carrier, that can be loaded with instructions for each case, for example instructions received from the internet 61, or provided by an operator via a user interface 62.
[0045] The substrate 20 may be of a rigid or of a flexible nature. The term “flexible substrate” used in this text refers in particular to a substrate that is bendable enough to be used in a reel to reel process. In other words a flexible substrate as used in this text is a substrate that is flexible enough to allow bending over a certain curvature, e.g. with a radius of 1-100 centimeters (depending on the reel diameter), without the substrate losing essential functionality. Supply of chip bonding material matter 50 can e.g. be placed on a pad structure or on chip pads.
[0046] The functional material to be transferred is for example, a thermosettable isotropic conductive adhesive material with a volume resistivity of typically 400-1000 microOhm.Math.cm. To illustrate the general applicability of the method, an experimental conductive adhesive is transferred consisting of a highly viscous conductive adhesive with a viscosity of 160-180 Pa.Math.s. The conductive adhesive can be provided as homogenous layer of 20-30 micron, in particular, 25 micron thick. The thickness is controlled to be around 25 um or 50 um but could be theoretically be of any thickness. For example, a cavity 12 may be in the order of 5-10 micron deep and may have a smallest diameter of less than 50 micron.
[0047]
[0048] The upper part of
[0049] As shown in
[0050] As shown in
[0051]
[0052] As shown in
[0053] As further shown in
[0054]
[0055] The upper one of each series of cross-sections A,B,C indicates the plate 10 as it is initially provided at TO.
[0056] During a time interval T1, the resistive heater element 131 is heated. As a result, the portions of the material section 50A present in this range, denoted as AL1 on the left and AR2 on the right are heated to an extent that they are forced out by the vapor pressure locally created in the cavity. As a result, these portions fold inward (Fold 1) similarly as the portion 51 in
[0057] Analogously to what was described with reference to
[0058] During T4, heating of the heater elements 133 and 135 is performed in three heating cycles. This has as a result that in the last cycle of T4, the material of section 50B present in the range of resistive heater element 133, as well as the material of section 50C present in the range of resistive heater element 135 is ejected. Therewith the fused functional material originating from sections 50B and 50C is deposited as a single conducting strip 57 on the substrate. Also the portions, e.g. AL3, AL6 of material section 50 within the range of heater elements 133 and 135 are forced outwards, but because material section 50A is still adhered to the plate surface in the region of heater element 134, this has as the effect that the structure of material section is folded further, so that the original portions AL1 AL7 fuse with each other. Likewise portions AR1, AR7 fuse with each other. Therewith a bridge 58 is formed that has a first leg 58L formed by portions AL1 AL2, AL3, AL5, AL6 and AL7 at one side, a second leg 58R formed by portions AR1, AR2, AR3, AR5, AR6 and AR7 at the opposite side and a bridge body 58B formed by a portion A4 of the material section in the range of heater element 134. Because this heater element 134 was not yet activated, the bridge 58 is still suspended with the bridge body to the surface 11 of the plate 10.
[0059] Finally during T5 heater element 134 is heated so that the bridge 58 which was folded in the previous steps is now transferred towards the substrate 20, where it lands at its first and second leg 58L, 58R and with the bridge body 58B traverses the conducting strip 57 at distance.
A further exemplary application is shown in
[0060] In the previous examples it was presumed that the resistive heater elements were provided each with separate contacts.
[0061] Heater elements in the matrix can be individually addressed by connecting their corresponding pair of power lines to a power source. In the example shown element H22 is addressed in that rowline RL2 and column line CL2 are connected to the power source. Nevertheless, when connecting the powerlines RL2, CL2, also a current may flow via other heater elements, for example following the path via heater element H32, line CL3, heater element H33, line RL3 and heater element H23. Although the current flowing via the neighboring heater elements is substantially slower than that via the addressed element, it may be desired to suppress these leakage currents.
[0062] To that end, in one example the resistive heater elements are of a material with a negative temperature coefficient (NTC). The effect of this measure is shown in
[0063] In another example, illustrated with reference to
[0064]
[0065] A record carrier 60, as shown in
[0066] As shown further in
[0067] Other variations to the disclosed embodiments can be understood and by those skilled in the art in practicing the claimed invention, from a study of the drawings, the disclosure, and the appended claims. In the claims, the word “comprising” does not exclude other elements or steps, and the indefinite article “a” or “an” does not exclude a plurality. A single unit may fulfill the functions of several items recited in the claims. The mere fact that certain measures are recited in mutually different dependent claims does not indicate that a combination of these measured cannot be used to advantage. Any reference signs in the claims should not be construed as limiting the scope. In addition, the functional material may have a wide-range of viscosity, possible to transfer (from 50 Pa.Math.s to 1000 Pa.Math.s (non-exhaustive)). Contrary to stencil printing and screen printing it is a non-contact direct write method wherein the distance to the substrate surface is preferably kept higher than 1 micron. The transfer accuracy of the functional ink is dependent on the printing gap. Typically the printing gap needs to be in the same order as the feature size to obtain a good printing accuracy. When a small printing gaps are required, it becomes technically more difficult to align the print head with the sample holder. Therefore it is preferred to control the gap by using spacer pins and press the print head and sample holder together. It is preferred to have at least three degrees (heave, roll, pitch) of freedom between the print head and sample holder. In an example pastes can be formed as follows:
TABLE-US-00001 Solids content 90 ± 5 wt % Material Solids content Purpose Metal (Ag, Cu, Au): 86.5 ± 5 wt % Conductivity Polymer binder 2.5 ± 2 wt % Adhesion and cohesion Fumed silica 1 ± 1 wt % Anti-slump, rheology control Solvent: 10 ± 5 wt % Printability
[0068] with viscosities ranging between 100 en 1000 Pa*s. In contrast to conventional screen print paste and inks shear thinning may be minimized e.g. by adding fumed silica to prevent flow of the past on the acceptor substrate. This can also be prevented by curing/drying the ink e.g. by laser irradiation, which can be conveniently realized by a high solids content and low solvent content.
[0069] The power required to induce a gas pressure is dependent on the functional material used with the method. As a rule of thumb it may be required that the control circuitry connected to the resistive heating elements configured to heat the a heating element in less than 100 microseconds at an average power of more than 10 kW/cm2. Alternatively, it may be required that the control circuitry allows the resistive heater elements to heat the functional material at a heating rate of at least 5K/microsecond in order to generate gas at the interface to provide for the gas pressure that forces the functional material out of the cavity. In case a direct ejection is not required the heating power is provided in a sequence of cycles as shown for example in
[0070] In addition to controlling the transferring process by supplying individually addressable heater elements with an electric power having a respective time dependent magnitude it is possible to control a heat flux distribution associated with an individual heat by means of its shape, as is illustrated in the following examples in
[0071] In each of these figures, the lower part shows a cross-section through the plate 10 while functional material is being deposited. The middle part shows in a view in a direction towards the surface 11 of the plate 10, a cross-section of the individual addressable resistive heating element 13. The upper part schematically shows the local heat flux (solid line) as a function of the position along the cavity 12 and the associated release time (dashed line).
[0072] In the example of
[0073] In the second example, shown in
[0074]
[0075] While the present invention has been described with respect to a limited number of embodiments, those skilled in the art will appreciate numerous modifications and variations therefrom within the scope of this present invention as determined by the appended claims. For example, as noted above, a donor area may be at level with the surrounding surface or may be formed as a cavity in the donor surface. Also in some embodiments a plate is provided with one or more donor areas at level with the surrounding surface and other donor areas formed as a cavity. For example, according to a modification within the scope of the claims a plate having a donor area formed as a cavity in the donor surface may be replaced with a plate having a donor area at level with the surrounding donor surface.