APPARATUS FOR ANALYZING AND/OR PROCESSING A SAMPLE WITH A PARTICLE BEAM AND METHOD
20230238209 · 2023-07-27
Inventors
- Nicole Auth (Ginsheim-Gustavsburg, DE)
- Michael Budach (Hanau, DE)
- Thorsten Hofmann (Rodgau, DE)
- Jens Oster (Ober-Ramstadt, DE)
Cpc classification
H01J37/3174
ELECTRICITY
H01J2237/0206
ELECTRICITY
H01J2237/0458
ELECTRICITY
H01J37/09
ELECTRICITY
H01J37/20
ELECTRICITY
International classification
H01J37/20
ELECTRICITY
Abstract
An apparatus for analyzing and/or processing a sample with a particle beam, comprising: a sample stage for holding the sample; a providing unit for providing the particle beam comprising: an opening for guiding the particle beam to a processing position on the sample; and a shielding element for shielding an electric field generated by charges accumulated on the sample; wherein the shielding element covers the opening, is embodied in sheetlike fashion and comprises an electrically conductive material; wherein the shielding element comprises a convex section, this section being convex in relation to the sample stage; and wherein the convex section has a through opening for the particle beam to pass through to the sample.
Claims
1. An apparatus for analyzing and/or processing a sample with a particle beam, the sample being a lithography mask, comprising: a sample stage for holding the sample; a providing unit for providing the particle beam comprising: an opening for guiding the particle beam to a processing position on the sample; and a shielding element for shielding an electric field generated by charges accumulated on the sample; wherein the shielding element covers the opening, is embodied in sheetlike fashion and comprises an electrically conductive material; wherein the shielding element comprises a convex section, this section being convex in relation to the sample stage and being curved in the direction of the sample stage; wherein the convex section has a through opening for the particle beam to pass through to the sample; and wherein the apparatus is configured such that the convex section of the shielding element is at a distance from the sample of at most 500 μm during an analysis or processing of the sample with the particle beam.
2. The apparatus of claim 1, comprising a gas feed configured for feeding a process gas through the through opening of the shielding element to the processing position on the sample.
3. The apparatus of claim 1, comprising a gas feed configured for feeding a process gas into a gap, wherein the gap is formed by the sample arranged on the sample stage and by the shielding element.
4. The apparatus of claim 2, wherein the gas feed comprises a feed channel integrated into the shielding element.
5. The apparatus of claim 1, wherein the through opening comprises the point of a smallest distance between the shielding element and the sample stage.
6. The apparatus of claim 1, wherein the shielding element comprises a planar section, from which the convex section extends in the direction of the sample stage.
7. The apparatus of claim 1, wherein the convex section is embodied in funnel-shaped fashion, in particular with a circular cross section.
8. The apparatus of claim 1, wherein the convex section includes a strictly convex section, a spherical surface and/or a segment of a spherical surface.
9. The apparatus of claim 1, wherein the convex section is embodied in such a way that a connecting straight line that connects two points (P1, P2) on a surface of the convex section of the shielding element runs outside the shielding element for any combination of two points (P1, P2) on the surface of the convex section of the shielding element.
10. The apparatus of claim 1, wherein the shielding element comprises on its surface a layer composed of an electrically conductive material, wherein a layer thickness of the layer is greater than or equal to a penetration depth of the particles of the particle beam into the material.
11. The apparatus of claim 1, wherein the shielding element has exactly one through opening.
12. The apparatus of claim 1, wherein the shielding element has a plurality of through openings separated from one another by webs.
13. The apparatus of claim 12, wherein the through openings each have a hexagonal cross section.
14. The apparatus of claim 12, wherein the webs are shaped in such a way that a sample stage-side cross-sectional area of a respective one of the plurality of through openings in a first plane perpendicular to a surface normal of the shielding element on the through opening is smaller than an opening-side cross-sectional area of the respective through opening in a second plane parallel to the first plane.
15. The apparatus of claim 12, wherein one of the plurality of through openings has a geometric feature that distinguishes the through opening from the further through openings.
16. The apparatus of claim 12, wherein one of the plurality of through openings comprises the point of a smallest distance between the shielding element and the sample stage and the further through openings are arranged symmetrically with respect to the one through opening.
17. The apparatus of claim 1, comprising a beam generating unit and a beam guiding element, which is arranged between the beam generating unit and the shielding element and which is configured for guiding the particle beam, wherein provision is made of a voltage source for applying a voltage between the shielding element and the beam guiding element.
18. The apparatus of claim 17, wherein the shielding element is secured to the providing unit by use of a holding apparatus, wherein the holding apparatus and the shielding element are electrically insulated from one another, wherein provision is made of a further voltage source for applying a voltage between the holding apparatus and the beam guiding element and/or the shielding element.
19. The apparatus of claim 1, wherein the shielding element is held in an electrically insulated manner, and comprising a detecting unit for detecting a current that flows away from the shielding element.
20. The apparatus of claim 1, wherein the shielding element comprises a plurality of sections which are electrically insulated from one another and which delimit the through opening, wherein a voltage is able to be applied between in each case two oppositely arranged sections by use of a respective voltage source.
21. The apparatus of claim 1, wherein a plurality of shielding elements are arranged one behind another in the beam direction and cover the opening, wherein at least one of the plurality of shielding elements is held in a displaceable manner for the purpose of providing a settable stop opening.
22. A combination of an apparatus of claim 1 and a sample, the sample being a lithography mask.
23. A method for analyzing and/or processing a sample with a particle beam by use of an apparatus of claim 1, the sample being a lithography mask, the method comprising the following steps: arranging the sample on the sample stage; providing the particle beam; and radiating the particle beam through the through opening onto the processing position on the sample.
Description
DESCRIPTION OF DRAWINGS
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DETAILED DESCRIPTION
[0142] Identical elements or elements having an identical function have been provided with the same reference signs in the figures, unless indicated to the contrary. It should also be noted that the illustrations in the figures are not necessarily true to scale.
[0143]
[0144] The providing unit 110 comprises in particular a particle beam generating unit 111, which generates the particle beam 112. The particle beam 112 consists of charged particles, for example of ions or of electrons. An electron beam is involved in the example in
[0145] The electron column 110 has a dedicated vacuum housing, which is evacuated to a residual gas pressure of 10.sup.−7 mbar-10.sup.−8 mbar, for example. An opening 114 for the electron beam 112 is arranged at the underside. The opening 114 is covered by a shielding element 116. The shielding element 116 is embodied in sheetlike fashion and comprises an electrically conductive material. By way of example, the shielding element 116 is formed from gold. The shielding element 116 has a convex section 117, this section being convex relative to the sample stage 120. The convex section 117 curves in the direction of the sample stage 120. The convex section 117 has a through opening 118 for the particle beam 112 to pass through. The through opening 118 comprises in particular a point of the convex section 117 which is closest to the sample stage. The distance between the shielding element 116 and the sample stage 120 is thus the smallest in the region of the through opening 118. The distance between the through opening 118 and the sample 200 is preferably between 5 μm-30 μm, preferably 10 μm, during operation of the apparatus 100. Preferably, the sample stage 120 has a positioning unit (not shown), by use of which a distance between the sample stage 120 and the electron column 110 is settable.
[0146] The shielding element 116 can have a planar region 116A (see
[0147] Earth potential is applied to the shielding element 116. The shielding element is thus configured to shield an electric field E. In order to clarify this, charges Q that generate the electric field E are illustrated by way of example in
[0148] As a result of the shielding of the electric field E, firstly, an increased accuracy is achieved with regard to an impingement point and also a focus position of the electron beam 112 on the sample 200, which improves a resolution and process control. Secondly, a flight trajectory of backscattered electrons and secondary electrons that fly counter to the electron beam 112 in the direction of the beam providing unit 111 is influenced to a lesser extent, which likewise improves the resolution and the process control and additionally a sensitivity.
[0149]
[0150] When the apparatus 100 is operated, the sample stage 120 with the sample 200 arranged thereon is positioned below the providing unit 110, such that the through opening 118 is situated above the processing position 202 on the sample 200 in the beam direction. A gap forms between the sample 200 and the providing unit 110, in particular the shielding element 116.
[0151] In this example, the providing unit 110 has a gas feed 130 configured for feeding a process gas PG into the gap. The process gas PG flows along the gap and thus reaches the processing position 202 on the sample 200. By use of the gas feed 130, it is thus firstly ensured that the processing position 202 is sufficiently supplied with process gas PG; secondly a volumetric flow rate of the process gas PG through the through opening 118 into the providing unit 110 is comparatively low, in particular much lower than if the process gas PG were guided through the through opening 118 from above to the processing position 202.
[0152] The sample 200 is for example a lithography mask having a feature size in the range of 10 nm-10 μm. This can be for example a transmissive lithography mask for DUV lithography (DUV: “deep ultraviolet”, operating light wavelengths in the range of 30-250 nm) or a reflective lithography mask for EUV lithography (EUV: “extreme ultraviolet”, operating light wavelengths in the range of 1-30 nm). The processing processes that are carried out in this case comprise for example etching processes, in which a material is locally removed from the surface of the sample 200, deposition processes, in which a material is locally applied to the surface of the sample 200, and/or similar locally activated processes, such as forming a passivation layer or compacting a layer.
[0153] The process gas PG can comprise a mixture of a plurality of gaseous substances. Appropriate process gases PG suitable for depositing material or for growing elevated structures are, in particular, alkyl compounds of main group elements, metals or transition elements. Examples thereof are cyclopentadienyl trimethylplatinum CpPtMe.sub.3 (Me=CH.sub.4), methylcyclopentadienyl trimethylplatinum MeCpPtMe.sub.3, tetramethyltin SnMe.sub.4, trimethylgallium GaMe.sub.3, ferrocene Cp.sub.2Fe, bis-arylchromium Ar.sub.2Cr, and/or carbonyl compounds of main group elements, metals or transition elements, such as, for example, chromium hexacarbonyl Cr(CO).sub.6, molybdenum hexacarbonyl Mo(CO).sub.6, tungsten hexacarbonyl W(CO).sub.6, dicobalt octacarbonyl Co.sub.2(CO).sub.8, triruthenium dodecacarbonyl Ru.sub.3(CO).sub.12, iron pentacarbonyl Fe(CO).sub.5, and/or alkoxide compounds of main group elements, metals or transition elements, such as, for example, tetraethyl orthosilicate Si(OC.sub.2H.sub.5).sub.4, tetraisopropoxytitanium Ti(OC.sub.3H.sub.7).sub.4, and/or halide compounds of main group elements, metals or transition elements, such as, for example, tungsten hexafluoride WF.sub.6, tungsten hexachloride WCl.sub.6, titanium tetrachloride TiCl.sub.4, boron trifluoride BF.sub.3, silicon tetrachloride SiCl.sub.4, and/or complexes comprising main group elements, metals or transition elements, such as, for example, copper bis-(hexafluoroacetylacetonate) Cu(C.sub.5F.sub.6HO.sub.2).sub.2, dimethylgold trifluoroacetylacetonate Me.sub.2Au(C.sub.5F.sub.3H.sub.4O.sub.2), and/or organic compounds such as carbon monoxide CO, carbon dioxide CO.sub.2, aliphatic and/or aromatic hydrocarbons, and suchlike.
[0154] Appropriate process gases suitable for etching material are for example: xenon difluoride XeF.sub.2, xenon dichloride XeCl.sub.2, xenon tetrachloride XeCl.sub.4, water vapor H.sub.2O, heavy water D.sub.2O, oxygen O.sub.2, ozone O.sub.3, ammonia NH.sub.3, nitrosyl chloride NOCl and/or one of the following halide compounds: XNO, XONO.sub.2, X.sub.2O, XO.sub.2, X.sub.2O.sub.2, X.sub.2O.sub.4, X.sub.2O.sub.6, where X is a halide.
[0155] Additive gases, which can be admixed for example in proportions with the process gas PG in order to better control the processing process, comprise for example oxidizing gases such as hydrogen peroxide H.sub.2O.sub.2, nitrous oxide N.sub.2O, nitrogen oxide NO, nitrogen dioxide NO.sub.2, nitric acid HNO.sub.3, and further oxygen-containing gases, and/or halides such as chlorine Cl.sub.2, hydrogen chloride HCl, hydrogen fluoride HF, iodine I.sub.2, hydrogen iodide HI, bromium Br.sub.2, hydrogen bromide HBr, phosphorus trichloride PCl.sub.3, phosphorus pentachloride PCl.sub.5, phosphorus trifluoride PF.sub.3, and further halogen-containing gases, and/or reducing gases, such as hydrogen H.sub.2, ammonia NH.sub.3, methane CH.sub.4, and further hydrogen-containing gases. Said additive gases can be used for example for etching processes, as buffer gases, as passivating media and suchlike.
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[0157] In this case, the shielding element 116 comprises a channel that forms the last line section of the gas feed 130. In this case, therefore, the process gas PG is guided through the shielding unit 116. In this way, the process gas PG can be brought very close to the processing position 202. Escape of process gas PG into surroundings of the apparatus 100 can thus be reduced and a consumption of process gas PG can thus be reduced. In particular, a higher process gas pressure with at the same time a lower consumption of process gas can be achieved at the processing position 202. A processing speed can thus be increased.
[0158] The shielding element 116 with the integrated gas feed is produced for example by use of special production methods, in particular LIGA fabrication methods (LIGA: an abbreviation from the German Lithographie, Galvanik und Abformung [lithography, electroplating and moulding]).
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[0160] In the example in
[0161] In the example in
[0162] In the example in
[0163] In the example in
[0164] In the example in
[0165] The largest through opening 118 is arranged centrally in the convex section 117. The central through opening 118 comprises that point of the shielding element 116 which is closest to the sample stage 120 (see
[0166] The shielding element 116 of this example makes it possible, firstly, to produce an overview recording of the sample 200 by scanning the particle beam 112 over each of the through openings 118; secondly, however, at the same time a free cross-sectional area is reduced by the wide webs 119, thereby reducing a process gas volumetric flow rate through the shielding element 116.
[0167] In the example in
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[0169] It can be stated that the webs 119 taper upwards. The webs 119 can be embodied as triangular or trapezium-shaped, for example. What is achieved by this cross section is that backscattered electrons or secondary electrons that are emitted by the sample 200 can be detected in a larger solid angle range over the shielding element 116, as is illustrated by way of example by the cone with opening angle α depicted in
[0170] A detection efficiency and/or a resolution can thus be improved with the same mechanical stability of the shielding element 116.
[0171] If the shielding element 116 is embodied as a single-hole stop (see
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[0174] In this example, the providing unit 110 comprises a beam guiding element 113 arranged between the shielding element 116 and the beam generating unit 111. A voltage source U0 is configured to apply a specific accelerating voltage between the beam generating unit 111 and the beam guiding element 113. The charged particles of the particle beam 112 are therefore accelerated in the direction of the beam guiding element 113.
[0175] The shielding element 116 is held for example in a manner insulated from the providing unit 110. A further voltage source U1 is configured for applying a voltage between the beam guiding element 113 and the shielding element 116. As a result, an electric field (not illustrated) forms between the beam guiding element 113 and the shielding element 116. This electric field is controllable by way of the voltage applied by use of the further voltage source U1. The particle beam 112 can thus be guided, in particular accelerated or decelerated and/or deflected, in the region between the beam guiding element 113 and the shielding element 116. The same applies to charged particles which, coming from the sample 200, pass through the shielding element 116 counter to the beam direction. It can also be stated that the beam guiding element 113 together with the shielding element 116 and the voltage source U1 form an electro-optical element.
[0176] As an alternative to the illustration in
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[0178] In the beam direction two electric fields (not shown) arranged one behind the other thus arise, through which the particle beam 112 passes and by use of which the particle beam 112 can be influenced. A large number of different field configurations are settable with this construction.
[0179] As an alternative to the construction shown, the additional voltage source U2 can also be arranged between the holding apparatus 116* and the shielding element 116.
[0180] A further alternative is to arrange the voltage source U1 between the holding apparatus 116* and the beam guiding element 113 and the additional voltage source U2 between the holding apparatus 116* and the shielding element 116.
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[0182] Furthermore, a gas pressure in the region of the shielding element 116 can be deduced from the detected current since there is a positive correlation between the gas pressure and the current. Increased gas pressure gives rise to more collisions between particles of the particle beam and gas molecules, and so scattering occurs to a greater extent, thus resulting in an increase in the number of particles scattered to the shielding element 116, and thus also in the detected current.
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[0185] The special feature of this exemplary embodiment is that two shielding elements 116 are provided one behind the other in the beam direction, both of said shielding elements covering the opening 114. In this case, one of the shielding elements 116 is held by a positioning unit 140. The shielding element 116 can thus be displaced relative to the shielding element 116 arranged fixedly thereabove. In this way, the two shielding elements 116 form a settable stop. The positioning unit 140 comprises in particular one or more flexures and/or piezo-actuators. The shielding element 116 is thus displaceable along at least one axis. Preferably, the shielding element 116 is displaceable along at least two axes. Additionally and/or alternatively, the shielding element 116 can be held in a rotatable manner.
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[0187] In a first step S1, the sample 200 is arranged on the sample stage 120. This comprises for example positioning the sample 200 below the shielding element 116 (see
[0188] In a second step S2, the particle beam 112 is provided and, in a third step S3, the particle beam 112 is radiated through the through opening 118 onto the processing position 202 on the sample 200 and the sample 200 is analyzed and/or processed in this way.
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[0190] In this exemplary embodiment, the apparatus 100 is configured to establish an electrical contact with the sample 200 by way of the convex section 117 of the shielding element 116. This may be advantageous particularly in the case of samples 200 having a conductive surface, since charges can directly flow away from the surface of the sample, with the result that a disturbing electric field does not form. In particular, in this exemplary embodiment, before the sample 200 was contacted with the shielding element 116, a protective layer 204 was deposited on the surface of the sample around the processing position 202 by use of a particle beam-induced process. The deposition process was carried out by the apparatus 100, in particular. For this purpose, for example, molybdenum hexacarbonyl Mo(CO).sub.6 was used as process gas PG (see
[0191]
[0192] In this example, the providing unit 110 comprises a gas feed 130 configured for feeding a process gas PG through the through opening 118 of the shielding element 116 to the processing position 202 on the sample 200. The process gas PG flows along the beam direction of the particle beam 112 through the through opening 118 and thus reaches the processing position 202 on the sample 200.
[0193] With this arrangement of the gas feed 130, there is the risk of the process gas PG also flowing counter to the beam direction towards the beam generating unit 111 (see
[0194] At the same time an electrical potential can be applied to the aperture 132 and the latter can thus be used for beam guiding and/or else be used as a detector. In addition to the aperture 132, differential pump stages can be provided (not illustrated), which further reduce a gas flow upwards counter to the beam direction.
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[0196] All the shielding elements 116 illustrated in
[0197] The shielding element 116 illustrated in
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[0199] The shielding element 116 illustrated in
[0200] The shielding element 116 illustrated in
[0201] It should be noted that each of the shielding elements 116 illustrated in
[0202] The embodiments illustrated in
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[0204] The curved line 117 is convex, which is discernible for example from the fact that the connecting straight line LIN for any arbitrary pair of points P1, P2 on the curved line 117 runs outside the curved line 117, as illustrated by way of example for the two points P1, P2 in
[0205] Although the present invention has been described on the basis of exemplary embodiments, it is modifiable in diverse ways. In particular, the features and aspects explained in the various exemplary embodiments are combinable among one another, even if this is not explicitly mentioned in the respective description of the exemplary embodiment.
LIST OF REFERENCE SIGNS
[0206] 100 Apparatus [0207] 110 Providing unit [0208] 111 Beam generating unit [0209] 112 Particle beam [0210] 113 Beam guiding element [0211] 114 Opening [0212] 116 Shielding element [0213] 116* Holding apparatus [0214] 116A Planar region [0215] 117 Convex section [0216] 118 Through opening [0217] 118* Through opening [0218] 118A Cross-sectional area [0219] 118B Cross-sectional area [0220] 119 Web [0221] 120 Sample stage [0222] 130 Gas feed [0223] 132 Aperture [0224] 140 Positioning unit [0225] 200 Sample [0226] 202 Processing position [0227] 204 Protective layer [0228] A Opening angle [0229] E Electric field [0230] I1 Current measuring device [0231] Ia Section [0232] Ib Section [0233] IIa Section [0234] Illb Section [0235] IIa Section [0236] IIIb Section [0237] IVa Section [0238] IVb Section [0239] LIN Connecting straight line [0240] P1 Point [0241] P2 Point [0242] PG Process gas [0243] Q Charges [0244] S1 Method step [0245] S2 Method step [0246] S3 Method step [0247] U0 Voltage source [0248] U1 Voltage source [0249] U2 Voltage source [0250] UI Voltage source [0251] UII Voltage source [0252] UIII Voltage source [0253] UIV Voltage source