HIGH TOUGHNESS HOT ROLLED AND ANNEALED STEEL SHEET AND METHOD OF MANUFACTURING THE SAME

Abstract

A hot rolled and annealed steel sheet having a composition including, by weight percent: C: 0.1-0.25%, Mn: 3.00-5.00%, Si: 0.80-1.60%, B: 0.0003-0.004%, S≤0.010%, P≤0.020%, N≤0.008% the remainder of the composition being iron and unavoidable impurities resulting from the smelting, and having a microstructure consisting of, in surface fraction: more than 20% of recrystallized ferrite, the balance being non-recrystallized ferrite, more than 15% of said recrystallized ferrite having grain size larger than 5 μm and a density of carbides at grain boundary of recrystallized ferrite less than 5 carbides per 10 μm of grain boundary length

Claims

1-8. (canceled)

9. A hot rolled and annealed steel sheet, made of a steel having a composition comprising, by weight percent: C: 0.1-0.25% Mn: 3.00-5.00% Si: 0.80-1.60% B: 0.0003-0.004% S≤0.010% P≤0.020% N≤0.008% and optionally one or more of the following elements, in weight percentage: Ti≤0.04% Nb≤0.05% Mo≤0.3% Al≤0.90% Cr≤0.80% a remainder of the composition being iron and unavoidable impurities resulting from processing; the steel sheet having a microstructure including, in surface fraction, 20% or more of recrystallized ferrite, a balance being non-recrystallized ferrite, 15% or more of the recrystallized ferrite having grain size larger than 5 μm, and a density of carbides at a grain boundary of recrystallized ferrite being less than or equal to 5 carbides per 10 μm of grain boundary length.

10. The hot rolled and annealed steel sheet as recited in claim 9 wherein the recrystallized ferrite is between 40% and 60%.

11. The hot rolled and annealed steel sheet as recited in claim 9 wherein the recrystallized ferrite is between 80% and 100%.

12. The hot rolled and annealed steel sheet as recited in claim 9 wherein the manganese content is between 3.50% and 4.50%.

13. The hot rolled and annealed steel sheet as recited in claim 9 wherein the silicon content is between 1.00% and 1.60%.

14. The hot rolled and annealed steel sheet as recited in claim 9 wherein the hot rolled and annealed steel sheet has Charpy impact energy at 20° C. higher than 0.40 J/mm.sup.2, measured according to Standard ISO 148-1:2006 (F) and ISO 148-1:2017(F).

15. The hot rolled and annealed steel sheet as recited in claim 9 wherein the hot rolled and annealed steel sheet has a hardness level lower than 300HV.

16. A cold rolled steel sheet obtained from cold rolling of the hot rolled and annealed steel sheet as recited in claim 9.

Description

DETAILED DESCRIPTION

[0028] The invention will now be described in detail and illustrated by examples without introducing limitations.

[0029] Hereinafter, Ms designates the martensite start temperature, i.e. the temperature at which the austenite begins to transform into martensite upon cooling. These temperatures can be calculated from a formula:

Ms=560−(30*% Mn+13*% Si−15*% Al+12*% Mo)−600*(1-exp(−0.96*C))

[0030] The composition of the steel according to the invention will now be described, the content being expressed in weight percent.

[0031] According to the invention the carbon content is between 0.1% and 0.25%. Above 0.25% of carbon, weldability of the steel sheet may be reduced. If the carbon content is lower than 0.1%, the austenite fraction is not stabilized enough to obtain, after annealing, the targeted microstructure. In a preferred embodiment of the invention, the carbon content is between 0.15% and 0.20%.

[0032] The manganese content is comprised between 3.00% and 5.00%. Above 5.00% of addition, the risk of central segregation increases to the detriment of the toughness. The minimum is defined to stabilize austenite, to obtain, after annealing, the targeted microstructure. Preferably, the manganese content is between 3.50% and 5.00%. In a preferred embodiment of the invention, the manganese content is between 3.50% and 4.50%.

[0033] According to the invention, the silicon content is comprised between 0.80% and 1.60%. Above 1.60%, silicon is detrimental for toughness. Moreover, silicon oxides form at the surface, which impairs the coatability of the steel. A silicon addition of at least 0.80% helps to stabilize a sufficient amount of austenite to obtain, after annealing, the microstructure according to the invention. In a preferred embodiment of the invention, the silicon content is between 1.00% and 1.60%.

[0034] According to the invention, the boron content is comprised between 0.0003% and 0.004%. The presence of boron delays bainitic transformation to a lower temperature and the bainite formed at low temperature has a lath morphology which increases the toughness. Above 0.004%, the formation of borocarbides at the prior austenite grain boundaries is promoted, making the steel more brittle. Below 0.0003%, there is not a sufficient concentration of free B that segregates at the prior austenite grain boundaries to increase toughness of the steel. In a preferred embodiment of the invention, the boron content is between 0.001% and 0.003%.

[0035] Optionally some elements can be added to the composition of the steel according to the invention.

[0036] Titanium can be added up to 0.04% to provide precipitation strengthening. Preferably, a minimum of 0.01% of titanium is added in addition of boron to protect boron against the formation of BN.

[0037] Niobium can optionally be added up to 0.05% to refine the austenite grains during hot-rolling and to provide precipitation strengthening. Preferably, the minimum amount of niobium added is 0.0010%.

[0038] Molybdenum can optionally be added up to 0.3% in order to decrease the phosphorus segregation. Above 0.3%, the addition of molybdenum is costly and ineffective in view of the properties which are required.

[0039] Aluminium is a very effective element for deoxidizing the steel in the liquid phase during elaboration. The aluminium content can be added up to 0.90% maximum, to avoid the occurrence of inclusions and to avoid oxidation problems.

[0040] A maximum of 0.80% of chromium is allowed, above a saturation effect is noted, and adding chromium is both useless and expensive.

[0041] The remainder of the composition of the steel is iron and impurities resulting from the smelting. In this respect, P, S and N at least are considered as residual elements which are unavoidable impurities. Their content is less than 0.010% for S, less than 0.020% for P and less than 0.008% for N. In particular phosphorus segregates at grain boundary and for a phosphorus content higher than 0.020%, the toughness of the steel is reduced.

[0042] The microstructure of the hot rolled and annealed steel sheet according to the invention will now be described.

[0043] The hot rolled and annealed steel sheet has a microstructure consisting of, in surface fraction, 20% or more of recrystallized ferrite, the balance being non-recrystallized ferrite (including 0%), 15% or more of said recrystallized ferrite having grain size larger than 5 μm, and a density of carbides at grain boundary of recrystallized ferrite less than or equal to 5 carbides per 10 μm of grain boundary length.

[0044] Recrystallized ferrite corresponds to grains of ferrite which recrystallized during hot band annealing. During hot rolling, austenite grains are being elongated, and present a so-called pancake shape. Hot rolling generates dislocations, which stored energy. During annealing, such stored energy is a driving force for forming grains of ferrite, with a very low dislocation density inside the grain. As the recrystallization progresses, the hardness of the steel decreases. Below 20% of recrystallized ferrite, targeted properties are not reached. In a preferred embodiment of the invention, said recrystallized ferrite is between 40% and 60%. In another preferred embodiment of the invention, said recrystallized ferrite is between 80% and 100%.

[0045] 15% or more of recrystallized ferrite presents a grain size larger than 5 μm, in order to reach low hardness level.

[0046] Recrystallized ferrite can be distinguished from non-recrystallized ferrite thanks to its morphology which is equiaxed form. Recrystallized ferrite observed with BSE (Back Scattered Electron) mode in SEM (Scanning Electron Microscope) presents a homogeneous contrast, thanks to the low dislocation density.

[0047] The balance of the microstructure is non-recrystallized ferrite, which is comprised between 0% (including) and 80%. The part of bainite and martensite which cannot be recrystallized during hot band annealing is the portion of non-recrystalized ferrite.

[0048] The density of carbides at grain boundary of recrystallized ferrite is less than or equal to 5 carbides per 10 μm of grain boundary length to improve toughness of the steel.

[0049] The hot rolled and annealed steel sheet according to the invention has Charpy impact energy E at 20° C. higher than 0.40 J/mm.sup.2 measured according to Standard ISO 148-1:2006 (F) and ISO 148-1:2017(F).

[0050] The hot rolled and annealed steel sheet according to the invention has a Vickers hardness level lower than 300HV.

[0051] The steel sheet according to the invention can be produced by any appropriate manufacturing method and the man skilled in the art can define one. It is however preferred to use the method according to the invention comprising the following steps:

[0052] A semi-finished product able to be further hot-rolled is provided with the steel composition described above. The semi-finished product is heated to a temperature comprised between 1150° C. and 1300° C., so to make it possible to ease hot rolling, with a final hot rolling temperature FRT depending of the chemical composition of the steel.

[0053] To obtain targeted properties, a skilled person must select a finish rolling temperature FRT promoting recrystallisation of the matrix after hot band annealing. Beyond a certain value of FRT that directly depends on the chemical composition of the steel, stored energy is no longer sufficient to recrystallize ferrite after hot band annealing. Preferably, the FRT is comprised between 750° C. and 1000° C. More preferably, the FRT is comprised between 800° C. and 950° C.

[0054] The hot-rolled steel is then cooled and coiled at a temperature T.sub.coil comprised between 20° C. and 550° C. Preferably, the T.sub.coil temperature is comprised from (Ms−100° C.) to 550° C.

[0055] After the coiling, the sheet can be pickled to remove oxidation.

[0056] The coiled steel sheet is then annealed to an annealing temperature Ta that is below Ac1. The steel sheet is maintained at said temperature Ta for a holding time to comprised between 0.1 and 100h in order to decrease the hardness while maintaining the toughness above 0.4 J/mm.sup.2 of the hot-rolled steel sheet. To obtain targeted properties, a skilled person must select Ta to favor recrystallization of ferrite. Annealing at too low a temperature limits recrystallization of ferrite and promotes carbides at grain boundaries, decreasing toughness of the steel sheet. Preferably Ta is comprised between 500° C. and Ac1.

[0057] After hot band annealing, density of carbides at grain boundary is less than 5 carbides per 10 μm of grain boundary length, improving toughness of the steel. The hot rolled and annealed steel sheet is then cooled to room temperature.

[0058] The hot rolled and annealed steel sheet has good properties of toughness and hardness making further process possible. For example, the hot rolled and annealed steel sheet can then be cold rolled to obtain a cold rolled steel sheet having a thickness that can be, for example, between 0.7 mm and 3 mm, or even better in the range of 0.8 mm to 2 mm. The cold-rolling reduction ratio is preferably comprised between 20% and 80%.

[0059] The invention will be now illustrated by the following examples, which are by no way limiting.

Example 1

[0060] 3 grades, whose compositions are gathered in table 1, were cast in semi-finished products and processed into steel sheets following the process parameters gathered in table 2.

TABLE-US-00001 TABLE 1 Compositions The tested compositions are gathered in the following table wherein the element contents are expressed in weight percent. Steel C Mn Si B S P N Ti Mo Al Ac1(° C.) Ms(° C.) A 0.18 3.94 1.29 0.0022 0.002 0.01 0.002 0.023 0.19 0.03 640 328 B 0.18 3.85 1.27 0.0024 0.002 0.01 0.003 0.026 0.21 0.6 655 339 C 0.18 3.96 1.48 0.0022 0.002 0.01 0.002 0.024 0.19 0.03 640 325 Steels A-C are according to the invention.

[0061] Ac1 temperature has been determined through dilatometry tests and metallography analysis.

TABLE-US-00002 TABLE 2 Process parameters Steel semi-products, as cast, were reheated at 1200° C. during 1800 s, hot rolled and then coiled before the hot band annealing. The following specific conditions were applied: FRT Annealing Trial Steel (° C.) T.sub.Coil (° C.) Ta (° C.) ta (h) 1 A 950 450 620 23 2 A 900 450 620 23 3 A 850 450 620 23 4 A 800 450 620 23 5 B 950 450 620 23 6 B 900 450 620 23 7 B 850 450 620 23 8 B 800 450 620 23 9 C 950 450 620 23 10 C 900 450 620 23 11 C 850 450 620 23 12 C 800 450 620 23

[0062] The hot rolled and annealed sheets were then analyzed and the corresponding microstructure elements and mechanical properties were respectively gathered in table 3 and 4.

TABLE-US-00003 TABLE 3 Microstructure of the hot rolled and annealed steel sheet The phase percentages of the microstructures of the obtained hot rolled and annealed steel sheet were determined: Density of Recrystallized Non- carbides at grain ferrite with Recrystallized recrystallized boundary size > 5 Trial ferrite (%) ferrite (%) (number/10 μm) μm (%)  1  20 80 5 15  2  40 60 4 30  3  95  5 2 65  4  98  2 1.5 75  5   5 95 6  0  6  10 90 5  1  7  98  2 2 80  8 100  0 2 80  9   5 95 6  0 10   5 95 5  1 11  25 75 5  7 12  80 20 4 40 Underlined values: not corresponding to the invention

[0063] The surface fractions are determined through the following method: a specimen is cut from the hot rolled and annealed, polished and etched with a reagent known per se, to reveal the microstructure. The section is afterwards examined through scanning electron microscope, for example with a Scanning Electron Microscope with a Field Emission Gun (“FEG-SEM”) at a magnification greater than 5000×, in both secondary electron mode and back scattered electron mode.

TABLE-US-00004 TABLE 4 Mechanical properties of the hot rolled and annealed steel sheet Mechanical properties of the tested samples were determined and gathered in the following table: Charpy impact energy Trial (J/mm.sup.2) Hardness (HV)  1 0.40 278  2 0.49 263  3 0.69 211  4 0.70 204  5 0.34 285  6 0.30 293  7 0.69 210  8 0.66 214  9 0.31 296 10 0.28 290 11 0.30 269 12 0.44 221 Underlined values: do not match the targeted values

[0064] To obtain targeted properties, skilled person must select finish rolling temperature FRT in order to favor matrix recrystallization after annealing.

[0065] In order to obtain a final hot rolled and annealed steel sheet with more than 20% of recrystallized ferrite, the balance being non-recrystallized ferrite, trials have been carried out with FRT of 800° C., 850° C., 900° C. and 950° C., before being annealed at a temperature Ta of 620° C. during a time to of 23h.

[0066] In trials 1-4, steel A is hot rolled with a FRT of 950° C., 900° C., 850° C. and 800° C. respectively. These examples show all targeted properties thanks to their specific composition and microstructure.

[0067] In Trials 5-8, steel B is hot rolled with FRT of 800° C., 850° C., 900° C. and 950° C.

[0068] The high FRT of trials 5 and 6 respectively 950° C. and 900° C., leads to a level of recrystallized ferrite after annealing of 5% and 10%, smaller than the desired level. In trials 7-8, more than 98% of ferrite is recrystallized thanks to the low level of FRT of 850° C. and 800° C.

[0069] In trials 9-12, steel C is hot rolled with FRT of 800° C., 850° C., 900° C. and 950° C.

[0070] In this case, a FRT higher than 900° C. implies a microstructure out of the invention. For trials 9-11, the density of carbides at grain boundary is higher than the desired level, leading to a low toughness of the steel.

Example 2

[0071] 1 grade, whose composition is gathered in table 6, was cast in semi-products and processed into steel sheets following the process parameters gathered in table 7.

TABLE-US-00005 TABLE 6 Chemical composition Steel C Mn Si B S P N Ti Nb Mo Al Ac1(° C.) Ms(° C.) D 0.19 3.86 1.27 0.0021 0.001 0.01 0.003 0.029 0.02 0.20 0.39 650 331 Steel D is according to the invention.

TABLE-US-00006 TABLE 7 Process parameters Steel semi-products, as cast, were reheated at 1200° C. during 1800 s, hot rolled and then coiled before a hot band annealing. The following specific conditions were applied: FRT Annealing Trial Steel (° C.) T.sub.Coil (° C.) Ta (° C.) ta (h) 13 D 845 300 594 23 14 D 845 300 605 7 15 D 845 300 619 7 16 D 845 300 633 7 17 D 845 300 648 7

[0072] The hot rolled and annealed sheets were then analyzed, and the corresponding microstructure elements and mechanical property were respectively gathered in table 8 and 9.

TABLE-US-00007 TABLE 8 Microstructure of the hot rolled and annealed steel sheet The phase percentages of the microstructures of the obtained hot rolled and annealed steel sheet were determined: Density of Recrystallized Non- carbides at grain ferrite with Recrystallized recrystallized boundary size > 5 Trial ferrite (%) ferrite (%) (number/10 μm) μm (%) 13  5 95 10  0 14 30 70  6  7 15 45 55  3 40 16 55 45  2 48 17 60 40  1.5 50 Underlined values: not corresponding to the invention

[0073] The surface fractions are determined through the following method: a specimen is cut from the hot rolled and annealed, polished and etched with a reagent known per se, to reveal the microstructure. The section is afterwards examined through scanning electron microscope, for example with a Scanning Electron Microscope with a Field Emission Gun (“FEG-SEM”) at a magnification greater than 5000×, in both secondary electron mode and back scattered electron mode.

TABLE-US-00008 TABLE 9 Mechanical properties of the hot rolled and annealed steel sheet Mechanical properties of the tested samples were determined and gathered in the following table: Charpy impact energy Trial (J/mm.sup.2) Hardness (HV) 13 0.20 324 14 0.26 300 15 0.41 271 16 0.53 235 17 0.56 223 Underlined values: not corresponding to the invention

[0074] Trials 13-17 have been performed with a FRT of 845° C. and by varying the annealing temperature Ta, in order to obtain a final annealed steel sheet with more than 20% of recrystallized ferrite, the balance being non-recrystallized ferrite, and to limit carbides at grain boundaries.

[0075] If Ta is too low, as in trials 13 and 14, ferrite is not sufficiently recrystallized, and steel is too hard. The high quantity of carbides formed at grain boundary reduce toughness of the steel.