Method for the removing and reducing scaling

Abstract

The invention relates to improved elimination of scale in processing systems. The method removes existing scale while also eliminating buildup. The invention relates to phosphate and sulfate scale. The invention further allows for improved anti-scaling without the need to make any pH adjustments. The method provides all factor listed while in no way compromises the integrity of membranes that may be used in the system.

Claims

1. A method, comprising: adding an effective amount of a trimethylglycine composition into a water purification system comprising a membrane in order to reduce calcium phosphate scaling and scale buildup in the water purification system, wherein the trimethylglycine composition controls the initiation of the calcium phosphate scale nucleation, and mitigates its growth, wherein the trimethylglycine composition includes one or more of the following compounds selected from the group consisting of trimethylglycine hydrochloride and trimethylglycine-citric acid, wherein the trimethylglycine composition is put into the water purification system without the need for pH adjustment, and wherein the effective amount is between 0.2 ppm and 0.8 ppm.

2. The method of claim 1, wherein the trimethylglycine composition added in a concentration proportionate to a concentration of the scale in the water purification system.

3. The method of claim 1 wherein the trimethylglycine composition is added to the water purification system consistently.

4. The method of claim 1 wherein the trimethylglycine composition is added to the water purification system intermittently.

5. A method, consisting of: adding a scale inhibitor composition into a water purification system comprising a membrane, wherein the scale inhibitor composition consists of trimethylglycine hydrochloride.

6. The method of claim 5, wherein the scale inhibitor composition is added to the water purification system in an amount ranging from 0.2 ppm to 0.8 ppm.

7. The method of claim 5, wherein the scale inhibitor composition is added to the water purification system in an amount of 0.2 ppm.

8. A method, consisting of: adding a scale inhibitor composition into a water purification system comprising a membrane, wherein the scale inhibitor composition consists of a chemical of formula C.sub.5H.sub.11NO.sub.2.HCl.

Description

DETAILED DESCRIPTION

(1) The invention is a method for the reduction and/or control of scaling in a system with the addition of a trimethylglycine composition into the system reducing scaling and scale buildup. The trimethylglycine composition that is used in the method may include one or more of the following: trimethylglycine hydrochloride, carboxymethyl, betaine hydrochloride, trimethylammonium chloride and N,N,N-trimethylglycine hydrochloride, trimethylglycine-potassium hydroxide and/or trimethylglycine-citric acid. The most preferred trimethylglycine composition is trimethylglycine hydrochloride.

(2) The invention can be used with various systems and in one embodiment it is used in a water purification system. The system allows for the safe use of a membrane within the process. The current invention allows the membrane to maintain its integrity and can also increase its effectiveness by reducing any scale that can effect the membrane.

(3) The method has the trimethylglycine composition added in a concentration proportionate to the concentration of the scale in the system. The composition is preferable added in a concentration of greater than or equal to 0.2 ppm. The composition can also be added in a concentration equal to or less than 25 ppm. The invention can also use one or more anti scaling or cleaning composition in addition to the trimethylglycine composition. The method can be used with phosphate or sulfate scale.

(4) The trimethylglycine composition of the claimed invention may be a zwitterionic molecule. The zwitterionic molecule may have a trimethylammonium group and a carboxylate group connected by a single methylene group with a chloride group. The trimethylglycine composition in the claimed invention may be is added to the processing system consistently or intermittently. The invention also allows for the addition of trimethylglycine composition and eliminates the need for any pH adjustment by any means.

EXAMPLES

(5) The foregoing may be better understood by reference to the following examples, which are intended to illustrate methods for carrying out the invention and are not intended to limit the scope of the invention. The current experiments were run at 25 degrees Celsius and 45 minute induction periods. The process consisted of the use of 130 ml deionized water in an Erlenmeyer flask charged with a stir bar, standard solutions containing ions of 1.0 M NaCl (25 ml), 0.1 M Na.sub.2HPO.sub.4 (0.016 ml), and 0.1 M CaCl.sub.2 (40.0 ml) were added. If an antis-calant was evaluated then it was added at this step with the appropriate volume of deionized water added to experiment to keep the over all total volumes the same and thus ion concentrations the same. Then turbidity was measured using a handheld turbidity meter (aliquots removed for measurements were returned to mother liquid) and pH was measured using a VWR symphony pH meter. After 45 minutes the turbidity and pH were measured again followed by the addition of 0.1 M Na.sub.2HPO.sub.4. Finally the steps were repeated until the turbidity at the end of a 45 min period measured above 2.0 NTU, which concluded the experiment for that water chemistry.

(6) Ultimately, the collective data from a group experiments allows for the identification of scale initiation and scale failure for critical phosphate concentrations of ATMP (1 and 12.5 ppm), AA/AMPS (8.25 ppm), and TMG HCl (0.8 and 10 ppm). Table 1 gives the compilation of data to demonstrate the effectiveness of TMG and to some degree the ineffectiveness of AMP. AA/AMPS is a calcium phosphate anti-scalant used in cooling water and boiler applications with limited use in membrane applications at low concentrations for assured membrane compatibility.

(7) TABLE-US-00001 TABLE 1 Compilation of critical phosphate concentrations for various experiments. Phosphate Phosphate Concentration at Concentration at Scale Initiation Scale Failure (NTU > 0.3) (NTU > 2.0) Control 0 ppm 34 48.5 AMP 1 ppm 34 48.5 12.5 ppm 19.4 38.8 AA/AMPS 8.25 ppm 38.8 58.1 TMG HCl 0.8 ppm 43.6 53.3 10 ppm 53.3 62.9

(8) A follow-up experimental set was conducted to determine if the effect seen in the first set was from mitigation of calcium phosphate scale or from changes to the pH of the solutions. In addition to repeating the control and the TMG HCl work, a third experiment was prepared with the pH adjusted to be the same as the TMG HCl at 10 ppm. The water chemistry and experimental protocol is identical to the procedure used in example 1. These results prove the effect TMG HCl controls the initiation of calcium phosphate scale (nucleation) and mitigates the growth in some manner.

(9) TABLE-US-00002 TABLE 2 Compilation of critical phosphate concentrations for various experiments. Phosphate Phosphate Concentration at Concentration at Scale Initiation Scale Failure (NTU > 0.3) (NTU > 2.0) Control 0 ppm 24.3 43.6 HCl 38.8 53.3 TMG HCl 10 ppm 53.3 62.9
Phosphate Test for 10 ppm Trimethylglycine

(10) Tests were run to determine the types of phosphates present at the on-set of scale in the presence of TMG HCl at 10 ppm. The experiment was carried to the point of having 53.3 ppm phosphate added which gives a pH of 6.96 and turbidity of 0.74. The effectiveness of TMG as an inhibitor of calcium phosphate scale is corroborated by data showing 95% of the total phosphate measured as orthophosphate. This data indicates that scale is occurring, but the growth event is inhibited by the trimethylglycine.

(11) TABLE-US-00003 TABLE 3 Measured phosphate levels by filtered and unfiltered methods (total, inorganic, and ortho) along with the calculated values for filtered and unfiltered organic phosphate. Phosphate Types Filtered Unfiltered Total 54.5 ppm 55.5 ppm Inorganic 52.5 52.5 Ortho 52.0 53.0
Compatibility Tests for Trimethylglycine on ESPA1 Membrane

(12) Membrane compatibility tests were run to evaluate trimethylglycine using Hydronautics ESPA1 membranes and an Osmonics flat plate membrane system. To date dosages of 10, 20, and 40 ppm trimethylglycine hydrochloride have been run, with return to control levels for all parameters. During exposure of trimethylglycine there was a decrease in permeate conductivity (27% for 20 ppm and 40% for 40 ppm) with a slight increase in flux (0.7%) when running at 20 ppm trimethylglycine and a decrease in flux (1.8%) when running at 40 ppm trimethylglycine. For all sodium chloride controls all parameters have returned to original conditions. It is worth noting that these experiments were run evaluating actives concentrations. This is much higher what would be expected in the reject water of most systems and water chemistries.