BACK-ILLUMINATED SENSOR AND A METHOD OF MANUFACTURING A SENSOR
20200194476 ยท 2020-06-18
Inventors
- Yung-Ho Alex Chuang (Cupertino, CA, US)
- Jehn-Huar Chern (Morgan Hill, CA, US)
- John Fielden (Los Altos, CA)
- Jingjing Zhang (San Jose, CA, US)
- David L. Brown (Los Gatos, CA, US)
- Sisir Yalamanchili (Milpitas, CA, US)
Cpc classification
International classification
Abstract
An image sensor utilizes a pure boron layer and a second epitaxial layer having a p-type dopant concentration gradient to enhance sensing DUV, VUV or EUV radiation. Sensing (circuit) elements and associated metal interconnects are fabricated on an upper surface of a first epitaxial layer, then the second epitaxial layer is formed on a lower surface of the first epitaxial layer, and then a pure boron layer is formed on the second epitaxial layer. The p-type dopant concentration gradient is generated by systematically increasing a concentration of p-type dopant in the gas used during deposition/growth of the second epitaxial layer such that a lowest p-type dopant concentration of the second epitaxial layer occurs immediately adjacent to the interface with the first epitaxial layer, and such that a highest p-type dopant concentration of the second epitaxial layer occurs immediately adjacent to the interface with pure boron layer.
Claims
1. A method of fabricating an image sensor, the method comprising: forming a first epitaxial layer on a substrate; forming a circuit element first epitaxial layer; thinning the substrate to generate a thinned substrate, the thinned substrate exposing at least a surface portion of the first epitaxial layer; forming a second epitaxial layer on the exposed portion of the first epitaxial layer; and forming a pure boron layer on the second epitaxial layer, wherein forming the second epitaxial layer includes generating a p-type dopant concentration gradient in the second epitaxial layer by gradually increasing a concentration of a p-type dopant used during formation of the second epitaxial layer such that a first layer portion of the second epitaxial layer has a lower p-type dopant concentration than a subsequently formed second layer portion of the second epitaxial layer, and a highest p-type dopant concentration of the second epitaxial layer is adjacent to the pure boron layer.
2. The method of claim 1, wherein the p-type dopant comprises boron.
3. The method of claim 1, wherein forming the second epitaxial layer comprises utilizing a gas containing elemental boron at a temperature lower than about 350 C.
4. The method of claim 3, wherein forming the second epitaxial layer comprises growing said second epitaxial layer using molecular-beam epitaxial growth.
5. The method of claim 1, wherein the method further comprises depositing an anti-reflection layer on a surface of the pure boron layer.
6. The method of claim 1, wherein the method further comprises depositing a metal protective layer on the surface of the pure boron layer.
7. The method of claim 1, wherein the method further comprises attaching a handling wafer to the first epitaxial layer over the circuit elements prior to thinning the substrate.
8. The method of claim 7, wherein the method further comprises forming vias in at least one of the first epitaxial layer and the handling wafer prior to thinning the substrate.
9. The method of claim 8, wherein the method further comprises exposing the vias after forming the pure boron layer.
10. The method of claim 1, wherein forming the second epitaxial layer comprises utilizing a plasma-enhanced chemical vapor deposition process at a temperature lower than about 450 C.
11. An image sensor for sensing at least one of deep ultraviolet (DUV) radiation, vacuum ultraviolet (VUV) radiation, extreme ultraviolet (EUV) radiation, and charged particles, the image sensor comprising: a semiconductor membrane comprising a first epitaxial layer and including circuit elements and metal interconnects formed on a first surface of the first epitaxial layer; a second epitaxial layer formed on a second surface of the first epitaxial layer; and a pure boron layer formed on the second epitaxial layer, wherein the second epitaxial layer includes a p-type dopant concentration gradient that has a minimum p-type doping concentration adjacent to the second surface of the first epitaxial layer and has a maximum p-type doping concentration immediately adjacent to the pure layer boron layer.
12. The image sensor of claim 11, wherein the first epitaxial layer has a thickness in the range of about 10 m to about 40 m.
13. The image sensor of claim 12, wherein the pure boron layer has a thickness in the range of 2 nm to 20 nm.
14. The image sensor of claim 11, further comprising an anti-reflection coating deposited on the pure boron layer.
15. The image sensor of claim 11, further comprising a handling wafer attached to the first epitaxial layer over the circuit elements.
16. The image sensor of claim 11, further comprising a protective layer formed on the first epitaxial layer over the circuit elements.
17. The image sensor of claim 11, wherein the p-type dopant comprises boron.
18. The image sensor of claim 13, wherein the image sensor comprises a charge-coupled device (CCD) or a CMOS device.
19. An image sensor for sensing at least one of deep ultraviolet (DUV) radiation, vacuum ultraviolet (VUV) radiation, extreme ultraviolet (EUV) radiation, and charged particles, the image sensor comprising: a semiconductor membrane comprising a first epitaxial layer and including circuit elements formed on a first surface thereof, and metal interconnects connected to at least one of said circuit elements; a second epitaxial layer formed on a second surface of the first epitaxial layer; and a pure boron layer formed on the second epitaxial layer, wherein the second epitaxial layer includes a p-type dopant concentration gradient configured such that a first layer portion of the second epitaxial layer has a lower p-type dopant concentration than a second layer portion of the second epitaxial layer, and includes a p-type dopant maximum concentration immediately adjacent to the pure boron layer, said second epitaxial layer being disposed between said first layer portion and the pure boron layer.
20. The image sensor of claim 19, wherein the pure boron layer has a thickness in the range of 2 nm to 20 nm, and wherein the semiconductor membrane has a thickness in the range of 10 m to 40 m.
21. The image sensor of claim 19, the image sensor further comprising one of an anti-reflection and a protective layer disposed on the pure boron layer, wherein the pure boron layer is between 3 nm and 10 nm thick.
22. The image sensor of claim 19, wherein p-type dopant consists of boron.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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[0024]
DETAILED DESCRIPTION OF THE DRAWINGS
[0025] Although claimed subject matter will be described in terms of certain embodiments, other embodiments, including embodiments that do not provide all of the benefits and features set forth herein, are also within the scope of this disclosure. Various structural, logical, process step, and electronic changes may be made without departing from the scope of the disclosure. Accordingly, the scope of the disclosure is defined only by reference to the appended claims.
[0026] The following description is presented to enable one of ordinary skill in the art to make and use the disclosure as provided in the context of a particular application and its requirements. As used herein, directional terms such as top, bottom,, front, back, over, under, upper, upward, lower, down, and downward are intended to provide relative positions for purposes of description, and are not intended to designate an absolute frame of reference. Various modifications to the preferred embodiment will be apparent to those with skill in the art, and the general principles defined herein may be applied to other embodiments. Therefore, the present disclosure is not intended to be limited to the particular embodiments shown and described, but is to be accorded the widest scope consistent with the principles and novel features herein disclosed.
[0027]
[0028] In one embodiment, first epitaxial layer 101 comprises a layer of lightly p-doped epitaxial silicon having a thickness T1 in a range of 10 m to 40 m and a p-type (e.g., boron) dopant concentration in a range of about 10.sup.13 cm.sup.3 to 10.sup.14 cm.sup.3.
[0029] Circuit element 103 includes a sensor device (e.g., a light sensitive device such as a photodiode) and associated control transistors that are formed on (i.e., into and over) an upper (first) surface 101U of first epitaxial layer 101 using known techniques. In the depicted exemplary embodiment, circuit element 103 includes spaced-apart n+ doped diffusion regions 103-11, 103-12 and 103-12 that extend from upper surface 101U into corresponding portions of epitaxial layer 101, and polycrystalline silicon (polysilicon) gate structures 103-21 and 103-22 that are respectively separated from upper surface 101U by intervening gate oxide layers. First metal interconnects 110 and second metal interconnects 120, along with corresponding first metal vias 115 and second metal vias 125, are formed over circuit element 113 and are operably electrically connected to associated regions of circuit element 113 using known techniques. First metal interconnects 110 are formed in or on one or more dielectric layers 112 deposited over circuit element 113, and first metal vias 115 extend through dielectric layers 112 using known via formation techniques. Second metal interconnects 120 are formed in a second dielectric layer 122 that is disposed over first metal interconnects 110, and second metal vias 125 extend through one or both dielectric layers 112 and 122. In one embodiment, a protection layer (not shown in
[0030] Second epitaxial layer 101 is disposed on lower surface 101L of first epitaxial layer 101 and has a thickness T2 in the range of 1 nm to 100 nm, and more preferably in the range of about 2 nm and about 20 nm.
[0031] Referring to the bubble located at the bottom of
[0032] In one embodiment, pure boron layer 106 is formed using techniques described below such that pure boron layer 106 has a thickness T3 in the range of 2 nm and 10 nm. In one embodiment, pure boron layer 106 comprises a boron concentration of 80% or higher, with inter-diffused silicon atoms and oxygen atoms predominantly making up the remaining 20% or less.
[0033] In one specific embodiment, thickness T3 of pure boron layer 106 is in the range of 3 nm to 10 nm, and optional anti-reflection coating 108 comprises a silicon dioxide layer deposited on a lower (outward-facing) surface 106L of pure boron layer 106.
[0034]
[0035] In step 203, the front-side surface of the wafer can be protected. This protection may include depositing one or more protective layers on top of the circuit elements formed during step 201. The one or more protective layers may comprise silicon dioxide, silicon nitride or other material. This protection may include attaching the wafer to a handling wafer, such as a silicon wafer, a quartz wafer, or a wafer made of other material. The handling wafer may include through-wafer vias for connecting to the circuit elements.
[0036] Step 205 involves thinning the wafer from the back-side so as to expose the first epitaxial layer in, at least, the active sensor areas. This step may involve polishing, etching, or both. In some embodiments, the entire wafer is back-thinned. In other embodiments, only the active sensor areas are thinned all the way to the first epitaxial layer.
[0037] Step 207 includes cleaning and preparing the back-side surface prior to deposition of a second epitaxial layer. During this cleaning, the native oxide and any contaminants, including organics and metals, should be removed from the back-side surface. In one embodiment, this cleaning can be performed using a dilute HF solution or using an RCA clean process. After cleaning, the wafer can be dried using the Marangoni drying technique or a similar technique to leave the surface dry and free of water marks.
[0038] In preferred embodiments, the wafer is protected in a controlled environment between steps 207 and 208 (e.g. in a vacuum environment or in an environment purged with a dry, inert gas such as nitrogen) to minimize native oxide regrowth after the cleaning.
[0039] In step 208, a second epitaxial silicon layer is grown (deposited) on, at least, the exposed portion of the first epitaxial layer. In one embodiment the second epitaxial layer is grown by molecular-beam epitaxy (MBE) or other process at a temperature of about 350 C. or lower. In another embodiment, the second epitaxial layer is grown by a chemical vapor deposition (CVD) or plasma-enhanced CVD (PECVD) process at a temperature of about 450 C. or lower. As depicted in
[0040] In step 209, boron is deposited on the surface of the second epitaxial layer. In one preferred embodiment, this deposition can be done using diborane, or a diborane-hydrogen mixture, diluted in nitrogen at a temperature between about 300 C. and about 450 C., thereby creating a high-purity amorphous boron layer. In an alternative embodiment, the deposition may be done at a temperature lower than about 350 C., for example, by using a gas containing elemental boron. The thickness of the deposited boron layer depends on the intended application for the sensor. Typically, the boron layer thickness will be between about 2 nm and 20 nm, preferably between about 3 nm and 10 nm. The minimum thickness is set by the need for a pinhole-free uniform film, whereas the maximum thickness depends on the absorption of the photons or charged particles of interest by the boron, as well as the maximum length of time that the wafer can be kept at the deposition temperature.
[0041] More details on depositing boron from diborane gas can be found in Chemical vapor deposition of a-boron layers on silicon for controlled nanometer-deep p.sup.+-n junction formation, Sarubbi et al., J. Electron. Material, vol. 39, pp. 162-173, 2010, which is incorporated by reference herein.
[0042] After step 209, other layers may be deposited on top of the boron layer. These other layers may include anti-reflection coatings comprised of one or more materials, such as silicon dioxide, silicon nitride, aluminum oxide, hafnium dioxide, magnesium fluoride, and lithium fluoride. These other layers may include a thin protective layer comprising a metal such as aluminum, ruthenium, tungsten or molybdenum. One or more of these other layers may be deposited using ALD. An advantage of using an ALD process for depositing these layers is that ALD processes typically allow very precise (single monolayer) control of the thickness of the deposited layer(s). In an alternative embodiment, other layers may be deposited on top of the boron layer after step 213.
[0043] In one embodiment, the protective front-side layer may be removed in step 213. In another embodiment, in step 213, holes or vias can be opened or exposed in the handling wafer and/or protective front-side layer, or through-silicon vias around the edges of the device can be exposed, thereby allowing connection to the circuit elements.
[0044] In step 215, the resulting structure may be packed in a suitable package. The packing step may comprise flip-chip bonding or wire bonding of the device to a substrate. The package may include a window that transmits wavelengths of interest, or may comprise a flange or seal for interface to a vacuum seal.
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[0053] The above examples are not meant to limit the scope of the invention disclosed herein. They are meant merely as illustrations of how a p-type doped second epitaxial layer may be deposited on a back-side surface of a first epitaxial layer. The second epitaxial layer is subsequently coated with a boron layer on its photo-sensitive surface. Because the second epitaxial layer includes a concentration gradient of the p-type dopant which has its maximum value adjacent to the boron, the image sensor has high efficiency even for short-wavelength light, or low-energy charged particles, which may penetrate only a few nm, or a few tens of nm into the epitaxial layers.
[0054]
[0055] In one aspect of the present invention, the detector assembly 500 may include one or more light sensitive sensors 504 disposed on the surface of an interposer 502. In one embodiment, the one or more interposers 502 of the assembly 500 may include, but are not limited to, a silicon interposer. In a further aspect of the present invention, the one or more light sensitive sensors 504 of the assembly 500 are back-thinned and further configured for back-illumination including a boron layer and a p-type doped second epitaxial layer adjacent to the boron layer as described above.
[0056] In another aspect of the present invention, various circuit elements of the assembly 500 may be disposed on or built into the interposer 502. In one embodiment, one or more amplification circuits (e.g., charge conversion amplifier) (not shown) may be disposed on or built into the interposer 502. In another embodiment, one or more conversion circuits 508 (e.g., analog-to-digital conversion circuits, i.e. digitizers 508) may be disposed on or built into the interposer 502. In another embodiment, one or more driver circuits 506 may be disposed on or built into the interposer 502. For example, the one or more driver circuits 506 may include a timing/serial drive circuit. For instance, the one or more driver circuits 506 may include, but are not limited to, clock driver circuitry or reset driver circuitry. In another embodiment, one or more decoupling capacitors (not shown) may be disposed on or built into the interposer 502. In a further embodiment, one or more serial transmitters (not shown in
[0057] In another aspect of the present invention, one or more support structures may be disposed between the bottom surface of the light sensitive array sensor 504 and the top surface of the interposer 502 in order to provide physical support to the sensor 504. In one embodiment, a plurality of solder balls 516 may be disposed between the bottom surface of the light sensitive array sensor 504 and the top surface of the interposer 502 in order to provide physical support to the sensor 504. It is recognized herein that while the imaging region of the sensor 504 might not include external electrical connections, the back-thinning of the sensor 504 causes the sensor 504 to become increasingly flexible. As such, solder balls 516 may be utilized to connect the sensor 504 to the interposer 502 in a manner that reinforces the imaging portion of the sensor 504. In an alternative embodiment, an underfill material may be disposed between the bottom surface of the light sensitive array sensor 504 and the top surface of the interposer 502 in order to provide physical support to the sensor 504. For example, an epoxy resin may be disposed between the bottom surface of the light sensitive array sensor 504 and the top surface of the interposer 502.
[0058] In another aspect of the present invention, the interposer 502 and the various additional circuitry (e.g., amplification circuit, driver circuits 506, digitizer circuits 508, and the like) are disposed on a surface of a substrate 510. In a further aspect, the substrate 510 includes a substrate having high thermal conductivity (e.g., ceramic substrate). In this regard, the substrate 510 is configured to provide physical support to the sensor 504/interposer 502 assembly, while also providing a means for the assembly 500 to efficiently conduct heat away from the imaging sensor 504 and the various other circuitry (e.g., digitizer 506, driver circuitry 508, amplifier, and the like). It is recognized herein that the substrate may include any rigid highly heat conductive substrate material known in the art. For example, the substrate 510 may include, but is not limited to, a ceramic substrate. For instance, the substrate 510 may include, but is not limited to, aluminum nitride.
[0059] In another embodiment, the substrate 510 may be configured to provide an interface to a socket or an underlying printed circuit board (PCB). For example, as shown in
[0060] The various embodiments of the structures and methods of this invention that are described above are illustrative only of the principles of this invention and are not intended to limit the scope of the invention to the particular embodiments described. For example, additional steps may be added to the flow chart depicted in