Apparatus and method for preparing bisphenol A

Abstract

The present application relates to a bisphenol A preparation apparatus and preparation method, and provides a bisphenol A preparation apparatus and preparation method, which can increase the overall energy efficiency of a process by using an internal heating source.

Claims

1. A method for preparing bisphenol A comprising steps of: crystallizing bisphenol A through a first crystallizer in a bisphenol A concentration stream comprising a reaction product that phenol and acetone are reacted and discharging the adduct of crystallized bisphenol A and phenol; separating the adduct of crystallized bisphenol A and phenol in said first crystallizer from the mother liquor through a first solid-liquid separator and discharging it; introducing a phenol stream into the adduct of crystallized bisphenol A and phenol discharged from said first solid-liquid separator through a phenol introduction port and discharging a mixed stream of the phenol with said adduct of crystallized bisphenol A and phenol; heating said phenol stream through a first heat exchanger before introducing the phenol stream through said phenol introduction port; melting the adduct of crystallized bisphenol A and phenol in the mixed stream flowing out from said phenol introduction port through a second heat exchanger to discharge a molten stream; and introducing said discharged molten stream to recrystallize bisphenol A through a second crystallizer.

2. The method for preparing bisphenol A according to claim 1, wherein the first heat exchanger comprises a separation line for separating pentane present in said phenol stream.

3. The method for preparing bisphenol A according to claim 2, further comprising a step of separating pentane in the phenol stream through a separation line of the first heat exchanger.

4. The method for preparing bisphenol A according to claim 1, wherein the introduction of the phenol stream comprises introducing phenol in a range of 40 C. to 100 C. through the phenol introduction port.

5. The method for preparing bisphenol A according to claim 1, wherein the introduction of the phenol stream comprises introducing phenol having a flow rate of 10 ton/hr to 50 ton/hr through the phenol introduction port.

6. The method for preparing bisphenol A according to claim 1, wherein the mixed stream is discharged from the phenol introduction port at a flow rate of 30 to 200 ton/hr.

7. The method for preparing bisphenol A according to claim 1, wherein the molten stream is in a range of from 70 C. to 200 C.

8. The method for preparing bisphenol A according to claim 1, wherein the molten stream comprises 20 wt % to 60 wt % of bisphenol A.

9. The method for preparing bisphenol A according to claim 2, wherein the separation line introduces separated pentane into the second crystallizer.

10. The method for preparing bisphenol A according to claim 1, wherein the first heat exchanger heats the phenol stream by introducing a heat source of 120 C. or lower.

11. The method for preparing bisphenol A according to claim 9, wherein the first heat exchanger comprises a vent for discharging pentane and said vent is connected to the separation line to separate pentane.

12. The method for preparing bisphenol A according to claim 1, wherein the second heat exchanger melts the adduct of crystallized bisphenol A and phenol by introducing steam having a pressure of 200 kPa to 500 kPa.

13. The method for preparing bisphenol A according to claim 1, comprising returning the adduct of crystallized bisphenol A and phenol discharged from the first solid-liquid separator via a return line, wherein said return line comprises the second heat exchanger and the phenol introduction port, and a stream flowing out through said return line is again mixed with the adduct of crystallized bisphenol A and phenol discharged from the first solid-liquid separator.

14. The method for preparing bisphenol A according to claim 1, further comprising reacting phenol and acetone in a main reactor, discharging a reaction product from the main reactor via a reaction product stream, and introducing said reaction product stream into a flasher, and separating the reaction product stream into a bisphenol A concentration stream and a phenol concentration stream, wherein the bisphenol A concentration stream separated from said flasher is introduced into the first crystallizer and the mother liquid stream separated in the first solid-liquid separator flows out to said main reactor.

15. The method for preparing bisphenol A according to claim 1, further comprising separating the adduct of crystallized bisphenol A and phenol, and the mother liquid, flowing out from the second crystallizer in a second solid-liquid separator.

16. The method for preparing bisphenol A according to claim 15, further comprising discharging the molten stream of the adduct of crystallized bisphenol A and phenol discharged from the second solid-liquid separator via a bisphenol A refining line.

17. The method for preparing bisphenol A according to claim 16, further comprising introducing a molten stream flowing out through the bisphenol A refining line into a bisphenol A refining drum.

Description

BRIEF DESCRIPTION OF DRAWINGS

(1) FIG. 1 is a process diagram showing a conventional apparatus for preparing bisphenol A.

(2) FIGS. 2 to 4 are process diagrams showing apparatuses for preparing bisphenol A according to the present application.

EXPLANATION OF REFERENCE NUMERALS

(3) 10: bisphenol A concentration stream 11: molten stream 12: mixed stream 13: phenol stream 14: mother liquid stream 15: bisphenol A refining line 16: product stream 17: separation line 18: return line 21: second heat exchanger 22: phenol introduction port 23: first heat exchanger 31: first crystallizer 32: first solid-liquid separator 33: second crystallizer 34: second solid-liquid separator 35: bisphenol A refining drum

BEST MODE

(4) Hereinafter, the apparatus and method for preparing bisphenol A will be described in detail with reference to the following Examples, but the scope of the production apparatus and the production method is not limited by the following Examples.

Example 1

(5) Bisphenol A was prepared using the production apparatus and processes of FIG. 2. Phenol and acetone were introduced to the main reactor at a weight ratio of 9:1 and reacted at 60 C., and then water was removed from the reaction product by vaporization in a dehydrator at 178 C. and 550 mmHg, and the water-removed reaction product was supplied to the flasher. A bisphenol A concentration stream (10) excluding the phenol vaporized in the flasher is introduced into the first crystallizer (31) to produce a suspension comprising an adduct of crystallized bisphenol A and phenol. The suspension is supplied to a rotary centrifuge as the first solid-liquid separator (32), and the adduct of crystallized bisphenol A and phenol excluding the liquid phase portion separated in the rotary centrifuge is discharged. A phenol stream (13) is introduced into the discharged adduct of crystallized bisphenol A and phenol through the phenol introduction port (22). The phenol stream (13) is 58.2 C., but it is heated by a heat source of about 100 C. through the first heat exchanger (23) and introduced through the phenol introduction port (22) at a flow rate of 35 ton/hr in a state elevated to 90 C. Another phenol stream from the phenol stream (13) is introduced into the second crystallizer (33) to be described below at a flow rate of 29 ton/hr. The mixed stream (12) in which the phenol stream (13) is mixed has a flow rate of 129 ton/hr and is heated and melted with a low pressure steam of 300 kPa through the second heat exchanger (21). The melted molten stream is finally introduced into the second crystallizer (33). The molten stream is separated into the adduct of crystallized bisphenol A and phenol via the second crystallizer (33) and the second solid-liquid separator, and the adduct is discharged to the bisphenol A refining drum through the bisphenol A refining line to produce bisphenol A.

(6) The heat quantity of the steam used in the second heat exchanger was 1.298 Gcal/hr.

Example 2

(7) Bisphenol A was prepared using the production apparatus and processes of FIG. 4.

(8) Phenol and acetone were introduced to the main reactor at a weight ratio of 9:1 and reacted at 60 C., and then water was removed from the reaction product by vaporization in a dehydrator at 178 C. and 550 mmHg, and the water-removed reaction product was supplied to the flasher. A bisphenol A concentration stream (10) excluding the phenol vaporized in the flasher is introduced into the first crystallizer (31) to produce a suspension comprising an adduct of crystallized bisphenol A and phenol. The suspension is supplied to a rotary centrifuge as the first solid-liquid separator (32), and the adduct of crystallized bisphenol A and phenol excluding the liquid phase portion separated in the rotary centrifuge is discharged. A phenol stream (13) is introduced into the discharged adduct of crystallized bisphenol A and phenol through the phenol introduction port (22). The phenol stream (13) is 58.2 C., but it is heated by a heat source of about 100 C. through the first heat exchanger (23) and introduced through the phenol introduction port (22) at a flow rate of 33.3 ton/hr in a state elevated to 90 C. The gaseous pentane generated in the phenol stream (13) heated by the heat source of 100 C. in the first heat exchanger (23) was introduced into the second crystallizer (33) through the vent via the separation line (17). The gaseous pentane is separated by a flow rate of 16 ton/hr at a temperature of 90 C. Another phenol stream from the phenol stream (13) is introduced into the second crystallizer (33) to be described below at a flow rate of 29 ton/hr. The mixed stream (12) in which the phenol stream (13) is mixed is heated and melted with a low pressure steam of 300 kPa through the second heat exchanger (21). The melted molten stream is circulated through the return line (18) and finally introduced into the second crystallizer (33). The molten stream is separated into the adduct of crystallized bisphenol A and phenol via the second crystallizer (33) and the second solid-liquid separator, and the adduct is discharged to the bisphenol A refining drum through the bisphenol A refining line to produce bisphenol A.

(9) The heat quantity of the steam used in the second heat exchanger was 1.264 Gcal/hr.

Comparative Example 1

(10) Bisphenol A was prepared using the production apparatus and processes of FIG. 1. Phenol and acetone were introduced to the main reactor at a weight ratio of 9:1 and reacted at 60 C., and then water was removed from the reaction product by vaporization in a dehydrator at 178 C. and 550 mmHg, and the water-removed reaction product was supplied to the flasher. A bisphenol A concentration stream (10) excluding the phenol vaporized in the flasher is introduced into the first crystallizer (31) to produce a suspension comprising an adduct of crystallized bisphenol A and phenol. The suspension is supplied to a rotary centrifuge as the first solid-liquid separator (32), and the adduct of crystallized bisphenol A and phenol excluding the liquid phase portion separated in the rotary centrifuge is discharged. The adduct of crystallized bisphenol A and phenol is heated and melted by medium pressure steam through the second heat exchanger (21). The melted stream is mixed with the phenol stream (13) flowing through the phenol introduction port (22) and introduced into the second crystallizer. The phenol stream (13) flows through the phenol introduction port (22) at a temperature of 58.2 C. and a flow rate of 64 ton/hr. The mixed stream is separated into the adduct of crystallized bisphenol A and phenol via the second crystallizer and the second solid-liquid separator, and the adduct is discharged to the bisphenol A refining drum through the bisphenol A refining line to produce bisphenol A.

(11) The heat quantity of the steam used in the second heat exchanger was 1.826 Gcal/hr.

(12) TABLE-US-00001 TABLE 1 Exam- Exam- Comparative ple 1 ple 2 Example 1 Required heat quantity in 1.298 1.264 1.826 second heat exchanger (Gcal/hr) Temperature at second heat 93 90 120.1 exchanger inlet ( C.) Temperature at second heat 128.5 127.9 134 exchanger outlet ( C.) Flow rate at second heat 60 60 233 exchanger outlet (ton/hr) Overall heat transfer 864.7 1079.8 1434.5 coefficient of second heat exchanger (kacl/hrcm.sup.2 C.) Required heat exchange area 26.9 20.4 42.24 of second heat exchanger (m.sup.2) Pentane concentration of 4.96 2.82 0.82 mixed stream (wt %)

(13) In the above, the second heat exchanger requires a heat quantity (Q) sufficient to melt the material from the solid-liquid separator. As a result of introducing no phenol stream, since the heat quantity required in the melting in the second heat exchanger is larger than those of Examples 1 and 2, Comparative Example 1 lowers the efficiency of the process. On the other hand, the overall heat transfer coefficient means how well the heat transfer is in the heat exchanger. Also, as the overall heat transfer coefficient is higher, the heat exchange at the desired level proceeds due to the heat exchange at a smaller heat exchange area, and thus it is efficient. In Comparative Example 1, since the phenol stream is not mixed, there is almost no gaseous pentane, so that the overall heat transfer coefficient is high, but the required heat quantity in the second heat exchanger is large and the required heat exchange area is also very high, and thus it is inefficient. In Example 1, the gaseous pentane is introduced into the mixed stream and the gas phase and the liquid phase coexist on the mixed stream, whereby the overall heat transfer coefficient is small over Example 2 and the required heat exchange area of the second heat exchanger is also large over Example 2. In the present application, the overall heat transfer coefficient and the required heat exchange area were calculated through an ASPEN EDR heat exchanger simulator.