Electromechanical detection device, particularly for gravimetric detection, and method for manufacturing the device
10670507 · 2020-06-02
Assignee
Inventors
Cpc classification
G01L1/18
PHYSICS
G01N5/02
PHYSICS
G01N29/022
PHYSICS
G01N2291/0256
PHYSICS
International classification
Abstract
Electromechanical detection device, particularly for gravimetric detection, and method for manufacturing the device. The electromechanical detection device includes a support including a face defining a plane, at least one beam that can move relative to the support, and means of detecting beam displacement, outputting a signal that depends on the displacement. The beam is anchored to the support through an end and is approximately perpendicular to the plane, and the other end of the beam includes at least one reception zone that can receive one or several particles causing or modifying displacement of the beam, in order to determine at least one physical property of the particle(s) from the signal. According to the invention, the detection means are located between the reception zone and the support.
Claims
1. A micro-electromechanical or nano-electromechanical detection device comprising: a support including a face defining a plane, at least one beam with first and second ends, the second end being moveable relative to the support, and means of detecting beam displacement, adapted to output a signal that depends on the displacement, wherein each beam is anchored to the support through its first end and is approximately perpendicular to said plane, and the second end of each beam is provided with a tray comprising a plane face that is approximately perpendicular to the beam and forms a reception zone, that can receive one or several particles that can provoke or modify displacement of the beam in order to determine at least one physical property of the particle(s) from the signal output by the displacement detection means, wherein the detection means are located between the reception zone and the support.
2. Device according to claim 1, in which a section of the reception zone in a first plane that is parallel to said plane, is larger than a section of the beam in a second plane that is also parallel to said plane.
3. Device according to claim 1, comprising a set of beams organized into an array.
4. Device according to claim 1, in which the beam forms a resonator for which the resonant frequency varies when the reception zone receives the particle(s), and the device also comprises means of actuating the beam.
5. Device according to claim 4, in which the actuation means are chosen from among electrostatic actuation means, piezoelectric actuation means, thermoelastic actuation means and optical actuation means.
6. Device according to claim 1, in which detection means are chosen from among piezoresistive strain gauge detection means, capacitive detection means, piezoelectric detection means and optical detection means.
7. Device according to claim 6, in which piezoresistive strain gauges are chosen from among silicon gauges, metal gauges, graphene gauges and carbon nanotube-based gauges.
8. Device according to claim 1, further comprising a signal processor for processing the signal output by the displacement detection means, the signal processor being designed to determine said physical property.
9. Device according to claim 1, wherein the reception zone of each beam is covered with a layer that has a chemical affinity towards a gas to be detected.
10. A micro-electromechanical or nano-electromechanical detection device comprising: a support including a face defining a plane, at least one beam with first and second ends, the second end being moveable relative to the support, and means of detecting beam displacement, adapted to output a signal that depends on the displacement, wherein each beam is anchored to the support through its first end and is approximately perpendicular to said plane, the second end of each beam comprising at least one reception zone, that can receive one or several particles that can provoke or modify displacement of the beam in order to determine at least one physical property of the particle(s) from the signal output by the displacement detection means, and each beam being manufactured in a standalone form by a surface technology, wherein the detection means are located between the reception zone and the support and formed by a thin film deposition technique in at least one layer which is parallel to said plane.
11. Device according to claim 10, in which a section of the reception zone in a first plane that is parallel to said plane, is larger than a section of the beam in a second plane that is also parallel to said plane.
12. Device according to claim 10, comprising a set of beams organized into an array.
13. Device according to claim 10, in which the beam forms a resonator for which the resonant frequency varies when the reception zone receives the particle(s), and the device also comprises means of actuating the beam.
14. Device according to claim 13, in which the actuation means are chosen from among electrostatic actuation means, piezoelectric actuation means, thermoelastic actuation means and optical actuation means.
15. Device according to claim 10, in which detection means are chosen from among piezoresistive strain gauge detection means, capacitive detection means, piezoelectric detection means and optical detection means.
16. Device according to claim 15, in which piezoresistive strain gauges are chosen from among silicon gauges, metal gauges, graphene gauges and carbon nanotube-based gauges.
17. Device according to claim 10, further comprising a signal processor for detecting displacement of the beam, the signal processor being designed to determine said physical property.
18. Device according to claim 10, wherein the reception zone of each beam is covered with a layer that has a chemical affinity towards a gas to be detected.
19. Device according to claim 10, further comprising a signal processor for processing the signal output by the displacement detection means, the signal processor being designed to determine said physical property.
20. A micro-electromechanical or nano-electromechanical detection device comprising: a support including a face defining a plane, at least one beam with first and second ends, the second end being moveable relative to the support, and means of detecting beam displacement, adapted to output a signal that depends on the displacement, wherein each beam is anchored to the support through its first end and is approximately perpendicular to said plane, and the second end of each beam is provided with a tray comprising a plane face that is approximately perpendicular to the beam and forms a reception zone, that can receive one or several particles that can provoke or modify displacement of the beam in order to determine at least one physical property of the particle(s) from the signal output by the displacement detection means, wherein the detection means are located between the reception zone and the support, and wherein the tray does not comprise an opening.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) This invention will be better understood after reading the description of example embodiments given below for information and that are in no way limitative, with reference to the appended drawings in which:
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DETAILED PRESENTATION OF PARTICULAR EMBODIMENTS
(15)
(16) According to the invention, the beam 8 is anchored to the substrate 4 at a first end and is approximately perpendicular to the plane 6. The second end of the beam 8 comprises a reception zone 12 in which one or several particles 14 that modify displacement of the beam can be received. And a physical property of the particle(s) 14 is determined from the signal output by the displacement detection means 10.
(17) It can be seen that the section of the reception zone 12 in a plane parallel to the plane 6 is larger than the section of the beam 8 in a plane parallel to the plane 6.
(18) Note that in the example shown in
(19) The device shown in
(20) The device is a chemical sensor for gas detection, but this is simply an illustrative example that is in no way limitative. The reception zone that forms part of the beam and that will be discussed in more detail later, is covered with a layer (not shown) that has a chemical affinity towards the gas to be detected. Thus in this case, the physical property is the particular mass of gas atoms or molecules to be detected. Detection of the mass of the particle(s) absorbed by the reception zone can also be used to determine the concentration of the analysed gas, if required.
(21) Admittedly, the reception zone could be composed of the free surface of the second end of the beam 8. However, in the example shown in
(22) As can be seen in
(23) In fact, a unit device is not used so as to obtain an appropriate capture area: a device according to the invention comprising more than one beam, namely a set of beams organised in an array, is used. This is diagrammatically shown in
(24) This
(25) The detection means and displacement means (not shown) that are respectively associated with the beams in the array, are also included between the substrate and the corresponding trays 20.
(26) In fact in this particular embodiment, the surface of the substrate has been broken down into elementary capture pixels, with a very good coverage density, and everything that does not participate in the capture area thus formed (particularly the detection means, connections and contacts) has been placed under the pixels considered.
(27)
(28) Note that this figure is a block diagram representing an example of a detection device with its elementary electronic circuit 32, for example comprising CMOS transistors. This circuit 32 makes it possible to address and possibly to amplify the signal output from the detection means. This
(29) In the examples shown in
(30)
(31)
(32) The actuation means may be electrostatic (as we have just seen) or piezoelectric or even thermoelastic or even optical. And the detection means may also be capacitive detection means, or piezoresistive detection means with silicon gauges or metal gauges (as we have seen above) or piezoelectric detection means or even optical detection means. We will consider this matter further in the description of
(33) Conducting lines, for example made of metal, have to be pulled to the lower levels of interconnections used by the CMOS technology in order to make the electrical connections to the unit devices. Therefore, it would also be possible to envisage co-integrating these unit devices with more or less elementary CMOS electronic circuits at each pixel, all these circuits being connected to a global electronic read circuit located at the periphery of the array of unit devices. Therefore it could be envisaged that each unit device is partly or entirely made in or above the interconnection levels called the back-end of the CMOS, and is therefore made of metal.
(34) If these devices are made above classical CMOS interconnection levels, we will for example refer to the above-IC sensor technology. If these devices are made in or between interconnection levels, we will for example refer to the co-integrated technology. This means that conventional elements using the CMOS technology are made at the same time as the elements of the sensor, for example in the back-end.
(35) Consider
(36) The figure shows the beam 8 supported on the substrate 4, the tray 20 provided on the beam 8, the piezoresistive gauges 22 and 24 that may for example be made of doped silicon or metallic, in the back-end of the CMOS above the substrate 4, the electrode 16 for the electrostatic actuation also above the substrate 4, and an elementary electronic circuit 32 buried in this substrate 4 and formed by a set of transistors for example of the CMOS type. In the case of gauges above the CMOS 32, said gauges may be transferred using the wafer bonding technique or they may be deposited.
(37) Anchors 28 and 30 can also be seen. These anchors 28 and 30 are connected to the elementary electronic circuit 32 through lower interconnection levels 34. The connections between the various elements are not all visible on the diagrammatic sectional view in
(38) In
(39) Let us return to the problem of the active surface density. This problem is similar to the problem concerning microbolometers. These microbolometers are sensors that are densely distributed on a surface so as to absorb infrared radiation. However, the concept of the microbolometer is very different from this invention and is more similar to prior art, more particularly to
(40) In a microbolometer, the transduction means (to read the resistance) and contacts are not below the device, but are above it and in a plane parallel to it. Furthermore, the structures used are membranes and are not single-dimensional.
(41) This is shown in
(42)
(43)
(44) The substrate 4, the beam 8 and the tray 20 can also be seen. In this example, the detection means 10 and the actuation means 16 are composed of a single piezoelectric stack. This stack is conventionally composed of a piezoelectric layer included between two electrically conducting layers.
(45) Care has to be taken with the design of the shape of the piezoelectric stack such that the stress field produced by bending of the device does not cancel out the charges collected between the two electrodes in the stack. For example, as shown in
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(47) The substrate 4, the beam 8 and the tray 20 can also be seen. In this example, the actuation means 16 comprise a metallic layer 56 formed on the substrate 4. The beam 8 is supported on the substrate through the layer 56.
(48) As can be seen, a cavity 58 is provided in the substrate 4 under the layer 56, such that (as for
(49) The metallic layer 56 is heated by passing a current through it, which requires electrical connections (not shown). Differential expansion between the metal and the layer 56 and the material from which the substrate 4 is made causes a bimetallic strip effect and therefore actuation of the device.
(50) In the examples of the invention that have been given so far, the device was resonant. But the invention is not limited to this case; a device according to the invention may also be non-resonant. In this case, detection is said to be in static mode. Such a device can detect a force, for example a cellular force.
(51) This consists of measuring the mechanical force that a cell can apply on its environment or on itself as a function of the conditions of this environment or the chemical species present, in order to understand fundamental mechanisms or for therapeutic purposes.
(52) Refer to the following document on this subject:
(53) US 2010/0041091, Axelrod et al., Microfluidic embedded polymer NEMS force sensors
(54) and particularly
(55) The objective is to place a living cell (that is therefore in a fluid medium) between a support and a NEMS device for which a property, for example the resistance, changes as a function of the force or displacement imposed by the cell on the device.
(56) One of the major problems that arises with this technique before it can be used in practice in an industrial context originates from the difficulty in placing a cell at the required location; a fluid containing the cells is passed on the surface of a NEMS in the hope that a cell will latch on at the right location.
(57) This invention can increase this probability of capture by several orders of magnitude; all that is necessary is for a cell to at least partly cover the trays of two adjacent unit devices according to the invention. The force applied by the cell can be determined using the displacement reading means disclosed above.
(58) An example of a non-resonant unit device according to the invention is identical to the example shown in
(59) As we have seen, in this case a non unit device comprising several unit devices is rather used.
(60) We will now refer to
(61) A silicon substrate 60 with full wafer doping is used, for example with a doping concentration of 10.sup.19 atoms per cubic centimetre (
(62) Contacts such as the contact 82 that will be considered in more detail later are formed on the substrate, and a layer 62 of SiO.sub.2 is deposited for example with a thickness equal to 1 m, and lithography is done on this layer to expose the pattern 64 of the NEMS contained in the device (
(63) Silicon 64 is deposited selectively relative to SiO.sub.2 on the pattern thus obtained by epitaxy, for example over a thickness of 1 m (
(64) A thickness is eliminated from the layer 62 to expose the deposited silicon 66 corresponding to the beam in the device (
(65) A layer 70 of SiO.sub.2 is deposited on the structure thus obtained, for example 200 nm thick (
(66) A polysilicon layer 72 is deposited on top of the layer 70 by LPCVD or a conducting material, for example AlSi, is deposited for example with a thickness of 1 m. A conducting deposit (for example AlSi) is then made to obtain the corresponding contacts 74; and these contacts are formed by lithography and then etching (
(67) Part of the layer 72 is eliminated by lithography and etching (
(68) A silica layer 76 is deposited on the structure obtained, for example more than 2 m of SiO.sub.2, and it is then planarised by CMP, in other words using a mechanical chemical polishing method (
(69) A polysilicon or metal layer is then deposited, for example 20 nm thick, and the tray 78 of the device is then formed by lithography and etching (
(70) A silica protection layer 80 is then deposited on the structure obtained, this layer 80 is eliminated locally by successive photolithography and etching operations, to once again expose the contacts 74 and other contacts such as the contact 82 that were obtained during a first deposit-litho-etching of a metal layer at the beginning of the process (
(71) The silica layers are then partly eliminated by etching using hydrofluoric acid HF, to expose the beam with the tray (
(72) We will now describe another example of a standalone type method in order to manufacture a unit device according to the invention with reference to
(73) A silicon substrate 90 is used and an asymmetric piezoelectric stack 92 is formed on the substrate 90. This is done for example by depositing a layer of molybdenum 94 thereon and lithography is performed on this layer, a layer 96 for example made of AIN is deposited on the layer 94 and lithography is performed on this layer, a layer made for example from molybdenum 98 is deposited on the layer 96 and lithography is performed on this layer 98 (
(74) A layer 100 for example made of SiO.sub.2 and 750 nm thick is then deposited on the structure obtained. Lithography is performed to expose the pattern 102 of the NEMS contained in the device (
(75) A layer 104 for example made of silicon oxide is deposited on the structure obtained (
(76) The layer 104 is then etched at the previously formed pattern 102 to define the location 106 of the beam of the device (
(77) Polysilicon 108 for example is then deposited at this location up to the surface of the layer 104 to form this beam (
(78) Polysilicon is deposited by LPCVD, for example over a thickness of 20 nm, and lithography is performed on this polysilicon to form the tray 110 of the device (
(79) Wet etching of the resulting structure is applied to expose the beam with its tray, for example using hydrofluoric acid (
(80) Devices conforming with the invention can also be made by a co-integrated or above-IC method as shown in
(81) An SOI substrate can thus be used comprising an upper silicon layer, previously doped and activated, before cold molecular bonding above the CMOS. This can be done using the process described in the following document:
(82) FR 2 961016, Circuit intgr dispositif de type FET sans jonction et depletion (Integrated circuit with junctionless depletion-mode FET type device), invention by T. Ernst et al.
(83) In particular, this method uses a lower stop layer, for example made of HfO.sub.2 or BN or SiN as shown in
(84)
(85) It should be noted that the successive steps in the method are diagrammatically illustrated by the sectional views in
(86)
(87) The structure 116 that was transferred onto the CMOS wafer by cold molecular bonding can also be seen. The reference of the bonding interface is 118. This structure 116 may be an SOI type substrate comprising an oxide bonding layer 117, for example 200 nm thick, a stop layer 124 for example 10 nm to 100 nm thick, a buried oxide 120 for example 400 nm thick, above which there is an upper layer 122 made of silicon for example 50 nm thick, previously doped with boron and activated. The oxide layer 117 enables molecular bonding with the layer 115. The combination of the layers 115 and 117 has reference numeral 117a in
(88) More generally, a layer of piezoelectric material may be used to replace this silicon layer.
(89) The stop layer 124 between the buried oxide 120 and the bonding layer 117 can also be seen; for example it can be made of SiN, HfO.sub.2 or BN.
(90) For example, a 50 nm thick BN stop layer is used.
(91) The structure 116 can also be obtained by successive deposits of appropriate layers.
(92) Photolithography is then performed (
(93) A silica insulating layer 126 for example 400 nm thick is then deposited on the upper layer 122 (
(94) The next step (
(95) The next step is to deposit a silica layer 132 on the structure thus obtained (
(96)
(97)
(98) Finally (
(99) Let us return to the device, object of the invention, more precisely to the beam displacement detection means. Hereafter we precise the interest of having displacement detection means which are integrated, unlike displacement detection means which are known in the state of the art.
(100) Let us explain the interest and difficulty for making a vertical NEMS with integrated detection means (as opposed to this state of the art where an optical detection, external to a chip, is used:
(101) The integration of thin layers transduction means, which are conventionally electrical (driving and/or detection), is very often sought and is therefore a conventional problem per se; it makes it possible to strongly reduce the amount of spare used by the device, its cost and consumption, and in some cases improves the measurement precision. On the other hand, it may be very difficult to address a large number of resonators on the chip by an external means, as is the case for an array of resonators which is useful so as to cover a large capture area. In that case an integrated transduction is a solution to this problem.
(102) In the case of a vertical device, made of thin layers, integrating the electrical detection means to the manufacturing method is much less obvious, particularly at small nanometric dimensions. This is because the device is obtained via successive layers in that case, and the etching thereof together with the correct manufacturing of the mechanical structure require finding means for avoiding too important disaligning between levels, typically of the same order of magnitude as the lateral dimensions of the device. Since the detection means measure a displacement or a stress their good operation depends on a well controlled positioning between the mechanical structure and these mans. In addition, when one wishes to get an active area (for detecting the particles) above and covering the detection means, the latter must be much less cumbersome than the resonator itself, which strongly limits possibilities.