A METHOD USING PHOTOCATALYTIC ELECTRODE COUPLED WITH MICROBIAL FUEL CELL TO PROMOTE TREATMENT OF COKING WASTEWATER

Abstract

A method of promoting the treatment of coking wastewater using photocatalytic electrode coupled with microbial fuel cellin the technical field of coking wastewater treatment, energy-saving and resource utilization. La-ZnIn.sub.2S.sub.4/RGO/BiVO.sub.4 and silica sol were fixed and coated on stainless steel mesh to form conductive catalytic composite membrane electrode. HSO.sub.3.sup.was added to coking wastewater. Graphite Carbon rods are inserted into the anodic chamber with microorganisms and connected the cathode with wires to form circuit loops. Halogen tungsten lamp was applied as light source to act on the catalytic electrode, forming a coupled system with photocatalytic electrode and microbial fuel cell for treating coking wastewater. The effects of La-ZnIn.sub.2S.sub.4/RGO/BiVO.sub.4 catalysts with different RGO contents on the catalytic degradation of coking wastewater were realized, and the effects of NaHSO.sub.3 and Na.sub.2SO.sub.4 solutions at the same concentration on the degradation of coking wastewater were also realized.

Claims

1. A method using photocatalytic electrode coupled with microbial fuel cell to promote treatment of coking wastewater, wherein it has the following steps: (1) the preparation of the series of La-ZnIn.sub.2S.sub.4/RGO/BiVO.sub.4 composites: Bi(NO.sub.3).sub.3.5H.sub.2O was dissolved in 14 wt % HNO.sub.3, stirred it, and then added CTAB solution into it; controlling the mass ratio of CTAB to Bi(NO.sub.3).sub.3.5H.sub.2O at 1:15 then adding GO and stirring the solution to obtain mixed solution A; NH.sub.4VO.sub.3 was dissolved in 2 mol/L NaOH solution and added to liquid A drop by drop; the molar ratio of NH.sub.4VO.sub.3 to Bi(NO.sub.3).sub.3.5H.sub.2O in liquid A was 1:1; 2 mol/L NaOH solution was used to adjust pH=6; stirring the solution; the mixture was obtained by reaction at 200 C. for 2 h and cooling; after washing, centrifuging, drying, grinding, x RGO/BiVO.sub.4 was obtained, grinding it to powder, xRGO/BiVO.sub.4 was obtained; X meant mass ratio of RGO to BiVO.sub.4 in RGO/BiVO.sub.4 is less than 1.5%; Zn(NO.sub.3).sub.36H.sub.2O, In(NO.sub.3).sub.3.5H.sub.2O and excessive TAA were dissolved in deionized water, then La(NO.sub.3).sub.3 and RGO/BiVO.sub.4 were added to the deionized water; stirring the solution; the mixture was prepared by reaction for 6 h at 80 C.; after centrifugation, drying and grinding, yLa-ZnIn.sub.2S.sub.4/xRGO/BiVO.sub.4 was obtained, which was ground into powder, i.e. yLa-ZnIn.sub.2S.sub.4/xRGO/BiVO.sub.4; among them, the mass ratio of La-ZnIn.sub.2S.sub.4 to RGO/BiVO.sub.4 is 1:5, and Y is 0.01 for La and ZnIn.sub.2S.sub.4; (2) preparation of photocatalytic electrode-coupled microbial fuel cell membrane module: adding silica sol into yLa-ZnIn.sub.2S.sub.4/xRGO/BiVO.sub.4 series composites prepared in step (1), the ratio of yLa-ZnIn.sub.2S.sub.4/xRGO/BiVO.sub.4 series composite to silica sol was 1 g: 1 L; homogenizing it by ultrasonic, and coating it on stainless steel mesh and drying it; (3) construction of photocatalytic electrode-coupled microbial fuel cell membrane catalytic treatment system: the system was divided into two chambers by proton exchange membrane, in which microorganisms were placed in one chamber and carbon rods were inserted as anodes; coking wastewater contained NaHSO.sub.3 was put in the other chamber, photocatalytic electrode-coupled microbial fuel cell membrane module made in step (2) was prepared as cathodes; placing halogen-tungsten lamp in the second chamber, which was connected by wires to form a circuit; halogen tungsten lamp vertical irradiated photocatalytic electrode coupled with microbial fuel cell membrane module.

2. The photocatalytic electrode coupled with the microbial fuel cell described in claim 1, wherein the pollutant is organic pollutant in coking wastewater.

Description

DESCRIPTION OF DRAWINGS

[0017] FIG. 1 is a comparison figure of the degradation of coking wastewater under the coupling system of photocatalytic electrode and microbial fuel cell with the same concentration of NaHSO.sub.3 and different RGO content in La-ZnIn.sub.2S.sub.4/RGO/BiVO.sub.4 catalyst. In the figure, the abscissa is time (h), and the ordinate is TOC degradation efficiency (%) of coking wastewater.

[0018] FIG. 2 is a comparison of degradation of coking wastewater by adding the same concentration of NaHSO.sub.3 and Na.sub.2SO.sub.4 in the cathodic coking wastewater under the coupling system of photocatalytic electrode and microbial fuel cell. In the figure, the abscissa is time (h), and the ordinate is TOC degradation efficiency (%) of coking wastewater.

SPECIFIC IMPLEMENTATION METHODS

[0019] Specific implementation methods of the present invention are described in detail below in connection with the technical scheme and the accompanying drawings.

Implementation Example 1: Degradation of Coking Wastewater by Catalysts with Different RGO Contents

[0020] In the two-chamber cuboid reactor system of photocatalytic membrane electrode coupled with microbial fuel cell, the membrane module and halogen tungsten lamp are put into the system, and carbon rods are put into the microbial anode separated by proton exchange membrane. The coking wastewater containing NaHSO.sub.3 in the photocatalytic system is in the photo cathode. The aerator is continuously aerated at the bottom of the cathode chamber. The top of the membrane was connected with a crocodile clamp. The halogen tungsten lamp is put into the reaction device. The halogen tungsten lamp is power-off before reaction. After in dark reaction for 0.5 h, the power supply of halogen tungsten lamp is turned on for 4 h. After reaction begins, samples were taken with pipette every 0.5 hours in the first 2.5 hours, and every 1.0 hours in the next two hours. The reaction lasts 4.5 hours. The TOC content in the samples was detected by TOC/TN detector, and the degradation effect of organic pollutants in coking wastewater was calculated.

[0021] In FIG. 1, 0.5% RGO had the best degradation effect, which was 82.02%.

Implementation Example 2: Degradation of Coking Wastewater by Systems Containing NaHSO.SUB.3 .and Na.SUB.2.SO.SUB.4 .of the Same Concentration

[0022] In the two-chamber cuboid reactor system of photocatalytic membrane electrode coupled with microbial fuel cell, the membrane module and halogen tungsten lamp are put into the system. Carbon rods are put into the microbial anode separated by proton exchange membrane. One is the coking wastewater containing NaHSO.sub.3 in the photocatalytic system as photo-electrochemical cathode (the other is the coking wastewater containing Na.sub.2SO.sub.4 in the photocatalytic system as photo-electrochemical cathode, other conditions are the same.) The aerator is continuously aerated at the bottom of the cathode chamber. The top of the membrane was connected with a crocodile clamp. The halogen tungsten lamp is put into the reaction device. Before the reaction, the power of halogen tungsten lamp is turned off After the dark reaction for 0.5 hours, the halogen tungsten lamp power is turned on for 4 hours. After the reaction starts, samples were taken with pipette every 0.5 hours in the first 2.5 hours, and the second two hours are sampled every 1.0 hours. The reaction lasts for 4.5 hours. TOC content in samples was detected by TOC/TN detector, and the degradation effect of organic pollutants in coking wastewater was calculated.

[0023] In FIG. 2, coking wastewater containing NaHSO.sub.3 was compared with coking wastewater containing Na.sub.2SO.sub.4. It was found that the degradation efficiency of coking wastewater containing NaHSO.sub.3 in the system of photocatalytic membrane electrode coupled with microbial fuel cell (82%) was much better than that of coking wastewater containing Na.sub.2SO.sub.4 (15%).