COMPOSITION CONTAINING QUATERNARY AMMONIUM COMPOUND, ESPECIALLY FOR PRODUCING CARE AND CLEANING FORMULATIONS

Abstract

The invention relates to a composition comprising: A) at least one non-silicone-containing quaternary ammonium compound, B) at least one cosmetic oil, C) at least one nonionic surfactant, D) at least one nonaqueous solvent, E) water.

Claims

1. A composition comprising A) at least one non-silicone-containing quaternary ammonium compound, B) at least one cosmetic oil, C) at least one nonionic surfactant, D) at least one nonaqueous solvent, and E) water.

2. The composition according to claim 1, wherein the composition is a microemulsion.

3. The composition according to claim 1, wherein the composition contains A) in an amount of from 1 wt % to 40 wt %, B) in an amount of from 5 wt % to 60 wt %, C) in an amount of from 5 wt % to 50 wt %, D) in an amount of from 2 wt % to 50 wt %, and E) in an amount of from 1 wt % to 60 wt %, wherein the percentages by weight refer to the total composition.

4. The composition according to claim 1, wherein A) is selected from the group of the ester quats and imidazolinium salts,

5. The composition according to claim 1, wherein the mass of the component B) is greater than the mass of the component A) in the composition.

6. The composition according to claim 1, wherein A) is selected from the group of the liquid ester quats consisting of quaternized fatty acid alkanolamine ester salts.

7. The composition according to claim 1, wherein A) is selected from the group of the liquid ester quats comprising compounds of the general formula (I) ##STR00005## wherein R.sup.1 is an acyl radical of an at least monounsaturated fatty acid having a chain length of 18 to 24 carbon atoms or the acyl radical of isostearic acid or ricinoleic acid, wherein R.sup.2 is an alkyl radical having 1 to 6 carbon atoms, and wherein X.sup. is a counterion to the positive charge on the quaternary nitrogen group, wherein a=1 to 3 and b=1 to 3, with the proviso that a+b=4.

8. The composition according to claim 1, wherein component C) is selected from those of the general formula IV ##STR00006## wherein n=2 to 16, and R.sup.7, R.sup.8, R.sup.9=are independently the same or different and are selected from H and saturated or unsaturated, linear or branched acyl radical having 4-36 carbon atoms and containing at least one hydroxyl group.

9. The composition according to claim 1, wherein D) is selected from the group consisting of hydrotropes and polyols.

10. The composition according to claim 1, wherein the composition comprises F) amphoteric surfactant,

11. The process for producing care and cleaning formulations, comprising the process steps of: 1) providing a composition according to claim 1, 2) mixing the composition with an aqueous phase.

12. A care and cleaning formulations containing a composition according to claim 1.

13. A care and cleaning formulations containing a composition obtained by the process according to claim 11.

14. The composition according to claim 1, wherein the composition contains A) in an amount of from 1.5 wt % to 30 wt %, B) in an amount of from 10 wt % to 50 wt %, C) in an amount of from 10 wt % to 40 wt %, D) in an amount of from 3 wt % to 40 wt %, and E) in an amount of from 3 wt % to 50 wt %, wherein the percentages by weight refer to the total composition.

15. The composition according to claim 1, wherein the composition contains A) in an amount of from 5 wt % to 25 wt %, B) in an amount of from 15 wt % to 40 wt %, C) in an amount of from 15 wt % to 35 wt %, D) in an amount of from 5 wt % to 30 wt %, and E) in an amount of from 5 wt % to 45 wt %, wherein the percentages by weight refer to the total composition.

16. The composition according to claim 1, wherein A) is selected from the group of liquid ester quats and liquid imidazolinium salts.

17. The composition according to claim 1, wherein A) is selected from the group of the quaternized fatty acid ethanolamine ester salts and the quaternized fatty acid isopropanolamine ester salts.

18. The composition according to claim 1, wherein A) is selected from the group of the liquid ester quats comprising compounds of the general formula (I) ##STR00007## where R.sup.1 is an acyl radical of an at least monounsaturated fatty acid having a chain length of 18 to 24 carbon atoms or the acyl radical of isostearic acid or ricinoleic acid, wherein R.sup.2 is methyl, ethyl, propyl or isopropyl, and wherein X.sup. is a counterion to the positive charge on the quaternary nitrogen group, wherein a=1.7 to 2.3 and b=1.7 to 2.3, with the proviso that a+b=4.

19. The composition according to claim 1, wherein A) is selected from the group of the liquid ester quats comprising compounds of the general formula (I) ##STR00008## wherein R.sup.1 is an acyl radical of an at least monounsaturated fatty acid having a chain length of 18 to 24 carbon atoms or the acyl radical of isostearic acid or ricinoleic acid, wherein R.sup.2 is methyl, and wherein X.sup. is a counterion to the positive charge on the quaternary nitrogen group, wherein a=1.7 to 2.3 and b=1.7 to 2.3, with the proviso that a+b=4.

20. The composition according to claim 1, wherein component C) is selected from those of the general formula IV ##STR00009## where n=3 to 14, and R.sup.7, R.sup.8, R.sup.9=are selected from the acyl radicals of natural fatty acids.

Description

[0084] The following FIGURES are part of the examples:

[0085] FIG. 1: Water content of the hair strands after use of 1 g of a diluted formulation

EXAMPLES

Example ME1: Inventive Microemulsion

[0086] 25.0% of TEGOSOFT M (Isopropyl Myristate, Evonik Nutrition & Care GmbH), 12.5% of VARISOFT PATC (Palmitamidopropyltrimonium Chloride, Evonik Nutrition & Care GmbH), 10.0% of dipropylene glycol and 30.0% of TEGOSOFT PC 31 (Polyglyceryl-3 Caprate, Evonik Nutrition & Care GmbH) were mixed in 22.5% of water. A clear microemulsion is formed. The proportion of significantly hair-conditioning active substances (TEGOSOFT M and VARISOFT PATC) is 37.5%.

Example ME2: Inventive Microemulsion

[0087] 26.7% of TEGOSOFT M (Isopropyl Myristate, Evonik Nutrition & Care GmbH), 13.3% of VARISOFT EQ 100 (Bis-(Isostearoyl/Oleoyl Isopropyl) Dimonium Methosulfate, Evonik Nutrition & Care GmbH), 24.0% of dipropylene glycol and 26.7% of TEGOSOFT PC 41 (Polyglyceryl-4 Caprate, Evonik Nutrition & Care GmbH) were mixed in 9.3% of water. A clear microemulsion is formed. The proportion of significantly hair-conditioning active substances (TEGOSOFT M and VARISOFT EQ 100) is 40%.

Example ME3: Inventive Microemulsion

[0088] 25.0% of TEGOSOFT M (Isopropyl Myristate, Evonik Nutrition & Care GmbH), 2.5% of VARISOFT PATC (Palmitamidopropyltrimonium Chloride, Evonik Nutrition & Care GmbH), 10.0% of propylene glycol, 20% of TEGOSOFT PC 31 (Polyglyceryl-3 Caprate, Evonik Nutrition & Care GmbH) and 15.0% of TEGOSOFT PC 41 (Polyglyceryl-4 Caprate, Evonik Nutrition & Care GmbH) were mixed in 27.5% of water. A clear microemulsion is formed. The proportion of significantly hair-conditioning active substances (TEGOSOFT M and VARISOFT PATC) is 27.5%.

Example ME4: Noninventive Microemulsion

[0089] Plantasil Micro (Dicaprylyl Ether (and) Decyl Glucoside (and) Glyceryl Oleate, BASF), with approximately 28% of hair-conditioning active constituents (Dicaprylyl Ether and Glyceryl Oleate).

Example ME5: Noninventive Microemulsion

[0090] Lamesoft OD (Coco-Caprylate (and) Lauryl Glucoside (and) Glycerin (and) Polyglyceryl-2 Dipolyhydroxystearate (and) Polyglyceryl-3 Diisostearate, BASF).

Example ME6: Inventive Microemulsion

[0091] 23.9% of TEGOSOFT CT (Caprylic/Capric Triglyceride, Evonik Nutrition & Care GmbH), 21.0% of TEGOSOFT PC 31 (Polyglyceryl-3 Caprate, Evonik Nutrition & Care GmbH), 9.0% of VARISOFT EQ 100 (Bis-(Isostearoyl/Oleoyl Isopropyl) Dimonium Methosulfate, Evonik Nutrition & Care GmbH) and 18.0% of dipropylene glycol were mixed in 28.1% of water. A clear microemulsion is formed. The proportion of significantly hair-conditioning active substances (TEGOSOFT CT and VARISOFT EQ 100) is 32.9%.

Example ME7: Inventive Microemulsion

[0092] 21.0% of TEGOSOFT DEC (Diethylhexyl Carbonate, Evonik Nutrition & Care GmbH), 18.0% of TEGOSOFT PC 31 (Polyglyceryl-3 Caprate, Evonik Nutrition & Care GmbH), 8.0% of VARISOFT EQ 100 (Bis-(Isostearoyl/Oleoyl Isopropyl) Dimonium Methosulfate, Evonik Nutrition & Care GmbH) and 15.6% of dipropylene glycol were mixed in 37.4% of water. A clear microemulsion is formed. The proportion of significantly hair-conditioning active substances (TEGOSOFT DEC and VARISOFT EQ 100) is 29.0%.

Example ME8: Inventive Microemulsion

[0093] 19.8% of TEGOSOFT DEC (Diethylhexyl Carbonate, Evonik Nutrition & Care GmbH), 17.3% of TEGOSOFT PC 31 (Polyglyceryl-3 Caprate, Evonik Nutrition & Care GmbH), 5.0% of TEGO Betain F 50 (Cocamidopropyl Betaine, Evonik Nutrition & Care GmbH), 7.0% of VARISOFT EQ 100 (Bis-(Isostearoyl/Oleoyl Isopropyl) Dimonium Methosulfate, Evonik Nutrition & Care GmbH) and 14.0% of dipropylene glycol were mixed in 36.9% of water. A clear microemulsion is formed. The proportion of significantly hair-conditioning active substances (TEGOSOFT DEC and VARISOFT EQ 100) is 26.8%.

Example ME9: Inventive Microemulsion

[0094] 15.8% of TEGOSOFT OER (Oleyl Erucate, Evonik Nutrition & Care GmbH), 15.8% of TEGOSOFT M (Isopropyl Myristate, Evonik Nutrition & Care GmbH), 22.8% of TEGO Solve 61 (Polyglyceryl-6 Caprylate (and) Polyglyceryl-3 Cocoate (and) Polyglyceryl-4 Caprate (and) Polyglyceryl-6 Ricinoleate, Evonik Nutrition & Care GmbH), 22.8% of VARISOFT EQ 100 (Bis-(Isostearoyl/Oleoyl Isopropyl) Dimonium Methosulfate, Evonik Nutrition & Care GmbH) and 10.1% of dipropylene glycol were mixed in 12.7% of water. A clear microemulsion is formed. The proportion of significantly hair-conditioning active substances (TEGOSOFT OER, TEGOSOFT M und VARISOFT EQ 100) is 54.4%.

Example ME10: Inventive Microemulsion

[0095] 15.8% of TEGOSOFT OER (Oleyl Erucate, Evonik Nutrition & Care GmbH), 15.8% of TEGOSOFT M (Isopropyl Myristate, Evonik Nutrition & Care GmbH), 22.8% of TEGOSOFT PC 41 (Polyglyceryl-4 Caprate, Evonik Nutrition & Care GmbH), 22.8% of VARISOFT EQ 100 (Bis-(Isostearoyl/Oleoyl Isopropyl) Dimonium Methosulfate, Evonik Nutrition & Care GmbH) and 10.1% of dipropylene glycol were mixed in 12.7% of water. A clear microemulsion is formed. The proportion of significantly hair-conditioning active substances (TEGOSOFT OER, TEGOSOFT M and VARISOFT EQ 100) is 54.4%.

Example ME11: Inventive Microemulsion

[0096] 25.0% of TEGOSOFT P (Isopropyl Palmitate, Evonik Nutrition & Care GmbH), 18.0% of TEGOSOFT PC 41 (Polyglyceryl-4 Caprate, Evonik Nutrition & Care GmbH), 18.0% of VARISOFT EQ 100 (Bis-(Isostearoyl/Oleoyl Isopropyl) Dimonium Methosulfate, Evonik Nutrition & Care GmbH) and 8.0% of dipropylene glycol were mixed in 31.0% of water. A clear microemulsion is formed. The proportion of significantly hair-conditioning active substances (TEGOSOFT P and VARISOFT EQ 100) is 43%.

Example ME12: Inventive Microemulsion

[0097] 8.3% of TEGOSOFT OER (Oleyl Erucate, Evonik Nutrition & Care GmbH), 22.9% of TEGOSOFT P (Isopropyl Palmitate, Evonik Nutrition & Care GmbH), 16.5% of TEGOSOFT PC 41 (Polyglyceryl-4 Caprate, Evonik Nutrition & Care GmbH), 16.5% of VARISOFT EQ 100 (Bis-(Isostearoyl/Oleoyl Isopropyl) Dimonium Methosulfate, Evonik Nutrition & Care GmbH) and 7.3% of dipropylene glycol were mixed in 28.5% of water. A clear microemulsion is formed. The proportion of significantly hair-conditioning active substances (TEGOSOFT OER, TEGOSOFT P and VARISOFT EQ 100) is 47.7%.

Example ME13: Inventive Microemulsion

[0098] 6.3% of TEGOSOFT OER (Oleyl Erucate, Evonik Nutrition & Care GmbH), 18.7% of TEGOSOFT P (Isopropyl Palmitate, Evonik Nutrition & Care GmbH), 18.0% of TEGO Solve 61 (Polyglyceryl-6 Caprylate (and) Polyglyceryl-3 Cocoate (and) Polyglyceryl-4 Caprate (and) Polyglyceryl-6 Ricinoleate, Evonik Nutrition & Care GmbH), 18.0% of VARISOFT EQ 100 (Bis-(Isostearoyl/Oleoyl Isopropyl) Dimonium Methosulfate, Evonik Nutrition & Care GmbH) and 8.0% of dipropylene glycol were mixed in 31.0% of water. A clear microemulsion is formed. The proportion of significantly hair-conditioning active substances (TEGOSOFT OER, TEGOSOFT P and VARISOFT EQ 100) is 43%.

Example ME14: Inventive Microemulsion

[0099] 15.8% of TEGOSOFT OER (Oleyl Erucate, Evonik Nutrition & Care GmbH), 15.8% of TEGOSOFT P (Isopropyl Palmitate, Evonik Nutrition & Care GmbH), 11.4% of TEGO Solve 61 (Polyglyceryl-6 Caprylate (and) Polyglyceryl-3 Cocoate (and) Polyglyceryl-4 Caprate (and) Polyglyceryl-6 Ricinoleate, Evonik Nutrition & Care GmbH), 11.4% of TEGOSOFT PC 41 (Polyglyceryl-4 Caprate, Evonik Nutrition & Care GmbH), 22.8% of VARISOFT EQ 100 (Bis-(Isostearoyl/Oleoyl Isopropyl) Dimonium Methosulfate, Evonik Nutrition & Care GmbH) and 10.1% of dipropylene glycol were mixed in 12.7% of water. A clear microemulsion is formed. The proportion of significantly hair-conditioning active substances (TEGOSOFT OER, TEGOSOFT P and VARISOFT EQ 100) is 54.4%.

Example ME15: Inventive Microemulsion

[0100] 25.0% of TEGOSOFT DEC (Diethylhexyl Carbonate, Evonik Nutrition & Care GmbH), 30.0% of TEGOSOFT PC 31 (Polyglyceryl-3 Caprate, Evonik Nutrition & Care GmbH), 5.0% of VARISOFT PATC (Palmitamidopropyltrimonium Chloride, Evonik Nutrition & Care GmbH) and 15.0% of propylene glycol were mixed in 25.0% of water. A clear microemulsion is formed. The proportion of significantly hair-conditioning active substances (TEGOSOFT DEC and VARISOFT PATC) is 30.0%.

Example ME16: Inventive Microemulsion

[0101] 18.4% of TEGOSOFT AC (Isoamyl Cocoate, Evonik Nutrition & Care GmbH), 20.1% of TEGOSOFT PC 41 (Polyglyceryl-4 Caprate, Evonik Nutrition & Care GmbH), 16.9% of VARISOFT EQ 100 (Bis-(Isostearoyl/Oleoyl Isopropyl) Dimonium Methosulfate, Evonik Nutrition & Care GmbH) 1.0% of VARISOFT 300 (Cetrimonium Chloride, Evonik Nutrition & Care GmbH), 1.0% of REWOTERIC AM C (Sodium Cocoamphoacetate, Evonik Nutrition & Care GmbH) and 13.8% of dipropylene glycol were mixed in 28.8% of water. A clear microemulsion is formed. The proportion of significantly hair-conditioning active substances (TEGOSOFT AC, VARISOFT 300 and VARISOFT EQ 100) is 36.3%.

Example ME17: Inventive Microemulsion

[0102] 17.8% of TEGOSOFT AC (Isoamyl Cocoate, Evonik Nutrition & Care GmbH), 19.3% of TEGOSOFT PC 41 (Polyglyceryl-4 Caprate, Evonik Nutrition & Care GmbH), 16.5% of VARISOFT EQ 100 (Bis-(Isostearoyl/Oleoyl Isopropyl) Dimonium Methosulfate, Evonik Nutrition & Care GmbH) 1.0% of VARISOFT 300 (Cetrimonium Chloride, Evonik Nutrition & Care GmbH), 2.0% of ANTIL Soft SC (Sorbitan Sesquicaprylate, Evonik Nutrition & Care GmbH) and 16.5% of dipropylene glycol were mixed in 26.9% of water. A clear microemulsion is formed. The proportion of significantly hair-conditioning active substances (TEGOSOFT AC, VARISOFT 300 and VARISOFT EQ 100) is 35.3%.

Example ME18: Inventive Microemulsion

[0103] 25.5% of TEGOSOFT M (Isopropyl Myristate, Evonik Nutrition & Care GmbH), 4.9% of TEGOSOFT OER (Oleyl Erucate, Evonik Nutrition & Care GmbH), 12.6% of VARISOFT EQ 100 (Bis-(Isostearoyl/Oleoyl Isopropyl) Dimonium Methosulfate, Evonik Nutrition & Care GmbH), 22.8% of dipropylene glycol and 25.4% of TEGOSOFT PC 41 (Polyglyceryl-4 Caprate, Evonik Nutrition & Care GmbH) were mixed in 8.8% of water. A clear microemulsion is formed. The proportion of significantly hair-conditioning active substances (TEGOSOFT M, TEGOSOFT OER and VARISOFT EQ 100) is 43%.

Example ME19: Inventive Microemulsion

[0104] 25.3% of TEGOSOFT M (Isopropyl Myristate, Evonik Nutrition & Care GmbH), 4.8% of argan oil (Argania Spinosa Oil (Argania Spinosa Kernel Oil), DSM Nutritional Products Ltd.), 12.7% of VARISOFT EQ 100 (Bis-(Isostearoyl/Oleoyl Isopropyl) Dimonium Methosulfate, Evonik Nutrition & Care GmbH), 22.9% of dipropylene glycol and 25.4% of TEGOSOFT PC 41 (Polyglyceryl-4 Caprate, Evonik Nutrition & Care GmbH) were mixed in 8.9% of water. A clear microemulsion is formed. The proportion of significantly hair-conditioning active substances (TEGOSOFT M, argan oil and VARISOFT EQ 100) is 42.8%.

Example ME20: Inventive Microemulsion

[0105] 26.7% of TEGOSOFT M (Isopropyl Myristate, Evonik Nutrition & Care GmbH), 13.3% of VARISOFT EQ F 75 Pellets (70% Distearoylethyl Hydroxyethylmonium Methosulfate; 30% Cetearyl Alcohol, Evonik Nutrition & Care GmbH), 24% of dipropylene glycol and 26.7% of TEGOSOFT PC 41 (Polyglyceryl-4 Caprate, Evonik Nutrition & Care GmbH) were mixed in 9.3% of water. A clear microemulsion is formed. The proportion of significantly hair-conditioning active substances (TEGOSOFT M and Distearoylethyl Hydroxyethylmonium Methosulfate) is 36%.

Example ME21: Inventive Microemulsion

[0106] 30.0% of siloxane, a Polysiloxane Multi-T-Quat with N=350 having the following statistical formula: (R.sub.2Me.sub.2SiO.sub.1/2).sub.7 (Me.sub.2SiO.sub.1/2).sub.338 (MeSiO.sub.3/2).sub.5, with

##STR00004##

10.0% of propylene glycol, 10.0% of TEGOSOFT PC 31 (Polyglyceryl-3 Caprate, Evonik Nutrition & Care GmbH), 5.0% of TEGO Betain F 50 (Cocamidopropyl Betaine, 38% strength, Evonik Nutrition & Care GmbH), 2.4% VARISOFT PATC (Palmitamidopropyltrimonium Chloride, Evonik Nutrition & Care GmbH) were mixed in 42.6% of water. A clear microemulsion is formed. The proportion of significantly hair-conditioning active substances (siloxane and VARISOFT PATC) is 32.4%.

Example ME22: Inventive Microemulsion

[0107] 8% of Glyceryl Monooleate (TEGIN O V, Evonik), 25% of Dioctylether (Cetiol OE, BASF), 10% of Hexadecyl Hexadecanoate (Cutinal CP, BASF), 20.4% of C12-16 fatty alcohol 1,4-glucoside (50% in H.sub.2O)(Plantacar 1200 UP, BASF), 13.6% of C8-16 fatty alcohol 1,4-glucoside (50% in H.sub.2O)(Plantacare 2000 UP, BASF), 5.0% of Trimethylhexadecylammonium Chloride (CTAC) (Aldrich-Merck), 1.0% of Benzoic acid, 2.0% of Citric acid were mixed in 15.0% of water. A clear microemulsion is formed. The proportion of significantly hair-conditioning active substances (Dioctylether, Hexadecyl Hexadecanoate and Trimethylhexadecylammonium Chloride) is 40%.

Application-Related Properties:

[0108] Formulation constituents are named in the compositions which follow in the form of the commonly acknowledged INCI nomenclature using the English terms. All concentrations in the application examples are given in percent by weight.

Removal of the Odor of Frying from Hair, by Means of Moist Hair Wipes

Formulations Tested:

Example A (not According to the Invention):

[0109] 0.67% of VARISOFT EQ 100 and 1.33% of TEGOSOFT M were stirred into water. A dispersion was formed, which separated after standing for a short time. This means that a homogeneous formulation and hence a homogeneous application to the moist wipes was not possible.

Example B (Noninventive):

[0110] 1.33% of TEGOSOFT M were stirred into water. A dispersion was formed, which separated after standing for a short time. This means that a homogeneous formulation and application to the moist wipes was not possible.

Example C (Noninventive)

[0111] 0.67% of VARISOFT EQ 100 was dispersed in water. A slightly cloudy dispersion was formed.

Example D (Inventive):

[0112] 5% of example ME2 was dispersed in water and a homogeneous, very slightly opaque solution was formed.

Example E (Noninventive):

[0113] 10% of Plantasil Micro (example ME4) was stirred into water. A homogeneous, clear solution was formed.

Treatment of the Hair:

[0114] For the application-related assessment, hair tresses (4 g of Caucasian hair, Kerling, Germany) were predamaged by means of a bleach treatment in a standardized way. For this, customary hairstyling products were used. The test procedure, the base materials used and the details of the assessment criteria are described in DE 103 27 871.

[0115] The hair strands were pre-washed with an SLES solution (12% of Sodium Laureth Sulfate in water) and dried overnight in a climate-controlled chamber at 50% humidity and 22 C. A deep-fat fryer (Tristar FR-6935) containing 2 l of frying oil (Palmin) was set to 170 C. and 750 g of chips (Mc Cain, 1-2-3-Frites Original) were fried for 10 minutes. During the frying process, the hair strands were hung at a distance of 20 cm above the deep-fat fryer, such that they absorbed the odor of frying.

Moist Wipes:

[0116] Moist wipes (Sontara Style 8838, Woodpulp/Polyester, 2020 cm, 50.8 g/m.sup.2, American FlexPack, Inc., Green Bay, Wis., USA) were sprinkled with 5 ml of the formulation solution and stored lying horizontally for 30 min at 25 C. in a closed airtight bag in order to ensure uniform distribution of the ingredients on the nonwoven fabric.

[0117] Subsequently, the hair strands were wiped three times from top to bottom with the moist wipe (the hair tress was guided within the moist wipe while doing so). The hair strands were dried for 1 h in a climate-controlled chamber (22 C., 50% humidity) and subsequently evaluated in a panel test.

Panel Test:

[0118] The hair strands were evaluated on a scale of 1 to 5 (5=best) in terms of odor, feel (softness and silkiness of the hair) and appearance (non-greasiness) by a trained panel of 10 people. The mean values from the panel evaluations obtained are given in the following table. 5 hair strands were evaluated for each formulation.

TABLE-US-00001 Blank value Example C Example E (demin. (non- Example D (non- water) inventive) (inventive) inventive) Odor 1.0 3.0 3.9 2.2 Feel 1.4 4.2 5.0 3.1 Appearance 1.0 3.1 4.1 3.3

[0119] It can be clearly seen that the inventive formulation D (with the microemulsion ME2 with VARISOFT EQ 100 and TEGOSOFT M) gives better panel results for all three evaluation criteria than the noninventive formulation C (only with VARISOFT EQ 100) and the noninventive formulation E with the commercially available microemulsion. In particular, the very good result in terms of odor removal is surprising in this case.

Protection Against the Development of Odors on Hair

[0120] Hair strands, which were pre-washed as described above with an SLES solution, were treated with the moist wipes from application example 1 as described in said example, and subsequently hung over a deep-fat fryer as in example 1. Following the frying process, the odor of the hair was directly evaluated.

TABLE-US-00002 Blank value, Example C Example D Example E water (noninventive) (inventive) (noninventive) Odor 1.0 1.7 2.8 1.5

[0121] The result shows that the inventive formulation D also exerted a significantly protective effect on the hair in terms of the development of frying odor.

Rapid Drying of Hair

[0122] Hair tresses (4 g of Caucasian hair, Kerling, Germany), which were predamaged by means of a bleach treatment in a standardized way, were pre-washed with a Sodium Laureth Sulfate/Cocamidopropyl Betaine solution (9%: 3%) and dried overnight in a climate-controlled chamber at 50% humidity and 22 C., and weighed the next day (m.sub.1).

[0123] For the measurement, the strands were wetted for ten seconds with water (38 C.) and once again pre-washed with 1 g of the Sodium Laureth Sulfate/Cocamidopropyl Betaine solution (9%: 3%), by the surfactant solution being massaged in for 1 minute. The hair was subsequently rinsed for 1 minute with water (38 C.).

[0124] The wet hair was laid in a dish and the formulations to be tested were sprayed from an atomizer in diluted form thereon. 1 g of the diluted formulation was sprayed on; the tresses were regularly turned in the receptacle in order to achieve uniform coverage. The tresses were then left for 1 minute, and excess water was uniformly squeezed out twice between two fingers, from top to bottom. The hair strands were weighed again (m.sub.2).

[0125] The hair was then washed again with 1 g of the Sodium Laureth Sulfate/Cocamidopropyl Betaine solution (9%: 3%) for 1 minute, rinsed with water for 1 minute and left to drip for 1 minute, without the hair being treated again with the formulations. The hair was squeezed out as described and weighed again (m.sub.3).

[0126] 10 hair tresses were tested per formulation, and the mean value was determined.

[0127] The water content of the hair after applying the formulations is calculated from the difference m.sub.2-m.sub.1 and describes the effect of applying the formulation on the water content of the hair.

[0128] The water content of the hair after application and washing the hair again is calculated from the difference m.sub.3-m.sub.1 and shows if the formulation still exerts an effect on the water content even after washing again.

Example F (Inventive):

[0129] 1.25% of example ME2 in water

Example G (Inventive):

[0130] 2.5% of example ME2 in water

Example H (Noninventive):

[0131] 2.5% of Plantasil Micro (example ME4; Dicaprylyl Ether (and) Decyl Glucoside (and) Glyceryl Oleate, BASF) in water

Example I (Noninventive):

[0132] 2.5% of Lamesoft OD (example ME5; Coco-Caprylate (and) Lauryl Glucoside (and) Glycerol (and) Polyglyceryl-2 Dipolyhydroxystearate (and) Polyglyceryl-3 Diisostearate, BASF) in water

[0133] As shown in FIG. 1, the formulations of example F and G with the inventive microemulsion of example ME2 surprisingly showed a significantly lower water uptake than the comparative examples. This can be measured both directly after use of the respective aqueous formulation and also after a subsequent wash with a surfactant formulation. The hair can therefore be dried more rapidly after using the inventive formulations.

Testing the Conditioning of Hair by Means of Sensory TestingShampoo Application 1

[0134] For the application-related assessment of the conditioning of hair, the inventive microemulsions, examples ME1, ME2 and ME3, and also the comparative example, ME4, Plantasil Micro, were tested in a simple cosmetic shampoo formulation (table 1). In each case approximately 1% of active substance (i.e. the sum total of all primarily conditioning active substances) was used.

TABLE-US-00003 TABLE 1 Shampoo formulations for testing the hair conditioning properties. Formulation examples 0a 1a 2a 3a C4a Texapon NSO, 28% strength, 32% 32% 32% 32% 32% BASF, (INCI: Sodium Laureth Sulfate) TEGO Betain F 50, 38% 8% 8% 8% 8% 8% strength, Evonik Nutrition & Care GmbH, (INCI: Cocamidopropyl Betaine) UCARE Polymer JR-400, 0.3% 0.3% 0.3% 0.3% 0.3% Dow Chemicals, (INCI: Polyquaternium-10) ANTIL 171, Evonik 2.5% 2.5% 2.5% 2.5% 2.5% Nutrition & Care GmbH, (INCI: PEG-18 Glyceryl Oleate/Cocoate) NaCl 0.2% 0.2% 0.2% 0.2% 0.2% Water, demineralized to 100.0% Citric acid (10% solution in to pH 5.5 0.3 water) Microemulsion example 2.7 ME1 (inventive) Microemulsion example 2.5 ME2 (inventive) Microemulsion example 3.6 ME3 (inventive) Comparative example 3.6 ME4 - Plantasil Micro (noninventive) Viscosity (Brookfield, 6100 4000 3400 3600 40 25 C., in mPa .Math. s)

[0135] It is noteworthy that, with the inventive formulations 1a, 2a and 3a, unlike the comparative formulation C4a, surprisingly significantly higher viscosities in the shampoo can be reached.

[0136] The hair tresses that were predamaged by means of bleaching as already described above in the first application example (Removal of the odor of frying from hair, by means of moist hair wipes) were treated as follows with the shampoo formulations: The hair tresses were wetted under running warm water. The excess water was squeezed out gently by hand, and then the shampoo was applied and worked gently into the hair (1 ml/hair tress (2 g)). After a contact time of 1 min, the hair was rinsed for 1 min with warm water (38 C.). The excess water was again gently squeezed out by hand and the wet sensory analysis was carried out. Before the sensory assessment of the dry hair, the tresses were dried for at least 12 h in the air at 50% humidity and 25 C.

[0137] Assessment criteria: The sensory evaluations are made using grades awarded on a scale from 1 to 5, with 1 being the worst evaluation and 5 being the best evaluation. The individual test criteria each receive their own evaluation. The test criteria are as follows: Wet combability, wet feel, dry combability, dry feel, appearance/shine.

[0138] The results of the sensory assessment of the treatment of the hair strands, carried out as described above, are compared in the following table. The panel consisted of 5 trained people.

TABLE-US-00004 TABLE 2 Sensory results of the conditioning of hair from shampoo formulation Wet Dry comb- Wet comb- Dry ability feel ability feel Shine Control formulation 0a 3.1 2.8 4.0 3.8 3.0 (placebo) Inventive formulation 1a 4.0 4.0 4.1 4.0 3.4 Inventive formulation 2a 4.3 4.2 4.3 4.1 4.0 Inventive formulation 3a 3.8 3.6 4.1 3.9 3.5 Comparative formulation 3.5 3.5 4.0 3.7 3.1 C4a (noninventive)

[0139] The results show that, surprisingly, particularly the inventive formulation 2a with the inventive microemulsion ME2 receives significantly better evaluations than the comparative formulation C4a with the comparative example ME4 according to the prior art. The good assessment of the shine properties of all inventive formulations is particularly noteworthy. The two other inventive formulations 1a and 3a with the inventive microemulsions ME1 and ME3, respectively, are also significantly better than the comparative formulation C4a.

Testing the Conditioning of Hair by Means of Sensory TestingConditioner Application

[0140] For the application-related assessment of the conditioning of hair, the inventive microemulsion of example ME2 was also tested in a simple cosmetic conditioner formulation (table 3). For comparison, the two conditioning active ingredients from ME2, i.e. Isopropyl Myristate and Ester quat, were also individually (and not in the form of a microemulsion) incorporated into a formulation. In each case 1% of active substance (i.e. the sum total of all primarily conditioning active substances) was used.

TABLE-US-00005 TABLE 3 Conditioner formulations for testing the hair conditioning properties. Formulation examples 0b 1b C2b TEGO Alkanol 1618, Evonik 7% 7% 7% Nutrition & Care GmbH, (INCI: Cetearyl Alcohol) TEGINACID C, Evonik 1% 1% 1% Nutrition & Care GmbH, (INCI: Ceteareth-25) Microemulsion example 2.5% ME2 (inventive) VARISOFT EQ 100, Evonik 0.33% Nutrition & Care GmbH, (INCI: Bis-(Isostearoyl/Oleoyl Isopropyl) Dimonium Methosulfate) TEGOSOFT M, Evonik 0.67% Nutrition & Care GmbH, (INCI: Isopropyl Myristate) Water, demineralized to 100.00% Citric acid (10% solution in to pH 4.0 0.2 water) Viscosity (Brookfield, 25 C., 14 000 13 900 6000 in mPa .Math. s)

[0141] The inventive formulation 1b has surprisingly, unlike the comparative formulation C2b, a significantly higher viscosity in the conditioner (despite the additional constituents in the microemulsion).

[0142] The hair tresses that were predamaged by means of bleaching and prewashed as already described above in the first application example were treated as follows with the conditioner formulations: The hair tresses were wetted under running warm water. The excess water was squeezed out gently by hand, and then the conditioner was applied and worked gently into the hair (1 ml/hair tress (2 g)). After a contact time of 1 min, the hair was rinsed for 3 min with warm water (38 C.). The excess water was again gently squeezed out by hand and the wet sensory analysis was carried out.

[0143] Assessment criteria: The sensory evaluations are made using grades awarded on a scale from 1 to 5, with 1 being the worst evaluation and 5 being the best evaluation. The individual test criteria each receive their own evaluation. The test criteria are as follows: Detanglability of the hair, wet combability, wet feel.

[0144] The results of the sensory assessment of the treatment of the hair strands, carried out as described above, are compared in the following table 4. The panel consisted of 4 trained people.

TABLE-US-00006 TABLE 4 Sensory results of the conditioning of hair from conditioner formulation Wet Wet Detanglability combability feel Control formulation 2.0 1.8 1.6 0b (placebo) Inventive 3.6 3.8 4.2 formulation 1b Comparative 3.3 3.3 3.5 formulation C2b (noninventive)

[0145] The results show that, surprisingly, the inventive formulation 1b with the inventive microemulsion ME2 receives very much better evaluations than the comparative formulation C2b, in which the conditioning active substances were incorporated separately.

Testing the Conditioning of Hair by Means of Sensory Testing Shampoo Application 2

[0146] For the application-related assessment of the conditioning of hair, the inventive microemulsions, examples ME2, ME20, ME21 and ME22 were tested in a simple cosmetic shampoo formulation (table 5).

TABLE-US-00007 TABLE 5 Shampoo formulations for testing the hair conditioning properties. Formulation examples 0c 1c 2c 3c 4c Texapon NSO, 28% 32% 32% 32% 32% 32% strength, BASF, (INCI: Sodium Laureth Sulfate) TEGO Betain F 50, 38% 8% 8% 8% 8% 8% strength, Evonik Nutrition & Care GmbH, (INCI: Cocamidopropyl Betaine) UCARE Polymer JR- 0.3% 0.3% 0.3% 0.3% 0.3% 400, Dow Chemicals, (INCI: Polyquaternium- 10) ANTIL 171, Evonik 2.5% 2.5% 2.5% 2.5% 2.5% Nutrition & Care GmbH, (INCI: PEG-18 Glyceryl Oleate/Cocoate) NaCl 0.2% 0.2% 0.2% 0.2% 0.2% Water, demineralized to 100.0% Citric acid (10% to pH 5.5 0.3 solution in water) Microemulsion example 2.8 ME20 (inventive) Microemulsion example 2.5 ME2 (inventive) Microemulsion example 2.5 ME22 (inventive) Microemulsion example 3.1 ME21 (inventive) - Viscosity (Brookfield, 6000 1500 2900 540 110 25 C., in mPa .Math. s)

[0147] The testing of the formulations from table 5 was also carried out exactly as described above for table 2:

TABLE-US-00008 TABLE 6 Sensory results of the conditioning of hair from shampoo formulation Wet Dry comb- Wet comb- Dry ability feel ability feel Shine Control 3.0 3.0 4.0 3.8 3.2 formulation 0c (placebo) Inventive 4.0 4.0 4.2 4.0 3.6 formulation 1c Inventive 4.3 4.3 4.3 4.2 3.9 formulation 2c Inventive 3.6 3.5 4.0 3.9 3.3 formulation 3c Inventive 4.4 4.5 4.3 3.7 3.9 formulation 4c

[0148] The results show that the inventive formulation 2c has similarly very good values to the formulation 4c that is additionally provided with silicone quat, and also significantly exceeds the silicone quat formulation, especially in terms of dry feel.

[0149] For the formulations 1c and 2c, the good viscosities stand out; the formulations thus require fewer rheological additives and thickeners in order to achieve a viscosity customary for shampoos; thus, they are very readily thickened.

Further Formulation Examples:

[0150] The formulation examples given in the tables below show exemplary representatives of a large number of possible compositions according to the invention.

[0151] If the preparation of the formulation requires the separate preparation or mixing of formulation constituents beforehand, this is termed multiphase preparation.

[0152] If a two-phase preparation is required, the two phases are labelled A and B in the stated tables. In the case of three-phase processes, the three phases are called A, B and C. Unless otherwise indicated, the amounts in the tables below are amounts in wt %.

Formulation Example 1) Clear Shampoo

[0153]

TABLE-US-00009 TEXAPON NSO, BASF, 28% 32.00% strength (INCI: Sodium Laureth Sulfate) Microemulsion ME3 2.00% Perfume 0.20% TEGO Betain F 50, Evonik 8.00% Nutrition & Care GmbH, 38% strength (INCI: Cocamidopropyl Betaine) ANTIL 171 Evonik Nutrition & 1.70% Care GmbH, (INCI: PEG-18 Glyceryl Oleate/Cocoate) Water to 100.00% NaCl 0.80% Citric acid, 30% strength q.s. to pH 5.5 Preservative q. s.

Formulation Example 2) Clear Conditioning Shampoo

[0154]

TABLE-US-00010 TEXAPON NSO, BASF, 28% 35.00% strength (INCI: Sodium Laureth Sulfate) ANTIL 200, Evonik Nutrition & 1.50% Care GmbH (INCI: PEG-200 Hydrogenated Glyceryl Palmate; PEG-7 Glyceryl Cocoate) Microemulsion ME1 2.00% Perfume 0.25% Water to 100.00% Polymer JR 400, Amerchol, 0.20% (INCI : Polyquaternium-10) TEGO Betain F 50, Evonik 8.00% Nutrition & Care GmbH, 38% strength (INCI: Cocamidopropyl Betaine) NaCl 1.50% Citric acid, 30% strength q.s. to pH 5.5 Preservative q.s.

Formulation Example 3) Clear Conditioning Shampoo

[0155]

TABLE-US-00011 TEXAPON NSO, BASF, 28% 20.00% strength (INCI: Sodium Laureth Sulfate) ANTIL 200, Evonik Nutrition & 1.80% Care GmbH, (INCI: PEG-200 Hydrogenated Glyceryl Palmate; PEG-7 Glyceryl Cocoate) ABIL Quat 3272, Evonik 1.00% Nutrition & Care GmbH, (INCI: Quaternium-80) Microemulsion ME2 2.50% Perfume 0.25% Water to 100.00% Polymer JR 400, Amerchol 0.30% (INCI : Polyquaternium-10) TEGO Betain F 50, Evonik 18.00% Nutrition & Care GmbH, 38% strength (INCI: Cocamidopropyl Betaine) NaCl 0.90% Lactic acid, 80% strength q.s. to pH 5.5 Preservative q. s.

Formulation Example 4) Clear Conditioning Shampoo

[0156]

TABLE-US-00012 TEXAPON NSO, BASF, 28% strength 32.00% (INCI: Sodium Laureth Sulfate) ANTIL 500 Pellets, Evonik Nutrition & Care GmbH 1.00% (INCI: PEG-200 Glyceryl Stearate) ABIL B 8832, Evonik Nutrition & Care GmbH 0.50% (INCI: Bis-PEG/PPG-20/20 Dimethicone) Microemulsion ME6 3.50% Perfume 0.20% Water to 100.00% Polymer JR 400, Amerchol 0.20% (INCI: Polyquaternium-10) TEGO Betain F 50, Evonik 8.00% Nutrition & Care GmbH, 38% strength (INCI: Cocamidopropyl Betaine) NaCl 0.80% Citric acid, 30% strength q.s. to pH 5.5 Preservative q. s.

Formulation Example 5) Clear Conditioning Shampoo

[0157]

TABLE-US-00013 TEXAPON NSO, BASF, 28% strength 32.00% (INCI: Sodium Laureth Sulfate) VARISOFT PATC, Evonik Nutrition & Care GmbH, 1.50% (INCI: Palmitamidopropyltrimonium Chloride) REWODERM LI S 80, Evonik Nutrition & Care 2.50% GmbH, (INCI: PEG-200 Hydrogenated Glyceryl Palmate; PEG-7 Glyceryl Cocoate) Microemulsion ME13 2.00% Perfume 0.15% Water to 100.00% TEGO Cosmo C 100, Evonik Nutrition & Care GmbH, 1.00% (INCI: Creatine) Jaguar C-162, Solvay, (INCI: Hydroxypropyl 0.30% Guar Hydroxypropyltrimonium Chloride) TEGO Betain F 50, Evonik Nutrition & Care GmbH, 8.00% 38% strength (INCI: Cocamidopropyl Betaine) NaCl 1.50% Citric acid, 30% strength q.s. to pH 5.5 Preservative q. s.

Formulation Example 6) Clear Conditioning Shampoo

[0158]

TABLE-US-00014 Microemulsion ME16 2.50% Argan Oil, DSM Nutritional Products Ltd., 0.1% (INCI: Argania Spinosa Oil (Argania Spinosa Kernel Oil)) TEXAPON NSO, BASF, 28% strength 32.00% (INCI: Sodium Laureth Sulfate) REWODERM LI S 80, Evonik Nutrition & Care 2.00% GmbH, (INCI: PEG-200 Hydrogenated Glyceryl Palmate; PEG-7 Glyceryl Cocoate) Perfume 0.25% Water to 100.00% TEGO Cosmo C 100, Evonik Nutrition & 1.50% Care GmbH, (INCI: Creatine) Jaguar C-162, Solvay, (INCI: Hydroxypropyl 0.20% Guar Hydroxypropyltrimonium Chloride) TEGO Betain F 50, Evonik Nutrition & Care 8.00% GmbH, 38% strength (INCI: Cocamidopropyl Betaine) NaCl 2.50% Citric acid, 30% strength q.s. to pH 5.0 Preservative q. s.

Formulation Example 7) Pearlized Shampoo

[0159]

TABLE-US-00015 TEXAPON NSO, BASF, 28% strength 32.00% (INCI: Sodium Laureth Sulfate) Microemulsion ME19 5.50% Perfume 0.15% Water to 100.00% TEGO Betain F 50, Evonik Nutrition & 8.00% Care GmbH, 38% strength (INCI: Cocamidopropyl Betaine) TEGO Pearl N 300, Evonik Nutrition & Care 2.00% GmbH, (INCI: Glycol Distearate; Laureth-4; Cocamidopropyl Betaine) ANTIL 171 Evonik Nutrition & Care GmbH, 2.50% (INCI: PEG-18 Glyceryl Oleate/Cocoate) NaCl 0.90% Citric acid, 30% strength q.s. to pH 5.5 Preservative q.s.

Formulation Example 8) Turbid Conditioning Shampoo

[0160]

TABLE-US-00016 TEXAPON NSO, BASF, 28% strength (INCI: 32.00% Sodium Laureth Sulfate) ANTIL 200, Evonik Nutrition & Care GmbH, (INCI: 2.00% PEG-200 Hydrogenated Glyceryl Palmate; PEG-7 Glyceryl Cocoate) Microemulsion ME18 1.00% Perfume 0.25% Water to 100.00% Polymer JR 400, Amerchol, (INCI: Polyquaternium-10) 0.40% TEGO Betain F 50, Evonik Nutrition & Care GmbH, 8.00% 38% strength (INCI: Cocamidopropyl Betaine) DC1503 Fluid, Dow Corning, (INCI: Dimethicone, 1.00% Dimethiconol) TEGO Pearl N 300, Evonik Nutrition & Care 2.00% GmbH, (INCI: Glycol Distearate; Laureth-4; Cocamidopropyl Betaine) NaCl 0.30% Citric acid, 30% strength q.s. to pH 5.5 Preservative q. s.

Formulation Example 9) Bodycare Foam

[0161]

TABLE-US-00017 TEXAPON NSO, BASF, 28% strength 15.00% (INCI: Sodium Laureth Sulfate) Perfume 0.30% Microemulsion ME7 1.50% REWOTERIC AM C, Evonik Nutrition & Care GmbH, 8.00% 32% strength (INCI: Sodium Cocoamphoacetate) Water to 100.00% TEGOCEL HPM 50, Evonik Nutrition & Care GmbH, 0.50% (INCI: Hydroxypropyl Methylcellulose) LACTIL, Evonik Nutrition & Care GmbH, 1.00% (INCI: Sodium Lactate; Sodium PCA; Glycine; Fructose; Urea; Niacinamide; Inositol; Sodium benzoate; Lactic Acid) Citric Acid Monohydrate 0.50% Preservative q. s.

Formulation Example 10) Bodycare Product

[0162]

TABLE-US-00018 TEXAPON NSO, BASF, 28% strength 30.00% (INCI: Sodium Laureth Sulfate) TEGOSOFT PC 31, Evonik Nutrition & Care GmbH, 0.50% (INCI: Polyglyceryl-3 Caprate) Microemulsion ME2 4.50% Perfume 0.30% Water to 100.00% TEGOCEL HPM 4000, Evonik Nutrition & 0.30% Care GmbH, (INCI: Hydroxypropyl Methylcellulose) Jaguar C-162, Solvay, (INCI: Hydroxypropyl Guar 0.20% Hydroxypropyltrimonium Chloride) REWOTERIC AM C, Evonik Nutrition & Care GmbH, 12.00% 32% strength (INCI: Sodium Cocoamphoacetate) Citric Acid Monohydrate 0.50% REWODERM LI S 80, Evonik Nutrition & 2.00% Care GmbH, (INCI: PEG-200 Hydrogenated Glyceryl Palmate; PEG-7 Glyceryl Cocoate) TEGO Pearl N 300, Evonik Nutrition & Care GmbH, 2.00% (INCI: Glycol Distearate; Laureth-4; Cocamidopropyl Betaine) NaCl 1.00% Preservative q.s.

Formulation Example 11) Bodycare Foam

[0163]

TABLE-US-00019 TEXAPON NSO, BASF, 28% strength 14.30% (INCI: Sodium Laureth Sulfate) ANTIL 500 pellets, Evonik Nutrition & Care GmbH 0.70% (INCI: PEG-200 Glyceryl Stearate) Perfume 0.30% Microemulsion ME3 1.00% REWOTERIC AM C, Evonik Nutrition & Care GmbH, 10.00% 32% strength (INCI: Sodium Cocoamphoacetate) NaCl 1.50% Water to 100.00% Merquat 550, Nalco, (INCI: Polyquaternium-7) 0.30% LACTIL, Evonik Nutrition & Care GmbH, 0.50% (INCI: Sodium Lactate; Sodium PCA; Glycine; Fructose; Urea; Niacinamide; Inositol; Sodium benzoate; Lactic Acid) Citric acid, 30% strength q.s. to pH 5.5

Formulation Example 12) Mild Foam Bath

[0164]

TABLE-US-00020 TEXAPON NSO, BASF, 28% strength 27.00% (INCI: Sodium Laureth Sulfate) REWOPOL SB FA 30, Evonik Nutrition & 12.00% Care GmbH, 40% strength (INCI: Disodium Laureth Sulfosuccinate) TEGOSOFT LSE 65 K SOFT, Evonik Nutrition & 2.00% Care GmbH, (INCI: Sucrose Cocoate) Water to 100.00% Jaguar C-162, Solvay, (INCI: Hydroxypropyl 0.15% Guar Hydroxypropyltrimonium Chloride) REWOTERIC AM C, Evonik Nutrition & Care GmbH, 12.00% 32% strength (INCI: Sodium Cocoamphoacetate) Microemulsion ME7 1.50% Citric acid, 30% strength 3.00% ANTIL 171, Evonik Nutrition & Care GmbH, 1.75% (INCI: PEG-18 Glyceryl Oleate/Cocoate) NaCl 1.00% TEGO Pearl N 300 Evonik Nutrition & Care GmbH 2.00% (INCI: Glycol Distearate; Laureth-4; Cocamidopropyl Betaine)

Formulation Example 13) Moisturizing Skin Cleanser

[0165]

TABLE-US-00021 A TEXAPON NSO, BASF, 28% strength, 30.00% (INCI: Sodium Laureth Sulfate) Microemulsion ME2 3.70% Perfume 0.30% B Water to 100.00% TEGOCEL fluid HPM 4000, Evonik 1.20% Nutrition & Care GmbH, (INCI: Hydroxypropyl Methylcellulose) TEGO Betain C 60, Evonik Nutrition & Care GmbH, 46% strength, 8.10% (INCI: Cocamidopropyl Betaine) TEGOSOFT APM, Evonik 1.00% Nutrition & Care GmbH, (INCI: PPG-3 Myristyl Ether) Cutina TS, BASF (INCI:PEG- 3 Distearate) 1.00% REWODERM LI S 80, Evonik 1.50% Nutrition & Care GmbH, (INCI: PEG-200 Hydrogenated Glyceryl Palmate; PEG-7 Glyceryl Cocoate) Preservative 0.60% Citric acid, 30% strength q.s. to pH 5.5

Formulation Example 14) Shower Gel

[0166]

TABLE-US-00022 TEXAPON NSO, BASF, 28% strength 15.00% (INCI: Sodium Laureth Sulfate) Microemulsion ME3 1.50% Microemulsion ME19 1.00% Perfume 0.30% PGFAC-S, BASF, (INCI: Sodium cocoyl hydrolysed 1.00% wheat protein glutamate) REWOPOL SB CS 50 B, Evonik Nutrition & Care 7.50% GmbH, 40% strength, (INCI: Disodium PEG-5 Laurylcitrate Sulfosuccinate; Sodium Laureth Sulfate) Water to 100.00% TEGO Betain F 50, Evonik Nutrition & Care GmbH, 9.00% 38% strength, (INCI: Cocamidopropyl Betaine) TEGO Betain 810, Evonik Nutrition & Care GmbH, 4.00% 38% strength, (INCI: Capryl/Capramidopropyl Betaine) Merquat 550, Nalco, (INCI: Polyquaternium-7) 0.50% ANTIL 200, Evonik Nutrition & Care GmbH, (INCI: 2.00% PEG-200 Hydrogenated Glyceryl Palmate; PEG-7 Glyceryl Cocoate) NaCl 1.80% Citric acid, 30% strength q.s. to pH 5.2 Preservative q. s.

Formulation Example 15) Body Cleanser

[0167]

TABLE-US-00023 A TEXAPON NSO, BASF, 28% strength, 30.00% (INCI: Sodium Laureth Sulfate) Microemulsion ME7 1.50% ABIL B 8832, Evonik Nutrition & Care GmbH, 0.30% (INCI: Bis-PEG/PPG-20/20 Dimethicone) Perfume 0.30% B Water to 100.00% TEGOCEL fluid HPM 4000, Evonik Nutrition & 1.20% Care GmbH, (INCI: Hydroxypropyl Methylcellulose) Jaguar C-162, Solvay, (INCI: Hydroxypropyl 0.15% guar hydroxypropyltrimonium chloride Citric Acid Monohydrate 0.50% REWOTERIC AM C, Evonik Nutrition & Care 10.00% GmbH, 32% strength, (INCI: Sodium Cocoamphoacetate) Cutina TS, BASF, (INCI: PEG- 3 Distearate) 2.00% REWODERM LI S 80, Evonik Nutrition & Care 2.60% GmbH, (INCI: PEG-200 Hydrogenated Glyceryl Palmate; PEG-7 Glyceryl Cocoate) C Preservative 0.60%

Formulation Example 16) Body Cleansing Foam

[0168]

TABLE-US-00024 TEXAPON NSO, BASF, 28% strength 18.00% (INCI: Sodium Laureth Sulfate) Perfume 0.30% Microemulsion ME18 0.70% Cropure Olive, Croda, (INCI: Olea Europaea (Olive) 0.10% Fruit Oil) REWOTERIC AM C, Evonik Nutrition & Care GmbH, 8.00% 32% strength (INCI: Sodium Cocoamphoacetate) TEGO Betain F 50, Evonik Nutrition & Care GmbH, 8.00% 38% strength (INCI: Cocamidopropyl Betaine) Water to 100.00% Jaguar C-162, Solvay, (INCI: Hydroxypropyl 0.25% Guar Hydroxypropyltrimonium Chloride) ANTIL Soft SC, Evonik Nutrition & Care GmbH, 0.50% (INCI: Sorbitan Sesquicaprylate) ANTIL 120 Plus, Evonik Nutrition & Care GmbH, 1.50% (INCI: PEG-120 Methyl Glucose Dioleate) TEGO Cosmo C 100, Evonik Nutrition & Care GmbH, 1.00% (INCI: Creatine) NaCl 1.00% Panthenol, BASF, (INCI: D- Panthenol) 0.20% Citric Acid Monohydrate 0.50%

Formulation Example 17) Anti-Dandruff Shampoo

[0169]

TABLE-US-00025 TEXAPON LS 35, BASF, 30% strength 24.00% (INCI: Sodium Lauryl Sulfate) TAGAT CH 40, Evonik Nutrition & 2.00% Care GmbH, (INCI: PEG-40 Hydrogenated Castor Oil) TEGOSOFT GC, Evonik Nutrition & 1.00% Care GmbH, (INCI: PEG-7 Glyceryl Cocoate) Cropure Avocado, Croda, 0.15% (INCI: Persea Gratissima (Avocado) Oil) Microemulsion ME19 2.00% Perfume 0.20% Water to 100.00% Polymer JR 400, Amerchol, (INCI: Poly 0.20% quaternium-10) TEGO Betain F 50, Evonik Nutrition & Care 16.00% GmbH, 38% strength (INCI: Cocamidopropyl Betaine) Hostapon SG, Clariant, (INCI: Sodium Cocoyl 5.00% Glycinate) Microcare ZP, Thor, (INCI: Zinc Pyrithione) 0.20% Octopirox, Clariant, (INCI: Octopirox) 0.10% ABIL Quat 3272, Evonik Nutrition & 0.80% Care GmbH, (INCI: Quaternium-80) REWOMID D 212, Evonik Nutrition & 0.80% Care GmbH, (INCI: Cocamide MEA) ANTIL 500, Evonik Nutrition & Care GmbH, 0.80% (INCI: PEG-200 Glyceryl Stearate) Glycerol 1.50% NaCl 0.90% Citric acid, 30% strength q.s. to pH 5.5 Preservative q. s.

Formulation Example 18) PEG-Free Shampoo

[0170]

TABLE-US-00026 TEXAPON LS 35, BASF, 30% strength 12.00% (INCI: Sodium Lauryl Sulfate) TEGO Betain F 50, Evonik Nutrition & Care GmbH, 18.00% 38% strength (INCI: Cocamidopropyl Betaine) Iselux, Innospec, (INCI: Sodium Lauroyl Methyl 4.00% Isethionate) TEGOSOFT PC 41, Evonik Nutrition & Care 2.00% GmbH, (INCI: Polyglyceryl-4 Caprate) Microemulsion ME18 1.50% Perfume 0.25% Water to 100.00% Jaguar C-162, Solvay (INCI: Hydroxypropyl 0.20% Guar Hydroxypropyltrimonium Chloride) Versene 100, The Dow Chemical Company, 0.20% (INCI: Tetrasodium EDTA) REWOMID D 212, Evonik Nutrition & Care GmbH, 0.80% (INCI: Cocamide MEA) ANTIL SPA 80, Evonik Nutrition & Care GmbH, 0.80% (INCI: Isostearamide MIPA; Glyceryl Laurate) Keltrol CG-SFT, CP Kelco, (INCI: Xanthan Gum) 0.20% Glycerol 1.50% NaCl 0.70% Citric acid, 30% strength q.s. to pH 5.1 Preservative q. s.

Formulation Example 19) Conditioning Anti-Dandruff Shampoo

[0171]

TABLE-US-00027 A TEGIN G 1100 Pellets, Evonik Nutrition & Care 3.00% GmbH, (INCI: Glycol Distearate) TEXAPON NSO, BASF, 28% strength, 40.00% (INCI: Sodium Laureth Sulfate) B Perfume 0.30% Zinc-Pyrion NF, WeyIChem, 48% strength, (INCI: 2.00% Zinc Pyrithione) Microemulsion ME3 2.00% C Water to 100.00% TEGO Carbomer 341 ER, Evonik Nutrition & Care 0.20% GmbH, (INCI: Acrylates/C10-30 Alkyl Acrylate Crosspolymer) Water 0.30% NaOH, 25% strength 0.30% D REWOTERIC AM B U 185, Evonik Nutrition & 12.50% Care GmbH, 30% strength, (INCI: Undecylenamidopropyl Betaine) ANTIL SPA 80, Evonik Nutrition & Care GmbH, 3.70% (INCI: Isostearamide MIPA; Glyceryl Laurate) Preservative q. s.

Formulation Example 20) PEG- and Sulfate-Free Shampoo

[0172]

TABLE-US-00028 REWOTERIC AM C, Evonik 16.00% Nutrition & Care GmbH, 32% strength, (INCI: Sodium Cocoamphoacetate Plantapon ACG 50, BASF, 3.80% (INCI: Disodium Cocoyl Glutamate) Plantacare 818 UP, BASF, 51% strength, 5.00% (INCI: Coco Glucoside) Microemulsion ME2 2.50% Perfume 0.30% Water to 100.00% TEGO Betain F 50, Evonik Nutrition & Care 6.00% GmbH, 38% strength, (INCI: Cocamidopropyl Betaine) ANTIL SPA 80, Evonik Nutrition & Care GmbH, 1.80% (INCI: Isostearamide MIPA; Glyceryl Laurate) Preservative q. s. Citric acid, 30% strength q. s. to pH 5.0

Formulation Example 21) PEG- and Sulfate-Free Shampoo

[0173]

TABLE-US-00029 A REWOTERIC AMC, Evonik Nutrition & Care 20.00% GmbH, 32% strength, (INCI: Sodium Cocoamphoacetate) REWOPOL SB F 12 P, Evonik Nutrition & Care 6.00% GmbH, 96% strength, (INCI: Disodium Lauryl Sulfosuccinate) Microemulsion ME18 2.00% ANTIL SPA 80, Evonik Nutrition & Care GmbH, 1.70% (INCI: Isostearamide MIPA; Glyceryl Laurate) B Water to 100.00% Jaguar C-162, Solvay, (INCI: Hydroxypropyl Guar 0.10% Hydroxypropyltrimonium Chloride) Citric acid, 30% strength 3.60% C ANTIL HS 60, Evonik Nutrition & Care GmbH, 3.00% (INCI: Cocamidopropyl Betaine; Glyceryl Laurate) Preservative q. s.

Formulation Example 22) Mild Hair & Body Wash, PEG- and Sulfate-Free

[0174]

TABLE-US-00030 Plantacare 1200 UP, BASF, 50% strength, (INCI: Lauryl 11.40% Glucoside) Plantacare 818 UP, BASF, 51% strength, (INCI: Coco 5.60% Glucoside) Water to 100.00% ANTIL Soft SC, Evonik Nutrition & Care GmbH, 0.90% (INCI: Sorbitan Sesquicaprylate) Microemulsion ME3 1.00% TEGOSOFT LSE 65 K SOFT, Evonik Nutrition & Care 1.50% GmbH, (INCI: Sucrose Cocoate) TEGO Betain F 50, Evonik Nutrition & Care GmbH, 38% 18.00% strength, (INCI: Cocamidopropyl Betaine) Perfume, preservative q. s. Citric acid, 30% strength q.s. to pH 5.0

Formulation Example 23) Sulfate-Free Mild Shampoo

[0175]

TABLE-US-00031 Plantacare 1200 UP, BASF, 50% strength, 8.50% (INCI: Lauryl Glucoside) Plantacare 818 UP, BASF, 51% strength, 2.30% (INCI: Coco Glucoside) Water to 100.00% ANTIL 200, Evonik Nutrition & Care GmbH, 4.00% (INCI: PEG-200 Hydrogenated Glyceryl Palmate; PEG-7 Glyceryl Cocoate) Microemulsion ME3 5.00% REWOPOL SB FA 30 B, Evonik Nutrition & Care 9.00% GmbH, (INCI: Disodium Laureth Sulfosuccinate) TEGO Betain F 50, 14.70% Evonik Nutrition & Care GmbH, 38% strength, (INCI: Cocamidopropyl Betaine) Perfume, preservative q. s. Citric acid, 30% strength q.s. to pH 5.0

Formulation Example 24) Sulfate-Free Mild Shampoo

[0176]

TABLE-US-00032 Plantacare 1200 UP, BASF, 50% strength, (INCI: Lauryl 8.50% Glucoside) Plantacare 818 UP, BASF, 51% strength, (INCI: Coco 2.30% Glucoside) Water to 100.00% Tilamar 740, DSM, 0.20% (INCI: Polyquatemium-7) ANTIL 171, Evonik Nutrition & Care GmbH, 0.60% (INCI: PEG-18 Glyceryl Oleate/Cocoate) Microemulsion ME3 3.00% Perlastan SC 25 NKW, Schill&Seilacher, 14.40% (INCI: Disodium Cocoyl Glutamate, Sodium Cocoyl Glutamate) TEGO Betain F 50, Evonik Nutrition & Care GmbH, 38% 14.70% strength, (INCI: Cocamidopropyl Betaine) Perfume, preservative q.s. Citric acid, 30% strength q.s. to pH 5.3

Formulation Example 25) PEG- and Sulfate-Free Mild Shampoo

[0177]

TABLE-US-00033 Plantacare 1200 UP, BASF, 50% strength, (INCI: Lauryl 10.00% Glucoside) Water to 100.00% UCARE Polymer JR-400, Dow Chemicals, 0.10% (INCI: Polyquatemium-10) ANTIL SPA 80, Evonik Nutrition & Care GmbH, 1.20% (INCI: Isostearamide MIPA; Glyceryl Laurate) Microemulsion ME2 2.50% REWOTERIC AM C, Evonik Nutrition & Care GmbH, 21.30% 32% strength, (INCI: Sodium Cocoamphoacetate TEGO Betain P 50 C, Evonik Nutrition & Care GmbH, 10.50% 38% strength, (INCI: Cocamidopropyl Betaine) Perfume, preservative q.s. Citric acid, 30% strength q.s. to pH 5.1

Formulation Example 26) Shampoo

[0178]

TABLE-US-00034 TEXAPON NSO, BASF, 28% strength, 32.10% (INCI: Sodium Laureth Sulfate) Water to 100.00% UCARE Polymer JR-400, Dow Chemicals, 0.20% (INCI: Polyquaternium-10) ANTIL SPA 80, Evonik Nutrition & Care GmbH, 0.50% (INCI: Isostearamide MIPA; Glyceryl Laurate) ANTIL 171, Evonik Nutrition & Care GmbH, 2.00% (INCI: PEG-18 Glyceryl Oleate/Cocoate) Microemulsion ME3 5.00% TEGO Pearl N 300, Evonik Nutrition & Care GmbH, 1.50% (INCI: Glycol Distearate; Laureth-4; Cocamidopropyl Betaine) TEGO Betain F 50, Evonik Nutrition & Care GmbH, 7.90% 38% strength, (INCI: Cocamidopropyl Betaine) Sodium Chloride 1.00% Perfume, preservative q.s. Citric acid, 30% strength q.s. to pH 5.0

Formulation Example 27) PEG-Free Shampoo

[0179]

TABLE-US-00035 TEXAPON LS 35, BASF, 30%, 28.00% (INCI: Sodium Lauryl Sulfate) Water to 100.00% UCARE Polymer JR-400, Dow Chemicals, 0.10% (INCI: Polyquaternium-10) Jaguar C-162, Solvay, 0.10% (INCI: Hydroxypropyl Guar Hydroxypropyltrimonium Chloride) ANTIL CM 90, Evonik Nutrition & Care GmbH, 0.50% (INCI: Cocamide MEA) ANTIL SPA 80, Evonik Nutrition & Care GmbH, 1.00% (INCI: Isostearamide MIPA; Glyceryl Laurate) Xanthan Gum 0.50% Microemulsion ME3 3.00% Argan Oil, DSM Nutritional Products Ltd., (INCI: Argania 0.10% Spinosa Oil) Dehyton AB 30, BASF, 31%, (INCI: Coco-Betaine) 8.00% Prifrac 2920, Croda, (INCI: Lauric Acid) 0.50% TEGOSOFT PC 41, Evonik Nutrition & Care GmbH, 1.00% (INCI: Polyglyceryl-4 Caprate) Glycerol 1.00% Uvinul MS 40, BASF, (INCI: Benzophenon-4) 0.10% Versene 100, The Dow Chemical Company, (INCI: 0.1% Tetrasodium EDTA) Sodium Chloride 1.00% Perfume, preservative q. s. Citric acid, 30% strength q.s. to pH 5.0

Formulation Example 28) Sulfate-Free Shampoo

[0180]

TABLE-US-00036 Bioterge AS-40 AOS, Stepan, 30.00% (INCI: Sodium C14-16 Olefin Sulfonate) Water to 100.00% Jaguar C-162, Solvay, 0.15% (INCI: Hydroxypropyl Guar Hydroxypropyltrimonium Chloride) ANTIL 500 Pellets, Evonik Nutrition & Care GmbH, 0.20% (INCI: PEG-200 Glyceryl Stearate) ANTIL SPA 80, Evonik Nutrition & Care GmbH, 0.50% (INCI: Isostearamide MIPA; Glyceryl Laurate) Microemulsion ME2 3.50% Cropure Avocado, Croda, (INCI: Persea Gratissima 0.10% (Avocado) Oil) Dehyton AB 30, BASF, 31%, (INCI: Coco-Betaine) 8.00% TAGAT CH 40, Evonik Nutrition & Care GmbH, 1.00% (INCI: PEG-40 Hydrogenated Castor Oil) Glycerol 1.00% Uvinul MS 40, BASF, (INCI: Benzophenon-4) 0.10% Sodium Chloride 1.50% Perfume, preservative q. s. Citric acid, 30% strength q.s. to pH 5.5

Formulation Example 29) Sulfate-Free Shampoo

[0181]

TABLE-US-00037 TEGO Betain F 50, Evonik Nutrition & Care GmbH, 22.00% 38% strength, (INCI: Cocamidopropyl Betaine) Water to 100.00% Jaguar C-162, Solvay, 0.10% (INCI: Hydroxypropyl Guar Hydroxypropyltrimonium Chloride) ANTIL 500 Pellets, Evonik Nutrition & Care GmbH, 0.30% (INCI: PEG-200 Glyceryl Stearate) REWOPAL PEG 6000 DS A, Evonik Nutrition & Care 0.50% GmbH, (INCI: PEG-150 Distearate) Microemulsion ME3 2.50% Cropure Olive, Croda, (INCI: Olea Europaea (Olive) Fruit 0.10% Oil) Hostapon SG, Clariant, (INCI: Sodium Cocoyl Glycinate) 10.00% TEGO Solve 61, Evonik Nutrition & Care GmbH, 1.00% (INCI: Polyglycery1-6 Caprylate; Polyglycery1-3 Cocoate; Polyglycery1-4 Caprate; Polyglycery1-6 Ricinoleate) Glycerol 0.50% Sodium Chloride 1.00% Perfume, preservative q. s. Citric acid, 30% strength q.s. to pH 4.8

Formulation Example 30) Rinse-Off Conditioner

[0182]

TABLE-US-00038 Water to 100.00% VARISOFT BT 85, Evonik Nutrition & Care GmbH, 2.00% (INCI: Behentrimonium Chloride) Microemulsion ME2 3.50% TEGO Alkanol 1618, Evonik Nutrition & Care GmbH, 5.00% (INCI: Cetearyl Alcohol) Citric acid, 30% strength q.s. to pH 4.5 Preservative, perfume q.s.

Formulation Example 31) Rinse-Off Conditioner

[0183]

TABLE-US-00039 Water to 100.00% VARISOFT EQ 65, Evonik Nutrition & Care GmbH, 2.00% (INCI: Distearoylethyl Dimonium Chloride; Cetearyl Alcohol) VARISOFT BT 85, Evonik Nutrition & Care GmbH, 1.00% (INCI: Behentrimonium Chloride) Microemulsion ME19 1.80% TEGO Alkanol 1618, Evonik Nutrition & Care GmbH, 5.00% (INCI: Cetearyl Alcohol) Citric acid, 30% strength q.s. to pH 4.0 Preservative, perfume q.s.

Formulation Example 32) Rinse-Off Conditioner

[0184]

TABLE-US-00040 Water to 100.00% VARISOFT EQ 65, Evonik Nutrition & Care GmbH, 2.00% (INCI: Distearoylethyl Dimonium Chloride; Cetearyl Alcohol) VARISOFT BT 85, Evonik Nutrition & Care GmbH 2.00% (INCI: Behentrimonium Chloride) ABIL Quat 3272, Evonik Nutrition & Care GmbH, 0.50% (INCI: Quaternium-80) Microemulsion ME18 4.50% TEGINACID C, Evonik Nutrition & Care GmbH, 0.50% (INCI: Ceteareth-25) TEGO Alkanol 1618, Evonik Nutrition & Care GmbH, 5.00% (INCI: Cetearyl Alcohol) Citric acid, 30% strength q.s. to pH 3.5 Preservative, perfume q.s.

Formulation Example 33) Rinse-Off Conditioner

[0185]

TABLE-US-00041 TEGINACID C, Evonik Nutrition & Care GmbH, 0.50% (INCI: Ceteareth-25) TEGO Alkanol 16, Evonik Nutrition & Care GmbH, 2.00% (INCI: Cetyl Alcohol) TEGO Amid S 18, Evonik Nutrition & Care GmbH, 1.00% (INCI: Stearamidopropyl Dimethylamine) Microemulsion ME2 3.50% Propylene Glycol 2.00% Citric Acid Monohydrate 0.30% Water to 100.00% Preservative, perfume q.s.

Formulation Example 34) Rinse-Off Conditioner

[0186]

TABLE-US-00042 TEGINACID C, Evonik 0.50% Nutrition & Care GmbH, (INCI: Ceteareth-25) TEGO Alkanol 1618, Evonik 6.50% Nutrition & Care GmbH, (INCI: Cetearyl Alcohol) Microemulsion ME19 3.50% Water to 100.00% TEGO Cosmo C 100, Evonik 0.50% Nutrition & Care GmbH, (INCI: Creatine) Propylene Glycol 2.00% Citric acid, 30% strength q.s. to pH 4.0 Preservative, perfume q.s.

Formulation Example 35) Rinse-Off Conditioner

[0187]

TABLE-US-00043 Water to 100.00% TEGIN M Pellets, Evonik Nutrition & 1.00% Care GmbH, (INCI: Glyceryl Stearate) Oleyl Alcohol 0.70% Glycerol 1.50% Microemulsion ME2 2.50% TEGO Alkanol 1618, Evonik 4.50% Nutrition & Care GmbH, (INCI: Cetearyl Alcohol) Citric acid, 30% strength q.s. to pH 4.0 Preservative, perfume q.s.

Formulation Example 36) Rinse-Off Conditioner

[0188]

TABLE-US-00044 Water to 100.00% TEGIN M Pellets, Evonik 1.00% Nutrition & Care GmbH, (INCI: Glyceryl Stearate) Oleyl Alcohol 0.50% Glycerol 2.00% Pure-Gel, Grain Processing 1.50% Corporation, (INCI: Sodium Hydroxypropyl Starch Phosphate) Microemulsion ME2 2.80% TEGO Alkanol 1618, Evonik 6.00% Nutrition & Care GmbH, (INCI: Cetearyl Alcohol) Citric acid, 30% strength q.s. to pH 4.0 Preservative, perfume q.s.

Formulation Example 37) Rinse-Off Conditioner

[0189]

TABLE-US-00045 Water to 100.00% TEGINACID C, Evonik 1.00% Nutrition & Care GmbH, (INCI: Ceteareth-25) SF 1708, Momentive, 1.00% (INCI: Amodimethicone) DC 1503 Fluid, Dow Corning, (INCI: 0.50% Dimethicone, Dimethiconol) Microemulsion ME3 3.80% TEGO Alkanol 1618, Evonik 6.00% Nutrition & Care GmbH, (INCI: Cetearyl Alcohol) Citric acid, 30% strength q.s. to pH 4.0 Preservative, perfume q.s.

Formulation Example 38) Rinse-Off Conditioner

[0190]

TABLE-US-00046 Water to 100.00% TEGIN M Pellets, Evonik Nutrition & 1.00% Care GmbH, (INCI: Glyceryl Stearate) TEGO Care PSC 3, Evonik Nutrition & 0.50% Care GmbH, (INCI: Polyglyceryl-3 Dicitrate/Stearate) Jaguar C-162, Solvay, 0.10% (INCI: Hydroxypropyl Guar Hydroxypropyltrimonium Chloride) Microemulsion ME2 5.00% TEGO Alkanol 1618, Evonik 6.00% Nutrition & Care GmbH, (INCI: Cetearyl Alcohol) Citric acid, 30% strength q.s. to pH 4.5 Preservative, perfume q.s.

Formulation Example 39) Rinse-Off Conditioner

[0191]

TABLE-US-00047 Water to 100.00% TEGIN M Pellets, Evonik Nutrition & 1.00% Care GmbH, (INCI: Glyceryl Stearate) Oleyl Alcohol 0.30% Lauryl Alcohol 0.30% TEGO Care PSC 3, Evonik Nutrition & 0.80% Care GmbH, (INCI: Polyglyceryl-3 Dicitrate/Stearate) Glycerol 0.50% Microemulsion ME2 5.50% TEGO Alkanol 1618, Evonik 6.00% Nutrition & Care GmbH, (INCI: Cetearyl Alcohol) Citric acid, 30% strength q.s. to pH 4.5 Preservative, perfume q.s.

Formulation Example 40) Rinse-Off Conditioner

[0192]

TABLE-US-00048 Water to 100.00% CORN PO4 PH B, Agrana Starch, 4.00% (INCI: Distarch Phosphate) Microemulsion ME2 2.50% TEGO Alkanol 16, Evonik 1.00% Nutrition & Care GmbH,(INCI: Cetyl Alcohol) TEGO Alkanol 18, Evonik 1.70% Nutrition & Care GmbH, (INCI: Stearyl Alcohol) Citric acid, 30% strength q.s. to pH 4.3 Preservative, perfume q.s.

Formulation Example 41) Leave-In Conditioner Spray

[0193]

TABLE-US-00049 Lactic Acid, 80% 0.40% Water to 100.00% TEGO Amid S 18, Evonik Nutrition & 1.00% Care GmbH, (INCI: Stearamidopropyl Dimethylamine) TEGIN G 1100 Pellets, Evonik Nutrition & 0.60% Care GmbH, (INCI: Glycol Distearate) TEGO Care PS, Evonik Nutrition & 1.20% Care GmbH, (INCI: Methyl Glucose Sesquistearate) Glycerol 1.50% Microemulsion ME2 3.00% Preservative, perfume q.s.

Formulation Example 42) Leave-In Conditioner Spray

[0194]

TABLE-US-00050 TAGAT CH-40, Evonik Nutrition & Care 2.00% GmbH, (INCI: PEG-40 Hydrogenated Castor Oil) Ceramide VI, Evonik Nutrition & Care 0.10% GmbH, (INCI: Ceramide 6 II) Perfume 0.20% Glycerol 1.00% Water to 100.00% Microemulsion ME2 5.00% LACTIL, Evonik Nutrition & Care GmbH, 2.00% (INCI: Sodium Lactate; Sodium PCA; Glycine; Fructose;Urea; Niacinamide; Inositol; Sodium benzoate; Lactic Acid) TEGO Betain F 50, Evonik Nutrition & 2.30% Care GmbH, 38% (INCI: Cocamidopropyl Betaine) Citric acid, 10% strength 2.00%

Formulation Example 43) Leave-In Conditioner Foam

[0195]

TABLE-US-00051 Microemulsion ME3 3.50% TEGOSOFT PC 41, Evonik Nutrition & 3.00% Care GmbH, (INCI: Polyglyceryl-4 Caprate) Perfume 0.20% TEGO Betain 810, Evonik Nutrition & 2.00% Care GmbH, (INCI: Capryl/Capramidopropyl Betaine) Water to 100.00% TEGO Cosmo C 100, Evonik Nutrition & 0.50% Care GmbH, (INCI: Creatine) TEGOCEL HPM 50, Evonik Nutrition & 0.30% Care GmbH,(INCI: Hydroxypropyl Methylcellulose) Citric acid, 30% strength 0.10% Preservative q. s.

Formulation Example 44) Strong Hold Styling Gel

[0196]

TABLE-US-00052 TEGO Carbomer 141, Evonik Nutrition & 1.20% Care GmbH, (INCI: Carbomer) Water to 100.00% NaOH, 25% strength 2.60% PVP/VA W-735, ISP, 16.00% (INCI: PVP/VA Copolymer) Microemulsion ME2 4.80% Alcohol Denat. 10.00% TAGAT O 2 V, Evonik Nutrition & Care 2.00% GmbH, (INCI: PEG-20 Glyceryl Oleate) Perfume 0.30% ABIL B 88183 PH, Evonik Nutrition & 0.30% Care GmbH, (INCI: PEG/PPG-20/6 Dimethicone) Preservative q. s.

Formulation Example 45) Sprayable Hairmilk, PEG-Free

[0197]

TABLE-US-00053 A Water to 100.00% Lactic acid, 80% strength 0.40% B Glycerol 1.20% TEGIN G 1100 Pellets, Evonik 0.50% Nutrition & Care GmbH, (INCI: Glycol Distearate) TEGO Care PS, Evonik Nutrition & 1.20% Care GmbH, (INCI: Methyl Glucose Sesquistearate) Microemulsion ME18 2.50% Perfume, preservative q. s.

Formulation Example 46) Hair Colorant

[0198]

TABLE-US-00054 Water to 100.00% TEGO Alkanol 1618, Evonik Nutrition & 10.00% Care GmbH, (INCI: Cetearyl Alcohol) Eutanol G, BASF, (INCI: Octyldodecanol) 3.50% REWOMID C 212, Evonik Nutrition & 1.70% Care GmbH, (INCI: Cocamide MEA) Super Hartolan B, Croda, (INCI: Lanolin 3.00% Alcohol) Avocado oil, Henry Lamotte, (INCI: Persea 1.50% Gratissima Oil) Pristerene 4960, Uniquema, (INCI: Stearic 6.00% Acid) EDTA BD, BASF, (INCI: Disodium EDTA) 0.10% Texapon K12G, BASF, (INCI: Sodium 0.60% Lauryl sulfate) Propylene glycol 5.00% Timica Silver Sparkle, BASF, (INCI: MICA; 1.00% TitaniumDioxide) Ammonia solution, 25% strength 6.00% 2,5-Diaminotoluene sulfate, (INCI: Toluene- 1.40% 2,5-Diamine) Rodol RS, Jos. H. Lowenstein & Sons, 0.30% (INCI: Resorcinol) HC Blue A42, (INCI: 2,4- 0.10% Diaminophenoxyethanol di HCl) Sodium sulfite 0.50% Perfume 0.20% Microemulsion ME3 1.00%

Formulation Example 47) Hair Colorant

[0199]

TABLE-US-00055 Water to 100.00% TEGO Alkanol 1618, Evonik 12.00% Nutrition & Care GmbH, (INCI: Cetearyl Alcohol) Super Hartolan B, Croda, (INCI: Lanolin 2.50% Alcohol) Meadowfoam Seed Oil, Fanning, (INCI: 1.00% Limnanthes Alba) Pristerene 4960, Uniquema, (INCI: 5.50% Stearic Acid) EDTA BD, BASF, (INCI: Disodium 0.30% EDTA) Glycerol 3.00% Texapon N 70, BASF, (INCI: Sodium 2.00% Laureth Sulfate) Monoethanolamine 4.00% 2,5-Diaminotoluene sulfate, (INCI: 0.90% Toluene-2,5-Diamine) Rodol RS, Jos. H. Lowenstein & Sons, 0.20% (INCI: Resorcinol) Jarocol 4A3MP, Vivimed Labs, 0.60% (INCI: 4-Amino-M-Cresol) Rodol PAOC, Jos. H. Lowenstein & 0.50% Sons, (INCI: 4-Amino-2-Hydroxytoluene) Uantox EBATE, Universal Preserv- 0.50% A-Chem, (INCI: Erythorbic Acid) Perfume 0.20% Microemulsion ME2 1.00%

Formulation Example 48) Hair Colorant

[0200]

TABLE-US-00056 Water to 100.00% TEGO Alkanol 1618, Evonik 10.00% Nutrition & Care GmbH, (INCI: Cetearyl Alcohol) Eutanol G, BASF, (INCI: 1.00% Octyldodecanol) REWOMID C 212, Evonik Nutrition & 2.00% Care GmbH, (INCI: Cocamide MEA) TEGIN VS, Evonik Nutrition & Care 5.00% GmbH, (INCI: Glyceryl Stearate SE) Fitoderm, Hispano Quimica S. A., 1.00% (INCI: Squalane) Coenzyme Q 10 0.10% EDTA BD, BASF, (INCI: Disodium 0.30% EDTA) Texapon K12G, BASF, (INCI: Sodium 0.20% Lauryl Sulfate) Propylene glycol 5.00% Ammonia solution, 25% strength 3.00% Rodol ERN, Jos. H. Lowenstein & 0.30% Sons, (INCI: 1-Naphthol) Imexine OAG, Chimex, 1.00% (INCI: 2-Methyl-5- Hydroxyethylaminophenol) Colorex WP5, Teluca, 2.60% (INCI: 1-Hydroxyethyl 4,5-Diamino Pyrazole Sulfate) Ascorbic acid 0.20% Perfume 0.30% Microemulsion ME6 2.50%