BENZOTRIAZOLE DERIVATIVE COMPOUND

20200157059 ยท 2020-05-21

Assignee

Inventors

Cpc classification

International classification

Abstract

Provided are benzotriazole derivative compounds of the general formula that are novel compounds capable of strongly absorbing light in the ultraviolet range, particularly 300-330 nm, while strongly absorbing light in the visible light short-wavelength range up to around 450 nm and being used suitably as a light absorber having high light fastness with a light-blocking function over an extended period of time. [Preferably, R.sub.1 is a hydrogen atom or alkyl group, R.sub.2 is a C1-8 alkyl group, R.sub.3 is a hydrogen atom, alkyl group, acryloyloxyalkyl group, or methacryloyloxyalkyl group]

Claims

1. A benzotriazole derivative compound represented by the following general formula (1): ##STR00011## wherein in general formula (1), R.sub.1 represents a hydrogen atom or an alkyl group whose carbon number is 1 to 8, R.sub.2 represents a hydrogen atom, an alkyl group whose carbon number is 1 to 18, a carboxyalkyl group whose alkyl carbon number is 1 to 7, an alkyl oxycarbonylalkyl group of which a total of each alkyl carbon number is 2 to 15,a hydroxyalkyl group whose carbon number is 1 to 8, an alkylcarbonyloxyalkyl group of which a total of each alkyl carbon number is 2 to 15, an acryloyloxyalkyl group whose alkyl carbon number is 1 to 4, an acryloyloxyhydroxyalkyl group whose alkyl carbon number is 1 to 4, a methacryloyl oxyalkyl group whose alkyl carbon number is 1 to 4, or a methacryloyl oxyhydroxyalkyl group whose alkyl carbon number is 1 to 4, R3 represents a hydrogen atom or an alkyl group whose carbon number is 1 to 18, a carboxyalkyl group whose alkyl carbon number is 1 to 7, an alkyloxycarbonylalkyl group of which a total of each alkyl carbon number is 2 to 15, phenyl group, tolyl group, an acryloyl oxyalkyl group whose alkyl carbon number is 1 to 4, an acryloyloxyalkyl group whose alkyl carbon number is 1 to 4, an acryloyloxyhydroxyalkyl group whose alkyl carbon number is 1 to 4, a methacryloyloxyalkyl group whose alkyl carbon number is 1 to 4, a methacryloyloxyhydroxyalkyl group whose alkyl carbon number is 1 to 4.

2. The benzotriazole derivative compound according to claim 1, wherein R.sub.1 in the above general formula (1) is a hydrogen atom, or an alkyl group whose carbon number is 1 to 8, wherein R.sub.2 in the above general formula (1) is an alkyl group whose carbon number is 1 to 8, and wherein R.sub.3 in the above general formula (1) is a hydrogen atom, an alkyl group whose carbon number is 1 to 8, an acryloyl oxyalkyl group whose alkyl carbon number is 1 to 2, or a methacryloyl oxyalkyl group whose alkyl carbon number is 1 to 2.

3. The benzotriazole derivative compound according to claim 1, wherein R.sub.1 in the above general formula (1) is a hydrogen atom, or an alkyl group whose carbon number is 1 to 8, wherein R.sub.2 in the above general formula (1) is an alkyl group whose carbon number is 1 to 8, and wherein R.sub.3 in the above general formula (1) is an acryloyl oxyalkyl group whose alkyl carbon number is 1 to 2 or a methacryloyl oxyalkyl group whose alkyl carbon number is 1 to 2.

4. A light-absorber including the benzotriazole derivative compound according to claim 1.

5. A light-absorbing resin composition wherein the benzotriazole derivative compound according to claim 1 is compounded in a resin.

Description

BRIEF EXPLANATION OF DRAWINGS

[0098] FIG. 1 shows UV-visible absorption spectrum of a compound (a).

[0099] FIG. 2 shows UV-visible absorption spectrum of a compound (b).

[0100] FIG. 3 shows UV-visible absorption spectrum of a compound (c).

[0101] FIG. 4 shows UV-visible absorption spectrum of a compound (d).

[0102] FIG. 5 shows UV-visible absorption spectrum of a compound (e).

[0103] FIG. 6 shows UV-visible absorption spectrum of a compound (f).