Ferrite magnet

Abstract

This ferrite magnet has a magnetoplumbite structure and is characterized in that, when representing the composition ratios of the total of each metal element A, R, Fe and Me with expression (1) A.sub.1-xR.sub.x(Fe.sub.12-yMe.sub.y).sub.z, the Fe.sup.2+ content (m) in the ferrite magnet is greater than 0.1 mass % and less than 5.4 mass % (in expression (1), A is at least one element selected from Sr, Ba, Ca and Pb; R is at least one element selected from the rare-earth elements (including Y) and Bi, and includes at least La, and Me is Co, or Co and Zn). The invention makes it possible to achieve a ferrite magnet with increased Br.

Claims

1. A ferrite magnet comprising a magnetoplumbite structure, wherein a constitutional proportion of metal elements of A, R, Fe, and Me is represented by a formula (1) of A.sub.1-xR.sub.x(Fe.sub.12-yMe.sub.y).sub.z, where A is at least one element selected from Sr, Ba, Ca, and Pb, R is at least one element selected from rare earth elements (including Y) and Bi and R at least includes La, and Me is Co or Co and Zn, x, y, and z of the formula (1) satisfy the following formulae (2), (3), (4), and (5):
0.71≤x≤0.84  (2);
0.30≤y≤0.60  (3);
0.80≤z≤1.10  (4);
1.60<x/yz<4.00  (5), a Fe.sup.2+ content of the ferrite magnet is more than 0.1 mass % and less than 5.4 mass %, a residual magnetic flux density (Br) of the ferrite magnet is 4.7 (kG) or more, and the ferrite magnet further comprises Si, wherein a Si content is more than 0.03 mass % and less than 0.11 mass % in terms of SiO.sub.2.

2. The ferrite magnet according to claim 1, wherein A is at least Sr.

3. The ferrite magnet according to claim 1, wherein 0.76≤x≤0.84.

4. The ferrite magnet according to claim 1, wherein 0.76≤x≤0.81.

5. The ferrite magnet according to claim 1, wherein 0.30≤y≤0.55.

6. The ferrite magnet according to claim 1, wherein 0.30≤y≤0.51.

7. The ferrite magnet according to claim 1, wherein 0.34≤y≤0.51.

8. The ferrite magnet according to claim 1, wherein 0.80≤z≤1.04.

9. The ferrite magnet according to claim 1, wherein 0.84≤z≤1.04.

10. The ferrite magnet according to claim 1, wherein 0.84≤z≤1.00.

11. The ferrite magnet according to claim 1, wherein 1.62≤x/yz≤2.97.

12. The ferrite magnet according to claim 1, wherein 1.75≤x/yz≤2.97.

13. The ferrite magnet according to claim 1, wherein 1.75≤x/yz≤2.62.

14. The ferrite magnet according to claim 1, wherein Fe.sup.2+ content is 0.5 to 5.0 mass %.

15. The ferrite magnet according to claim 1, wherein Fe.sup.2+ content is 0.5 to 4.4 mass %.

16. The ferrite magnet according to claim 1, wherein Fe.sup.2+ content is 1.4 to 4.4 mass %.

17. The ferrite magnet according to claim 1, wherein Si content is 0.03 to 0.09%, in terms of SiO.sub.2.

Description

BRIEF EXPLANATION OF THE DRAWINGS

(1) FIG. 1 is a figure illustrating a relation between Fe.sup.2+ content and Br of a ferrite sintered magnet. (Experimental Example 1)

(2) FIG. 2 is a figure illustrating a relation between Fe.sup.2+ content and HcJ of a ferrite sintered magnet. (Experimental Example 1)

(3) FIG. 3 is a figure illustrating a relation between SiO.sub.2 content and Br of a ferrite sintered magnet. (Experimental Example 5)

(4) FIG. 4 is a figure illustrating a relation between SiO.sub.2 content and HcJ of a ferrite sintered magnet. (Experimental Example 5)

DESCRIPTION OF EMBODIMENTS

(5) The ferrite magnet according to the present embodiment is a ferrite magnet including a magnetoplumbite structure, wherein

(6) a constitutional proportion of metal elements of A, R, Fe, and Me is represented by a formula (1) of A.sub.1-xR.sub.x(Fe.sub.12-yMe.sub.y).sub.z, where A is at least one element selected from Sr, Ba, Ca, and Pb, R is at least one element selected from rare earth elements (including Y) and Bi and R at least includes La, and Me is Co or Co and Zn,

(7) x, y, and z of the formula (1) satisfy the following formulae (2), (3), (4), and (5):
0.60≤x≤0.84  (2);
0.30≤y≤0.60  (3);
0.80≤z<1.10  (4);
1.60≤x/yz<4.00  (5), and

(8) a Fe.sup.2+ content of the ferrite magnet is more than 0.1 mass % and less than 5.4 mass %.

(9) In the present embodiment, the composition of the whole ferrite magnet is expressed in terms of the above composition formula (1). Thus, when the ferrite magnet of the present embodiment contains a phase (e.g., hematite, spinel, orthoferrite, etc.) in addition to a phase having a magnetoplumbite structure, a ratio of elements constituting these phases is converted into the formula (1).

(10) In other words, “x”, “y”, and “z” are calculated by applying an amount of each element contained in the whole ferrite magnet to the formula (1).

(11) Hereinafter, the above-mentioned ferrite magnet is explained in more detail.

(12) A:

(13) “A” is at least one element selected from Sr, Ba, Ca, and Pb. To improve coercive force (HcJ), “A” is most preferably at least Sr.

(14) R(x):

(15) “x” in the above composition formula (1) represents a proportion of substitution of “A” by “R”. When “x” is less than 0.60 in the composition formula (1), that is, when an amount of “R” is too small, a solid solution amount of “R” in the ferrite magnet is insufficient, and Br and HcJ decrease. Meanwhile, when “x” is more than 0.84, Br and HcJ decrease. In the present invention, the range of “x” is thereby set to 0.60≤x≤0.84. The value of “x” is preferably 0.71≤x≤0.84, more preferably 0.76≤x≤0.84, and still more preferably 0.76≤x≤0.81.

(16) “R” is at least one element selected from Bi and rare earth elements including Y, but to improve residual magnetic flux density (Br), “R” is preferably La. In the present invention, La is thereby essential.

(17) Me(y):

(18) “y” in the above composition formula (1) represents a proportion of substitution of Fe by “Me”, that is, an amount of Co or an amount of Co+Zn. Similarly to “x”, “y” is set to obtain a high residual magnetic flux density (Br) in the present invention. When “y” is less than 0.30, a solid solution amount of “Me” in the ferrite magnet is insufficient, and Br and HcJ decrease. On the other hand, when “y” is more than 0.60, there exists “Me”, which is an excess element that cannot be substituted by solid solution in the hexagonal M-type ferrite. In the present invention, “y” is thereby set to 0.30≤y≤0.60. The value of “y” is preferably 0.30≤y≤0.55, more preferably 0.30≤y≤0.51, and still more preferably 0.34≤y≤0.51.

(19) z:

(20) “z” in the above composition formula (1) represents a ratio of a sum of Fe and Me to a sum of “A” and “R”. When “z” is too small, the nonmagnetic phase including “A” and “R” increases, and a saturation magnetization thereby decreases. On the other hand, when “z” is too large, the α-Fe.sub.2O.sub.3 phase or the spinel ferrite phase containing “Me” increases, and a saturation magnetization thereby decreases. In the present invention, “z” is thereby set to 0.80≤z<1.10. The value of “z” is preferably 0.80≤z≤1.04, more preferably 0.84≤z≤1.04, and still more preferably 0.84≤z≤1.00.

(21) x/yz:

(22) x/yz in the above composition formula (1) represents a proportion of a substitution amount of “R” and a substitution amount of “Me”. In the present embodiment, x/yz is 1.60<x/yz<4.00. When “x”, “y”, and “z” satisfy this relation, favorable Br and HcJ can be obtained. When the proportion is too high or too low, Br and HcJ tend to rather decrease. The value of x/yz is preferably 1.62≤x/yz≤2.97, more preferably 1.75≤x/yz≤2.97, and still more preferably 1.75≤x/yz≤2.62.

(23) Fe.sup.2+ Content:

(24) The ferrite magnet of the present embodiment has a main phase composed of an M-type ferrite phase (a ferrite phase having a magnetoplumbite structure), and a Fe.sup.2+ content is more than 0.1 mass % and less than 5.4 mass %. When a Fe.sup.2+ content satisfies such a condition, a high Br and a favorable HcJ can be obtained. When a Fe.sup.2+ content is too large, however, Br and HcJ may decrease, and an upper limit of Fe.sup.2+ content is thereby preferably determined based on desired Br and HcJ. The Fe.sup.2+ content is preferably 0.5 to 5.0 mass %, more preferably 0.5 to 4.4 mass %, and still more preferably 1.4 to 4.4 mass %.

(25) The Fe.sup.2+ content in the ferrite magnet can be measured by, for example, oxidation-reduction titration or phenanthroline absorption photometry.

(26) Fe.sup.2+ contained in the ferrite magnet of the present embodiment is not limited to those contained in the above-mentioned main phase, and may be contained in sub-phases, grain boundaries, grain boundary phases, and the like.

(27) Preferably, the ferrite magnet of the present embodiment further contains Si. Specifically, a Si content is preferably more than 0.002 mass % and less than 0.15 mass % in terms of SiO.sub.2. When a Si content satisfies such a condition, a ferrite magnet having high Br and HcJ can be obtained. When a Si content is 0.002 mass % or less in terms of SiO.sub.2, however, a sufficient effect cannot be obtained, and Br and HcJ decrease due to insufficient sintering. When a Si content is too large, Br and HcJ may decrease, and a Si content is thereby preferably determined based on desired Br and HcJ.

(28) To obtain favorable Br and HcJ, a Si content is more preferably 0.03 to 0.11 mass %, still more preferably 0.03 to 0.09%, in terms of SiO.sub.2.

(29) The M-type ferrite phase constituting the ferrite magnet of the present embodiment is contained in the ferrite magnet of the present embodiment as a main phase at preferably 60.0 mol % or more, more preferably 70 mol % or more.

(30) The presence of the M-type ferrite phase in the ferrite magnet in the present embodiment can be confirmed by X-ray diffraction, electron beam diffraction, or the like under the following conditions. The molar ratio occupied by the M-type ferrite phase in the structure of the ferrite magnet is determined by comparing an X-ray diffraction intensity for a mixture obtained by mixing powder samples of M-type ferrite, orthoferrite, hematite, and spinel at a predetermined ratio and an X-ray diffraction intensity for an actually manufactured ferrite magnet.

(31) X-ray generator

(32) Continuous rating: 3 kW

(33) Tube voltage: 45 kV

(34) Tube current: 40 mA

(35) Sampling width: 0.02 deg

(36) Scanning speed: 4.00 deg/min

(37) Divergence slit: 1.00 deg

(38) Scattering slit: 1.00 deg

(39) Reception slit: 0.30 mm

(40) The composition formula (1) of the present embodiment represents a compositional ratio of metal elements of “A”, “R”, Fe, and “Me”, but when O (oxygen) is also contained, the composition formula (1) of the present embodiment can be represented by A.sub.1-xR.sub.x(Fe.sub.12-yMe.sub.y).sub.zO.sub.19. Here, the number of O (oxygen) atoms is 19, which represents a stoichiometric composition ratio of oxygen when “Me” is all divalent, Fe and “R” are all trivalent, and x=y and z=1 are satisfied.

(41) Since “x”, “y”, “z”, and Fe.sup.2+ content vary within the above-mentioned ranges and can take various values, however, the number of atoms of oxygen varies based on values of “x”, “y”, “z”, and Fe.sup.2+ content. For example, when the firing atmosphere is a reducing atmosphere, oxygen loss (vacancy) may occur. The valence of Co and/or “Me” may change, and “R” may also take a valence other than trivalent, whereby the ratio of oxygen to metal elements changes. From the above, the number of oxygen atoms may actually be deviated from 19, and the present invention also includes such a case.

(42) The ferrite magnet according to the present embodiment may contain Ca as a sub-component in addition to Si. Si and Ca are added for the purpose of improving sinterability of the M-type ferrite, controlling magnetic properties, adjusting a crystal grain size of the sintered body, and the like.

(43) The ferrite magnet according to the present embodiment may contain components other than Si and Ca as sub-components, and may contain, for example, Al and/or Cr as other sub-components. When these elements are contained, HcJ of the permanent magnet tends to improve. To obtain a favorable improvement effect of HcJ, the amount of Al and/or Cr is preferably 0.1 mass % or more in total in terms of Al.sub.2O.sub.3 and Cr.sub.2O.sub.3 with respect to the whole ferrite magnet. However, these components may reduce Br of the permanent magnet, and the amount of these components is thereby preferably 3 mass % or less so as to obtain a favorable Br.

(44) The sub-components may contain B as, for example, B.sub.2O.sub.3. When B is contained, it is possible to lower the calcining temperature and the firing temperature in obtaining a sintered body composed of a ferrite magnet and to obtain a permanent magnet with high productivity. When a B content is too large, however, the saturation magnetization of the permanent magnet may decrease, and a B content to the whole ferrite magnet is thereby preferably 0.5 mass % or less in terms of B.sub.2O.sub.3.

(45) Furthermore, the ferrite magnet of the present embodiment may contain a sub-component of Ga, Mg, Cu, Mn, Ni, In, Li, Ti, Zr, Ge, Sn, V, Nb, Ta, Sb, As, W, Mo, etc. in the form of an oxide. In terms of an oxide having a stoichiometric composition of each atom, the amounts of these elements are preferably 5 mass % or less of gallium oxide, 5 mass % or less of magnesium oxide, 5 mass % or less of copper oxide, 5 mass % or less of manganese oxide, 5 mass % or less of nickel oxide, 3 mass % or less of indium oxide, 1 mass % or less of lithium oxide, 3 mass % or less of titanium oxide, 3 mass % or less of zirconium oxide, 3 mass % or less of germanium oxide, 3 mass % or less of tin oxide, 3 mass % or less of vanadium oxide, 3 mass % or less of niobium oxide, 3 mass % or less of tantalum oxide, 3 mass % or less of antimony oxide, 3 mass % or less of arsenic oxide, 3 mass % or less of tungsten oxide, and 3 mass % or less of molybdenum oxide. When a plurality of these are contained in combination, however, the total is preferably 5 mass % or less so as to avoid deterioration of magnetic characteristics.

(46) Preferably, the ferrite magnet of the present embodiment does not contain a sub-component of alkali metal elements (Na, K, Rb, etc.). Alkali metal elements tend to reduce saturation magnetization of the permanent magnet, but may be contained, for example, in a raw material for obtaining a ferrite magnet. As long as alkali metal elements are contained unavoidably, alkali metal elements may be contained in the ferrite magnet. An amount of alkali metal elements that does not significantly influence magnetic characteristics is 3 mass % or less in total.

(47) The composition of the ferrite magnet can be analyzed by fluorescent X-ray quantitative analysis.

(48) The ferrite magnet of the present embodiment has any form as long as it has the above composition. For example, the ferrite magnet of the present embodiment is a ferrite sintered magnet, a ferrite magnet powder, a bonded magnet where ferrite magnet powder is dispersed in a resin, a film-like magnetic layer contained in the magnetic recording medium, and the like.

(49) For example, the ferrite sintered magnet and the bonded magnet are processed into predetermined shapes and used for a wide variety of applications as described below.

(50) For example, the ferrite sintered magnet and the bonded magnet can be used as a motor for a motor vehicle, such as a fuel pump, a power window, an ABS (antilock brake system), a fan, a wiper, a power steering, an active suspension, a starter, a door lock, and an electric mirror.

(51) Also, the ferrite sintered magnet and the bonded magnet can be used as a motor for OA/AV equipment, such as FDD spindle, VTR capstan, VTR rotary head, VTR reel, VTR loading, VTR camera capstan, VTR camera rotary head, VTR camera zoom, VTR camera focus, capstans of radio cassette players etc., CD/LD/MD spindle, CD/LD/MD loading, and CD/LD optical pickup.

(52) Furthermore, the ferrite sintered magnet and the bonded magnet can be used as a motor for household electric appliances, such as air conditioner compressor, freezer compressor, electric tool driving, dryer fan, shaver driving, and electric toothbrush. Furthermore, the ferrite sintered magnet and the bonded magnet can be used as a motor for FA equipment, such as robot axle, joint drive, robot main drive, machine tool table drive, and machine tool belt drive.

(53) For other applications, the ferrite sintered magnet and the bonded magnet can be used for a motor generator for motorcycle, a magnet for speaker or headphone, a magnetron tube, a magnetic field generator for MRI, a damper for CD-ROM, a sensor for distributor, a sensor for ABS, a fuel or oil level sensor, a magnet latch, an isolator, and the like.

(54) When the ferrite magnet of the present embodiment has a form of powder, this powder preferably has an average particle size of 0.1 to 5.0 μm. The powder for the bonded magnet more preferably has an average particle size of 0.1 to 2.0 μm, and still more preferably has an average particle size of 0.1 to 1.0 μm. In manufacturing the bonded magnet, a ferrite magnet powder is kneaded with various binders of resin, metal, rubber, etc. and pressed in a magnetic field or a non-magnetic field. Preferably, the binder is acrylonitrile butadiene rubber (NBR), chlorinated polyethylene, polyamide resin, and the like. After the pressing, the pressed material is hardened and turned into a bonded magnet.

(55) (Manufacturing Method of Ferrite Sintered Magnet)

(56) Next, a method of manufacturing a ferrite sintered magnet among the above-mentioned ferrite magnets is described. In the method of manufacturing the ferrite sintered magnet of the present embodiment, the ferrite sintered magnet can be manufactured through a blending step, a calcining step, a pulverizing step, a pressing step, and a firing step. Each step is described below.

(57) <Blending Step>

(58) In the blending step, raw materials of a ferrite magnet are blended to obtain a raw material composition. First, raw materials of the ferrite magnet can be compounds (raw material compounds) containing one or more elements among elements constituting the ferrite magnet. The raw material compounds are preferably powdery, for example. The raw material compounds can be an oxide of each element or a compound to be an oxide by firing (carbonate, hydroxide, nitrate, etc.), and examples of the raw material compounds include SrCO.sub.3, La(OH).sub.3, Pr.sub.6O.sub.11, Nd.sub.2O.sub.3, ZnO, Fe.sub.2O.sub.3, BaCO.sub.3, CaCO.sub.3, and Co.sub.3O.sub.4. To achieve homogeneous blending, the powders of the raw material compounds preferably have an average particle size of about 0.1 to 2.0 μm, for example. If necessary, the raw material powders may be blended with other sub-components of raw material compounds (elemental simple substance, oxide, etc.).

(59) The blending can be carried out, for example, by weighing each raw material so as to obtain a desired composition of the ferrite magnet and mixing and pulverizing the weighed raw materials for about 0.1 to 20 hours using a wet attritor, a ball mill, or the like. In the blending step, not all of the raw materials need to be mixed, and some of the raw materials may be added after the calcination described below.

(60) <Calcining Step>

(61) In the calcining step, the raw material powders obtained in the blending step are calcined. The calcination can be carried out, for example, in an oxidizing atmosphere of air or so. The calcining temperature is preferably 1000 to 1340° C., more preferably 1100 to 1340° C., and still more preferably 1250 to 1340° C. The calcining time can be 1 second to 10 hours, preferably 1 second to 3 hours. The calcined body obtained by the calcination contains 60.0 mol % or more of the main phase (M phase) as described above. The primary particle diameter of the main phase is preferably 10 μm or less, more preferably 2 μm or less.

(62) In the calcining step, the heating rate is preferably 5° C./min or more, more preferably 15° C./min or more, and the cooling rate is preferably 7 to 1000° C./min, more preferably 50 to 1000° C./min.

(63) <Pulverizing Step>

(64) In the pulverizing step, the calcined body formed into granules or lumps by the calcining step is pulverized and turned into a powder again. This facilitates pressing in the pressing step described below. In the pulverizing step, raw materials that are not blended in the blending step may be added (post-addition of raw materials). For example, the pulverizing step may be constituted by two steps of pulverizing the calcined body to a coarse powder (coarse pulverization) and finely pulverizing this coarse powder (fine pulverization).

(65) The coarse pulverization can be carried out, for example, using a vibration mill or so until the average particle diameter reaches 0.5 to 5.0 μm. In the fine pulverization, the coarsely pulverized material obtained by the coarse pulverization is further pulverized by a wet attritor, a ball mill, a jet mill, or the like. The fine pulverization is carried out so that the average particle size of the finely pulverized material obtained is preferably about 0.08 to 2.0 μm, more preferably about 0.1 to 1.0 μm, and still more preferably about 0.2 to 0.8 μm. Preferably, the finely pulverized material has a specific surface area (for example, determined by the BET method) of about 7 to 14 m.sup.2/g. A favorable pulverization time differs depending on the pulverization method. For example, the pulverization time is preferably 30 minutes to 10 hours when a wet attritor is used, and the pulverization time is preferably about 10 to 50 hours when a ball mill is used.

(66) When some of the raw materials are added in the pulverizing step, the addition can be carried out, for example, in the fine pulverizing step.

(67) To increase the degree of magnetic orientation of the sintered body obtained after firing, for example, a polyhydric alcohol represented by a general formula of C.sub.n(OH).sub.nH.sub.n+2 is preferably added in the fine pulverizing step. In the polyhydric alcohol represented by the general formula, “n” is preferably 4 to 100, more preferably 4 to 30, still more preferably 4 to 20, and further still more preferably 4 to 12. For example, the polyhydric alcohol is sorbitol. Two or more polyhydric alcohols may be used in combination. In addition to the polyhydric alcohol, other known dispersants may be used in combination.

(68) When a polyhydric alcohol is added, an addition amount of the polyhydric alcohol is preferably 0.05 to 5.0 mass %, more preferably 0.1 to 3.0 mass %, and still more preferably 0.2 to 2.0 mass % with respect to an addition target (e.g., coarsely pulverized material). The polyhydric alcohol added in the fine pulverizing step is removed by thermal decomposition in the firing step described below.

(69) <Pressing Step>

(70) In the pressing step, the pulverized material obtained after the pulverizing step (preferably, finely pulverized material) is pressed in a magnetic field to obtain a green compact. The pressing can be carried out by dry pressing or wet pressing. To increase the degree of magnetic orientation, the pressing is preferably carried out by wet pressing.

(71) When the pressing is carried out by wet pressing, for example, it is preferable to obtain a slurry by performing the above-mentioned fine pulverizing step in a wet state and then to concentrate the slurry to a predetermined concentration to obtain a slurry for wet pressing. The slurry can be concentrated by centrifugal separation, filter press, or the like. Preferably, the finely pulverized material accounts for about 30 to 80 mass % to the total amount of the slurry for wet pressing. In the slurry, water is preferable as a dispersion medium for dispersing the finely pulverized material. In this case, the slurry may be added with a surfactant of gluconic acid, gluconate, sorbitol, or the like. The dispersion medium may be a nonaqueous solvent. The nonaqueous solvent may be an organic solvent of toluene, xylene, or the like. In this case, a surfactant of oleic acid or so is preferably added. The slurry for wet pressing may be prepared by adding a dispersion medium or so to the finely pulverized material in a dry state after the fine pulverization.

(72) In the wet pressing, the slurry for wet pressing is subsequently pressed in a magnetic field. In that case, the pressing pressure is preferably about 9.8 to 49 MPa (0.1 to 0.5 ton/cm.sup.2), and the magnetic field to be applied is preferably about 398 to 1194 kA/m (5 to 15 kOe).

(73) <Firing Step>

(74) In the firing step, the green compact obtained in the pressing step is fired and turned into a sintered body. A permanent magnet (ferrite sintered magnet) composed of the sintered body of the ferrite magnet as described above is thereby obtained. The firing can be performed in an oxidizing atmosphere of air or so. The firing temperature is preferably 1050 to 1340° C., more preferably 1250 to 1340° C. The firing time (the time where the firing temperature is held) is preferably about 0.5 to 3 hours.

(75) When the green compact is obtained by wet pressing as described above, if the green compact is fired without sufficiently being dried, the green compact containing a dispersion medium or so is heated rapidly, and the dispersion medium or so is volatilized severely, which may cause cracks in the green compact. To avoid such inconveniences, for example, the green compact is thereby preferably dried sufficiently by being heated from a room temperature to about 100° C. at a slow heating rate of about 0.5° C./min before the temperature reaches the above-mentioned firing temperature. Furthermore, when a surfactant (dispersant) or so is added, the surfactant (dispersant) is preferably sufficiently removed (degreasing treatment) by, for example, heating the green compact at a heating rate of about 2.5° C./min in a temperature range of about 100 to 500° C. These treatments may be performed at the beginning of the firing step or may be performed separately before the firing step.

(76) To control the generation and amount of Fe.sup.2+, the heating rate from about 500° C. to the firing temperature and/or the cooling rate from the firing temperature to a room temperature is/are preferably 6 to 200° C./min, more preferably 25 to 200° C./min.

(77) To control the amount of Fe.sup.2+, the green compact may be fired in a non-oxidizing atmosphere of nitrogen atmosphere, argon gas atmosphere, or the like, or may be fired in an oxidizing atmosphere having an oxygen concentration.

(78) A favorable method of manufacturing the ferrite sintered magnet is described above, but the above method is not only one method as far as at least the ferrite magnet according to the present embodiment is used, and conditions or so may appropriately be changed.

(79) When a bonded magnet is manufactured instead of a ferrite sintered magnet, for example, a bonded magnet containing powder of the ferrite magnet of the present embodiment can be obtained by, for example, carrying out the above-mentioned steps until the pulverizing step, mixing the pulverized material obtained and the binder, and pressing the mixture in a magnetic field.

EXAMPLES

(80) Hereinafter, the present invention is described in more detail with reference to examples, but the present invention is not limited to these examples.

(81) [Experimental Example 1] (Manufacture of Ferrite Sintered Magnet)

(82) First, iron oxide (Fe.sub.2O.sub.3), strontium carbonate (SrCO.sub.3), cobalt oxide (CoO), and lanthanum hydroxide (La(OH).sub.3) were prepared as raw materials of a main composition of a ferrite magnet, and these raw materials were weighed so that the composition of the sintered body after firing would be the following composition formula.
A.sub.1-xR.sub.x(Fe.sub.12-yMe.sub.y).sub.z  Composition Formula:

(83) In the formula, A=Sr, R=La, and Me=Co are satisfied, and x=0.82, y=0.39, and z=0.94 are satisfied.

(84) The weighed raw materials were subsequently mixed and pulverized for 1 hour with a wet attritor to obtain a slurry (blending step). The slurry was dried and thereafter calcined by holding at 1310° C. for 2 hours in air provided that the heating rate and the cooling rate were 15° C./min (calcining step).

(85) The obtained calcined powder was coarsely pulverized for 10 minutes with a small rod vibration mill. SiO.sub.2 were added to the sintered body after firing so that the Si content would be 0.05 mass % in terms of SiO.sub.2. This mixture was finely pulverized for 40 hours using a wet ball mill to obtain a slurry (so far, pulverizing step).

(86) The slurry obtained after the fine pulverization was adjusted and turned into a slurry for wet pressing so that the solid content concentration was 73 to 75%. The slurry for wet pressing was pressed in a magnetic field of 796 kA/m (10 kOe) using a wet magnetic field pressing machine to obtain a green compact having a cylindrical shape whose diameter was 30 mm and thickness was 15 mm (pressing step).

(87) The obtained green compact was sufficiently dried at a room temperature in air and heated at a heating rate of 5° C./min from the room temperature to 500° C. To change the Fe.sup.2+ content, the green compact was fired from 500° C. under the conditions of Table 1, and ferrite sintered magnets were thereby obtained (firing step).

(88) The upper and lower surfaces of the cylinder of each ferrite sintered magnet obtained in Experimental Example 1 were processed, and Br (G) and HcJ (Oe) of the ferrite sintered magnets were obtained using a B-H tracer with the maximum applied magnetic field of 955 kA/m (12 kOe). Furthermore, the ratio (mol %) of the M phase (ferrite phase having a magnetoplumbite structure) in each of the ferrite sintered magnets obtained in Experimental Example 1 was obtained by the X-ray diffraction described above.

(89) Furthermore, each sample of the ferrite sintered magnets obtained in Experimental Example 1 was pulverized, and heated and dissolved after addition of oxalic acid and strong phosphoric acid. Deaerated water was added to this, and the Fe.sup.2+ content of the ferrite sintered magnet was determined by potentiometric titration using a K.sub.2Cr.sub.2O.sub.7 solution. The obtained results are summarized in Table 1.

(90) TABLE-US-00001 TABLE 1 firing conditions 500° C. to 1280° C. 1280° C.-1 hr 1280° C. to room Fe.sup.2+ M phase heating rate (° C./ holding temperature content Br HcJ ratio No. min) condition cooling rate (° C./min) (mass %) (G) (Oe) (mol %) 1-1  1 in air 1(hr) in air  1 in air 0.1 4601 2500 91.5 1-2  6 in air 1(hr) in air  6 in air 0.5 4709 2559 93.8 1-3 25 in air 1(hr) in air 50 in air 1.4 4721 2666 92.3 1-4 52 in air 1(hr) in air 50 in air 2.1 4720 2704 92.6 1-5 52 in air 1(hr) in air 100 in air  4.4 4721 2684 95.0 1-6 52 in air 1(hr) in air 200 in air  5.0 4706 2690 93.9 1-7 25 in air 1(hr) in N.sub.2 50 in N.sub.2 5.4 4250 2292 89.4

(91) As shown in Table 1, it was found that when the Fe.sup.2+ content was more than 0.1 mass % and less than 5.4 mass %, a sintered body having Br of 4.7 (kG) or more and HcJ of 2.0 (kOe) or more was obtained, and that a high Br and a favorable HcJ could be obtained.

(92) [Experimental Example 2] (Manufacture of Ferrite Sintered Magnet)

(93) In Experiment Example 2, ferrite sintered magnets were manufactured in a similar manner to Experimental Example 1 except that the composition of the sintered body after firing was set to be the composition formula in Table 2, and that in the firing step, the temperature was increased from 500 to 1290° C. at 55° C./min, held at 1290° C. for 1 hour, and decreased to a room temperature at 100° C./min.

(94) In Experimental Example 2, various ferrite sintered magnets of Samples 2-1 to 2-8 were manufactured particularly by greatly changing the atomic ratio of La (x=0.51 to 0.91). Br(G), HcJ(Oe), M phase ratio, and Fe.sup.2+ content of each ferrite sintered magnet obtained in Experimental Example 2 were determined in a similar manner to Experimental Example 1. The obtained results are shown in Table 2.

(95) TABLE-US-00002 TABLE 2 composition formula: firing Fe.sup.2+ M phase A.sub.1−xR.sub.x(Fe.sub.12−yMe.sub.y).sub.z temperature Br HcJ content ratio No. x y z x/yz (° C.) (G) (Oe) (mass %) (mol %) 2-1 0.51 0.33 0.94 1.64 1290 4533 2089 0.1 100.0 2-2 0.58 0.38 0.94 1.62 1290 4568 2142 0.9 99.5 2-3 0.71 0.41 0.94 1.84 1290 4701 2169 2.7 98.8 2-4 0.76 0.41 0.94 1.97 1290 4705 2204 2.7 96.0 2-5 0.81 0.41 0.94 2.10 1290 4733 2307 4.2 93.3 2-6 0.84 0.41 0.94 2.18 1290 4710 2250 4.1 91.1 2-7 0.88 0.41 0.94 2.28 1290 4109 2503 4.0 86.2 2-8 0.91 0.41 0.94 2.36 1290 3708 2604 4.0 76.1

(96) As shown in Table 2, it was found that when the ratio (x) of La was 0.60 or more and 0.84 or less, a sintered body having Br of 4.7 (kG) or more and HcJ of 2.0 (kOe) or more was obtained, and that a high Br and a favorable HcJ could be obtained.

(97) [Experimental Example 3] (Manufacture of Ferrite Sintered Magnet)

(98) In Experimental Example 3, ferrite sintered magnets were manufactured in a similar manner to Experimental Example 2 except that the composition of the sintered body after firing was set to be the composition formula in Table 3, and that the firing temperature was 1310° C.

(99) In Experimental Example 3, various ferrite sintered magnets of Samples 3-1 to 3-7 were manufactured particularly by greatly changing the atomic ratio of Co (y=0.20 to 0.61). Br(G), HcJ(Oe), M phase ratio, and Fe.sup.2+ content of each ferrite sintered magnet obtained in Experimental Example 3 were determined in a similar manner to Experimental Example 1. The obtained results are shown in Table 3.

(100) TABLE-US-00003 TABLE 3 composition formula: firing Fe.sup.2+ M phase A.sub.1−xR.sub.x(Fe.sub.12−yMe.sub.y).sub.z temperature Br HcJ content ratio No. x y z x/yz (° C.) (G) (Oe) (mass %) (mol %) 3-1 0.84 0.20 0.94 4.47 1310 3738 2653 3.9 94.6 3-2 0.84 0.30 0.94 2.97 1310 4705 2133 4.0 94.3 3-3 0.84 0.34 0.94 2.62 1310 4713 2222 4.2 92.9 3-4 0.84 0.43 0.94 2.07 1310 4721 2333 4.4 93.6 3-5 0.84 0.51 0.94 1.75 1310 4709 2014 4.6 93.5 3-6 0.84 0.55 0.94 1.62 1310 4706 2001 4.6 93.6 3-7 0.84 0.61 0.94 1.46 1310 4415 2528 4.7 92.5

(101) As shown in Table 3, it was found that when the ratio (y) of Co was 0.30 or more and 0.60 or less, a sintered body having Br of 4.7 (kG) or more and HcJ of 2.0 (kOe) or more was obtained, and that a high Br and a favorable HcJ could be obtained. It was also found that when x/yz was more than 1.60 and less than 4.00, a sintered body having Br of 4.7 (kG) or more and HcJ of 2.0 (kOe) or more was obtained, and a high Br and a favorable HcJ could be obtained.

(102) [Experimental Example 4] (Manufacture of Ferrite Sintered Magnet)

(103) In Experimental Example 4, iron oxide (Fe.sub.2O.sub.3), strontium carbonate (SrCO.sub.3), cobalt oxide (Co.sub.3O.sub.4), and lanthanum hydroxide (La(OH).sub.3) were prepared as raw materials of a main composition of a ferrite magnet, and these raw materials were weighed so that the composition after calcination would be the following composition formula.
A.sub.1-xR.sub.x(Fe.sub.12-yMe.sub.y).sub.z  Composition Formula:

(104) In the formula, A=Sr, R=La, and Me=Co are satisfied, and x=0.80, y=0.35, and z=1.10 are satisfied.

(105) The weighed raw materials were subsequently mixed and pulverized for 1 hour with a wet attritor to obtain a slurry (blending step). This slurry was dried and thereafter calcined by holding at 1310° C. for 2 hours in air provided that the heating rate and the cooling rate were 15° C./min (calcining step).

(106) The obtained calcined powder was coarsely pulverized for 10 minutes with a small rod vibration mill. The coarsely pulverized material was added with iron oxide, strontium carbonate, cobalt oxide, and lanthanum hydroxide so that the sintered body after firing had the composition shown in Table 4 by the following composition formula. Furthermore, SiO.sub.2 was added to the sintered body after firing so that the Si content would be 0.04 mass % in terms of SiO.sub.2. This mixture was finely pulverized for 40 hours using a wet ball mill to obtain a slurry (so far, pulverizing step).
A.sub.1-xR.sub.x(Fe.sub.12-yMe.sub.y).sub.z  Composition Formula:

(107) In the formula, A=Sr, R=La, and Me=Co are satisfied.

(108) The slurry obtained after the fine pulverization was adjusted and turned into a slurry for wet pressing so that the solid content concentration was 73 to 75%. The slurry for wet pressing was pressed in a magnetic field of 796 kA/m (10 kOe) using a wet magnetic field pressing machine to obtain a green compact having a cylindrical shape whose diameter was 30 mm and thickness was 15 mm. The obtained green compact was sufficiently dried at a room temperature in air, and was heated from a room temperature to 500° C. at a heating rate of 5° C./min and from 500 to 1310° C. at a heating rate of 55° C./min and held for 1 hour at 1310° C. After the holding, a firing step was carried out by reducing the temperature to the room temperature at a cooling rate of 100° C./min, and ferrite sintered magnets were thereby obtained.

(109) In Experimental Example 4, various ferrite sintered magnets of Samples 4-1 to 4-10 were manufactured particularly by greatly changing the atomic ratio of “z” (z=0.70 to 1.10). Br(G), HcJ(Oe), M phase ratio, and Fe.sup.2+ content of each ferrite sintered magnet obtained in Experimental Example 4 were determined in a similar manner to Experimental Example 1. The obtained results are shown in Table 4.

(110) TABLE-US-00004 TABLE 4 composition formula: firing Fe.sup.2+ M phase A.sub.1−xR.sub.x(Fe.sub.12−yMe.sub.y).sub.z temperature Br HcJ content ratio No. x y z x/yz (° C.) (G) (Oe) (mass %) (mol %) 4-1 0.80 0.53 0.70 2.15 1310 4173 2575 3.8 65.1 4-2 0.80 0.50 0.75 2.15 1310 4425 2843 3.8 70.6 4-3 0.80 0.47 0.80 2.15 1310 4709 2016 3.9 74.9 4-4 0.80 0.43 0.84 2.20 1310 4702 2392 4.0 83.7 4-5 0.80 0.41 0.90 2.15 1310 4710 2351 4.1 89.0 4-6 0.80 0.39 0.94 2.16 1310 4732 2301 4.2 93.3 4-7 0.80 0.39 0.95 2.16 1310 4702 2315 4.1 96.0 4-8 0.80 0.37 1.00 2.15 1310 4700 2257 3.9 99.1 4-9 0.80 0.35 1.04 2.20 1310 4712 2164 3.9 98.7 4-10 0.80 0.35 1.10 2.08 1310 4227 3010 3.9 94.7

(111) As shown in Table 4, it was found that when “z” was 0.80 or more and less than 1.10, a sintered body having Br of 4.7 (kG) or more and HcJ of 2.0 (kOe) or more was obtained, and that a high Br and a favorable HcJ could be obtained.

(112) [Experimental Example 5] (Manufacture of Ferrite Sintered Magnet)

(113) In Experimental Example 5, iron oxide (Fe.sub.2O.sub.3), strontium carbonate (SrCO.sub.3), cobalt oxide (Co.sub.3O.sub.4), and lanthanum hydroxide (La(OH).sub.3) were prepared as raw materials of a main composition of a ferrite magnet, and these raw materials were weighed so that the composition after calcination would be the following composition formula.
A.sub.1-xR.sub.x(Fe.sub.12-yMe.sub.y).sub.z  Composition Formula:

(114) In the formula, A=Sr, R=La, and Me=Co are satisfied, and x=0.80, y=0.35, and z=0.94 are satisfied.

(115) The weighed raw materials were subsequently mixed and pulverized for 1 hour with a wet attritor to obtain a slurry (blending step). This slurry was dried and thereafter calcined by holding at 1310° C. for 2 hours in air provided that the heating rate and the cooling rate were 15° C./min (calcining step).

(116) The obtained calcined powder was coarsely pulverized for 10 minutes with a small rod vibration mill. SiO.sub.2 was added to the coarsely pulverized material so that the Si content to the sintered body after firing would be the value of Table 1 in terms of SiO.sub.2. This mixture was finely pulverized for 40 hours using a wet ball mill to obtain a slurry (so far, pulverizing step).

(117) The slurry obtained after the fine pulverization was adjusted and turned into a slurry for wet pressing so that the solid content concentration was 73 to 75%. This slurry for wet pressing was pressed in a magnetic field of 796 kA/m (10 kOe) using a wet magnetic field pressing machine to obtain a green compact having a cylindrical shape whose diameter was 30 mm and thickness was 15 mm (pressing step).

(118) The obtained green compact was sufficiently dried at a room temperature in air, and was heated from the room temperature to 500° C. at a heating rate of 5° C./min and from 500 to 1300° C. at a heating rate of 55° C./min and held for 1 hour at 1300° C. After the holding, a firing step was carried out by reducing the temperature to the room temperature at a cooling rate of 100° C./min, and ferrite sintered magnets were thereby obtained (firing step).

(119) Br(G), HcJ(Oe), M phase ratio, and Fe.sup.2+ content of each ferrite sintered magnet obtained in Experimental Example 5 were determined in a similar manner to Experimental Example 1. The obtained results are shown in Table 5.

(120) TABLE-US-00005 TABLE 5 composition formula: sub-component firing Fe.sup.2+ M phase A.sub.1−xR.sub.x(Fe.sub.12−yMe.sub.y).sub.z SiO.sub.2 content temperature Br HcJ content ratio No. x y z x/yz (mass %) (° C.) (G) (Oe) (mass %) (mol %) 5-1 0.80 0.35 0.94 2.15 0.002 1300 4516 2150 4.0 96.1 5-2 0.80 0.35 0.94 2.15 0.03 1300 4715 2401 4.1 94.1 5-3 0.80 0.35 0.94 2.15 0.07 1300 4706 2333 4.1 92.9 5-4 0.80 0.35 0.94 2.15 0.09 1300 4704 2319 4.1 94.5 5-5 0.80 0.35 0.94 2.15 0.11 1300 4701 2305 4.2 92.7 5-6 0.80 0.35 0.94 2.15 0.15 1300 4569 2244 4.2 90.3

(121) As shown in Table 5, it was found that when the SiO.sub.2 content was more than 0.002 mass % and less than 0.15 mass %, a sintered body having Br of 4.7 (kG) or more and HcJ of 2.0 (kOe) or more was obtained, and that a high Br and a favorable HcJ could be obtained.

INDUSTRIAL APPLICABILITY

(122) The ferrite sintered magnet according to the present invention is favorable as a variable magnetic force magnet, and can also favorably be used for automotive electrical components, such as various motors, generators, and speakers, parts for electrical components, and the like. In particular, the ferrite sintered magnet according to the present invention can contribute to miniaturization, weight reduction, and high efficiency of these components.