METHOD FOR PRODUCING A PRINTED CONCRETE ELEMENT

Abstract

A method for producing a printed concrete element, in particular a printed concrete block, a printed concrete slab or a printed concrete step, is described, comprising at least the following steps: filling concrete into a mold to form a concrete element; printing at least one surface area of the concrete element with a printing composition comprising a binder A and a dye B, the binder A containing at least one siloxane and at least one silane; and curing the concrete element after printing.

Claims

1-40. (canceled)

41. A method for producing a printed concrete element comprising the steps: (a) filling a mold with concrete to form a concrete element; (b) printing at least one surface of the concrete element with a printing composition comprising a binder A and a dye B, wherein the binder A comprises at least one siloxane and at least one silane; and (c) curing the concrete element after printing.

42. The method according to claim 41, wherein the siloxane is a silicone resin.

43. The method according to claim 41, wherein the printing is carried out using an inkjet, laser, dot matrix, or electrostatic printer.

44. The method according to claim 41, wherein the printing step comprises screen printing, liquid printing, liquid printing, or pad printing.

45. The method according to claim 41, wherein binder A comprises a condensed, pre-crosslinked, silicone resin; and the silicone resin comprises 50 to 85% of inorganic material.

46. The method according to claim 45, wherein binder A comprises a silane formed from one or more silane monomers of the formula (R).sub.aSi(OR).sub.b where a is 0, 1, or 2, b is 2, 3, or 4, and each R is independently selected from an unsubstituted or substituted methyl, ethyl, propyl, or phenyl.

47. The method according to claim 46, wherein the silane monomers are at least one selected from the group consisting of Me-Si(OEt).sub.3, PrSi(OEt).sub.3, Ph-Si(OMe).sub.3, Me.sub.2Si(OMe).sub.2 and Si(OEt).sub.4.

48. The method according to claim 41, wherein binder A comprises silicone resin and silane in a mass ratio of from 10:90 to 90:10.

49. The method according to claim 41, wherein dye B is an organic dye or an inorganic dye.

50. The method according to claim 41, wherein the printing composition further comprises a curing catalyst C.

51. The method according to claim 50, wherein curing catalyst C is a phosphoric acid, a phosphoric acid ester, a phosphoric acid diester, a phosphonic acid, a phosphonic acid ester, a phosphonic acid diester, a metal alkoxide, an amine, or an aminosilane.

52. The method according to claim 51, wherein the printing composition comprises from 0.5 to 20 wt % of curing catalyst C based on the total weight of the printing composition.

53. The method according to claim 41, further comprising the step of compressing the concrete after the mold is filled with the concrete.

54. The method according to claim 53, wherein the concrete element is demolded before the printing step is carried out.

55. The method according to claim 54, wherein the concrete element is demolded after the concrete has been compressed.

56. The method according to claim 41, further comprising brushing or embossing at least a portion of a surface of the concrete after the printing step and prior to the curing step.

57. The method according to claim 41, wherein the mold is filed with core and face concrete.

58. The method according to claim 57, wherein the printing is carried out on the face concrete.

59. The method according to claim 58, wherein at least a portion of the face concrete has a water-binder ratio of 0.30 to 0.50 at the time of printing.

60. The method according to claim 59, wherein at least a portion of the face concrete comprises 10 to 35 wt % of a binder.

61. The method according to claim 60, wherein the binder in the face concrete comprises cement, an alkali silicate, hydraulic lime, or gypsum.

62. The method according to claim 41, wherein face concrete comprises cement, sand, gravel, and water.

63. The method according to claim 62, wherein the face concrete optionally comprises color pigments or other additives for improving the concrete properties.

64. The method according to claim 41, further comprising the step of applying at least one cover layer D onto the printed surface of the concrete before or after the curing step.

65. The method according to claim 64, wherein the cover layer D comprises a water-based acrylate resin, a water-based polyurethane resin, or a water-based epoxy resin.

66. The method according to claim 65, wherein the cover layer D further comprises a solids content from 20 to 45 wt %.

67. The method according to claim 64, wherein the cover layer D is a sol-gel coating based on silicone resin and/or silane.

68. The method according to claim 67, wherein the sol-gel coating has a solids content from 60 to 100 wt %.

69. The method according to claim 64, wherein the cover layer D cures upon exposure to heat or radiation.

70. The method according to claim 64, wherein the cover layer D cures upon exposure to heat or radiation and is applied to the printed surface of the concrete before the curing step.

71. The method according to claim 64, wherein the cover layer D is applied to the printed surface of the concrete by spraying, rolling, or curtain coating the printed surface of the concrete.

72. The method according to claim 41, wherein the printed concrete element is a printed concrete block, a printed concrete slap, or a printed concrete step.

73. A concrete element comprising at least one visible surface, wherein the visible surface is embedded with a printing composition comprising a binder A according to any one of claims 45-48 and a dye B, wherein dye B is an organic or inorganic dye.

74. The concrete element of claim 73, further comprising at least one cover layer D according to any one of claims 65-69, wherein the cover layer D at least partially covers the printing composition.

Description

EXAMPLE

[0048] Raw concrete was poured into a mold for a paving stone. Subsequently, face concrete consisting of cement, a (crushing) sand gravel chippings mixture and water having a water-binder ratio (w/b ratio) of 0.35, a maximum grain size of 4 mm and a cement proportion in the face concrete layer of 19 wt. %, based on the total composition of the face concrete layer, is poured onto the core concrete and into the mold. Using a vibrating tamper method, the concrete was then compressed to form a paving stone and the concrete element was demolded from the mold immediately afterward. Immediately after demolding, the wet concrete was printed with an ink using an inkjet printer. The ink was prepared as follows:

[0049] 30 g of Silres MSE100 (silicone resin; WACKER CHEMIE AG) and 30 g of Dynasil A (tetraethyl orthosilicate; EVONIK INDUSTRIES AG) were mixed and stirred for 10 minutes at room temperature. Subsequently, 18 g Bayferrox 306 black (dye; LANXESS AG), 3 g Silbond 6000 EST (SiO.sub.2 powder; QUARZWERKE GmbH), 2.5 g 3-aminopropyltriethoxysilane, 0.18 g Tego Glide 410 (additive; TEGO/EVONIK INDUSTRIES AG) and 3 g Hordaphos MDAH (phosphoric acid ester; CLARIANT AG) were added to the mixture with stirring, and the whole mixture was stirred for 24 hours at room temperature. The obtained ink could be used directly afterward.

[0050] A printed image was produced by the wet concrete being printed with ink. The printed image was then provided with a clear coating based on a sol-gel mixture. The concrete element was cured at a temperature of from 25 to 30 C. for a period of 12 hours. Finally, a further clear coating layer based on an aqueous acrylate/polyurethane mixture was applied to the cured concrete element and cured under a UV lamp. The paving stone obtained in this way had a splitting tensile strength determined according to DIN EN 1338 of >2.6 MPa and, in the case of a plate, a bending tensile strength of >4.0 MPa and an abrasion resistance according to DIN EN 1338, Annex H of <18,000 cm.sup.3/5,000 mm.sup.2. Furthermore, the cured concrete layer of the paving stone had a density according to DIN EN 13369 of >2.25 kg/m.sup.3. The printed image on the concrete element was completely preserved after curing of the concrete and coating.