Styrene copolymer composite film

Abstract

The present invention relates to a composite film comprising a styrene copolymer layer (a), a metal layer (b), optionally a coloured layer (c), and a transparent polymer layer (d), wherein (b) is located between (a) and (d) and optionally (c) is located between (b) and (d). Moreover, the present invention refers to a method for producing a composite film and to the use of such composite film for laminating a surface or a part thereof. Finally, the present invention further relates to a product that is at least partly laminated by a composite film according to the present invention.

Claims

1. A composite film having a thickness of not more than 1 mm comprising: (a) an acrylonitrile styrene acrylate (ASA) copolymer layer having a thickness of 50 to 500 m; (b) a metal layer having a thickness of 0.1 to 50 m; (c) optionally a coloured layer having a thickness of 0.1 to 50 m; and (d) a transparent polymer layer that is a UV-protective, glossy, chemically inert or weatherproof layer and has a thickness of 0.5 to 50 m, wherein said transparent polymer layer comprises one or more types of polystyrene, one or more types of styrene-acrylonitrile copolymer (SAN), one or more types of styrene-butadiene copolymer (SB), one or more types of acrylonitrile butadiene styrene copolymer (ABS), one or more types of polymethacrylate, one or more types of poly(methyl methacrylate), one or more types of (methyl)methacrylate-butadiene-styrene copolymer ((M)MBS), one or more types of acrylonitrile styrene acrylate (ASA), one or more types of styrene-maleic acid anhydride copolymer (SMA), one or more types of styrene-maleic acid anhydride-butadiene copolymer (SMAB), one or more types of styrene butadiene methylmethacrylate copolymer (SBMMA), one or more types of methyl methacrylate acrylonitrile butadiene copolymer, one or more types of polyethylene, one or more types of polypropylene, one or more types of polydimethylsiloxane (PDMS), one or more types of polylactone, one or more types of polyester, one or more types of poly(methyl methacrylate) (PMMA) or a blend of two or more thereof, wherein layer (b) is located between layers (a) and (d) and optionally layer (c) is located between layers (b) and (d).

2. The composite film according to claim 1, wherein the ASA copolymer layer (a) comprises a texturized pattern.

3. The composite film according to claim 1, wherein the ASA copolymer layer (a) has a thickness of 50-300 m.

4. The composite film according to claim 1, wherein the metal layer (b) is an aluminium layer.

5. The composite film according to claim 1, wherein the metal layer (b) has a thickness of 0.5-20 m.

6. The composite film according to claim 1, wherein said composite film comprises a coloured layer (c) that is a printed layer, which is optionally a pattern printed, pattern embossed or pattern printed and embossed layer, or a hologram in case of no texturized pattern on the ASA copolymer layer (a).

7. The composite film according to claim 1, wherein said composite film comprises a coloured layer (c) that has a thickness of 0.5-20 m.

8. The composite film according to claim 1, wherein the transparent polymer layer (d) is scratch resistant, or has an elongation of break of at least 10% in a stress/strain test according to ISO 527.

9. The composite film according to claim 1, wherein the transparent polymer layer (d) has a thickness of 2-20 m.

10. The composite film according to claim 1, wherein said composite film comprises a layer structure of (a)-(b)-(c)-(d) and has a thickness of 100-350 m.

11. The composite film according to claim 1, wherein said composite film is an adhesive composite film, further comprising at least one adhesive coating on at least one of the two outer surfaces of said composite film.

12. The composite film according to claim 1, wherein the ASA copolymer layer (a) has a thickness of 100-300 m.

13. The composite film according to claim 1, wherein the metal layer (b) has a thickness of 1-10 m.

14. The composite film according to claim 1, wherein said composite film comprises a coloured layer (c) that has a thickness of 1-10 m.

15. The composite film according to claim 11, wherein the at least one adhesive coating is reversibly covered by a strippable non-adhesive film.

16. The composite film according to claim 1, wherein said composite film comprises a layer structure of (a)-(b)-(c)-(d) and has a thickness of 100-350 m, wherein (a) the ASA copolymer layer (a) has a thickness of less than 200 m; (b) the metal layer (b) has a thickness of less than 15 m; (c) the coloured layer (c) a thickness of less than 15 m; (d) the transparent polymer layer (d) a thickness of less than 20 m.

17. The composite film according to claim 3, wherein the texturized pattern is a stainless steel hairline pattern.

18. The composite film according to claim 1, wherein said composite film is an adhesive composite film, further comprising an adhesive coating on the surface of said composite film on surface of the ASA copolymer layer (a) opposed to its surface adjacent to the metal layer (b).

Description

EXAMPLES

(1) TABLE-US-00001 TABLE 1 Two different composite films according to the invention are prepared. Example Components Example 1 (a) Luran S 757RE layer of a thickness of 250 m (b) sputtered aluminium film of a thickness of 5 m (c) pattern printing of a thickness of 5 m (d) UV protective transparent polymer layer of a thickness of approximately 10-15 m Example 2 (a) Luran S 757RE layer of a thickness of 200 m (b) sputtered aluminium film of a thickness of 5 m (c) pattern printing of a thickness of 5 m (d) UV protective transparent polymer layer of a thickness of approximately 10-15 m Luran S is an ASA-copolymer of Styrolution (Germany)

(2) These coatings are tested by the following test methods:

(3) Erichsen Test:

(4) Cross cutting 5 mm interval pushing by 8 mm in depth in Erichsen tester

(5) Boiling Test:

(6) Contacting with water of 95 C. for 2 h, subsequently maintain it for 1 h at room temperature and cross cutting base on

(7) Bending Test:

(8) Bending by 180 in a curved manner

(9) Constant temperature humidity test:

(10) Incubating the composite film at a humidity of 90% at 60 C. for 24 h after Erichsen Test

(11) Pencil hardness:

(12) Using Mitsibishi Uni pencil, checking pencil trace mark when down at 45 direction with 500 g, comparison with common pencil hardness degrees B, 2B, HB, H, etc.

(13) The following results are obtained:

(14) TABLE-US-00002 TABLE 2 Results Example Test method Result Example 1 Erichsen Test no peeling Boiling Test no change on the surface Bending Test no change Constant temperature humidity test no peeling Pencil hardness approximately 2B Example 2 Erichsen Test no peeling Boiling Test no change on the surface Bending Test no change Constant temperature humidity test no peeling Pencil hardness >2B