PREPARATION METHOD OF LIGHT METAL/BORON CARBIDE COMPOSITE MATERIAL

Abstract

The present invention provides a preparation method of a light metal/boron carbide composite material, comprising: (A) providing a boron carbide precursor and a light metal powder to perform a pretreatment mixing process to form a precursor; (B) performing a vacuum hot pressing molding or a vacuum cold isostatic pressing molding on the precursor to make the precursor form a light metal/boron carbide compound green body that is uniform; (C) performing a thermal treatment on the light metal/boron carbide compound green body to make the light metal/boron carbide compound green body form a light metal/boron carbide compound sintered body; and (D) performing a cold rolling treatment or a hot rolling treatment on the light metal/boron carbide compound sintered body to obtain a light metal/boron carbide composite material.

Claims

1. A preparation method of a light metal/boron carbide composite material, comprising: (A) providing a boron carbide precursor and a light metal powder to perform a pretreatment mixing process to form a precursor; (B) performing a vacuum hot pressing molding or a vacuum cold isostatic pressing molding on the precursor to make the precursor form a light metal/boron carbide compound green body that is uniform; (C) performing a thermal treatment on the light metal/boron carbide compound green body to make the light metal/boron carbide compound green body form a light metal/boron carbide compound sintered body; and (D) performing a cold rolling treatment or a hot rolling treatment on the light metal/boron carbide compound sintered body to obtain a light metal/boron carbide composite material.

2. The preparation method of a light metal/boron carbide composite material of claim 1, wherein the boron carbide precursor includes boron carbide and/or a mixture of h-boron nitride and carbon black, a mixture of boron oxide and carbon black or a combination thereof, wherein a weight percent of boron carbide is more than or equal to 50%.

3. The preparation method of a light metal/boron carbide composite material of claim 2, wherein the boron carbide precursor comprises 1 wt % to 49 wt % of boron oxide and 0.1 to 4.9 wt % of carbon black, and/or 1 wt % to 49 wt % of h-boron nitride and 1 to 4.9 wt % of carbon black.

4. The preparation method of a light metal/boron carbide composite material of claim 1, wherein the light metal powder is selected from aluminum powder, magnesium powder, titanium powder and a combination thereof, wherein the aluminum powder, magnesium powder, and titanium powder can be spherical or flake-like, and the light metal powder has an average particle size of 1 to 100 microns.

5. The preparation method of a light metal/boron carbide composite material of claim 1, wherein the pretreatment mixing process of step (A) uses a high-speed mixer, which has a rotation speed of more than or equal to 300 rpm and a running time of more than or equal to 1 minute, for mixing.

6. The preparation method of a light metal/boron carbide composite material of claim 1, wherein the vacuum cold isostatic pressing molding puts the precursor into a vacuum package mold for proceeding with a cold isostatic pressing process, so that the precursor is molded by isostatic pressing to form the light metal/boron carbide compound green body.

7. The preparation method of a light metal/boron carbide composite material of claim 6, wherein the cold isostatic pressing molding uses a molding pressure of more than or equal to 3000 kgf/cm.sup.2.

8. The preparation method of a light metal/boron carbide composite material of claim 1, wherein the vacuum hot pressing molding uses a pressure of more than or equal to 200 kgf/cm.sup.2, an operation temperature of more than or equal to 500° C., an operation time of more than or equal to 60 minutes and a vacuum degree of more than or equal to 1×10.sup.−2 torr.

9. The preparation method of a light metal/boron carbide composite material of claim 1, wherein the thermal treatment uses a vacuum microwave irradiation or a vacuum thermal treatment temperature of more than or equal to 600° C., wherein the microwave irradiation uses a microwave output power of more than or equal to 1950 W, a microwave irradiation time between 1 and 14 hours, and a vacuum degree of more than or equal to 1×10.sup.−2 torr.

10. The preparation method of a light metal/boron carbide composite material of claim 1, wherein the hot rolling treatment uses a hot rolling temperature of more than or equal to 500° C.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0027] FIG. 1 is a flow chart showing a preparation method of a light metal/boron carbide composite material of the present invention.

DETAILED DESCRIPTION OF THE INVENTION

[0028] The following describes the embodiments of the present invention with specific examples, and those skilled in the art can easily understand the advantages and effects of the present creation from the content disclosed in the specification.

[0029] Please refer to FIG. 1, which is a flow chart showing a preparation method of a light metal/boron carbide composite material of the present invention. One of the solutions proposed by the present invention provides a preparation method of a light metal/boron carbide composite material. The steps comprises: step S1 provides a boron carbide precursor and a light metal powder to perform a pretreatment mixing process to form a precursor, step S2 performs a vacuum hot pressing molding or a vacuum cold isostatic pressing molding on the precursor to make the precursor form a light metal/boron carbide compound green body that is uniform, step S3 performs a thermal treatment on the light metal/boron carbide compound green body to make the light metal/boron carbide compound green body form a light metal/boron carbide compound sintered body, and then step S4 performs a cold rolling treatment or a hot rolling treatment (the hot rolling temperature ≥500° C.) on the light metal/boron carbide compound sintered body to obtain a light metal/boron carbide composite material.

[0030] In the present embodiment, step S1 provides the boron carbide precursor and the light metal powder to perform the pretreatment mixing process to form the precursor. The boron carbide precursor includes boron carbide and/or a mixture of h-boron nitride and carbon black, a mixture of boron oxide and carbon black or a combination thereof, wherein the weight percent of boron carbide is more than or equal to 50%. The boron carbide precursor comprises 1 wt % to 49 wt % of boron oxide and 0.1 to 4.9 wt % of carbon black, and/or 1 wt % to 49 wt % of h-boron nitride and 1 to 4.9 wt % of carbon black. The boron carbide precursor has an average particle size of less than or equal to 100 microns.

[0031] In the present embodiment, the light metal powder is selected from aluminum powder, magnesium powder, titanium powder and a combination thereof, wherein the aluminum powder, magnesium powder, and titanium powder can be spherical or flake-like, and the light metal powder has an average particle size of 1 to 100 microns.

[0032] In the present embodiment, step S2 proceeds with the vacuum hot pressing molding or the vacuum cold isostatic pressing molding to make the precursor form the uniform light metal/boron carbide compound green body, and the pretreatment mixing process of step S1 uses the high-speed mixer for mixing. The rotation speed is more than or equal to 300 rpm, and the running time is more than or equal to 1 minute.

[0033] In the present embodiment, the vacuum cold isostatic pressing molding puts the precursor into the vacuum package mold for proceeding with the cold isostatic pressing process, and the molding pressure of the cold isostatic pressing molding is more than or equal to 3000 kgf/cm.sup.2.

[0034] In the present embodiment, the pressure of the vacuum hot pressing molding is more than or equal to 200 kgf/cm.sup.2, the operation temperature is more than or equal to 500° C., the operation time is more than or equal to 60 minutes and the vacuum degree is more than or equal to 1×10.sup.−2 torr.

[0035] In the present embodiment, step S3 performs the thermal treatment process to form the light metal/boron carbide compound sintered body, and the thermal treatment process uses the microwave irradiation or vacuum thermal treatment temperature of more than or equal to 600° C., in which the microwave output power of the microwave irradiation is more than or equal to 1950 W, the vacuum microwave irradiation time is between 1 and 14 hours, and the vacuum degree is above 1×10.sup.−2 torr.

[0036] The embodiment of the preparation method proposed by the present invention provides a preparation method of the aluminum/boron carbide composite material. The steps may comprise: first, the boron carbide precursor containing 90 wt % of boron carbide, 9 wt % of boron oxide compound and 0.9 wt % of carbon black (in the embodiment of the present invention, the weight percent of boron carbide may be 90 wt %, into which 5 wt % to 10 wt % of boron oxide and 1-4.9 wt % of carbon black are added) is mixed for 1 to 4 hours through high speed ball milling to form the boron carbide precursor. The boron carbide precursor of this embodiment may include boron carbide and/or the mixture of h-boron nitride and carbon black, the mixture of boron oxide and carbon black or a combination thereof. Next, the boron carbide precursor and the aluminum powder perform the pretreatment mixing process to mix and form the precursor. Next, the precursor is put into the vacuum package, which is then put in the fixed polymer mold to carry out the cold isostatic pressing process, thereby forming the aluminum/boron carbide compound green body. The parameter of the molding machine is set to have a pressure of more than or equal to 3000 kgf/cm.sup.2. Next, the aluminum/boron carbide compound green body is heated to a temperature above 600° C., and the calcination time is at least 1 hour for vacuum sintering (the heat treatment equipment for vacuum sintering may be a microwave calcination furnace or a vacuum calcination furnace), so as to make the aluminum/boron carbide compound green body transform into the boron carbide crystalline phases and obtain the aluminum/boron carbide composite material, contributing to better bonding.

[0037] To sum up, the preparation method of the light metal/boron carbide composite material of the present invention has the following advantages. (1) The present invention is also a precursor conversion method, which can replace part of boron carbide as a raw material, and can reduce the cost of raw materials. Another object uses light metal as an interface for catalytic reaction. Through the cold isostatic pressing process, the precursor can be heated and then cooled to form a uniform solid to synthesize and manufacture the light metal/boron carbide composite material. The advantage of cold isostatic pressing or hot pressing is that it can increase the contact area and uniformity of the powder. Through use of aluminum or magnesium metal as the catalytic medium, the boron carbide precursor can be catalyzed and transformed into boron carbide, which can improve the uniformity of the cracking reaction and reduce the cost of raw materials, and then the heat treatment through microwave irradiation may be carried out. (2) The light metal/boron carbide composite material of the present invention has simple operation of the preparation method, low raw material cost, indirect use of boron carbide as a precursor, and improved densification degree through microwave irradiation and cold rolling treatment, which is suitable for industrial production. The light metal/boron carbide composite material obtained by the preparation method of the present invention has the advantages of high strength, light weight, high toughness, good friction and wear performance and the like.

[0038] The embodiments described above are only illustrative of the features and efficacies of the present invention, and are not intended to limit the scope of the essential technical content of the present invention. Anyone skilled in the art can modify and change the above-mentioned embodiments without departing from the spirit and scope of the present invention. Therefore, the protection scope of the present invention should be determined by the appended claims.