Nanofiber based composite false twist yarn and manufacturing method therefor

Abstract

Provided is a nanofiber based composite false twist yarn that is obtained by producing a nanofiber tape yarn by precisely slitting a nanofiber membrane produced by electrospinning and then twisting a nanofiber-only twist yarn that is obtained by twisting the nanofiber tape yarn or composite-twisting a nanofiber-only twist yarn and a natural fiber or synthetic fiber. The nanofiber based composite false twist yarn includes: a nanofiber tape yarn including at least one bonding portion or a false twist yarn which is obtained by false twisting the nanofiber tape yarn; and a natural fiber yarn or a synthetic fiber yarn that is composite-false-twisted with the nanofiber tape yarn or the false twist yarn, wherein the nanofiber tape yarn is made of a nanofiber web that is obtained by integrating polymer nanofibers made of a fiber-forming polymer material and having an average diameter of less than 1 m thereby having fine pores.

Claims

1. A method of manufacturing a nanofiber based composite false twist yarn, the method comprising: preparing a spinning solution by dissolving a fiber-forming polymer material in a solvent; electrospinning the spinning solution to obtain a polymer nanofiber web, the polymer nanofiber web being formed of polymer nanofibers having an average diameter of less than 1 m; laminating the polymer nanofiber web to obtain a polymer nanofiber membrane; winding the polymer nanofiber membrane to obtain a first rolled polymer nanofiber membrane having a first roll width and a first roll diameter, primary-slitting the first rolled polymer nanofiber membrane to obtain a plurality of second rolled polymer nanofiber membranes each having a second roll width being smaller than the first roll width and the second roll diameter being same as the first roll diameter; bonding at least two of the second rolled polymer nanofiber membranes to form a third rolled polymer nanofiber membrane having a third roll width being same as the second roll width and a third roll diameter being larger than the second roll diameter; secondary-slitting the third rolled polymer nanofiber membrane to obtain a nanofiber tape yarn; and obtaining a composite false twist yarn by composite-false-twisting the nanofiber tape yarn or a false twist yarn obtained by false-twisting the nanofiber tape yarn with a natural fiber yarn or a synthetic fiber yarn.

2. The method of manufacturing a nanofiber based composite false twist yarn of claim 1, wherein the first roll width is set according to a width of a precision slitter to which the secondary slitting is performed.

3. The method of manufacturing a nanofiber based composite false twist yarn of claim 1, wherein a bonding portion between the at least two of the second rolled polymer nanofiber membranes is set in a range of 0.5 mm to 1 mm.

4. The method of manufacturing a nanofiber based composite false twist yarn of claim 3, wherein the bonding is performed by any one of thermal bonding, ultrasonic bonding, pressing and rolling.

5. The method of manufacturing a nanofiber based composite false twist yarn of claim 1, wherein the third rolled polymer nanofiber membrane has a length of 500 meters or more.

6. The method of manufacturing a nanofiber based composite false twist yarn of claim 1, wherein the nanofiber tape yarn has a basis weight of 0.5 gsm to 100 gsm and a width of 0.1 mm to 5 mm.

7. The method of manufacturing a nanofiber based composite false twist yarn of claim 1, wherein the false twist yarn is one of a right handed yarn or a left handed yarn of a nanofiber-only tape yarn, and a two-ply yarn obtained by composite-twisting the right handed yarn and the left handed yarn.

8. The method of manufacturing a nanofiber based composite false twist yarn of claim 1, wherein the false twist yarn is a low twist yarn at a T/M (twisting/meter) of not more than 500 or a crepe hard twist yarn at a T/M of not less than 2,500.

9. The method of manufacturing a nanofiber based composite false twist yarn of claim 1, further comprising: hot rolling or thermal fixing the false twist yarn and the composite false twist yarn so as to prevent twist of the false twist yarn and the composite false twist yarn from being loosened.

10. The method of manufacturing a nanofiber based composite false twist yarn of claim 9, wherein the hot rolling or the thermal fixing is performed in a temperature range between a glass transition temperature (Tg) and a melting temperature (Tm) of the fiber-forming polymer material.

11. The method of manufacturing a nanofiber based composite false twist yarn of claim 9, wherein the hot rolling is performed at different speed of up and down disks.

12. A nanofiber based composite false twist yarn comprising: a nanofiber tape yarn including at least one bonding portion or a false twist yarn which is obtained by false twisting the nanofiber tape yarn; and a natural fiber yarn or a synthetic fiber yarn that is composite-false-twisted with the nanofiber tape yarn or the false twist yarn, wherein the nanofiber tape yarn is made of a nanofiber web having fine pores, the nanofiber web being made of polymer nanofibers, the polymer nanofibers being made of a fiber-forming polymer material and having an average diameter of less than 1 m.

13. The nanofiber based composite false twist yarn of claim 12, wherein the nanofiber tape yarn is formed by slitting a polymer nanofiber membrane obtained by laminating the nanofiber web.

14. The nanofiber based composite false twist yarn of claim 12, wherein the at least one bonding portion is joined in a range of 0.5 mm to 1 mm, and the nanofiber tape yarn has a basis weight of 0.5 gsm to 100 gsm and a width of 0.1 mm to 5 mm.

15. The nanofiber based composite false twist yarn of claim 12, wherein the false twist yarn is one of a right handed yarn or a left handed yarn of a nanofiber-only tape yarn, and a two-ply yarn obtained by composite-twisting the right handed yarn and the left handed yarn.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) FIG. 1 is a flowchart showing a method of manufacturing a nanofiber based composite false twist yarn according to an embodiment of the present invention.

(2) FIG. 2 is a scanning electron micrograph (SEM) image of a PVDF nanofiber web prepared according to an example 1 of the present invention.

(3) FIG. 3A is a photograph of a result obtained by rolling PVDF nanofiber membranes obtained by calendering the PVDF nanofiber web of FIG. 2, FIG. 3B is a photograph illustrating a process of primarily slitting the roll-type nanofiber membrane by using a primary slitter, FIG. 3C is a conceptual view showing a process of obtaining a large-diameter slitting roll by bonding a nanofiber membrane between a slitting roll and another slitting roll, and FIG. 3D is a photograph of a large-diameter slitting roll.

(4) FIG. 4A is a photograph showing a secondary slitting process of the large-diameter slitting roll using a precision slitter, FIG. 4B is a nanofiber tape yarn wound on a flat bobbin, FIG. 4C is a SEM image of a nanofiber tape yarn, and FIG. 4D is a photograph of a nanofiber tape yarn wound on an H bobbin.

(5) FIG. 5A is a photograph of a cone sample of a two-for-one false twist yarn manufactured by using a two-for-one twister, and FIG. 5B is a SEM image of a two-for-one false twist yarn.

(6) FIG. 6A is a photograph of a sample of a nanofiber-only composite false twist yarn obtained by composite-twisting a nanofiber false twist yarn whose right handed twist (S twist) and left handed twist (Z twist) are false-twisted at T/M 500, respectively, under the condition of T/M 1000 by using a composite twister, and FIG. 6B is a SEM image of a nanofiber composite false twist yarn (2-ply yarn).

(7) FIG. 7A is a schematic view of a composite false twist yarn manufacturing process of natural and synthetic fibers and nanofiber tape yarns, and FIG. 7B is a SEM image of a composite false twist yarn obtained by composite-false-twisting a PVDF nanofiber tape yarn and a nylon 20d monofilament yarn under the condition of T/M 1000.

(8) FIG. 8 is a SEM image of a composite false twist yarn obtained by composite-false-twisting a PVDF nanofiber tape yarn and cotton of count of yarns 60 (D).

(9) FIG. 9 is (a) a schematic view of the hot rolling of a PVDF nanofiber tape yarn, and (b) a photograph showing a process of performing a hot rolling of a PVDF nanofiber tape yarn slitted at 1.5 mm by varying speeds of an up-disk and a down-disk at 150 C.

BEST MODE

(10) Hereinafter, embodiments of the present invention will be described in detail with reference to the accompanying drawings. The sizes and shapes of the components shown in the drawings may be exaggerated for clarity and convenience.

(11) Referring to FIG. 1, a method of manufacturing a composite false twist yarn containing nanofibers according to an embodiment of the present invention includes: preparing a solution at a spinnable concentration by dissolving a fiber-forming polymer in an appropriate solvent; after transferring the solution to a spinner of an of electrospinning device and then applying a high voltage to a nozzle of the spinner, electrospinning the solution to have a basis weight of 0.5 gsm to 100 gsm; after laminating the electrospun result, primarily slitting the laminated result; and secondarily precision-slitting the primarily slitted result so as to have a width of 0.1 mm to 5 mm to obtain a nanofiber tape yarn composed of nanofibers.

(12) The thus-obtained nanofiber tape yarn is right-handed twisted (S twist) or left-handed twisted (Z twist) by using a conventional twister or the like, to obtain a false twist yarn composed of nanofibers.

(13) Thereafter, the above-mentioned nanofiber false twist yarn is composite-twisted with an existing material to produce a nanofiber based composite false twist yarn. The manufactured nanofiber tape yarn or nanofiber-only false twist yarn is thermally fixed or hot-rolled so as not to be untwisted through a post-treatment process, thereby improving the physical properties of the nanofiber.

(14) FIG. 1 is an overall flowchart showing a method of manufacturing a nanofiber based composite false twist yarn according to an embodiment of the present invention.

(15) Respective steps of the overall flowchart will be described in detail below.

(16) (Preparation of Spinning Solution)

(17) A polymer is dissolved at a spinnable concentration by using an appropriate solvent to prepare a spinning solution (S11). In some embodiments of the present invention, any polymer material is not particularly limited as long as it is a polymer that is formed as nanofibers by electrospinning a thermosetting polymer or a thermoplastic polymer.

(18) The content of the polymer material in the preparation of the spinning solution is suitably about 5 wt % to about 50 wt %. When the content of the polymer material is less than 5 wt %, the nanofibers are not formed but are sprayed in a bead form, and thus it is difficult to form a membrane. Meanwhile, when the content of the polymer material exceeds 50 wt %, the viscosity of the spinning solution is too high, and thus the spinnability is poor to cause it difficult to form fibers. Therefore, although there is no particular restriction on the preparation of the spinning solution, it is preferable to control the morphology of the fiber at a concentration that is easy to form a fibrous structure.

(19) (Forming of Nanofiber Web)

(20) The spinning solution is transferred to a spin pack using a metering pump. Here, a voltage is applied to the spinning pack using a high voltage regulating device to conduct electrospinning (S12). In this case, the voltage to be used can be adjusted from 0.5 kV to 100 kV, and the collector can be grounded or charged with negative () polarity. In the case of the collector, it is advisable to use a suction collector in order to smooth focusing of fibers during spinning.

(21) It is also preferable to adjust the distance between the spin pack and the collector to 5 cm to 50 cm. It is preferable that a discharge amount during spinning should be equally discharged and spun by using a metering pump, and the spinning is performed in an environment of a relative humidity of 30% to 80% in a chamber capable of controlling temperature and humidity during spinning.

(22) In some embodiments of the present invention, a nanofiber web composed of polymer nanofibers is formed by electrospinning nanofibers on one side of a transfer sheet (or a support), in which the transfer sheet transports a spinning solution from a spin pack through a lower-side collector, by using a transferring method. The polymer nanofiber web collected on the transfer sheet is integrated with the polymer nanofibers to have three-dimensional micropores.

(23) The transfer sheet can be made of, for example, a paper material (release paper), or a nonwoven fabric made of a polymer material which is not dissolved by a solvent contained in the spinning solution during spinning thereof, and a polyolefin film such as PE or PP.

(24) When the polymer nanofiber web itself is used alone, it is difficult to carry out the drying process, the laminating process and the winding process while being conveyed at a high transfer speed because the tensile strength is low. In addition, it is difficult to continuously carry out the subsequent process with the high transfer speed after the production of the polymer nanofiber web. However, when the above-mentioned transfer sheet is used, the process treatment speed can be greatly increased by providing a sufficient tensile strength.

(25) In addition, when a polymer nanofiber web is used alone, electrostatic phenomenon causes the phenomenon to adhere to other objects, thereby deteriorating the workability. However, this problem can be solved when a transfer sheet is used.

(26) Furthermore, the electrospun nanofibers have a phenomenon in which integration occurs in the collector and a phenomenon that is laminated along the pattern of the integrated portion. Therefore, in order to produce a porous polymer nanofiber web of nanofibers having good uniformity (pore size, air permeability, thickness, weight, etc.), it is preferable to spin the nanofibers on a transfer sheet such as paper and peel off the spun nanofibers after the subsequent process.

(27) (Laminating of Nanofiber Web)

(28) The prepared polymer nanofiber web is laminated by various methods such as compression, rolling, thermal bonding, ultrasonic bonding, or calender bonding, to produce a nanofiber membrane having a basis weight of 0.5 gsm to 100 gsm (S13). In some embodiments of the present invention, laminating is a step of forming the nanofiber web into a film by pressing and fixing the spun individual nanofibers by heat treatment or ultrasonic wave so that they cannot move independently.

(29) When the basis weight is less than 0.5 gsm, the probability of occurrence of defects at the time of handling or slitting is high, and when the basis weight is more than 100 gsm, the production cost is increased, so that the basis weight is preferably 0.5 gsm to 100 gsm.

(30) In addition, laminating can be carried out with heat treatment, and preferably carried out at a temperature in the range of 50 C. to 250 C. in which the polymer used is not melted. If the temperature is less than 50 C., the fusion between the nanofibers is unstable due to too a low heat treatment temperature, or if the polymer having a high glass transition temperature is hardly fused between the nanofibers, there is a high possibility that the subsequent slitting does not proceed smoothly at the time of producing a tape yarn. Also, when the heat treatment temperature exceeds 250 C., it is undesirable that there is a high possibility that the polymer constituting the nanofiber is melted and thus the fibrous structure is lost.

(31) (Winding and Primary Slitting of Nanofiber Membranes)

(32) Since the nanofiber membrane is manufactured on a transfer sheet, the nanofiber membrane is wound or rolled simultaneously with the transfer sheet after laminating, or the nanofiber membrane is rolled alone and manufactured in a roll form through winding and unwinding while separating the transfer sheet. In this case, the width of the nanofiber membrane manufactured in a roll form can be variously manufactured from 500 mm to 2,000 mm according to the spinning equipment, but the length thereof is about 500 meters or so. The roll-type nanofiber membrane is primarily slitted together with a bobbin so as to match the width of a precision slitter, by using the same equipment as that shown in FIG. 3B to form a plurality of slitting rolls (S14).

(33) The plurality of slitting rolls obtained by the primary slitting are rolled through the bonding of the nanofiber membrane between the plurality of slitting rolls and through winding and unwinding thereof, into 500 meters or more, preferably, 1,000 meters or more, so that a secondary slitting operation at the precision slitter is continuously performed for a predetermined period of time in order to improve productivity, to form a large-diameter slitting roll (S15).

(34) (Production of Nanofiber Tape Yarn by Secondary Slitting of Nanofibers)

(35) The large-diameter slitting roll obtained by enlarging the plurality of primarily slitted slitting rolls is slitted to have a width of 0.1 mm to 5 mm by various methods using a precision slitter such as a cutter or a slitter to form a nanofiber tape yarn composed of nanofiber membranes (S16).

(36) When the width of the slitted nanofiber tape yarn is made less than 0.1 mm, the width thereof is too small to smoothly cut the slitted nanofiber tape yarn by using the slitter, as well as the probability of occurrence of yarn breakage in tension and twisting is increased. In addition, when the width thereof is more than 5 mm, the possibility of nonuniform twist in the twisting step increases, and the thickness of the twisted yarn becomes thick, resulting in deterioration of the merchantability as a fiber yarn. Therefore, the nanofiber tape yarn preferably has a basis weight of 0.5 gsm to 100 gsm and a width of 0.1 mm to 5 mm.

(37) (Production of Polymer Nanofiber False Twist Yarns)

(38) The prepared nanofiber tape yarn is twisted through a twister to give the right handed twist (S twist) or the left handed twist (Z twist) to the nanofiber tape yarn, to thereby impart a twisting (T/M; twisting/meter) to the nanofiber tape yarn (S17). Here, it is necessary to implement a twisting (T/M) by performing low-twisting a polymer with T/M 500 or less or crepe-hard-twisting a polymer with T/M 2500 or more to meet the kind of polymer or the end purpose.

(39) Further, as a method of imparting tension to a nanofiber tape yarn, it is possible to impart tension to the nanofiber tape yarn by passing the nanofiber tape yarn between an up-disk tensioner and a down-disk tensioner, and depending on the type of the polymer, hot rolling or thermal fixing can be carried out in a temperature range between the glass transition temperature (Tg) and the melting temperature (Tm).

(40) Further, two strands of the twisted nanofiber false twist yarn twisted with the right handed twist (S twist) or the left handed twist (Z twist) may be joined together and composite-twisted to form a twin yarn composed of the nanofibers (S17).

(41) Meanwhile, a nanofiber tape yarn and another nanofiber tape yarn may be folded together and continuously subjected to the twisting process. In this case, the nanofiber tape cannot only use homogeneous polymers, but also can join a different type of nanofiber tape yarns.

(42) (Production of Nanofiber Composite False Twist Yarns)

(43) The prepared nanofiber false twist yarns (S twist, Z twist, or 2-ply yarn) can be composite-false-twisted with natural fibers or synthetic fibers to produce a composite false twist yarn (S18). In this case, cotton, silk, wool, cellulose and the like can be selected as natural fibers for the final purpose, and PET, nylon, PP, PE, PVC, PU, PTFE, PVDF, etc., can be selected as synthetic fibers, to suit the final purpose, to then be composite-false-twisted, and the synthetic fibers are not limited to specific materials.

(44) (Post-Treatment of Nanofiber False Twist Yarn)

(45) The produced nanofiber-only false twist yarns or composite false twist yarns may be subjected to perform a process such as hot rolling or thermal fixing or the like so as not to be untwisted or to impart strength thereto (S19). Various methods such as hot rolling and cold rolling can be used as the rolling method, and it is preferable to use the thermal fixing in a temperature range in which the twisting is not untwisted depending on the material used. The preferred hot rolling or thermal fixing is carried out in a temperature range between the glass transition temperature (Tg) and the melting temperature (Tm) of the polymer used. Further, the hot rolling and thermal fixing process can be carried out not only in the post-treatment of the composite false twist process, but also in the pre-treatment thereof.

(46) Hereinafter, the present invention will be described in more detail with reference to embodiments. However, the embodiments are only for illustrating the present invention and the scope of the present invention should not be limited by these embodiments.

EXAMPLES

(Example 1) Manufacturing of PVDF Nanofiber Web and Primary Slitting

(47) PVDF polymers are dissolved in a mixed solvent (DMAc/Acetone=90/10 wt %) so as to be 20 wt % to prepare a spinning solution. This spinning solution was transferred to a spinning nozzle by using a metering pump, and was spun under the conditions of an applied voltage of 25 kV, a distance between a spinneret and a collector of 20 cm, a discharging amount of 0.05 cc/g.Math.hole per minute, a spinning temperature of 30 C., and a relative humidity of 60%, and a normal atmospheric pressure, to produce a nanofiber web.

(48) FIG. 2 is a scanning electron microscope (SEM) image of the PVDF nanofiber web obtained according to an embodiment of the present embodiment. It can be seen that the nanofiber web is composed of uniform PVDF nanofibers having an average diameter of about 300 nm.

(49) The basis weight of the nanofiber web was about 5 gsm. The nanofiber web was calendered at a pressure of 100 g/cm.sup.2 by using a roller heated at 150 C. to obtain a PVDF nanofiber membrane having a length of about 500 meters and a thickness of 10 m and then PVDF nanofiber membrane alone was rolled. The thus obtained nanofiber membrane was primarily slitted in accordance with the width of a second precision slitter to prepare a plurality of slitting rolls and then bonded between the slitting rolls through the nanofiber membrane using an ultrasonic bonding device to have a bonding surface of 1 mm, and then rewound to obtain a large-diameter slitting roll having a length of 500 meters or more in length.

(50) FIG. 3A is a photograph of a result obtained by rolling PVDF nanofiber membranes obtained by calendering the PVDF nanofiber web of FIG. 2, FIG. 3B is a photograph illustrating a process of primarily slitting the roll-type nanofiber membrane by using a primary slitter, FIG. 3C is a conceptual view showing a process of obtaining a large-diameter slitting roll by bonding a nanofiber membrane between a slitting roll and another slitting roll, and FIG. 3D is a photograph of a large-diameter slitting roll.

(Example 2) Manufacturing of PVDF Nanofiber Tape Yarn

(51) The large-diameter slitting roll prepared in Example 1 was subjected to secondary slitting using a secondary precision slitter having a knife interval of 1.5 mm and having twelve knives (see FIG. 4A), and then to rolling with a flat bobbin and an H bobbin (see FIGS. 4B and 4D) to obtain a PVDF nanofiber tape yarn composed of a nanofiber membrane. FIG. 4C shows a scanning electron microscope (SEM) image of the nanofiber tape yarn, and it was confirmed that the nanofiber tape yarn was precisely slitted at a width of 1.5 mm.

(Example 3) Manufacturing of Nanofiber False Twist Yarns and Composite False Twist Yarns

(52) The nanofiber tape yarn prepared in Example 2 was subjected to twisting of right handed twist (S twist) with T/M 500 using a two-for-one twister to produce a false twist yarn of nanofibers alone.

(53) FIGS. 5A and 5B show a cone sample image and a scanning electron microscope (SEM) image of a two-for-one false twist yarn manufactured using a two-for-one twister, respectively. As can be seen from the SEM image of FIG. 5B, the false twist yarn composed of the nanofibers alone could be confirmed.

(54) Further, the PVDF nanofiber tape yarn prepared in Example 2 was false-twisted in the right handed twist (S twist) and the left handed twist (Z twist), respectively, at a ratio of T/M 500, to obtain the false-twisted nanofiber false twist yarn and then the false-twisted nanofiber false twist yarn was composite-false-twisted at a ratio of T/M 1000 by using a composite twister, to produce a composite false twist yarn of the nanofibers alone.

(55) FIG. 6A is a photograph of a sample of a nanofiber-only composite false twist yarn obtained by composite-twisting a nanofiber false twist yarn whose right handed twist (S twist) and left handed twist (Z twist) are false-twisted at T/M 500, respectively, under the condition of T/M 1000 by using a composite twister, and FIG. 6B is a SEM image of a nanofiber composite false twist yarn (2-ply yarn). As shown in FIG. 6B, it was confirmed that the nanofiber tape yarns were 2-folded in a composite manner.

(Example 4) Manufacturing of a Composite False Twist Yarn of Nanofibers and Synthetic Fibers

(56) The PVDF nanofiber tape yarn prepared in Example 2 was composite-false-twisted with a nylon 20d monofilament yarn under the condition of T/M 1000 to prepare a composite false twist yarn of nanofibers and synthetic fibers.

(57) FIG. 7A is a schematic view of a composite false twist yarn manufacturing process of natural and synthetic fibers and nanofiber tape yarns. FIG. 7B is a SEM image of a composite false twist yarn obtained by composite-false-twisting a PVDF nanofiber tape yarn and a nylon 20d monofilament yarn under the condition of T/M 1000. As shown in FIG. 7B, it was confirmed that the composite false twisting between the nanofibers and the synthetic fibers was accomplished.

(Example 5) Manufacturing of a Composite False Twist Yarn of Nanofibers and Natural Fibers

(58) The PVDF nanofiber tape yarn and cotton No. 60 prepared in Example 2 was composite-false-twisted with cotton of count of yarns 60 (D), by the same method as in Example 4 to obtain a composite false twist yarn in which nanofibers and natural fibers were composite-false-twisted. FIG. 8 is a SEM image of a composite false twist yarn obtained by composite-false-twisting a PVDF nanofiber tape yarn and cotton of count of yarns 60 (D).

(Example 6) Post-Treatment of Nanofiber Tape Yarn and False Twist Yarn

(59) The 1.5 mm slitted PVDF nanofiber tape yarn prepared in Example 2 was hot-rolled at a temperature of 150 C. with different speeds of the up and down disks. FIG. 9A is a schematic view of hot rolling, and FIG. 9B is a photograph showing a hot rolling process.

(60) As shown in FIG. 9B, when the hot-rolling process was performed, it was confirmed that the nanofiber tape yarn was thermally stretched and tapered.

(61) Analysis of Tensile Strength and Elasticity

(62) Hereinbelow, the PVDF nanofiber tape yarn (slitting yarn) of Example 2, the false twist yarn (two-for-one twist yarn) of the nanofibers alone of Example 3 obtained by right-handed-twisting (S twist) the PVDF nanofiber tape yarn of Example 2 with the T/M 500 using the two-for-one twister, and the nanofiber-only composite false twist yarn (conjugated twist yarn) obtained by composite-twisting the PVDF nanofiber false twist yarn of Example 2 whose right handed twist (S twist) and left handed twist (Z twist) are false-twisted at T/M 500, respectively, under the condition of T/M 1000 by using a composite twister, were subjected to testing of the tensile strength according to the test standards of KSK0412 shown in the following Table 1. The results are shown in Table 2 below.

(63) TABLE-US-00001 TABLE 1 Distance The Type of twist between number of Test Count of yarns Type of testers clamps Tensile speed samples Specification yarns (D) Slitting yarns Constant speed 25 cm 30 2 (cm/min) 5 KSK0412 211.32 two-for-one tension type 208.26 twist yarns conjugated twist 468 yarns

(64) TABLE-US-00002 TABLE 2 Strength at Elongation at Strength of fracture Tensile strain at Tensile strain Type of Maximum maximum maximum load (standard) fracture at maximum twist yarns load (N) load (mm) (gf/den) (gf/den) (standard) (%) load (%) Slitting 1.12 257.43994 0.54215 0.02684 108.91198 102.97598 yarns two-for-one 1.05 177.43597 0.51641 0.02206 75.59679 70.97439 yarns conjugated 2.36 331.33062 0.51421 0.0082 140.74104 132.53225 twist yarns

(65) While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, by way of illustration and example only, it is clearly understood that the present invention is not to be construed as limiting the present invention, and various changes and modifications may be made by those skilled in the art within the protective scope of the invention without departing off the spirit of the present invention.

INDUSTRIAL APPLICABILITY

(66) The present invention relates to manufacturing of a nanofiber based composite false twist yarn that is obtained by twisting a nanofiber-only twist yarn that is obtained by twisting the nanofiber tape yarn or composite-twisting a nanofiber-only twist yarn and a natural fiber or synthetic fiber.