Multi-material-blade for active regenerative magneto-caloric or electro-caloric heat engines
10641527 ยท 2020-05-05
Assignee
Inventors
Cpc classification
F25B21/00
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
Y02B30/00
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
International classification
Abstract
The present invention describes the design and fabrication of Multi-Material-Blades used as active regenerative regenerators in active regenerative magneto-caloric or electro-caloric engines. The blades consist of a plurality of elements (2) that divide the blade body along its length. Each element (2) is made of a different magneto-caloric or electro-caloric material selected appropriately, and a plurality of dedicated channels (3) penetrates the blade body (1) and extends along the length of the blade. The dedicated channels (3) can be provided with fluid mixing structures, porous layers or hydrophobic coatings to reduce the HE loss in an active regenerative engine. The Multi-Material-Blades are obtainable by ink jet printing techniques to reduce costs. The Multi-Material-Blades can further have a curved shape to form an involute blade body (1). All measures can improve the performance of active regenerative magneto-caloric or electro-caloric engines, and lay the basis for commercial solutions.
Claims
1. Multi-Material-Blade for use in an active regenerative magneto-caloric or electro-caloric engine, the blade comprising a blade body (1) made from a plurality of elements (2) made from different magneto-caloric or electro-caloric materials, wherein the blade body (1) is divided along its length into said plurality of elements (2); a plurality of dedicated channels (3), which penetrate the blade body (1) and extend along the length of the blade, wherein the cross-section of the blade-body (1) perpendicular to the dedicated channels (3) has along a predetermined direction a plurality of regions of different porosity, wherein at an interface of adjacent regions the porosity changes abruptly by at least 10%.
2. Multi-Material-Blade according to claim 1, wherein at the interface of the adjacent regions the porosity changes abruptly by at least 30%.
3. Multi-Material-Blade according to claim 1, wherein each of the plurality of elements (2) is formed by a plurality of plates (4) made of magneto-caloric materials, the plates (4) are stacked on top of each other and are separated from each other by porous layers (19), the plates (4) have a lower porosity and the porous layers (19) have a higher porosity, and the porous layers (19) form the dedicated channels (3).
4. Multi-Material-Blade according to claim 2, wherein the magneto-caloric materials of the plates (4) have a porosity of less than 10%.
5. Multi-Material-Blade according to claim 2, wherein the porous layers (19) have porosities in the range of 25% to 95%.
6. Multi-Material-Blade according to claim 2, wherein the porous layers (19) have pores of a size in the range of 1 m to 100 m.
7. Multi-Material-Blade according to claim 3, wherein each of the plurality of plates (4) is made from a magneto-caloric material preferably selected from the group of LaFeSi, LaFeSiCo, LaFeSiH, MnPFeAs, MnPFeSi, MnAsSb, MnPFeGe, Gd, GdDy, CoMnSi, CoMnGe, and GdSiGe, or electrocaloric material P(VDF-TrFE-chlorofluoroethylene), PLZT (8/65/35), Pb(Mg1/2Nb2/3)03-35PbTiO3 (PMN-35PT)), BaTiO3, or (NH41)2SO4, that may additionally be provided with one or more dopants, wherein each material has a different Curie temperature, and each material has a porosity of 10% or less in respect to its volume.
8. Multi-Material-Blade according to claim 7, wherein each of the plurality of elements (2) has a thermal conductivity in a range of 0.1 W/mK to 30 W/mk, preferably 0.1 W/mK to 10 W/mk, more preferably 0.1 W/mK to 5 W/mk, most preferably 0.1 W/mK to 2 W/mk.
9. Multi-Material-Blade according to claim 8, wherein said plurality of elements (2) are designed and arranged such that the Curie temperature of the materials trace a temperature gradient established along the blade body (1) in an active regenerative magneto-caloric engine.
10. Multi-Material-Blade according to claim 2, wherein at least one porous layers (19) is flexible and can adapt its size and shape like a sponge-like structure.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) In the following, the present invention will be described in more detail in reference to the attached drawings.
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DETAILED DESCRIPTION OF THE INVENTION
(22) As described above the Multi-Material-Blade according to the present invention comprises a blade body 1 that is made from a plurality of elements 2 made from different magneto-caloric or electro-caloric materials. The blade body is divided along its length into the plurality of elements 2. Through the blade body 1 run a plurality of dedicated channels 3, which extend along the whole length of the blade. The plurality of dedicated channels 3 penetrates the blade body 1, so that in an active regenerative magneto-caloric or electro-caloric engine an exchange fluid can pumped through the dedicated channels 3 from one end of the blade to the other. In the following, the present invention will present several examples and designs for a Multi-Material-Blade. The examples can be combined where feasible, in order to achieve combinative advantageous features. Some principles are valid for all examples, but are not repeated in the same detail again and again.
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(24) Each plate 4 is made of a magneto-caloric material, wherein the plates of one element 2 are preferably made of the same material. However, also a variation of materials for the plates 4 of an element 2 can be used. A preferred group of materials is LaFeSi, LaFeSiCo, LaFeSiH, MnPFeAs, MnPFeSi, MnAsSb, MnPFeGe, Gd, GdDy, CoMnSi, CoMnGe, and GdSiGe, which may contain various dopants or ratios of the stated elements. Each of the plurality of elements 2 comprises at least one different magneto-caloric material compared to the other elements, or comprises at least one material that differ in its Curie temperature Tc. A difference in Curie temperature can for example be achieved by different doping of the same material.
(25) Each plate 4 has a thickness of around 50 m to 1500 m, preferably 70 m to 700 m, more preferably 90 m to 400 m. The values depend slightly on the used magneto-caloric material. The plates 4 of each element 2 can all have the same size and shape, as shown in
(26) The plates 4 are shown in
(27) The plates 4 can be made by extrusion techniques, wherein magneto-caloric powders are bound together by some sort of binder to form a solid plate 4. Naturally the plates 4 can also be made of solid blocks of a single magneto-caloric material, or an alloy of magneto-caloric materials.
(28) In any case, the plates 4 are to have a thermal conductivity that is as low as possible in a range of in a range of 0.1 W/mK to 10 W/mk, preferably 0.1 W/mK to 5 W/mk, more preferably 0.1 W/mK to 2 W/mk. Then also each of the plurality of elements 2 will have a low thermal conductivity. In case the plates 4 are fabricated by extruded powders that are mixed with binders, the binders should have a thermal conductivity that is lower or equal to the magneto-caloric materials. Consequently materials like plastic are preferred over metals for the binding agent. The low thermal conductivity of the plates 4 and the plurality of elements 2, respectively, minimize losses in the active regenerative magneto-caloric engine that are caused by backflow of the heat through the Multi-Material-Blade. Note that separators between adjacent ones of the plurality of elements 2 will not reduce the backflow as a of the total cooling power. However, separators between adjacent ones of the plurality of elements 2 can be used for assembly purposes, and to reduce local temperature gradients between adjacent materials.
(29) The spacers 5, which define the dedicated channels 3 through the blade body 1, have a thickness of 5 to 100 m, preferably 10 m to 75 m, more preferably 15 to 60 m. The values are again dependant on the magneto-caloric material of the plates 4, and also on the exchange fluid that runs through the dedicated channels 3 in an active regenerative engine. Ideally, the spacers 5 are as small as possible, since a narrower channels 3 experience less HE loss. However, a compromise between HE loss and viscous and pressure losses has to be taken into account. The spacers are preferably made of a low thermal conductivity material, that lies in the above-given range for the magneto-caloric materials or lower.
(30) The plurality of elements 2 in
(31) In an active regenerative magneto-caloric engine, one end of the blade body 1 is the cold end and the other is the hot end. An exchange fluid will be passed through the dedicated channels 3 from the hot end to the cold end and from the cold end to the hot end, when a magnetic field is applied or taken away from the Multi-Material-Blade, as appropriate. After the exchange fluid has gone through several cycles of pumping, a temperature gradient is established from the cold end of the blade body 1 to the hot end thereof. The total temperature gradient depends on the design of the blade, in particular the selection and arrangement of the magneto-caloric materials.
(32) The plurality of elements 2 that form the blade body 1 are thus to be made of such magneto-caloric materials, and/or doped in such a manner, that they can be arranged along the blade body in a way that the Curie temperatures of the magneto-caloric materials in each of the elements 2 trace the temperature gradient that establishes across the whole length of the blade body 1. The temperature gradient is preferably linear, which requires an adaption of the Curie temperatures, the length, and temperature span of each of the plurality of elements. Each of the plurality of elements 2 is further to be arranged in a position, where it works as close to its Curie temperature as possible. The plurality of elements 2 can have different lengths or can have the same length, in direction of the dedicated channels 3. The Curie temperatures, the length and the temperature change T across each of the plurality of elements 2 should preferably be selected so that the cooling capacity is close to uniform, wherein uniform is understood to have a deviation of 30%, preferably 20%, more preferably 10% immediately between the elements located along the length of the blade body 1, i.e. at boundaries of two elements.
(33) Local temperature gradients can establish in the blade body 1, between elements, and generate entropy that disrupts the performance of any active regenerative magneto-caloric engine. The heat can then not be transferred optimally from the plurality of elements to the exchange fluid. To counter this effect spacers or separators between some or all of the plurality of elements 2 may be used for assembly reasons, and to reduce local temperature gradients that may arise between sub-blades possessing different T at the boundary between the two materials. The above arrangement of magneto-caloric materials (and also electro-caloric materials) is valid for all examples of a Multi-Material-Blade according to the present invention.
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(35) Alternatively, or in addition, to the surface texture 6, a hydrophobic coating layer can be printed or otherwise applied onto some or each of the plates 4. The hydrophobic coating layer can be on both or on one surface of the plates 4. The hydrophobic coating layer and the surface texture 6 can for example be on opposite surfaces of a plate 4. Optionally, a thin glass or plastic layer may be arranged beneath each hydrophobic coating layer. A hydrophobic coating layer can create a slip boundary condition between the surface of the plate 4, i.e. the surface of the dedicated channel 3 and the exchange fluid, when the blade is used in an active regenerative magneto-caloric engine. The slip boundary condition serves to reduce the HE loss.
(36) Another mixing structure that can be applied with a stacked plate 4 assembly is shown in
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(38) Many designs of regions of different porosity in the blade body 1 are possible. The blade body 1 can exhibit at least two regions of different porosity along its vertical or its horizontal direction, but can also have multiple regions of differing porosity, and even each region can have a different porosity. The cross-section of each of the plurality of elements 2 of the blade body does not necessarily have to be the same. Also the number of regions of higher and or lower porosity can differ from element 2 to element 2.
(39) The regions of different porosity can be designed such that they serve as a mixing structure 6, which reduces the HE loss in a refrigerant system. Additionally, the different porosities can be used to control the pressure in the Multi-material-Blade, and thus to control and reduce vicious losses. The porous layer 19 shown in figure has a preferred vertical width of 15 to 80 m, at maximum 125 m, depending on the porosity. The material the porous layer 19 can be, for example, collagen glycosaminoglycan scaffolds or spontex. Further, collagen foam, polytetrafluoroethylene or hydroxyapatite ceramic can be used. Porosities are preferably in a range of 25 to 95%. Pore sizes are preferably in a range of 1 m to 100 m. Hydroxyapatite ceramic exhibits micro-pores. The size of the micro-pores is preferably 0.1 to 10 m. At least one region of high porosity can be made flexible, for example as a sponge-like structure that can adapt its size and shape. The flatness requirements of the plates 4 can thus be reduced for assembling the plurality of stacked elements of the blade body 1.
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(41) When the perforated plates 7 are stacked together, as shown in
(42) Into each of the pipes 10 or into each of the holes 9, symmetry or flow breakers 13 can be inserted. As can be seen in
(43) Another possibility to provide a mixing structure that reduces the HE loss are rough walls 11 on the insides of some or of each of the holes 9 or the pipe inserts 10, respectively.
(44) An alternative for reducing HE loss is shown in
(45) The use of HE loss reduction techniques can either drive a more efficient system. Alternatively, for a given loss, larger channels or holes, which may be easier to manufacture, are allowed.
(46) The Multi-Material-Blades of the present invention can also have a plurality of elements 2 that are made of at least one electro-caloric element 15, which represents a fourth example of the present invention.
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(48) The electro-caloric element 15 or the multi-layer capacitor structure 16 can be used in the manner of the plates 4 in
(49) However, the electro-caloric element 15 or the multi-layer capacitor structure 16 can also have perforations or holes, and each form one of the plurality of elements 2 that establish dedicated channels along the blade body as in
(50) The electrodes 14 can be metal electrodes, and are preferably 5% or less than the thickness of the electro-caloric element 15.
(51) The electro-caloric Multi-Material-Blade has the same requirements to the choice of materials as the magneto-caloric Multi-material-Blades described above. A transition temperature, around which there is a change in entropy, should follow the temperature defined by the temperature gradient along the blade in an active regenerative electro-caloric engine. In principle, the T and S in electro-caloric materials is in principle much larger than in magneto-caloric materials. This is due to the fact that bigger electric fields can be applied than magnetic ones, especially in the multi-layer capacitor structures. The large T and S also exist over wider temperature ranges, which means that less materials are needed along the length of an AER. Nevertheless, the basic principles remain the same as for an AMR.
(52) As has been described in short above, the shapes of the Multi-Material-Blades have been described as being flat. However, curved shapes are advantageous when using the blades with a rotary system, i.e. when multiple blades have to be packed and assembled in a circle.
(53) Multiple elements (2) can be combined vertically (or radially), to create a multi-material-blade structure (1). In general all of the examples can use the advantageous features and enhancements of the other examples. The examples can also be combined with each other.
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(55) In
(56) In summary the present invention describes the design and fabrication of Multi-Material-Blades used as active regenerative regenerators in active regenerative magneto-caloric or electro-caloric engines. The blades consist of a plurality of elements 2 that divide the blade body along its length. Each element 2 is made of a different magneto-caloric or electro-caloric material, and a plurality of dedicated channels 3 penetrate the blade body 1 and extend along the length of the blade. The dedicated channels 3 can be provided with fluid mixing structures, porous layers or hydrophobic coatings to reduce the HE loss in an active regenerative engine. The Multi-Material-Blades are obtainable by ink jet (or equivalent) techniques with reduced costs. The Multi-Material-Blades can further have a curved shape to form an involute blade body 1. All measures can improve the performance of active regenerative magneto-caloric or electro-caloric engines, and lay the basis for commercial solutions.