Method for producing a foam body

Abstract

A method for producing a foam body for a pressure or hydraulic accumulator has a bubble- or diaphragm-shaped, elastically flexible separating layer (12) separating gas and liquid chambers from each other within an accumulator housing. The production method includes introducing a flowable, preferably liquid, foam material into the pressure accumulator with the foam material being at least partially surrounded by the separating layer (12), curing the foam material in the hydraulic accumulator, and building up a pressure gradient in which the visibly curing foam material expands the separating layer (12) from an originally partially filled starting state in the direction of an end state in which the accumulator is finally filled with the cured foam (38).

Claims

1. A method for producing a foam body in a pressure accumulator, the method comprising the steps of: providing a pressure accumulator with an elastically flexible separating layer separating a gas working chamber from a fluid chamber inside an accumulator housing of the pressure accumulator, the pressure accumulator comprising a valve in the fluid chamber movable between an open position and a closed position; introducing a flowable foam material in the gas working chamber of the pressure accumulator so as to be at least partially surrounded by the separating layer; hardening the flowable foam material in the gas working chamber of the pressure accumulator; and building up a pressure gradient as the flowable foam material increasingly hardens and expands the separating layer from an original, partially-filled starting state to a final state in which the pressure accumulator is finally and fully filled with the hardened foam and the separating layer, wherein the hardening of the flowable foam material in the gas working chamber of the pressure accumulator and the building-up of the pressure gradient occur while the gas working chamber is closed to an environment surrounding the pressure accumulator, and wherein the pressure gradient expands the separating layer until the separating layer moves the valve from the open position to the closed position.

2. A method according to claim 1 wherein the flowable foam material is introduced into the pressure accumulator as a fluid.

3. A method according to claim 1 wherein said separating layer is a bladder or diaphragm shaped.

4. A method according to claim 1 wherein the valve comprises a poppet valve.

5. A method according to claim 1 wherein the flowable foam material is sprayed or injected into the gas working chamber of the pressure accumulator by a lance-shaped input, the input having a first free end opening in the pressure accumulator and extending into the gas working chamber by penetrating a gas connection of the pressure accumulator, the input having a second free end outside of the pressure accumulator connected to an admixer.

6. A method according to claim 5 wherein individual components of the flowable foam material are supplied by a dynamically or statically functioning mixing head of the admixer via at least two supply lines connected to the mixing head, a corresponding mix ratio of the individual components being introduced into the gas working chamber of the pressure accumulator from the admixer via the input.

7. A method according to claim 6 wherein the individual components comprise a polyol, a foaming agent and a crosslinker.

8. A method according to claim 7 wherein the polyol is a polyether polyol.

9. A method according to claim 7 wherein the foaming agent comprises water.

10. A method according to claim 7 wherein the crosslinker comprises diglycolamine.

11. A method according to claim 7 wherein the individual components also comprise a catalyst, a flame retardant and a stabilizer.

12. A method according to claim 11 wherein the catalyst is an amine catalyst or a tin catalyst.

13. A method according to claim 11 wherein the stabilizer is a silicone compound.

14. A method according to claim 1 wherein the hardened foam in the gas working chamber of the pressure accumulator has open cells with a recovery capacity as a three dimensional structure of 97 to 98 percent.

15. A method according to claim 1 wherein the hardened foam in the gas working chamber of the pressure accumulator has a volumetric weight in a range of 50 g/dm.sup.3 to 150 g/dm.sup.3.

16. A method according to claim 1 wherein the hardened foam in the gas working chamber of the pressure accumulator has a heat capacity at 20 C. greater than 1 J/gK.

17. A method according to claim 1 wherein the flowable foam material has a flow resistance in a range from 1400 to 3800 Ns/m.sup.3.

18. A method according to claim 1 wherein the separating layer is a closed accumulator bladder with dry inert gas in the gas working chamber having a temperature stability in a range from 40 C. to 140 C.

19. A method according to claim 1 wherein cells in the hardened foam when finished hardening are in a range of 0.01 mm.sup.3 to 375 mm.sup.3.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) Referring to the drawings that form a part of this disclosure:

(2) FIGS. 1 to 3 show a pressure accumulator in the form of a hydraulic accumulator with an accumulator bladder in different foam filling and production states according to an exemplary embodiment of the invention.

DETAILED DESCRIPTION OF THE INVENTION

(3) The hydraulic accumulator 10 depicted in the figures is designed as a bladder accumulator. The elastically flexible, in particular deformable, accumulator bladder 12 separates two media chambers from each other within a pressure accumulator housing 14. In particular, a gas working chamber 16 is separated from a fluid chamber 18, which chambers, in the subsequent operating state of the accumulator 10, receive a working gas, in particular in the form of nitrogen gas, and hydraulic oil, respectively. The accumulator housing 14 is formed substantially in one piece, is bottle-shaped and preferably is made of a steel material or die-cast material. The accumulator housing 14 can also be formed by a wrapped plastic laminate that is not depicted in detail, which housing is referred to as a liner construction in technical parlance. The accumulator bladder 12 forms the bladder-shaped, elastically flexible separating layer of the accumulator 10 and is pieced together, in particular vulcanized together, from sub-segments in accordance with the depictions of FIGS. 1 and 2. The construction of the accumulator bladder 12 in sub-segments is in particular suitable when, viewed in the axial length of the hydraulic accumulator 10, the pressure accumulator housing 14 has a correspondingly large length.

(4) The accumulator housing 14 has on its opposite longitudinal end sides two openings 20, 22. The bottom opening 20 receives a conventional closing valve, such as a poppet valve 24. The top opening 22 is provided with a closing valve device 26 (cf. FIGS. 2 and 3), which serves for subsequent supply of the working gas and which, if necessary, permits top-up operations with the working gas. Otherwise, the closing valve device 26 usually remains closed during operation of the accumulator. If the poppet valve 24 is in an opened position, as depicted in FIGS. 1 and 2, the working fluid, commonly in the form of hydraulic oil, can reach the fluid chamber side 18 of the accumulator 10 and be stored there until the stored pressure quantity and/or filling quantity is in turn required in the hydraulic circuit (not depicted) to which the accumulator 10 can be connected. This operating method corresponds to standard accumulator operation, and accordingly it will not be addressed in further detail here. However, if the accumulator bladder 12 is in its fully elongated or expanded state, as depicted in FIG. 3, the accumulator bladder 12 presses by its bottom end with force-locking contact against the poppet valve 24 and closes the valve. An input pressure of the fluid medium is then required on the fluid side of the accumulator, which pressure is greater than the counter pressure in the accumulator bladder 12, in order to effect an opening operation for the poppet valve 24.

(5) In order to obtain an operational hydraulic accumulator 10, the hydraulic accumulator must be correspondingly filled with a foam material, as will be described in detail below. For the input of the flow-capable, in particular fluid foam material, an admixing device 30 is employed. Admixing device 30 contains a statically or dynamically functioning mixing head 32 that, in accordance with the exemplary embodiment of FIG. 1, has two supply lines 34 connected to the mixing head 32 and that is to be placed or extends from the outside onto the accumulator 10 to be filled. Furthermore, a lance-shaped input device 36 is connected to the mixing head 32 on the bottom side thereof, with the one free end of the input device 36 opening into the top half of the pressure accumulator 10 and being guided in the gas working chamber 16. The other end the input device 36 penetrates the top opening 22 of the accumulator housing 14, which top opening is provided for the subsequent receiving of the closing valve device 26. For the input of the foam material, in accordance with the depiction of FIG. 1, the input device 36 is provided with corresponding spray openings or nozzle openings (not depicted in detail) in the region of the bottom end of the lance of the input device 36 in order to obtain a consistent foam input into the inside of the accumulator.

(6) The foam components that can be supplied via the respective supply line 34 form, once they are brought together in the mixing head 32, a flow-capable mixture of polyols, isocyanate, catalysts, retarders, crosslinkers and stabilizers and, if appropriate, water. In particular, long-chain polyether polyols are used and the catalysts can be amine catalysts or tin catalysts. Diglycolamine is particularly preferably used as crosslinker material. However, amino compounds, butanediol and alcohols can also be used. As stabilizer input material, silicone compounds have proven to be successful. The foam material components can also be supplemented with commercially available flame retardants. The above-mentioned individual components can, having been be combined with one another in advance in an obvious manner, be fed to the mixing head 32 via the supply lines 34 for further input into the accumulator bladder 12. Preferably, the components are supplied to the mixing head 32 separately from one another in a consecutive sequence. The mixing head then initiates the mixing and the input via the input device 36.

(7) If the polymer polyol used for the foam has hardened, a polyurethane (PU) soft foam 38 is created, which is crosslinked by the additional material or the additional components in the form of the crosslinker diglycolamine. The particular polyol used substantially produces the elastic foam behavior and the high recovery capability of the introduced hardened foam 38. The preferably open-cell foam 38 has a recovery capability of 97% to 98%. The above-mentioned 3D structure of the foam 38 ensures an optimal heat transfer.

(8) As can be seen in particular from FIG. 2, the still fluid foam material 28 is collected in the bottom accumulator bladder end 40 with the input amount individually required for the respective accumulator type. The accumulator 10 is then closed in a pressure-tight manner via the closing valve device 26 at the top end. As a result of the introduced components of the foam material 28, the foam material 28 then hardens and thereby expands in volume up to the final state according to the depiction of FIG. 3, in which the poppet valve 24 is then closed. In particular, the build-up of a pressure gradient occurs during the hardening of the foam material 28 in the pressure accumulator 10. During that build-up of pressure, the increasingly hardening foam material 28 expands the separating layer in the form of the accumulator bladder 12 from the original partially filled starting state in accordance with the depiction of FIG. 2 towards the final state, in which the accumulator 10 is finally and fully filled with the hardened foam 38 with the poppet valve 24 being closed. Due to the recovery capability of the foam 38, in the case of an opening poppet valve 24, the foam can, by the fluid pressure of the hydraulic circuit (not depicted in detail) to which the accumulator 10 is connected, be forced back, in particular, compressed with regards to the open-porosity of the foam cells, so that the fluid chamber 18 in the hydraulic accumulator 10 can be filled with the oil medium until another retrieval occurs and it can then be stored there under pressure from the compressed foam material.

(9) The desired volumetric weight for the finished foam 38 ranges from 50 g/dm.sup.3 and 150 g/dm.sup.3. The heat capacity of the PU foam 38 should be 20 C.>1 J/gK, and should particularly preferably be a value between 1.4 J/gK and 1.9 J/gK, with the latter value corresponding to an operating temperature of approximately 120 C. If the introduced PU soft foam 38 has a flame retardant added to it, it is then also possible to increase the heat capacity, in particular if the flame retardant is introduced into the foam 38 as a solid. The flow resistance, which is considered to be a measure for the porosity of the foam 38, should preferably be within a value range from 1400 to 3800 Ns/m.sup.3. However, the elasticity of the foam 38 is in any case such that the foam 38 in the ready-for-use state of the accumulator 10 can be compressed by 40% of the maximum possible foam volume input. Higher values are possible. If a dry inert gas is inserted on the gas working chamber side 16, such as nitrogen, helium, argon, xenon, CF.sub.4 or SF.sub.6, for example, a temperature stability of between 40 C. and 140 C. is obtained in the case of a degree of crosslinking of the PU input material of >90% and when there are no volatile components.

(10) Because the foam 38 is surrounded by the accumulator bladder 12 and also has no contact with the inside wall of the accumulator housing 14 or with the respective sealing materials (TPU, NBR, IIR, ECO, FKM), which are standard in accumulator construction, there is also no corresponding chemical reaction with the sealing material, which contributes to the longevity of the accumulator construction. If damage results in destruction of the hardened foam material 38 in the operational state of the accumulator according to FIG. 3, the accumulator 10 itself does not become unuseable, instead there is merely a return to the behavior of a standard accumulator without foam input. In addition, the above-mentioned sealing system of the accumulator 10 manages with a reduced lubricating film on the gas side and thus conforms with dry-run properties. If, contrary to expectations, foam particles or foam cells pass through via the seal or the separating layer material to the fluid side 18 of the accumulator 10, this input of foreign materials into the fluid does not lead to damage of the hydraulic system, because the PU foam does not have any observable damaging effect in this regard.

(11) As another embodiment, which is not however depicted or described in detail, the possibility exists to apply the method according to the invention together with the foam input in pressure accumulators which are designed as diaphragm accumulators, of the kind presented in the prior art for example in FIGS. 1 and 2 of the already mentioned PCT publication WO 2013/056835 A1.

(12) With the hydraulic accumulator solution according to the invention and using the described production method, accumulators can be realized having increased storage capacity and with good temperature stability and pressure stability, which prove to be very functionally-reliable during operation and which can be produced with little labor outlay and expense. There is no equivalent of this solution in the prior art.

(13) While one embodiment has been chosen to illustrate the invention, it will be understood by those skilled in the art that various changes and modifications can be made therein without departing from the scope of the invention as defined in the claims.