Lubricant composition

Abstract

A lubricant composition includes a base oil and melamine cyanurate. The base oil includes a perfluoropolyether oil having a straight chain structure. The lubricant composition is for one of a resin-resin sliding section and a resin-metal sliding section. A melamine cyanurate content is within a range of 1-20% by mass with respect to a sum of the base oil and melamine cyanurate.

Claims

1. A method of lubricating sliding sections, the method comprising lubricating the sliding sections with a lubricant composition consisting of a base oil and melamine cyanurate, wherein the base oil comprises a perfluoropolyether oil having a straight chain structure, wherein the perfluoropolyether oil is represented by the following general formula (i):
F(CF.sub.2CF.sub.2CF.sub.2O).sub.nCF.sub.2CF.sub.3(i), wherein, in the above formula (i), n is an integer of 2 to 200, wherein the evaporation loss rate for the perfluoropolyether oil is less than or equal to 5% by mass at 200 C. for 100 hours, wherein the perfluoropolyether oil content is within a range of 80-97.5% by mass with respect to the sum of the perfluoropolyether oil and melamine cyanurate, wherein the melamine cyanurate content is within a range of 5-12% by mass with respect to the sum of the base oil and melamine cyanurate, wherein the average particle diameter of the melamine cyanurate is 0.1 to 50 m, and wherein the lubricated sliding sections are resin-resin sliding sections and wherein the resin is selected from the group consisting of polyethylene (PE), polypropylene (PP), ABS resin (ABS), polyacetal (POM), nylon (PA), polycarbonate (PC), phenol formaldehyde resin (PF), polyethylene terephthalate (PET), polybutylene terephthalate (PBT), polyphenylene sulfide (PPS), polyethersulfone (PES), polyimide (PI), polyether ether ketone (PEEK) or polytetrafluoroethylene (PTFE).

2. The method of claim 1, wherein the melamine cyanurate content is within a range of 5-11% by mass with respect to the sum of the base oil and melamine cyanurate.

3. The method of claim 1, wherein the lubricated sliding sections are one direction motion sliding sections.

4. The method of claim 2, wherein the lubricated sliding sections are one direction motion sliding sections.

Description

DESCRIPTION OF THE PREFERRED EMBODIMENTS

(1) A lubricant composition of the invention includes a base oil and melamine cyanurate, the base oil including a perfluoropolyether oil having a straight chain structure, the lubricant composition being for one of a resin-resin sliding section and a resin-metal sliding section, and a melamine cyanurate content is within a range of 1 to 20% by mass with respect to a sum of the base oil and melamine cyanurate. Hereinafter, each of the components of the lubricant composition of the invention will be described in detail.

(2) [Base Oil]

(3) According to the invention, the base oil includes a perfluoropolyether oil having a straight chain structure.

(4) The perfluoropolyether oil having a straight chain structure is not particularly limited, and, preferably, a commonly known perfluoropolyether oil may be used. According to the invention, a perfluoropolyether oil (PFPE) represented by the following formula can be used.
F(CF.sub.2CF.sub.2CF.sub.2O).sub.nCF.sub.2CF.sub.3(i),

(5) where, in formula (i), n is an integer between 2 and 200.

(6) The perfluoropolyether oil represented by general formula (i) can be obtained by, for example, anionically polymerizing 2,2,3,3-tetrafluorooxetane using a fluoride ion supplier such as cesium fluoride as a catalyst to obtain polyether containing a fluorinated acyl group and having (CH.sub.2CF.sub.2CF.sub.2O) as a constituent unit, and then performing a fluorine gas treatment on the obtained polyether while irradiating an ultraviolet ray at about 160-300 C. (see Y. Ohsaka, Petrotech, 8, 840 (1985), Y. Ohsaka, T. Tozuka and S. Takaki (Daikin), Eur. Pat: Appl. 148482 (1985)). The perfluoropolyether oil represented by formula (i) may be PFPE-D, which is available on market, and, more specifically, DEMNUM (manufactured by Daikin Industries, Ltd.).
Rf.sup.1O[CF.sub.2CF.sub.2O].sub.mRf.sup.2(ii),

(7) where, in formula (ii), m is an integer of 2 to 200, and Rf.sup.1 and Rf.sup.2, each independently, represent perfluoroalkyl groups having 1 to 5 carbon atoms.

(8) The perfluoropolyether oil represented by formula (ii) is manufactured by, for example, anionically polymerizing, under a low temperature, a tetrafluoroethylene oxide using a fluoride ion supplier such as cesium fluoride as a catalyst and then performing a fluorine gas treatment on the obtained acid fluoride compound having a terminal-CFXCOF group (see formulae (I) and (II) indicated below). (See, for example, W. H. Gumprecht, ASLE Trans., 924 (1966), J. T. Hill, J. Macromol. Sci. Chem., A8, 499 (1974)). Note that, the perfluoroalkyl group having 1 to 5 carbons may be a perfluoromethyl group, a perfluoroethyl group, a perfluoropropyl group, a perfluorobutyl or a perfluoropentyl group. Specifically, a perfluoromethyl group and a perfluoroethyl group are preferable.

(9) ##STR00001##

(10) where, in formula (iii), k and l are numbers that satisfy k+l=3 to 200, and Rf.sup.3 and Rf.sup.4, each independently, represent perfluoroalkyl groups having 1 to 5 carbons. Particularly, those with k:l=10:90 to 90:10 and randomly bonded are preferable.

(11) The perfluoropolyether oil represented by formula (iii) can be obtained by causing tetrafluoroethylene to be subjected to a catalyst treatment to react with oxygen using an ultraviolet ray, and then reducing the thus obtained polyperoxide, which is an intermediate, to obtain polyether having acid fluoride, and thereafter performing a fluorination treatment under ultraviolet irradiation (see reaction formula (III) below) (see, for example, D. Sianesi, A. Pasetti, C. Corti, Makromol. Chem, 86, 308 (1965)). Specifically, it is PFPE-Z, which is available on market, and more specifically, Fomblin M (manufactured by SolvaySolexis company). Note that, the perfluoroalkyl group having 1 to 5 carbons may be the groups similar to those described above.

(12) ##STR00002##

(13) In the present invention, the aforementioned perfluoropolyether oil may be used alone or used as a mixture of a plurality of types thereof, but from a heat resistance point of view, a perfluoropolyether oil with no repeat unit represented by (CF2O) is preferable, and a perfluoropolyether oil represented by general formula (i) is particularly preferable. The perfluoropolyether oil has an evaporation loss rate (200 C., 100 hours) of preferably less than or equal to 30% by mass, more preferably less than or equal to 10% by mass, and further preferably less than or equal to 5% by mass. When the evaporation loss rate is greater than 30% by mass, the perfluoropolyether oil may turn into gas and move outside the system, thus impairing a lubricating function. The perfluoropolyether oil has a kinematic viscosity (40 C.) within a range of normally 10-2000 mm.sup.2/s, and preferably 10-1500 mm.sup.2/s, but not limited thereto. In a case where the kinematic viscosity is less than 10 mm.sup.2/s, the perfluoropolyether oil easily vaporizes and thus easily disperses out of the system, and in a case where it is greater than 2,000 mm.sup.2/s, since the fluidity decreases, it becomes difficult to be self-supplied to the sliding section and a lubrication performance may become insufficient.

(14) The base oil as used herein may include an oily ingredient other than the perfluoropolyether oil, as long as an object of the invention is not impaired. The oily ingredients that can be used in combination may be at least one kind of composite oil selected from a synthetic hydrocarbon oil, an ester-based synthetic oil, an ether-based synthetic oil and a glycol-based synthetic oil.

(15) The synthetic hydrocarbon oil may be at least one kind selected from poly--olefin, an ethylene--olefine copolymer, polybutene, alkylbenzene, alkyl naphthalene, or the like.

(16) The ester-based synthetic oil may be, for example, a mixture of at least one kind or two kinds or more selected from esters such as diester, polyol esters, an aromatic ester, or the like.

(17) The ether-based synthetic oil may be at least one kind selected from alkyl diphenyl ether, or the like.

(18) The glycol-based synthetic oil may be at least one kind selected from polyethylene glycol, polypropylene glycol, or the like.

(19) When other oily ingredients as described above are used in combination, a perfluoropolyether oil content in the base oil is preferably greater than or equal to 80% by mass and more preferably greater than or equal to 90% by mass. In a case where the perfluoropolyether oil content in the base oil is less than 80% by mass, the heat resistance of the base oil may be degraded. Also, in a case where other oily ingredients as described above are used in combination, an evaporation loss rate (200 C., 100 hours) of the whole base oil is preferably less than or equal to 30% by mass, more preferably less than or equal to 10% by mass, and further preferably less than or equal to 5% by mass.

(20) [Melamine Cyanurate]

(21) Melamine cyanurate used herein is not particularly limited, and, a commonly known melamine cyanurate may be used. Specifically, those described in, for example, Japanese Patent Publication No. S45-5595, Japanese Patent Publication No. S61-34430, Japanese Laid-Open Patent Publication H5-310716, Japanese Laid-Open Patent Publication H07-224049, etc., can be preferably used. Products available on market include, for example, MCA-1 (manufactured by Mitsubishi Chemical Corporation) and MC600, MC860, MC4000, MC6000 (each manufactured by Nissan Chemical Industries, Ltd.).

(22) Although an average particle diameter of melamine cyanurate is not particularly limited, it is preferably 0.1 to 50 m and more preferably 1 to 15 m. The term average particle diameter used herein is defined as a median diameter (50% particle diameter) of a volume-based particle size distribution obtained by a particle size distribution measuring apparatus which uses a laser diffraction scattering method as a principle of measurement. Out of this range, a lubrication performance (an effect of reducing a dynamic friction coefficient) may decrease.

(23) The melamine cyanurate content with respect to the total with the base oil is preferably 1-20% by mass, more preferably 2.5-15% by mass, and particularly preferably 5-12% by mass. In a case where melamine cyanurate is less than 1% by mass, a thickening effect on the base oil may not be sufficient and the base oil may flow out of the sliding system. In a case where it is greater than 20% by mass, the friction coefficient may increase.

(24) [Other Component]

(25) A solid lubricant other than melamine cyanurate, an antioxidant, an extreme pressure agent, an anti-rust agent, an anti-corrosion agent, a viscosity index improver, an oiliness agent, etc., may be appropriately selected and added to the grease composition of the present invention, as long as an advantage of the invention is not impaired.

(26) The solid lubricant other than melamine cyanurate may be, for example, other solid lubricants such as polytetrafluoroethylene (PTFE), sodium sebacate, carbon black, graphite, molybdenum disulfide, organo-molybdenum, graphite, boron nitride, nitride silane, or the like. However, among the above solid lubricants, for example, it is not preferable to use sodium sebacate, carbon black, or the like, which may cause an increase in the friction coefficient.

(27) The antioxidant may be, for example, a phenolic antioxidant such as 2,6-di-t-butyl-4-methyl phenol and 4,4-methylene bis(2,6-di-t-butyl phenol) and an amine-based antioxidant such as alkyl diphenylamine (the alkyl group has a number of carbons 4 to 20), triphenyl amine, phenyl--naphthylamine, phenothiazine, alkylating phenyl--naphthylamine, phenothiazine and alkylated phenothiazine.

(28) The extreme pressure agent may be, for example, a phosphorus compound such as phosphate esther, phosphite and amine phosphate esther, a sulfur compound such as sulfides and disulfides, a chlorine compound such as chlorinated paraffin and chlorinated diphenyl, and a metal organic compound such as dialkyl dithiophosphoric acid zinc (ZnDTP) and dialkyl dithiocarbamic acid molybdenum (MoDTP).

(29) The anti-rust agent may be, for example, fatty acid, fatty acid soap, alkyl sulfonate, fatty acid amine, oxidized paraffin, polyoxyethylene alkyl ether, or the like.

(30) The anti-corrosion agent may be, for example, benzotriazole, benzimidazole, thiadiazole or the like.

(31) The viscosity index improver may be a polymethacrylate, an ethylene-propylene copolymer, polyisobutylene, polyalkyl styrene, a styrene-isoprene copolymer hydride, or the like.

(32) The oiliness agent may be, for example, fatty acid, higher alcohol, polyhydric alcohol, polyhydric alcohol ester, aliphatic ester, aliphatic amine, fatty acid monoglyceride, or the like.

(33) Note that, each of the aforementioned additives may be used alone or in any combination of two or more of them. Further, these components are preferably within a range of 0-100 parts by mass, and further preferably, 0-50 parts by mass with respect to a total amount of the base oil and melamine cyanurate, which is 100 parts by mass. When a blending amount of the additives exceeds 100 parts by mass, a lowering effect of a dynamic friction coefficient may decrease.

(34) The lubricant composition of the invention can be prepared by mixing the aforementioned base oil, melamine cyanurate and other components, if applicable, using a normal mixing means. The mixing means may preferably be a three roll mill or a high-pressure homogenizer, but it is not particularly limited thereto.

(35) The lubricant composition of the invention has an improved lubrication property for the sliding between resin members (resin-resin) the sliding between a resin member and a metal member (resin-metal). Note that, in the present invention, resin includes rubber.

(36) Other than rubber, the resin for which the lubricant composition of the invention can be applied may be polyethylene (PE), polypropylene (PP), an ABS resin (ABS), polyacetal (POM), nylon (PA), polycarbonate (PC), a phenol formaldehyde resin (PF), polyethylene terephthalate (PET), polybutylene terephthalate (PBT), polyphenylene sulfide (PPS), polyethersulfone (PES), polyimide (PI) and polyether ether ketone (PEEK), but it is not particularly limited thereto.

(37) Rubber may be a nitrile rubber (NBR), a hydrogenated nitrile rubber (HNBR), an acrylic rubber (ACM), a styrene-butadiene rubber (SBR), a silicone rubber (VMQ), a fluorine rubber (FKM), an ethylene propylene rubber (EPDM), a chloropropylene rubber (CR), an urethane rubber (U), a butadiene rubber (BR), a butyl rubber (IIR), an isoprene rubber (IR), but it is not limited there to. The metal may be iron, aluminum and copper, but not limited thereto.

Examples

(38) Hereinafter, the invention will be described in a more detailed manner with reference to examples representative of the invention which may be embodied in various forms. Thus, specific compositional, structural, functional, and procedural details disclosed in the following examples are not to be interpreted as limiting. It is to be noted that, in the examples below, compositions are represented in % by mass with respect to the total composition.

(39) (1) Preparation of Lubricant Composition

(40) Lubricant compositions having compositions indicated in Tables 1 to 5 were prepared respectively by combining a solid lubricant with a perfluoropolyether oil and sufficiently kneading using a three roll mill or a high-pressure homogenizer.

(41) (Remarks)

(42) F(CF.sub.2CF.sub.2CF.sub.2O).sub.2-100C.sub.2F.sub.5: manufactured by Daikin Industries, Ltd., DEMNUM S200, 40 C. kinematic viscosity: 200 mm.sup.2/s, Evaporation loss rate (200 C., 100 hours): 0.4% by mass

(43) RfO [CF(CF.sub.3)CF.sub.2O].sub.mRf: manufactured by NOK Klueber Co., Ltd., BARRIERTA J400, 40 C. kinematic viscosity: 400 mm.sup.2/s, Evaporation loss rate (200 C., 100 hours): 2% by mass

(44) MCA (melamine cyanurate) 1: manufactured by Nissan Chemical Industries, Ltd., MC6000, Average particle diameter D.sub.50: Approx. 2 m, D.sub.90: Approx. 9 m

(45) MCA2: manufactured by Nissan Chemical Industries, Ltd., MC4000, Average particle diameter D.sub.50: 13 m, D.sub.90: 30 m

(46) Sodium sebacate: manufactured by Hokoku Corporation, SA-NA

(47) Graphite: manufactured by Nihon Graphite Industries, ltd., CB150, Average particle diameter 4 m

(48) PTFE (polytetrafluoroethylene): manufactured by Daikin Industries, Ltd., LUBRON L2

(49) (2) Testing Method for Lubricant Composition (Friction Coefficient)

(50) A friction coefficient is defined as an average value of dynamic friction coefficients measured using a PIN on DISK testing machine under the following conditions for 30 minutes. The lubricant composition was tested by applying 5 mg of lubricant composition to an upper specimen (cylinder type specimen).

(51) Upper Specimen:

(52) cylinder type ( 1010 mm)

(53) iron: S45C

(54) polyacetal (POM): resin rod manufactured by MISUMI Corporation

(55) polytetrafluoroethylene (PTFE): resin rod manufactured by MISUMI Corporation

(56) Lower Specimen: Plate Type

(57) iron: S45C

(58) polyimide (PI): manufactured by Toray DUPONT, Kapton 100H

(59) Test Condition

(60) temperature: 130 C.

(61) Load: 600 gf

(62) Sliding velocity: 360 mm.sup.2/s

(63) Test time: 30 minutes

(64) (3) Test Result

(65) Table 1 shows a result of measurement of a dynamic friction coefficient for the sliding between iron (S45C) and iron (S45C), Tables 2 and 3 show results of measurement of a dynamic friction coefficient for the sliding between polyacetal (POM) and polyimide (PI), and Tables 4 and 5 show results of measurement of a dynamic friction coefficient for the sliding between polytetrafluoroethylene (PTFE) and polyimide (PI).

(66) As can be seen from Table 1, when a lubricant composition was used for the sliding between metals, there was no significant change in a value of the friction coefficient irrespective of an increase or a decrease in a solid lubricant content.

(67) On the other hand, as can be seen from Tables 2 to 5, the lubricant composition of the invention has an improved lubrication property since the friction coefficients for the sliding between polyacetal (POM) and polyimide (PI) and the sliding between polytetrafluoroethylene (PTFE) and polyimide (PI) are 0.026-0.032 and 0.113-0.121, respectively. Also, it can be seen that the compound in which melamine cyanurate is 5-15% by mass of the total weight of melamine cyanurate and the base oil has a particularly improved lubrication property.

(68) By comparing Example 4 with Comparative Example 8, it can be seen that the lubricant composition of the invention has a more improved lubrication performance than the lubricant composition containing a perfluoropolyether base oil (base oil 2) having a branched chain structure.

(69) TABLE-US-00001 TABLE 1 PIN ON DISK TEST RESULT: SLIDING BETWEEN IRON (S45C) AND IRON (S45C) No. COMPARATIVE COMPARATIVE COMPARATIVE EXAMPLE 1 EXAMPLE 2 EXAMPLE 3 BASE OIL 1 F(CF.sub.2CF.sub.2CF.sub.2O).sub.nC.sub.2F.sub.5 95 90 85 SOLID MCA1 5 10 15 LUBRICANT FRICTION 0.13 0.13 0.14 COEFFICIENT

(70) TABLE-US-00002 TABLE 2 PIN ON DISK TEST RESULT: SLIDING BETWEEN POLYACETAL (POM) AND POLYIMIDE (PI) No. EXAM- EXAM- EXAM- EXAM- EXAM- EXAM- EXAM- EXAM- EXAM- EXAM- EXAM- PLE PLE PLE 1 PLE 2 PLE 3 PLE 4 PLE 5 PLE 6 PLE 7 PLE 8 PLE 9 10 11 BASE OIL 1 F(CF.sub.2CF.sub.2CF.sub.2O).sub.nC.sub.2F.sub.5 97.5 95 92.5 90 89 88 85 81 80 95 90 BASE OIL 2 RfO(CF(CF.sub.3)CF.sub.2O)mRf SOLID MCA 1 2.5 5 7.5 10 11 12 15 19 20 LUBRICANT MCA2 5 10 SODIUM SEBACATE GRAPHITE PTFE FRICTION COEFFICIENT 0.026 0.024 0.022 0.021 0.023 0.024 0.030 0.031 0.032 0.025 0.023

(71) TABLE-US-00003 TABLE 3 PIN ON DISK TEST RESULT: SLIDING BETWEEN POLYACETAL (POM) AND POLYIMIDE (PI) No. COMPARATIVE COMPARATIVE COMPARATIVE COMPARATIVE COMPARATIVE COMPARATIVE EXAMPLE 4 EXAMPLE 5 EXAMPLE 6 EXAMPLE 7 EXAMPLE 8 EXAMPLE 9 BASE F(CF.sub.2CF.sub.2CF.sub.2O).sub.nC.sub.2F.sub.5 75 70 95 95 89 OIL 1 BASE RfO(CF(CF.sub.3)CF.sub.2O)mRf 90 OIL 2 SOLID MCA 1 25 30 10 LUBRI- SODIUM SEBACATE 5 CANT GRAPHITE 5 PTFE 11 FRICTION COEFFICIENT 0.034 0.035 0.041 0.045 0.040 0.031

(72) TABLE-US-00004 TABLE 4 PIN ON DISK TEST RESULT: SLIDING BETWEEN POLYTETRAFLUOROETHYLENE (PTFE) AND POLYIMIDE (PI) No. EXAM- EXAM- EXAM- EXAM- EXAM- EXAM- EXAM- EXAM- EXAM- PLE 12 PLE 13 PLE 14 PLE 15 PLE 16 PLE 17 PLE 18 PLE 19 PLE 20 BASE OIL 1 F(CF.sub.2CF.sub.2CF.sub.2O).sub.nC.sub.2F.sub.5 97.5 95 92.5 90 89 88 85 81 80 BASE OIL 2 RfO(CF(CF.sub.3)CF.sub.2O)mRf SOLID MCA 1 2.5 5 7.5 10 11 12 15 19 20 LUBRICANT SODIUM SEBACATE GRAPHITE PTFE FRICTION COEFFICIENT 0.113 0.110 0.088 0.102 0.112 0.115 0.119 0.120 0.121

(73) TABLE-US-00005 TABLE 5 PIN ON DISK TEST RESULT: SLIDING BETWEEN POLYTETRAFLUOROETHYLENE (PTFE) AND POLYIMIDE (P1) No. COMPARATIVE COMPARATIVE COMPARATIVE COMPARATIVE COMPARATIVE COMPARATIVE EXAMPLE 10 EXAMPLE 11 EXAMPLE 12 EXAMPLE 13 EXAMPLE 14 EXAMPLE 15 BASE F(CF.sub.2CF.sub.2CF.sub.2O).sub.nC.sub.2F.sub.5 75 70 95 95 89 OIL 1 BASE RfO(CF(CF.sub.3)CF.sub.2O)mRf 90 OIL 2 SOLID MCA 1 25 30 10 LUBRI- SODIUM SEBACATE 5 CANT GRAPHITE 5 PTFE 11 FRICTION COEFFICIENT 0.130 0.140 0.150 0.160 0.152 0.122

INDUSTRIAL APPLICABILITY

(74) The lubricant composition of the invention provides an improved lubrication property for the sliding between resin members (resin-resin) or the sliding between a resin member and a metal member (resin-metal), and finds applicability in various fields.

(75) For example, the lubricant composition of the invention can be preferably used for the lubrication or protection of sliding sections or contact sections between solid bodies such as rolling bearings, plain bearings, sintered bearings, gears, valves, cocks, oil seals, parts for office appliances such as copying machines and printers, fuser rolls, fuser belt parts, running system parts, braking system parts such as ABSs, steering system parts, drive system parts such as transmissions, auxiliary parts for automobiles such as power window motors, power seat motors and sunroof motors, and electric contacts. More specifically, the lubricant composition is applicable to parts described below.

(76) For automobiles, the parts may be rolling bearings and plain bearings of electric radiator fan motors, fan couplings, electronically controlled EGRs, electronically controlled throttle valves, alternators, idler pulleys, electric brakes, hub units, water pumps, power windows, windshield wipers and electric power steering systems that require heat resistance and shear stability. Further, the parts may be electric contact portions of control switches for gear portion automatic transmission, lever control switches, push switches or the like that require heat resistance, shear stability and wear resistance. Further, the lubricant composition may be used for rubber sealing parts that require heat resistance and shear stability such as X ring portions of viscous couplings and O rings of exhaust brakes, and rolling bearings, plain bearings, gears or sliding portion of headlights, seats, ABSs, door locks, door hinges, clutch boosters, two part fly wheels, window regulators, ball joints, clutch boosters and the like.

(77) For office appliances, the parts may be rolling bearings, plain bearings, resin films, resin sliding portions or gear portions that require heat resistance and wear resistance of fuser rolls, fuser belts and the like of copying machines, laser beam printers and the like.

(78) For home electric appliances and information equipment, the parts may be rolling bearings, plain bearings, oil seals and the like of cooling fans of PCs, vacuum cleaners and washing machines.

(79) For resin manufacturing apparatuses, the parts may be rolling bearings, plain bearings, chains, pins, oil seals, gears and the like of film tenters, film laminators and banbury mixer that require heat resistance and load resistance.

(80) For paper manufacturing apparatuses, the parts may be rolling bearings, plain bearings, pins, oil seals, gears and the like in corrugate machines or the like that require heat resistance and wear resistance.

(81) For a timber processing apparatuses, the parts may be rolling bearings, plain bearings, pins, oil seals, gears and the like in continuous presses or the like that require heat resistance and wear resistance.

(82) For apparatuses for food products, the parts may be rolling bearings or the like of linear guides of bread-baking machines, ovens and the like that require heat resistance and wear resistance.

(83) In addition, the lubricant composition may be used for rolling bearings and plain bearings that require a low friction coefficient and sliding portions of hinges of mobile telephones that require shear stability and wear resistance. Further, it can also be used for rolling bearings and gears in vacuum pumps of semiconductor manufacturing apparatuses, liquid crystal manufacturing apparatuses and electron microscopes, and rolling bearings of electronically controlled crossing gates.