METHOD OF FORMING A SEAL, METHOD OF MANUFACTURING A SEALED UNIT, A SEALED UNIT, AND APPARATUS FOR FORMING A SEAL
20200122269 ยท 2020-04-23
Assignee
Inventors
Cpc classification
H10K50/8426
ELECTRICITY
Y02P70/50
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y02E10/549
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
International classification
Abstract
Methods and apparatus for forming a seal are disclosed. In one arrangement, a first panel and a second panel are provided. A sealer material is present between the first panel and the second panel. The sealer material is in contact with the first panel and the second panel along all of a seal path. A first heating process is performed to heat metal particles derived from the sealer material along the seal path to cause fusing of the metal particles along the seal path. A second heating process is performed, separately from the first heating process, to provide a continuous weld along the seal path between the fused metal particles and the first panel and between the fused metal particles and the second panel, thereby generating a seal along the seal path.
Claims
1. A method of forming a seal, the method comprising: providing a first panel and a second panel, wherein a sealer material is present between the first panel and the second panel, the sealer material is in contact with the first panel and the second panel along all of a seal path, performing a first heating process to heat metal particles derived from the sealer material along the seal path, while the sealer material is in contact with the first panel and the second panel along all of the seal path, to cause fusing of the metal particles along the seal path; and performing a second heating process, separate from the first heating process, to provide a continuous weld along the seal path between the fused metal particles and the first panel and between the fused metal particles and the second panel, thereby generating a seal along the seal path, wherein: the second heating process is performed using a laser.
2. The method of claim 1, wherein the fusing of the metal particles by the first heating process along the seal path is such that a largest gap between the fused metal particles and the first panel or the second panel along the seal path has a largest dimension that is smaller than 5 microns.
3. The method of claim 1, wherein the second heating process is performed using a laser configured to provide pulses having a pulse length of less than 50 ps.
4. The method of claim 1, wherein the providing of the first panel and the second panel comprises the following steps in order: depositing the sealer material on the first panel; heating the sealer material to remove a portion of the sealer material, thereby increasing the stiffness of the sealer material; and moving either or both of the first panel and the second panel so that the first panel and the second panel are brought into a facing configuration in which the sealer material is in contact with the first panel and the second panel along all of the seal path.
5. The method of claim 4, wherein the stiffness of the sealer material after said heating of the sealer material is such that a height of the sealer material can be reduced by at least 5% during the moving of either or both of the first panel and the second panel to bring the first panel and the second panel into the facing configuration, thereby to compensate for one or more of: irregularities in the first panel, irregularities in the second panel, and misalignment of the first panel relative to the second panel.
6. The method of claim 1, wherein the seal path at least partially encircles a region between the first panel and the second panel.
7. The method of claim 6, wherein the seal path comprises at least 95% of a closed loop.
8. The method of claim 6 or 7, wherein the continuous weld is provided along plural parallel lines along the seal path.
9. The method of claim 1, wherein the metal particles comprise one or more of the following: silver, gold, nickel, aluminium, copper.
10. The method of claim 1, wherein the metal particles comprise metal microparticles or metal nanoparticles.
11. The method of claim 1, wherein the sealer material comprises the metal particles held in a matrix.
12. The method of claim 11, wherein the matrix comprises a liquid or paste.
13. The method of claim 1, further comprising changing a pressure or composition of gas within a region at least partially encircled by the seal path and, subsequently, sealing said region.
14. The method of claim 1, wherein either or both of the first panel and the second panel are transparent to radiation in the visible spectrum.
15. The method of claim 1, wherein either or both of the first panel comprises a transparent glass material, preferably a silicate glass, more preferably a soda-lime glass.
16. A method of manufacturing a sealed unit comprising a first panel and a second panel, the method comprising forming a seal between the first panel and the second panel using the method of claim 1.
17. A sealed unit manufactured using the method of claim 16.
18. An apparatus for forming a seal, comprising: a deposition unit configured to deposit a sealer material along a seal path on a first panel; a panel handler configured to move either or both of the first panel and the second panel so that the first panel and second panel are brought into a facing configuration in which the sealer material is in contact with the first panel and the second panel along all of a seal path; a first heating unit configured to heat metal particles derived from the sealer material along the seal path, while the sealer material is in contact with the first panel and the second panel along all of the seal path, to cause fusing of the metal particles along the seal path; and a second heating unit configured to provide a continuous weld along the seal path between the fused metal particles and the first panel and between the fused metal particles and the second panel, thereby generating a seal along the seal path, wherein the second heating unit comprises a laser configured to provide the continuous weld.
19. (canceled)
20. The apparatus of claim 18, further comprising: a third heating unit configured to remove by heating a portion of the sealer material, thereby increasing the stiffness of the sealer material, wherein: the panel handler is configured to move either or both of the first panel and the second panel into the facing configuration after the stiffness of the sealer material has been increased by the third heating unit.
21. The apparatus of claim 18, wherein the seal path at least partially encircles a region between the first panel and a second panel, and the apparatus further comprising a gas control and sealing device configured to change a pressure or composition of gas within the region at least partially encircled by the seal path and, subsequently, seal said region.
22. (canceled)
Description
[0012] The invention will now be further described, by way of example, with reference to the accompanying drawings, in which:
[0013]
[0014]
[0015]
[0016]
[0017]
[0018]
[0019]
[0020]
[0021]
[0022] Embodiments relate to forming a seal between a first panel 1 and a second panel 2. The seal may be used to manufacture a sealed unit 5. The sealed unit may form part of a vacuum insulation glass assembly, an OLED display device, OLED lighting, a smart window, or a perovskite and organics based photovoltaic system, for example.
[0023] An example sealed unit 5 is depicted schematically in
[0024] The sealer material 4 is deposited along a seal path. The first panel, second panel and sealer material are configured such that the sealer material 4 is in contact with the first panel 1 and the second panel 2 along all of the seal path. Furthermore, as will be described in further detail below, the sealer material 4 is laser welded to the panels so that a seal is formed between the sealer material 4 and the first panel 1 and between the sealer material 4 and the second panel 2 along all of the seal path.
[0025] In various embodiments the seal path at least partially encircles the region 6 between the first panel 1 and the second panel 2. The seal path may for example comprise at least 95% of a closed loop 24, optionally at least 99%. An example of such a seal path is shown in
[0026] Typically the first panel 1 and the second panel 2 will have substantially complementary shapes (i.e. so that if the respective surfaces were perfectly formed and oriented they could be made to be perfectly parallel to each other). In an embodiment, the first panel 1 and the second panel 2 are both substantially planar. In another embodiment, the first panel 1 and the second panel 2 are curved with a constant radius of curvature common to both panels. Either or both of the first panel 1 and the second panel 2 may be transparent to radiation in the visible spectrum. Additionally, at least one of the first panel 1 and the second panel 2 should be sufficiently transparent to the radiation used to perform the laser welding (second heating processsee below).
[0027] Either or both of the first panel 1 and the second panel 2 may comprise a transparent glass material, such as a silicate glass. For cost and convenience the silicate glass preferably comprises a soda-lime glass. Soda-lime glass is well known in the art and may for example be composed approximately of 75% silicon dioxide (SiO.sub.2), sodium oxide (Na.sub.2O) from sodium carbonate (Na.sub.2CO.sub.3), calcium oxide, also called lime (CaO), and several minor additives. Soda-lime glass is susceptible to breakage when exposed to large variations in temperature and temperature gradients. The extremely localised nature of heating required to perform the methods disclosed herein avoid such problems and allow soda-lime glass to be used with high reliability and yield. Other transparent glass materials could be used, however, including for example materials with coefficients of thermal expansion lower than soda-lime glass, such as borosilicate glass, fused silica, etc.
[0028] The first panel 1 and the second panel 2 have respective surfaces (e.g. the upper surface of the first panel 1 and the lower surface of the second panel 2 in the figures) that face into a region 6 between the first panel 1 and the second panel 2 that is to be sealed at a later stage. The separation between the respective surfaces may be nominally constant within the region 6.
[0029] The seal provided along the seal path forms part of the seal around the region 6 when it is eventually sealed completely. The final seal may be made after a desired gas or vacuum state is established within the region 6. Thus, a method step prior to final sealing may comprise changing a pressure or composition of gas within the region 6. This may be achieved by connection of a suitable vacuum pump or gas source to a port leading into the region 6. The port may access the region 6 from the side (e.g. through a gap such as gap 26 in
[0030] Methods and apparatus for forming a seal and manufacturing a sealed unit 5 will now be described with reference to
[0031]
[0032] In an embodiment the sealer material 4 comprises metal particles held in a matrix. The nature of the matrix and the metal particles is not particularly limited as long as they can perform their respective roles to form the seal between the first panel 1 and the second panel 2, as described below. In an embodiment the matrix is non-metallic. At the point of being deposited, the sealer material 4 needs to have relatively low viscosity, so that it can be deposited efficiently. Later on, as will be described in further detail below, the sealer material 4 will need to provide various other functions, such as allowing the first panel 1 and the second panel 2 to be brought into contact with the sealer material 4 in such a way that there is a continuous contact with the sealer material and both panels along all of a seal path, allowing fusing (sintering) of the metal particles together and, subsequently, allowing a seal to be formed by welding of the fused metal particles to the first and second panels 1, 2.
[0033] In an embodiment, the metal particles comprise one or more of the following: silver, gold, nickel, aluminium and/or copper. Preferably the metal particles comprise silver and/or copper. The metal particles may comprise metal microparticles and/or metal nanoparticles. The matrix may be a liquid or paste. The matrix may comprise an organic carrier or a combination of organic carriers, for example, the matrix may comprise ethanol and/or ethylene glycol. In an embodiment, the matrix comprises one or more of the following: epoxies, acrylics and polyurethanes.
[0034] In a subsequent step, as depicted in
[0035] Increasing the stiffness of the sealer material 4 desirably increases a resistance to deformation of the sealer material 4 during a subsequent step, depicted schematically in
[0036] As depicted in
[0037] In an embodiment, the heating unit 21 comprises a laser, for example a diode-pumped solid state laser, a fibre laser, a laser diode, or a CO.sub.2 laser. The laser may be configured to provide a continuous wave (CW) laser beam, or a quasi-continuous wave (quasi-CW) laser beam. Alternatively, the laser may be configured to provide a pulsed laser beam. The laser preferably provides a laser beam with a wavelength of in the range of approximately 500 nm to 11000 nm. The heating unit 21 may be moveably mounted and/or beam scanning optics may be provided in order for a laser spot from the heating unit 21 to be moved along all of the seal path. The heating unit 21 could alternatively comprise an IR lamp, a microwave source, or an ultrasound source.
[0038] As depicted in
[0039] Laser welding of glass to metal has recently been demonstrated in a general context. The laser welding can be performed using a laser configured to provide a pulse length of less than 50 ps, optionally less than 15 ps, optionally less than 1 ps, optionally less than 500 fs. The laser preferably provides a laser beam with a wavelength of approximately 500 nm to 1100 nm. Repetition rates may typically be in the range of 100 kHz to 2 MHz. Relatively high repetition rates are desirable to allow thermal accumulation between successive pulses. Each pulse needs to arrive before the thermal energy from a preceding pulse has dissipated, which typically takes of the order of a microsecond. Furthermore, since the required relative geometrical displacement between successive spots is likely to be fixed, increasing the repetition rate allows the processing to progress more quickly along the welding line, thereby improving throughput. The heating unit 22 may comprise a first heating unit sub-unit 22a configured to provide welding at an interface between the sealer material 4 and the first panel 1 and a second heating unit sub-unit 22b configured to provide welding at an interface between the sealer material 4 and the second panel 2. Thus, the welding may be achieved by directing a laser onto the sealer material 4 from both sides. The heating unit 22 (including, if provided, the first heating unit sub-unit 22a and the second heating unit sub-unit 22b) may be moveably mounted and/or beam scanning optics may be provided in order for a laser spot or laser spots from the heating unit 22 to be moved along all of the seal path.
[0040] The amount of energy deposited into the sealer material 4 using such laser parameters is extremely small, typically an order of magnitude smaller for example than the energy required to perform the fusing of the metal particles in the preceding step (performed by the heating unit 21). Pulse energy, repetition rate, laser spot size and the relative speed of movement (spot speed) between the laser spot and the interface to be welded are selected/controlled to optimise the welding process. The pulse repetition rate and spot speed are such that laser spots associated with individual pulses overlap along the seal path.
[0041] Detailed techniques are described for example in the following two publications: 1) Zhang et al., APPLIED OPTICS Vol. 54, No. 30 8957-8961 (20 Oct. 2015); and 2) Carter et al., APPLIED OPTICS Vol. 53, No. 19 4233-4238 (1 Jul. 2014). Zhang et al. teaches for example that an 800 nm Ti:sapphire chirped pulse amplification femtosecond laser system with a repetition rate of 1 kHz and a pulse duration of 160 fs, focused to a spot of diameter 8 microns, can be used. Pulse energies in the range of 1-35 microJoules were used, with a relative speed of movement of the spot of 30-800 microns per second. Carter et al. used a 1030 nm laser with 7.12 ps pulses and a repetition rate of 400 kHz. Laser power was 1.79 W with a spot size of 1.2 microns and a spot speed of 1 mm per second.
[0042] The techniques disclosed in Zhang et al. and Carter et al. are applied to solid metals rather than to metals formed from a sealer material 4 that has been processed to fuse metal particles together. It is difficult to perform the laser welding over large distances where a solid metal is used because it is difficult to ensure that the solid metal is in continuous contact with the glass surface over all of the line to be welded. Any gaps that do exist need to be small enough that both interfaces are still within the focal depth of the laser and are small enough to contain any plasma. If the plasma escapes, ablation rather than welding will occur, which will disrupt the seal and damage the glass and/or metal. One approach to addressing this problem has been to clamp the metal and the glass together, but this can introduce undesirable stresses into the glass and/or be inconvenient. The inventors have recognised that these challenges can be overcome by providing a sealer material 4 comprising metal particles instead of a solid metal, and processing the sealer material 4 after the sealer material 4 has been sandwiched by the first and second panels 1, 2, to fuse the metal particles together ready to form the welding. A continuous contact between the fused metal particles and the surfaces of the first and second panels 1, 2 against which the welding is to be performed can be achieved reliably over large distances without requiring large clamping forces.
[0043] The effectiveness of the welding process is illustrated in the surface profiles shown in
[0044] Additional embodiments are disclosed in the following numbered clauses.
1. A method of forming a seal, the method comprising:
[0045] providing a first panel and a second panel, wherein a sealer material is present between the first panel and the second panel, the sealer material is in contact with the first panel and the second panel along all of a seal path,
[0046] performing a first heating process to heat metal particles derived from the sealer material along the seal path, while the sealer material is in contact with the first panel and the second panel along all of the seal path, to cause fusing of the metal particles along the seal path; and
[0047] performing a second heating process, separate from the first heating process, to provide a continuous weld along the seal path between the fused metal particles and the first panel and between the fused metal particles and the second panel, thereby generating a seal along the seal path, wherein:
[0048] the second heating process is performed using a laser.
2. The method of clause 1, wherein the fusing of the metal particles by the first heating process along the seal path is such that a largest gap between the fused metal particles and the first panel or the second panel along the seal path has a largest dimension that is smaller than 500 nm.
3. The method of clause 1 or 2, wherein the second heating process is performed using a laser configured to provide pulses having a pulse length of less than 50 ps.
4. The method of any preceding clause, wherein the providing of the first panel and the second panel comprises the following steps in order:
[0049] depositing the sealer material on the first panel;
[0050] heating the sealer material to remove a portion of the sealer material, thereby increasing the stiffness of the sealer material; and
[0051] moving either or both of the first panel and the second panel so that the first panel and the second panel are brought into a facing configuration in which the sealer material is in contact with the first panel and the second panel along all of the seal path.
5. The method of clause 4, wherein the stiffness of the sealer material after said heating of the sealer material is such that a height of the sealer material can be reduced by at least 5% during the moving of either or both of the first panel and the second panel to bring the first panel and the second panel into the facing configuration, thereby to compensate for one or more of: irregularities in the first panel, irregularities in the second panel, and misalignment of the first panel relative to the second panel.
6. The method of any preceding clause, wherein the seal path at least partially encircles a region between the first panel and the second panel.
7. The method of clause 6, wherein the seal path comprises at least 95% of a closed loop.
8. The method of clause 6 or 7, wherein the continuous weld is provided along plural parallel lines along the seal path.
9. The method of any preceding clause, wherein the metal particles comprise one or more of the following: silver, gold, nickel, aluminium, copper.
10. The method of any preceding clause, wherein the metal particles comprise metal microparticles or metal nanoparticles.
11. The method of any preceding clause, wherein the sealer material comprises the metal particles held in a matrix.
12. The method of clause 11, wherein the matrix comprises a liquid or paste.
13. The method of any preceding clause, further comprising changing a pressure or composition of gas within a region at least partially encircled by the seal path and, subsequently, sealing said region.
14. The method of any preceding clause, wherein either or both of the first panel and the second panel are transparent to radiation in the visible spectrum.
15. The method of any preceding clause, wherein either or both of the first panel comprises a transparent glass material, preferably a silicate glass, more preferably a soda-lime glass.
16. A method of manufacturing a sealed unit comprising a first panel and a second panel, the method comprising forming a seal between the first panel and the second panel using the method of any preceding clause.
17. A sealed unit manufactured using the method of clause 16.
18. An apparatus for forming a seal, comprising:
[0052] a deposition unit configured to deposit a sealer material along a seal path on a first panel;
[0053] a panel handler configured to move either or both of the first panel and the second panel so that the first panel and second panel are brought into a facing configuration in which the sealer material is in contact with the first panel and the second panel along all of a seal path;
[0054] a first heating unit configured to heat metal particles derived from the sealer material along the seal path, while the sealer material is in contact with the first panel and the second panel along all of the seal path, to cause fusing of the metal particles along the seal path; and
[0055] a second heating unit configured to provide a continuous weld along the seal path between the fused metal particles and the first panel and between the fused metal particles and the second panel, thereby generating a seal along the seal path,
[0056] wherein the second heating unit comprises a laser configured to provide the continuous weld.
19. The apparatus of clause 18, wherein the laser is configured to provide pulses having a pulse length of less than 50 ps.
20. The apparatus of clause 18 or 19, further comprising:
[0057] a third heating unit configured to remove by heating a portion of the sealer material, thereby increasing the stiffness of the sealer material, wherein:
[0058] the panel handler is configured to move either or both of the first panel and the second panel into the facing configuration after the stiffness of the sealer material has been increased by the third heating unit.
21. The apparatus of any of clauses 18-20, wherein the seal path at least partially encircles a region between the first panel and a second panel.
22. The apparatus of clause 21, further comprising a gas control and sealing device configured to change a pressure or composition of gas within the region at least partially encircled by the seal path and, subsequently, seal said region.