LIQUID CRYSTAL MIXTURE AND TEMPERATURE-RESPONSIVE INFRARED REFLECTION DEVICE

Abstract

Disclosed are a liquid crystal mixture and a temperature-responsive infrared reflection device made by using the liquid crystal mixture containing potassium laurate. Infrared light can pass through the device within a non-working temperature range, and a chiral dopant enables potassium laurate to form a cholesteric phase within a working temperature range. The birefringence value of the potassium laurate gradually increases with the increase of temperature between 12.5 C. and 26 C., so that the infrared reflection bandwidth of the device constantly increases. The birefringence value of the potassium laurate gradually decreases with the increase of temperature between 26 C. and 54.5 C., so that the infrared reflection bandwidth of the device constantly decreases. The infrared reflection bandwidth of the infrared reflection device can vary with temperature by adjusting the proportions of the ingredients of the liquid crystal mixture containing potassium laurate, so that the device can satisfy the demands of people which vary with the environment, and can be applied in many fields such as households and buildings.

Claims

1. A liquid crystal mixture, comprising: potassium laurate; heavy water; organic alcohol; and a chiral dopant.

2. The liquid crystal mixture of claim 1, wherein the organic alcohol is one selected from the group consisting of n-decanol, iso-decanol, and n-octanol.

3. The liquid crystal mixture of claim 1, wherein the chiral dopant is selected from one of S1011 and R1011.

4. The liquid crystal mixture according to claim 1, wherein the liquid crystal mixture comprises: 24.03 to 28.9 parts by weight of potassium laurate; 5.7 to 7.3 parts by weight of heavy water; 59.8 to 69.2 parts by weight of the organic alcohol; and 2.71 to 2.83 parts by weight of the chiral dopant.

5. A temperature-responsive infrared reflection device, comprising the liquid crystal mixture of claim 1.

6. The temperature-responsive infrared reflection device of claim 5, wherein the temperature-responsive infrared reflection device is capable of performing infrared reflection at 12.5 C. to 54.5 C.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0014] FIG. 1 is a partial cross-sectional schematic diagram of a temperature-responsive infrared reflection device at a non-working temperature (outside the range of 12.5 C. to 54.5 C.); and

[0015] FIG. 2 is a partial cross-sectional schematic diagram of a temperature-responsive infrared reflection device at a working temperature (12.5 C. to 54.5 C.).

DETAILED DESCRIPTION

[0016] Hereinafter, with reference to the embodiments and drawings, the conception, specific structures and technical effects of the present disclosure are to be clearly and completely described to fully understand the objectives, features and effects of the present disclosure. It is apparent that the following embodiments are only a part of the embodiments of the present disclosure, and are not all of the embodiments. Based on the embodiments of the present disclosure, other embodiments, which can be obtained by those skilled in the art without creative efforts, belong to the scope of protection of the present disclosure.

EXAMPLE 1

[0017] A liquid crystal mixture is obtained by mixing 25 parts by weight of potassium laurate, 6.8 parts by weight of heavy water, 65.45 parts by weight of n-decanol, and 2.75 parts by weight of chiral dopant S1011 well.

[0018] The potassium laurate has a structural formula as shown by

##STR00001##

[0019] The chiral dopants S1011 and R1011 used herein have similar structural formulae as shown by

##STR00002##

but opposite chirality.

EXAMPLE 2

[0020] A liquid crystal mixture is obtained by mixing 25 parts by weight of potassium laurate, 6.5 parts by weight of heavy water, 65.73 parts by weight of n-octanol, and 2.75 parts by weight of chiral dopant R1011 well.

EXAMPLE 3

[0021] A liquid crystal mixture is obtained by mixing 27.52 parts by weight of potassium laurate, 6.89 parts by weight of heavy water, 62.8 parts by weight of iso-decanol, and 2.79 parts by weight of chiral dopant R1011 well.

EXAMPLE 4

[0022] This example provides a temperature-responsive infrared reflection device, as shown in FIG. 1.

[0023] The temperature-responsive infrared reflection device comprises a first light-transmitting substrate 1 and a second light-transmitting substrate 2 which are arranged relatively. The opposite surfaces of the first light-transmitting substrate 1 and the second light-transmitting substrate 2 are spin-coated with parallel alignment layers 3, and are arranged through rubbing alignment. The liquid crystal mixture, which may be the mixture of Example 1, fills between the first light-transmitting substrate 1 and the second light-transmitting substrate.

[0024] When the temperature-responsive infrared reflection device of this example is at non-working temperature (outside the range of 12.5 C. to 54.5 C.), potassium laurate 4 cannot form a cholesteric phase with the chiral dopant of the liquid crystal mixture, and would be in isotropic status. Thus, infrared light 5 can pass through the device without affecting the transmission of visible light. In this example, the liquid crystal mixture of Example 1 is heated to convert potassium laurate into isotropic status, and then injected into the device, during the preparation of the temperature-responsive infrared reflection device. It would facilitate the filling by heating potassium laurate to reduce the viscosity thereof.

[0025] Referring to FIG. 2, when the temperature-responsive infrared reflection device of this example is at working temperature (12.5 C. to 54.5 C.), potassium laurate 4 can form a cholesteric phase of a spiral structure with the chiral dopant of the liquid crystal mixture, to reflect infrared light 5 within a certain range of wavelengths. From 12.5 C. to 26 C., the birefringence value (n) of potassium laurate 4 increases with the increase of temperature and reach the peak at 26 C. The infrared reflection bandwidth of the infrared reflection device, which is made by using the liquid crystal mixture of Embodiment 1, also constantly increases and reach the peak at 26 C. From 26 C. to 54.5 C., the birefringence value (n) of potassium laurate 4 decreases with the increase of temperature. The infrared reflection bandwidth of the infrared reflection device, which is made by using the liquid crystal mixture of Example 1, gradually decreases. Therefore, from 12.5 C. to 54.5 C., the infrared reflection bandwidth of the infrared reflection device, which is made by using the liquid crystal mixture, can vary with external temperature.

EXAMPLE 5

[0026] A liquid crystal mixture is obtained by mixing 28 parts by weight of potassium laurate, 7.3 parts by weight of heavy water, 61.9 parts by weight of n-decanol, and 2.8 parts by weight of chiral dopant R1011 well.

EXAMPLE 6

[0027] A liquid crystal mixture is obtained by mixing 26 parts by weight of potassium laurate, 5.9 parts by weight of heavy water, 65.34 parts by weight of iso-decanol, and 2.76 parts by weight of chiral dopant S1011 well.