BIODEGRADABLE AND COMPOSTABLE COMPOSITION

Abstract

The present invention concerns a biodegradable and compostable composition comprising i) 15-70% by weight of at least one biodegradable and/or decayable aromatic polyester; ii) 0-40% by weight of dolomite and/or calcium carbonate particles having a polished surface; iii) 0-30% by weight of starch of vegetable origin; iv) 1-5% by weight of at least one oil of vegetable origin; v) 5-30% by weight of an additive chosen from hydrated magnesium silicate such as talcum powder; vi) 0-50% by weight of at least one aliphatic polyester.

Claims

1. A biodegradable and compostable composition comprising: (i) 15-70% by weight of at least one biodegradable and/or decayable aromatic polyester; (ii) 10-40% by weight of dolomite and/or calcium carbonate particles having a polished surface; (iii) 0-30% by weight of starch of vegetable origin; (iv) 1-5% by weight of at least one oil of vegetable origin and/or at least one polyol; (v) 5-30% by weight of an additive chosen from hydrated magnesium silicate such as talcum powder; (vi) 0-50% by weight of at least one aliphatic polyester.

2. A composition according to claim 1, wherein said dolomite and/or calcium carbonate particles have been pre-treated with said at least one oil of vegetable origin and/or at least one polyol.

3. A composition according to claim 2, wherein said starch of vegetable origin is chosen from at least one of wheat, oat, rye and barley or a combination thereof.

4. A composition according to claim 1, wherein said dolomite and/or calcium carbonate particles have a particle size of 2-4 μm.

5. A composition according to claim 1, wherein said starch of vegetable origin has a particle size of 4-50 μm.

6. A composition according to claim 1, wherein said starch of vegetable origin has been pre-treated with at least one oil of vegetable origin.

7. A method for preparing a biodegradable and compostable composition, such as granules, according to claim 1, which method comprises: (a) polishing 10-40% by weight of particles of dolomite and/or calcium carbonate to remove sharp edges on the surface; (b) mixing said polished particles, with 1-5% by weight of at least one oil of vegetable origin or at least one polyol to provide a non-sticky mixture; (c) heat mixing a composition comprising (i) 15-70% by weight of at least one biodegradable and/or decayable aromatic polyester; (ii) optionally 0-30% by weight starch of vegetable origin; (iii) 5-30% by weight of an additive chosen from hydrated magnesium silicate such as talcum powder; and (iv) optionally 0-50% by weight of at least one aliphatic polyester; thereafter, during continued mixing, (d) adding said non-sticky mixture of step (b) to said heat mixed base composition; and (e) extruding the mixture of step (d) into granules of said composition.

8. A method for preparation of a composition according to claim 7, wherein the mixing in step (d) and extrusion in step (e) is performed under controlled pressure and heating.

9. A method for preparation of a composition according to claim 8, wherein the mixing in step (d) and extrusion in step (e) is performed at a pressure below 300 bar.

10. A method for preparation of a composition according to claim 8, wherein the mixing in step (d) and extrusion in step (e) is performed at a temperature from 150 to 200° C.

11. A granule prepared according to the method as described in claim 7.

12. A granule according to claim 11 for use as a formable material for replacing fossil-based plastics.

13. Use according to claim 12, wherein said formable material is formed into waste-bags, bags, cutleries, disposable articles such as disposable sheets, disposable aprons, and disposable hygiene articles.

14. A composition according to claim 1, wherein said starch of vegetable origin is chosen from at least one of wheat, oat, rye, and barley or a combination thereof.

15. A method for preparation of a composition according to claim 7, wherein the mixing in step (d) and extrusion in step (e) is performed at a pressure below 300 bar.

16. A method for preparation of a composition according to claim 7, wherein the mixing in step (d) and extrusion in step (e) is performed at a temperature from 150 to 200° C.

17. A granule comprising a composition according to claim 1.

18. A composition prepared according to the method according to claim 7.

19. A use of a composition according to claim 1.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0039] The present invention concerns a composition suitable for replacing plastics which is biodegradable, compostable, and which does not leave micro plastics in the ground or water during or after use. The composition according to the invention decomposes at lower temperatures than that required when poly lactic acid (PLA) is present as a component of the composition. PLA requires temperatures of about 70° C. in order to decompose and required a higher energy input.

[0040] The biodegradable and compostable composition suitable for replacing plastic according to the present invention thus comprises [0041] (i) 15-70% by weight of at least one biodegradable and/or decayable aromatic polyester; [0042] (ii) 10-40% by weight of dolomite and/or calcium carbonate particles having a polished surface; [0043] (iii) 0-30% by weight of starch of vegetable origin; [0044] (iv) 1-5% by weight of at least one oil of vegetable origin; [0045] (v) 5-30% by weight of an additive chosen from hydrated magnesium silicate such as talcum powder; [0046] (vi) 0-50 by weight of at least one aliphatic polyester.

[0047] In an embodiment, said dolomite and/or calcium carbonate has been pre-treated with at least one oil of vegetable origin.

[0048] In one embodiment said composition comprises 40% by weight of at least one biodegradable and/or decayable aromatic polyester 25% by weight of dolomite and/or calcium carbonate particles having a polished surface, 0% by weight of starch of vegetable origin chosen from at least one of wheat, oat, rye and barley, 5% by weight of at least one oil of vegetable origin, 10% by weight of an additive chosen from hydrated magnesium silicate such as talcum powder; and 20% at least one aliphatic polyester, wherein said dolomite and/or calcium carbonate has been pre-treated with at least one oil of vegetable origin. The composition being prepared as granules, suitable for further machine processing by blow molding into a film.

[0049] In another embodiment said composition comprises 27% by weight of at least one biodegradable and/or decayable aromatic polyester, 10% by weight of dolomite and/or calcium carbonate particles having a polished surface, 15% by weight of starch of vegetable origin chosen from at least one of wheat, oat, rye and barley, 3% by weight of at least one oil of vegetable origin, 5% by weight of an additive chosen from hydrated magnesium silicate such as talcum powder, and 40% by weight of at least one aliphatic polyester, wherein said dolomite and/or calcium carbonate has been pre-treated with at least one oil of vegetable origin. The composition being prepared as granules, suitable for further machine processing by thermo folding into a compostable trough.

[0050] In another embodiment said composition comprises 30% by weight of at least one biodegradable and/or decayable aromatic polyester, 10% by weight of dolomite and/or calcium carbonate particles having a polished surface, 0% by weight of starch of vegetable origin chosen from at least one of wheat, oat, rye and barley, 3% by weight of at least one oil of vegetable origin, 10% by weight of an additive chosen from hydrated magnesium silicate such as talcum powder, and 47% by weight of at least one aliphatic polyester, wherein said dolomite and/or calcium carbonate has been pre-treated with at least one oil of vegetable origin. The composition being prepared as granules, suitable for further machine processing by extrusion to straws.

[0051] In yet another embodiment, said composition comprises 30% by weight of at least one biodegradable and/or decayable aromatic polyester, 10% by weight of dolomite and/or calcium carbonate particles having a polished surface, 10% by weight of starch of vegetable origin chosen from at least one of wheat, oat, rye, and barley, 3% by weight of at least one oil of vegetable origin, 10% by weight of an additive chosen from hydrated magnesium silicate such as talcum powder, and 37% by weight of at least one aliphatic polyester, wherein said dolomite and/or calcium carbonate had been pre-treated with at least one oil of vegetable origin. The composition being prepared as granules, suitable for further machine processing by injection molding into cutlery.

[0052] In another embodiment said composition comprises (i) 68% by weight of at least one biodegradable and/or decayable aromatic polyester; (ii) 15% by weight of dolomite and/or calcium carbonate particles having a polished surface; (iii) 0% by weight of starch of vegetable origin chosen from at least one of wheat, oat, rye and barley; (iv) 2% by weight of at least one oil of vegetable origin; (v) 5% by weight of an additive chosen from hydrated magnesium silicate such as talcum powder; (vi) 10% by weight of at least one aliphatic polyester, wherein said dolomite and/or calcium carbonate has been pre-treated with at least one oil of vegetable origin. The composition being prepared as granules, suitable for further machine processing by blow molding into a film further processed to a bag.

[0053] In another embodiment said composition comprises (i) 15% by weight of at least one biodegradable and/or decayable aromatic polyester; (ii) 20% by weight of dolomite and/or calcium carbonate particles having a polished surface; (iii) 0% by weight of starch of vegetable origin chosen from at least one of wheat, oat, rye and barley; (iv) 2% by weight of at least one oil of vegetable origin; (v) 15% by weight of an additive chosen from hydrated magnesium silicate such as talcum powder; (vi) 48% by weight of at least one aliphatic polyester, wherein said dolomite and/or calcium carbonate has been pre-treated with at least one oil of vegetable origin. The composition being prepared as granules, suitable for further machine processing by blow molding into a film suitable for use as a bag, or for further machine processing by thermo folding into a compostable trough.

[0054] In one embodiment of the present invention the biodegradable and/or decayable aromatic polyester, may be a polybutylene adipate terephthalate (PBAT), a random copolymer produced from adipic acid, 1,4-butanediol, and terephthalic acid. Any other aromatic polyester with similar properties as PBAT may be used. The at least one biodegradable and/or decayable aromatic polyester is present in an amount of 15-70% by weight. For instance, 15-25, 25-35, 35-45, 45-55, 55-70% by weight. For example, the at least one biodegradable and/or decayable aromatic polyester is present in an amount of 15, 27, 30, 40 or 68% by weight as is disclosed in the experimental part.

[0055] In one embodiment of the present invention the composition may include dolomite and/or calcium carbonate particles. An alternative to calcium carbonate particles may be limestone particles or marble particles. Dolomite and/or calcium carbonate are materials acquired from the soil, where it originates from minerals. Said particles may have a polished surface, and by polishing the surface thereof the particles do not give rise to tear initiation in a film prepared from the composition. Thus, all edges that may give rise to a tear initiation in e.g. a film has been removed on the particles, and a level surface is produced which is smooth without any sharp corners. The particles constitute 10-40% by weight. For example, 10-20%, 20-30%, 30-40% by weight of the composition. In one embodiment the particles constitute 25% by weight of the composition, in another composition the particles constitute 35% by weight of the composition, in another embodiment the particles constitute 15% by weight of the composition and in yet other embodiments it constitutes 10% by weight of the composition.

[0056] Further, according to one embodiment of the present invention, said particles may have a size of about 2-4 μm.

[0057] Said particles are pre-treated with at least one oil of vegetable origin as to reach saturation. The mix of the particles and the oil converts the particles to a lubricant, which decreases the tear of the machines used.

[0058] In one embodiment, the composition according to the invention may include at least one oil and/or at least one polyol of vegetable origin or a combination thereof. The oil may be rape seed oil or glycerol. The at least one oil of vegetable origin constitute 1-5% by weight of the composition. For example, 3-5% by weight. The at least one oil of vegetable origin may for example constitute 2, 3, 4 or 5% by weight of the composition.

[0059] In one embodiment, the composition according to the invention may include an additive chosen from hydrated magnesium silicate. Where talcum powder being the preferred choice. The use of hydrated magnesium silicate further increases said lubricant effect, decreasing the tear of machines even further. The hydrated magnesium silicate, such as talcum constitute 5-30% by weight of the composition. For example, 5-10%, 10-15%, 15-20%, 20-25% or 25-30% by weight. In one embodiment the hydrated magnesium silicate constitutes 15% by weight of the composition, in another composition the hydrated magnesium silicate constitutes 10% by weight of the composition. In yet another embodiment it constitutes 5% by weight of the total weight of the composition.

[0060] The composition may in one embodiment according to the invention include starch of a vegetable origin, where said starch having a size of 4-50 μm, for instance around 4, 10, 20, 30, 40 or 50 μm. The starch of vegetable origin constitutes 0-30% by weight of the composition. For example, 0-5%, 5-10%, 10-15%, 15-20%, 20-25% or 25-30% by weight. The composition constitutes for example of 0, 5, 10 or 15% by weight of starch. In one embodiment the starch of vegetable origin is chosen from at least one of wheat, oat, rye and barley or a combination thereof. The starch source may be present in the form of a bran, or a flour and be obtained from any starch source such as wheat, oat, rye and barley or any other available starch sources. The starch may be present as such or in the form it is present naturally, for instance in any part of the cereal grain such as bran, germ, endosperm or a combination. The use of starch from e.g. a rye bran gives the composition a characteristic “wood-like” color. This “wood-like” color is beneficial for the end product since its appearance will differ from other products of the same category made from e.g. polyethylene (PE) products. The addition of starch gives the composition characteristics such that further processing of the granules made thereof will provide a material being non-elastic making said material suitable to use for bags carrying heavy loads without tearing of the fingers. In one further embodiment according to the invention, the starch being pre-treated with at least one oil of vegetable origin erasing water from the starch, increasing the firmness of the composition.

[0061] In one embodiment, the aliphatic polyester, is an acid modified with alcohol. In another embodiment, the aliphatic polyester consists of polymerized units, where the repeating units consist of up to 15 carbon atoms such as up to 10 carbon atoms. In yet another embodiment the aliphatic polyester is a biodegradable polyester, such as polybutylene succinate (PBS). Polybutylene succinate being a fossil-free renewable polyester synthesized from 1,4-butane diol and succinic acid. PBS consists of polymerized units of butylene succinate, with repeating C.sub.8H.sub.12O.sub.4 units. In another embodiment, the aliphatic polyester, may be polybutyl acrylate. Polybutyl acrylate (PBA) being synthesized e.g. from acetylene, 1-butyl alcohol, carbon monoxide, nickel carbonyl, and hydrochloric acid. PBA consists of polymerized units of butyl acrylate, with repeating (C.sub.7H.sub.12O.sub.2) units. In yet another embodiment, the aliphatic polyester, may be polyhydroxy butyrate (PHB). In one embodiment, the PHB may be poly-3-hydroxybutyrate (P3HB). In yet another embodiment the PHB may be poly-4-hydroxybutyrate (P4HB). Polyhydroxy butyrate is a polyhydroxyalkanoate (PHA), a polymer belonging to the polyesters class that are of interest as bio-derived and biodegradable. Polyhydroxyalkanoates or PHAs are polyesters produced in nature by numerous microorganisms. When produced by bacteria they serve as both a source of energy and as a carbon store. More than 150 different monomers can be combined within this family to give materials with extremely different properties. These materials are biodegradable and are used in the production of bioplastics. PHB is a compostable and biodegradable polyester and derived from renewable sources as it is produced by microorganisms as a response to physiological stress. Using polyhydroxyl butyrate allows for degradation of the end product in water. Any other aliphatic polyester having similar properties as polybutylene succinate, polybutyl acrylate or polyhydroxy butyrate may be used. The at least one aliphatic polyester may constitute 0-50% by weight of the composition. For example, 0-10%, 10-20%, 20-30%, 30-40%, 40-50% by weight of the composition. The composition constitutes for example 48, 47, 40, 37, 20 or 10% by weight of at least one aliphatic polyester as is described in the experimental part.

[0062] In a compost container, the formation of methane gas requires 30-35° C. to start. The methane gas further increases the growth of bacteria, which starts the decaying process. For the present invention, this is enough for the decaying process to start, while bioplastic compositions comprising PLA according to prior art require a temperature of 70° C. for the decomposition to start. A product, for example a film with the thickness of up to 70 μm, such as 25 μm, and even up to 1 mm, produced from the granules made from the composition according to the present invention can be fully decomposed in 180 days during the conditions stated above. If the temperature is further increased to 55° C. the decomposition process will be reduced to a time of some weeks.

[0063] During decaying process of products prepared from the granules created from the present invention, some of the product will decay and may give rise to biogas, and the remaining within the digested sludge will be spread out on the fields. Dolomite and/or calcium carbonate will not influence the decaying process but will act as soil improvement agent out on the fields as it will neutralize the pH, which is favorable for soil. The dolomite and/or calcium carbonate will for instance provide the soil with growth factors such as calcium and magnesium and other important minerals.

[0064] The problem with the use of plastic material from fossil sources, or from raw material which does not degrade in nature are getting increased attention from governments as well as the public. The use of plastics in products giving rise to micro plastics in soil and water has also gained interest during later years. The composition of the present invention is fully biodegradable and compostable, without being a source of micro plastics. The dolomite and/or calcium carbonate is a neutral component within the composition, as it returns back to the nature in the same form as it is withdrawn from the nature. The starch and the oil according to the present invention come from vegetable origin, which is a renewable raw material, while the aromatic polyesters available on the market as of today mostly is from non-renewable raw material, but also from partly renewable and fully degradable sources, such as PBAT disclosed above. The composition according to the present invention may only comprise 6-30% of non-renewable raw material.

[0065] The present invention further concerns a method for preparing a biodegradable and compostable composition, such as granules, according to above. The method according to the present invention comprises:

[0066] (a) polishing particles of dolomite and/or calcium carbonate to remove sharp edges on the surface;

[0067] (b) mixing said polished particles, with at least one oil of vegetable origin to provide a non-sticky mixture;

[0068] (c) heat mixing a composition comprising (i) at least one biodegradable and/or decayable aromatic polyester; and (ii) optionally starch of vegetable origin; (iii) an additive chosen from hydrated magnesium silicate such as talcum powder; and (iv) optionally at least one aliphatic polyester;

[0069] thereafter, during continued mixing,

[0070] (d) adding said non-sticky mixture of step (b) to said heat mixed base composition; and

[0071] (e) extruding the mixture of step (d) into granules of said composition.

[0072] In one embodiment of the present invention, the method steps (d) and (e) is performed under controlled pressure and heating.

[0073] The controlled pressure may be below 300 bar, for instance 100-200 bar depending on the temperature. The controlled temperature may be 150-200° C.

[0074] The granules of said composition may further be processed using conventional machines and processing techniques such as blow molding, thermo forming, extrusion, and injection molding. The use of dolomite and/or calcium carbonate, which is being saturated with at least one oil of vegetable origin, will act as a lubricant for the machine. Decreasing the tear thereof, as compared to processing of other materials.

[0075] From the processing of the granules, several products can be produced. Among them are hygiene articles, and disposable products. In one use, there is a film produced, the film being stretched so as to create micro cracks in the film making in breathable. Further use when the product comes in contact with the ground or water, where the composition has advantages for this use such that it does not release micro plastics to the surrounding environment, it does not include substances being toxic to nature or humans, and it does not soften even during higher air temperatures. For further use, said composition provides with characteristics for a material as to be very flexible, such that it can be hard to break even stiff products prepared from the granules of said composition. This might be advantageous since the breaking of products can give rise to sharp structures which can be harmful. A flexible non-breakable product can then erase the risk of using the product as a sharp weapon if the products is used as for instance a disposable cutlery. Further, a film produced from the granules of the present invention can be used as a coating of for instance cardboard boxes or cardboard packages as used for foods such as dairy products.

[0076] The use of at least one oil of vegetable origin to saturate dolomite and/or calcium carbonate particles as well as starch of vegetable origin prevents water from permeabilizing the composition which increases tear strength and reduces permeability. This increases comfortability and usability when the granules made from the present invention are further processed to be used as bags.

[0077] Mixing dolomite and/or calcium carbonate particles with at least one oil of vegetable origin until saturation and with an additive chosen from hydrated magnesium silicate such as talcum powder allows the mix to act as a lubricant, reducing the tear of the machines used.

[0078] The composition of polished dolomite and/or calcium carbonate particles pre-treated with oil of at least one vegetable origin, optionally pre-treated starch of vegetable origin, aromatic polyester, and at least one aliphatic polyester, is mixed at a temperature which may be 150-200° C. and under a pressure which may be below 300 bar during continued mixing. The mixing of the composition is preferably performed in an extruder, most preferably a twin-screw extruder.

[0079] The composition will be cut into granules. The granules may then be used for further processing using standard machine processes such as blow molding, thermo forming, extrusion, or injection molding. From such processes, several different products can be made such as hygiene products, disposable articles.

[0080] The present invention also concerns use of the composition or granules prepared from the composition as a formable material, wherein said formable material is processed and/or formed with known methods into waste-bags, bags, cutleries, disposable articles such as disposable sheets, disposable aprons, and disposable hygiene articles.

EXAMPLES

[0081] By way of examples, and not limitation, the following examples identify a variety of compositions pursuant to the embodiments of the present invention.

Experiment 1

[0082] In the first experiment dolomite particles, in a concentration of 25% by weight of the calculated final composition, were polished to acquire smooth edges. Next, the particles were mixed with 5% by weight of rapeseed oil to saturate the particles. The result of the mixing was a non-sticky mixture working as a lubricant in the further processing steps.

[0083] In parallel, 40% by weight of PBAT was mixed with 10% by weight of talcum powder and 20% of polybutylene succinate during heating to 150° C. under a pressure of 225 bar. The mixing was done in an extruder and the lubricant mixture from the first step was added to the extruder.

[0084] Using the extruder, the composition was pushed out of the extruder and cut into granules. The total weight of the composition was 5000 ton. The granules were further processed by blow molding into a film. The film was cooled down and stretched to acquire cracks of the film, to allow for air exchange through the film. The film was later used as a disposable sheet for use in e.g. hospitals.

Experiment 2

[0085] In the second experiment 10% by weight, of the final composition, of dolomite particles were polished to remove sharp edges. The particles were next mixed with 3% by weight of glycerol, to transform the particles into a lubricant.

[0086] Further, 27% by weight of PBAT was heat mixed at a temperature of 200° C. and a pressure of 225 bar with 15% by weight of rye bran as starch source, 5% by weight of talcum powder and 40% by weight of polybutylene succinate. The mixing was performed in an extruder and the lubricant mix of talcum powder and rapeseed oil was added to the mixture.

[0087] The mixture was pressed out of the extruder and cut into granules. The total weight of the composition was 5000 ton. The granules were further processed using thermo folding into a compostable trough. The use of rye in the mixture gave the trough a characteristic “wood-like” color, making it easy to distinguish it from other products of the same category.

Experiment 3

[0088] In a third experiment 10% by weight, of the final composition, of dolomite particles were polished to remove sharp edges. It was further mixed with 3% by weight of rapeseed oil to acquire a lubricant effect of the mixture.

[0089] 30% by weight of PBAT was further, under a temperature of 200° C. and a pressure of 225 bar, mixed with 10% by weight of talcum powder and 47% by weight of polybutylene succinate. The mixing was performed in an extruder and the lubricant mixture was further added. The mixture was further cut into granules. The total weight of the composition was 5000 ton. The granules were further processed by extrusion and was processed into a straw. The straw being fully biodegradable and compostable.

Experiment 4

[0090] In a fourth experiment 10%, by weight of the final composition, of dolomite particles was polished to acquire particles with no sharp edges. The particles were mixed with 2% by weight of rapeseed oil, to transform the particles into a lubricant.

[0091] Further, 30% by weight of PBAT was mixed with 10% by weight of rye bran as starch source, 10% by weight of talcum powder and 37% by weight of polybutylene succinate. The mixing was performed at 150° C. and under a pressure of 225 bar. Before mixing, the rye was pre-treated with 1% by weight of rapeseed oil until saturation. The mixing was performed in an extruder and the lubricant mix was further added. The composition was cut into granules. The total weight of the composition was 5000 ton. The granules were further processed by injection molding into cutlery. The cutlery being stiff, but yet flexible such that they cannot be broken into pieces that have sharp edges. This eliminates the risk of using the cutleries as sharp for instance sharp weapons.

Experiment 5

[0092] In a fifth experiment 15%, by weight of the total composition, of dolomite particles were polished to acquire a smooth surface of the particles.

[0093] They were further mixed with 2% by weight of rapeseed oil to transform them into a lubricant.

[0094] Further, 68% by weight of PBAT was mixed with 5% by weight of talcum powder and 10% by weight of polybutylene succinate during heating to 170° C. and under a pressure of 225 bar. The mixing was performed in an extruder and the lubricant mixture was further added to the mixture.

[0095] The composition was cut into granules. The total weight of the composition was 5000 ton. The granules were further processed by blow molding into a film. The film was further used as a bag for instance for groceries.

Experiment 6

[0096] In a sixth experiment 10%, by weight of the total composition, of dolomite particles were polished to a smooth surface and further blended with 2% by weigh of rapeseed oil to transform the particles into a lubricant.

[0097] Further, 15% by weight of PBAT was mixed with 15% of talcum powder and 48% by weight of polybutylene succinate. The mixing was performed at 200° C. and at a pressure of 225 bar, in an extruder. The lubricant mixture was further added to the extruder. Next, the composition was cut into granules and the granules was further processed in two separate ways. One part was processed through blow molding to a 50 μm thick film, which later was used as a waste bag and one part through thermo folding into trough.

Experiment 7

[0098] The seventh experiment was a decomposition experiment. The waste bag produced from the film, which was produced from the granules of the present invention, from experiment 5 was placed in a compost together with 70-95 kg organic waste added each day for one week. The temperature in the compost was approximately 30° C. at the start of the experiment. This induced the formation of methane gas, which in turn induced the growth of bacteria. During the decomposition process the temperature naturally increases over time to approximately 50° C., where the decomposition of the bag goes very fast. In under 180 days, the bag was completely decomposed, and the remaining sludge was used as soil fertilizer.

[0099] The film (waste bag) prepared by the composition of the invention decomposes at lower temperatures compared to prior art films containing e.g. PLA requiring higher temperatures for decomposition. This is an excellent sustainable improvement compared to the prior art plastic bags.

Experiment 8

[0100] The eight experiment was a decomposition experiment. The waste bag produced from the film, which was produced from the granules of the present invention, from experiment 5 was placed in a compost together with 70-95 kg organic waste added each day for one week. The temperature in the compost was approximately 30° C. at the start of the experiment. The temperature was by industrial means increased to reach 55° C. The increase in temperature fastened the decomposition process compared to experiment 7 and in a week the bag was completely decomposed, and the only remaining waste was soil. As a comparison, a waste bag including PLA was used in the same experiment. After the week, the waste bag containing PLA was still remained in stripes in the compost and could not be used as a soil improvement from that condition.

TABLE-US-00001 TABLE 1 decomposition experiment with two waste bags Experiment 7 Experiment 8 Waste bag of a No residues left No residues left composition according to Experiment 5 Prior art bag Stripes of the Stripes of the containing PLA bag were bag were (poly lactic acid) present present

[0101] Thus, it has been shown that a waste bag prepared by the composition according to the invention has excellent decomposition properties compared to prior art waste bags containing for instance poly lactic acid requiring higher temperatures for decomposition. In addition, no micro plastics are left in the soil after decomposition.