HAIR STYLING COMPOSITION CONTAINING DISACCHARIDES

Abstract

Methods and aqueous compositions for styling or reshaping keratinous fibers such as human hair are provided. An aqueous styling composition includes (a) 0.5 to 15.0% by weight of at least one disaccharide; and (b) 0.01 to 20.0% by weight of at least one alkali salt and/or alkaline earth salt, wherein the composition is free of synthetic film-forming polymers.

Claims

1. An aqueous styling composition comprising: a) 0.5 to 15.0% by weight of at least one disaccharide; and b) 0.01 to 20.0% by weight of at least one alkali salt and/or alkaline earth salt, wherein the composition is free of synthetic film-forming polymers.

2. The aqueous styling composition of claim 1, wherein the at least one disaccharide is sucrose.

3. The aqueous styling composition according to claim 1 wherein the at least one alkali salt and/or alkaline earth salt is a fluoride, chloride, bromide, iodide, nitrate, sulfate, citrate or lactate salt.

4. The aqueous styling composition according to claim 1 wherein the at least one alkali salt and/or alkaline earth salt is selected from magnesium sulfate, sodium chloride, sodium sulfate, calcium chloride and mixtures thereof.

5. The aqueous styling composition according to claim 1 wherein the at least one surfactant is an anionic, cationic, nonionic or amphoteric surfactant selected from PEG derivatives of hydrogenated castor oil.

6. The aqueous styling composition according to claim 1 wherein the at least one disaccharide is present in the styling composition in a proportion of 1.0 to 13.0% by weight, based on the total proportion of the styling composition.

7. The aqueous styling composition according to claim 1 wherein at least one alkali salt and/or alkaline earth salt is present in the styling composition in a proportion of 0.5 to 15.0% by weight, based on the total proportion of the styling composition.

8. The aqueous styling composition according to claim 1 wherein the composition comprises at least two different alkali salts and/or alkaline earth salts.

9. The aqueous styling composition according to claim 1 wherein the composition comprises at least one alkali salt and/or alkaline earth salt of chloride and one alkali salt and/or alkaline earth salt of sulfate.

10. A method for reshaping keratinous fibers comprising: applying to the keratinous fibers an aqueous styling composition comprising: 0.5 to 15.0% by weight of at least one disaccharide; and 0.01 to 20.0% by weight of at least one alkali salt and/or alkaline earth salt, wherein the composition is free of synthetic film-forming polymers.

11. The aqueous styling composition according to claim 1 wherein the at least one surfactant is a nonionic surfactant.

12. The aqueous styling composition according to claim 1 wherein the at least one surfactant is a nonionic surfactant selected from PEG derivatives of hydrogenated castor oil.

13. The aqueous styling composition according to claim 1 wherein the at least one disaccharide is present in the styling composition in a proportion of 3.5 to 6.0% by weight, based on the total proportion of the styling composition.

14. The aqueous styling composition according to claim 1 wherein at least one alkali salt and/or alkaline earth salt is present in the styling composition in a proportion of 2.0 to 5.0% by weight, based on the total proportion of the styling composition.

Description

DETAILED DESCRIPTION

[0014] The following detailed description is merely exemplary in nature and is not intended to limit the disclosure or the application and uses of the subject matter as described herein. Furthermore, there is no intention to be bound by any theory presented in the preceding background or the following detailed description.

[0015] Styling composition means a cosmetic composition, which may be formulated in conventional forms of styling compositions, preferably the styling composition is sprayable, particularly preferably it is a spray formulation.

[0016] The preferred cosmetically acceptable carrier component of the styling composition is water, particularly preferably distilled water, most preferably distilled water without H.sub.2O.sub.2. The proportion of water in the styling composition is 10 to 60% by weight, preferably 15 to 50% by weight, particularly preferably 20 to 45% by weight, most preferably 25 to 35% by weight, based on the total proportion of the styling composition.

[0017] In a particularly preferred embodiment of the present disclosure, the styling composition comprises sufficient water to complete the remaining components included in the styling composition to 100% by weight, based on the total weight of the styling composition, also referred to as “ad. 100”.

[0018] The sum of all components of the styling composition is 100% by weight, based on the total amount of the styling composition.

[0019] The styling composition is free of synthetic, film-forming polymers. Synthetic film-forming polymers are all polymers, which leave a continuous film when drying, especially on the hair. Furthermore, film-forming polymers are those polymers which, when used in 0.01 to 20% by weight, preferably 1 to 5% by weight, aqueous, alcoholic or aqueous-alcoholic solution, are capable of crosslinking and/or stiffening hair, for example a strand of hair, by film formation. Preferably, crosslinking or stiffening is achieved by depositing a transparent polymer film on the hair.

[0020] Preferably, the styling composition does not contain a synthetic film-forming polymer, in particular a homo- or copolymer, comprising monomer units selected from siloxane, vinylpyrrolidone, vinylcaprolactam, N-vinylformamide, vinyl ester, such as vinyl acetate, Vinyl alcohol, acrylamide, methacrylamide, C1 to C7 alkyl acrylamide, C1 to C7 dialkyl acrylamide, C1 to C7 alkyl methacrylamide, C1 to C7 dialkyl methacrylamide, C1 to C7 alkyl acrylate, acrylic acid, propylene glycol, maleic acid, styrene, itaconic acid and mixtures thereof.

[0021] Particularly preferably, the styling composition is free of synthetic film-forming polymers selected from vinylpyrrilidone/vinyl ester copolymers, polyvinylpyrrilidones, siloxanes, glycosidically substituted silicones, homopolyacrylic acid and polyvinylpyrrolidones, in particular acrylamides/ammonium acrylate copolymer, acrylamides/DMAPA acrylates/methoxy PEG methacrylate copolymer, acrylamidopropyltrimonium chloride/acrylamide copolymer, acrylamidopropyltrimonium chloride/acrylates copolymer, acrylates/acetoacetoxyethyl methacrylate copolymer, Acrylates/Acrylamide Copolymer, Acrylates/Ammonium Methacrylate Copolymer, Acrylates/t-Butylacrylamide Copolymer, Acrylates/C1-2 Succinates/Hydroxyacrylates Copolymer, Acrylates/Lauryl Acrylate/Stearyl Acrylate/Ethylamine Oxide Methacrylate Copolymer, Acrylates/Octylacrylamide Copolymer, Acrylates/Octylacrylamide/Diphenyl Amodimethicone Copolymer, Acrylates/Stearyl Acrylate/Ethylamine Oxide Methacrylate Copolymer, Acrylates/VA Copolymer, Acrylates/VP Copolymer, Adipic Acid/Diethylenetriamine Copolymer, Adipic Acid/Dimethylaminohydroxypropyl Diethylenetriamine Copolymer, Adipic Acid/Epoxypropyl Diethylenetriamine Copolymer, Adipic Acid/Isophthalic Acid/Neopentyl Glycol/Trimethylolpropane Copolymer, Allyl Stearate/VA Copolymer, Aminoethylacrylate Phosphate/Acrylates Copolymer, Aminoethylpropanediol-Acrylates/Acrylamides Copolymer, Aminoethylpropanediol-AMPD-Acrylates/Diacetoneacrylamides Copolymer, Ammonium VA/Acrylates Copolymer, AMPD-Acrylates/Diacetoneacrylamides Copolymer, AMP-Acrylates/Allyl Methacrylates Copolymer, AMP Acrylates/C1-18 Alkyl Acrylates/C1-8 Alkyl Acrylamides Copolymer, AMP Acrylates/Diacetoneacrylamide Copolymer, AMP Acrylates/Dimethylaminoethyl Methacrylates Copolymer, Bis-Butyloxyamodimethicone/PEG-60 Copolymer, Butyl Acrylates/Ethylhexyl Methacrylates Copolymer, Butyl Acrylate/Hydroxypropyl Dimethicone Acrylate Copolymer, Butylated PVP, Butyl Ester of Ethylene/MA Copolymer, Butyl Ester of PVM/MA Copolymer, Calcium/Sodium PVM/MA Copolymer, Diethylene Glycolamine/Epichlorohydrin/Piperazine Copolymer, Dimethicone Crosspolymer, Diphenyl Amodimethicone, Ethyl ester of PVM/MA copolymer, Isobutylene/ethylmaleimide/hydroxyethylmaleimide copolymer, Isobutylene/MA copolymer, Isobutyl methacrylate/bis-hydroxypropyl dimethicone acrylate copolymer, Isopropyl ester of PVM/MA copolymer, Lauryl acrylate crosspolymer, Lauryl Methacrylate/Glycol Dimethacrylate Crosspolymer, MEA sulfites, Methacrylic Acid/Sodium Acrylamidomethyl Propane Sulfonate Copolymer, Methacryloyl Ethyl Betaine/Acrylates Copolymer, Octylacrylamide/Acrylates/Butylaminoethyl Methacrylate Copolymer, PEG/PPG-25/25 dimethicone/acrylates copolymer, PEG-8/SMDI copolymer, polyacrylamide, polyacrylate-6, polybutylene terephthalate, polyester-1, polyethylacrylate, polyethylene terephthalate, polymethacryloyl ethyl betaine, polypentaerythrityl terephthalate, Polyperfluoroperhydrophenanthrene, Polysilicone-9, Polyurethane-1, Polyurethane-6, Polyurethane-10, Polyvinyl Acetate, Polyvinyl Butyral, Polyvinylcaprolactam, Polyvinylformamide, Polyvinyl Imidazolinium Acetate, Polyvinyl Methyl Ether, Potassium Butyl Ester of PVM/MA Copolymer, Potassium Ethyl Ester of PVM/MA Copolymer, PPG-70 Polyglyceryl-10 Ether, PPG-12/SMDI Copolymer, PPG-51/SMDI Copolymer, PPG-10 Sorbitol, PVM/MA Copolymer, PVP, PVP/VA/Itaconic Acid Copolymer, PVP/VA/Vinyl Propionate Copolymer, Sodium Butyl Ester of PVM/MA Copolymer, Sodium Ethyl Ester of PVM/MA Copolymer, Sodium Polyacrylate, Terephthalic Acid/Isophthalic Acid/Sodium Isophthalic Acid Sulfonate/Glycol Copolymer, Trimethylolpropane Triacrylate, Trimethyl siloxysilylcarbamoyl Pullulan, VA/Crotonates Copolymer, VA/Crotonates/Methacryloxybenzophenone-1 Copolymer, VA/Crotonates/Vinyl Neodecanoate Copolymer, VA/Crotonates/Vinyl Propionate Copolymer, VA/DBM Copolymer, VA/Vinyl Butyl Benzoate/Crotonates Copolymer, Vinylamine/Vinyl Alcohol Copolymer, Vinyl Caprolactam/VP/Dimethylaminoethyl Methacrylate Copolymer, VP/acrylates/lauryl methacrylate copolymer, VP/dimethylaminoethyl methacrylate copolymer, VP/DMAPA acrylates copolymer, VP/hexadecene copolymer, VP/VA copolymer, VP/vinyl caprolactam/DMAPA acrylates copolymer and styrene/VP copolymer polyimides, such as polyimide-1.

[0022] Free of synthetic, film-forming polymers means as contemplated herein that the proportion of synthetic, film-forming polymers in the styling composition is a maximum of 0.5% by weight, preferably a maximum of 0.25% by weight, particularly preferably a maximum of 0.1% by weight, even more preferably a maximum of 0.05% by weight, even more preferably 0.0% by weight, based on the total proportion of the styling composition.

[0023] For the purposes of the present disclosure, disaccharide refers to two-sugars composed of two monosaccharides selected from glucose, fructose, galactose, rhamnose and xylose. Preferred disaccharides are selected from sucrose, lactose, lactulose, trehalose, maltose, maltulose, cellobiose, gentobiose, isomaltose, isomaltulose, laminaribiose, melibiose, neohesperidose, neotrehalose, nigerose, rutinose, sambubiose, sophorose and mixtures thereof, particularly preferred from sucrose, lactose, maltose, trehalose and mixtures thereof.

[0024] Preferably, the at least one disaccharide comprises sucrose (INCI: Sucrose). Particularly preferred is the at least one disaccharide sucrose (INCI: Sucrose).

[0025] Preferably, the at least one alkali salt and/or alkaline earth salt is a fluoride, chloride, bromide, iodide, nitrate, sulfate, citrate or lactate.

[0026] Alkali salt refers to all salts of the alkali metals, which include lithium, sodium, potassium, rubidium, cesium and francium. Accordingly, alkaline earth salts are the salts of the alkaline earth metals, which include beryllium, magnesium, calcium, strontium, barium and radium.

[0027] Preferably, the at least one alkali salt and/or alkaline earth salt is a salt of magnesium, sodium, potassium or calcium, particularly preferably of magnesium or sodium.

[0028] Preferably, the at least one alkali salt and/or alkaline earth salt is selected from magnesium sulfate, sodium chloride, sodium sulfate, calcium chloride and mixtures thereof, particularly preferably sodium chloride and magnesium sulfate.

[0029] Preferably, the at least one surfactant is an anionic, cationic, nonionic or amphoteric surfactant, preferably a nonionic surfactant, particularly preferably selected from PEG derivatives of hydrogenated castor oil.

[0030] In a particular embodiment of the present disclosure, the styling composition may additionally comprise at least one nonionic, anionic, cationic and/or amphoteric or zwitterionic surfactant. Examples of anionic surfactants include soaps, alkylbenzene sulfonates, alkane sulfonates, olefin sulfonates, alkyl ether sulfonates, glycerol ether sulfonates, α-methyl ester sulfonates, sulfo fatty acids, Alkyl sulfates, fatty alcohol ether sulfates, glycerol ether sulfates, hydroxy mixed ether sulfates, monoglyceride (ether) sulfates, fatty acid amide (ether) sulfates, mono- and dialkyl sulfosuccinates, Mono- and dialkylsulfosuccinamates, sulfotriglyceride, amide soaps, ether carboxylic acids and their salts, fatty acid isethionates, fatty acid sarcosinates, fatty acid taurides, N-acyl amino acids, such as acyl lactylates, acyl tartrates, acyl glutamates and acyl partates, alkyl oligoglucoside sulfates, protein fatty acid condensates (especially wheat-based vegetable products) and alkyl (ether) phosphates. If the anionic surfactants contain polyglycol ether chains, these may have a conventional, but preferably a narrowed homolog distribution. Examples of non-ionic surfactants are fatty alcohol polyglycol ethers, alkylphenol polyglycol ethers, fatty acid polyglycol esters, fatty acid amide polyglycol ethers, fatty amine polyglycol ethers, alkoxylated triglycerides, mixed ethers or Mixed formals, optionally partially oxidized alk(en)yl oligoglycosides or glucoronic acid derivatives, fatty acid N-alkylglucamides, protein hydrolysates (in particular wheat-based vegetable products), polyol fatty acid esters, sugar esters, sorbitan esters, polysorbates and amine oxides. Where the nonionic surfactants contain polyglycol ether chains, these may have a conventional, but preferably a narrowed homolog distribution. Examples of cationic surfactants are quaternary ammonium compounds and esterquats, in particular quaternized fatty acid trialkanolamine ester salts. Typical examples of amphoteric or zwitterionic surfactants are alkyl betaines, alkylamidobetaines, aminopropionates, aminoglycinates, imidazolinium betaines and sulfobetaines. The surfactants mentioned are exclusively known compounds. With regard to the structure and production of these substances, reference should be made to relevant reviews, for example J. Falbe (ed.), “Surfactants in Consumer Products”, Springer Verlag, Berlin, 1987, pp. 54-124 or J. Falbe (ed.), “Katalysatoren, Tenside and Mineraloladditive”, Thieme Verlag, Stuttgart, 1978, pp. 123-217.

[0031] Preferred surfactants or emulsifiers or also surface-active substances are PEG derivatives of hydrogenated castor oil, which are available, for example, under the designation PEG Hydrogenated Castor Oil, e.g. PEG-30 Hydrogenated Castor Oil, PEG-33 Hydrogenated Castor Oil, PEG-35 Hydrogenated Castor Oil, PEG-36 Hydrogenated Castor Oil, PEG-40 Hydrogenated Castor Oil or PEG-60 Hydrogenated Castor Oil. Preferred is PEG-60 Hydrogenated Castor Oil.

[0032] The proportion of the at least one surfactant in the styling composition is preferably 0.05 to 3.5% by weight, particularly preferably 0.1 to 2.5% by weight, most preferably 0.2 to 1.0% by weight, based on the total proportion of the styling composition.

[0033] Preferably, the at least one disaccharide is included in the styling composition at a level of 1.0 to 13.0% by weight, preferably 2.0 to 10.0% by weight, more preferably 3.0 to 8.0% by weight, even more preferably 3.5 to 6.0% by weight, based on the total amount of the styling composition.

[0034] Preferably, the at least one alkali salt and/or alkaline earth salt is present in the styling composition in a proportion of 0.5 to 15.0% by weight, preferably 1.0 to 10.0% by weight, particularly preferably 1.5 to 8.0% by weight, even more preferably 2.0 to 5.0% by weight, based on the total proportion of the styling composition.

[0035] In a preferred embodiment, the proportion of the at least one disaccharide is greater than the proportion of the at least one alkali salt and/or alkaline earth salt.

[0036] Preferably, the proportion of the at least one disaccharide in the styling composition is at least 1.1-fold, more preferably at least 1.2-fold, very particularly preferably at least 1.3-fold greater than the proportion of the at least one alkali salt and/or alkaline earth salt included in the styling composition, preferably than the total proportion of all alkali salts and/or alkaline earth salts included in the styling composition.

[0037] Preferably, the composition comprises at least two different alkali salts and/or alkaline earth salts.

[0038] Preferably, in the styling composition the first of the at least two different alkali salts and/or alkaline earth salts is present in a proportion of 0.5 to 20.0% by weight, preferably 1.0 to 17.0% by weight, particularly preferably 1.5 to 15.0% by weight, even more preferably 2.0 to 13.0% by weight, based on the total amount of the styling composition, and the second of the at least two different alkali salts and/or alkaline earth salts is present in a proportion of 0.01 to 5.5% by weight, preferably 0.02 to 4.5% by weight, particularly preferably 0.03 to 4.0% by weight, even more preferably 0.04 to 3.5% by weight, in particular preferably 0.05 to 3.0% by weight, based on the total amount of the styling composition.

[0039] In a particular embodiment of the present disclosure, the proportions of the at least two different alkali salts and/or alkaline earth salts are selected from the above-mentioned preferred ranges so that they are equal. Equal means a ratio of at least two different alkali salts and/or alkaline earth salts of 1:1.

[0040] In a particular embodiment, the proportion of the at least one disaccharide, preferably sucrose, is greater than the proportion of the at least two different, preferably greater than the proportion of all alkali salts and/or alkaline earth salts included in the styling composition.

[0041] Preferably, the composition comprises at least one alkali salt and/or alkaline earth salt of chloride and one alkali salt and/or alkaline earth salt of sulfate, particularly preferably the composition comprises sodium chloride and magnesium sulfate.

[0042] Preferably, in the styling composition, the at least one alkali salt and/or alkaline earth salt of the sulfate, preferably the magnesium sulfate, is present in a proportion of 0.5 to 20.0% by weight, preferably 1.0 to 17.0% by weight, particularly preferably 1.5 to 15.0% by weight, even more preferably 2.0 to 13.0% by weight%, based on the total proportion of the styling composition, and the at least one alkali salt and/or alkaline earth salt of the chloride, preferably the sodium chloride, is present in the styling composition in a proportion of 0.01 to 5.5% by weight, preferably 0.02 to 4.5% by weight, particularly preferably 0.03 to 4.0% by weight, even more preferably 0.04 to 3.5% by weight, especially preferably 0.05 to 3.0% by weight, based on the total proportion of the styling composition.

[0043] In a preferred embodiment, the proportion of the at least one disaccharide, preferably sucrose, is greater than the proportion of the at least one alkali salt and/or alkaline earth salt of the chloride, preferably sodium chloride. Preferably, in this embodiment, the proportion of the at least one disaccharide, preferably sucrose, in the styling composition is at least 15-fold, more preferably at least 25-fold, most preferably at least 45-fold, even more preferably at least 65-fold, most preferably at least 75-fold greater than the proportion of the at least one alkali salt and/or alkaline earth salt of the chloride, preferably than the proportion of sodium chloride.

[0044] In a preferred embodiment, the proportion of the at least one disaccharide, preferably sucrose, is greater than the proportion of the at least one alkali salt and/or alkaline earth salt of the sulfate, preferably magnesium sulfate. Preferably, the proportion of the at least one disaccharide, preferably sucrose, in the styling composition is at least 1.1-fold, more preferably at least 1.2-fold, most preferably at least 1.3-fold, greater than the proportion of the at least one alkali salt and/or alkaline earth salt of the sulfate, preferably than the proportion of magnesium sulfate.

[0045] Furthermore, the styling composition may contain pH adjusting agents. Preferred agents are, for example, primary amino alcohols such as aminomethyl propanol (INCI), which is commercially available under the name AMP-ULTRA© PC, for example AMP-ULTRA© PC 2000. Further agents for adjusting the pH can be selected from alkali hydroxides, in particular sodium hydroxide and potassium hydroxide, organic acids, such as lactic acid, citric acid, hydrochloric acid, sulfuric acid, phosphoric acid, adipic acid, hydroxysuccinic acid, succinic acid, tartaric acid or malic acid, in particular from tetrahydroxypropyl ethylenediamine, known under the trade name Neutrol TE, and triethylamine (TEA). The proportion of the pH-adjusting agents in the styling composition is preferably 0.01 to 1.0% by weight, particularly preferably 0.05 to 0.1% by weight, most preferably 0.05 to 0.08% by weight, based on the total proportion of the styling composition.

[0046] Furthermore, the styling composition may contain a preservative, in particular those listed in the Cosmetic Products Regulation in Annex V (Regulation (EC) No 122+3/2009 of the European Parliament and of the Council of 30 Nov. 2009 on cosmetic products), especially preferably benzoic acid, benzoates and mixtures thereof, especially preferably sodium benzoate.

[0047] The proportion of preservatives in the styling composition is preferably 0.05 to 1.0% by weight, particularly preferably 0.075 to 0.6% by weight, most preferably 0.1 to 0.4% by weight, based on the total proportion of the styling composition.

[0048] Preferably, the styling composition is used to reshape keratinous fibers. Furthermore, it is preferably used for texturizing keratinous fibers, especially human scalp hair. Texturing, as contemplated herein, refers to changing the quality of the hair surface of a hairstyle.

[0049] It has been shown that the combination of components as contemplated herein results in a styling composition that meets the current increasing consumer demand for products with natural ingredients and, at the same time, is particularly well suited for temporarily reshaping keratinous fibers, preferably human scalp hair, while keeping the hairstyle in the desired shape, at the same time retaining its lightness and appearing neither weighed down nor stiff.

Analyzed Example

[0050] The composition of some other preferred styling compositions can be found in the following tables (data in % by weight based on the total weight of the styling composition unless otherwise stated).

TABLE-US-00001 Component Formula 1 Formula 2 Formula 3 Formula 4 Formula 5 Disaccharide  0.5-15.0 1.0-13.0 2.0-10.0 3.0-8.0 3.5-6.0 Alkali salt and/ 0.01-20.0 0.5-15.0 1.0-10.0 1.5-8.0 2.0-5.0 or alkaline earth salt synthetic, 0.0 0.0 0.0 0.0 0.0 film-forming polymers optional com- ad. 100 ad. 100 ad. 100 ad. 100 ad. 100 ponents and water

TABLE-US-00002 Component Formula 6 Formula 7 Formula 8 Formula 9 Formula 10 Sucrose  0.5-15.0 1.0-13.0 2.0-10.0 3.0-8.0 3.5-6.0 Alkali 0.01-20.0 0.5-15.0 1.0-10.0 1.5-8.0 2.0-5.0 salt and/ or alkaline earth salt synthetic, 0.0 0.0 0.0 0.0 0.0 film-forming polymers optional ad. 100 ad. 100 ad. 100 ad. 100 ad. 100 components and water

TABLE-US-00003 Component Formula 11 Formula 12 Formula 13 Formula 14 Formula 15 Disaccharide  0.5-15.0 1.0-13.0 2.0-10.0 3.0-8.0 3.5-6.0 Magnesium sulfate 0.01-20.0 0.5-15.0 1.0-10.0 1.5-8.0 2.0-5.0 synthetic, film-forming 0.0 0.0 0.0 0.0 0.0 polymers optional components ad. 100 ad. 100 ad. 100 ad. 100 ad. 100 and water

TABLE-US-00004 Component Formula 16 Formula 17 Formula 18 Formula 19 Formula 20 Sucrose  0.5-15.0 1.0-13.0 2.0-10.0 3.0-8.0 3.5-6.0 Magnesium sulfate 0.01-20.0 0.5-15.0 1.0-10.0 1.5-8.0 2.0-5.0 synthetic, film-forming 0.0 0.0 0.0 0.0 0.0 polymers optional components ad. 100 ad. 100 ad. 100 ad. 100 ad. 100 and water

TABLE-US-00005 Component Formula 21 Formula 22 Formula 23 Formula 24 Formula 25 Disaccharide  0.5-15.0  1.0-13.0  2.0-10.0 3.0-8.0 3.5-6.0 Alkali salt and/or 0.01-20.0  0.5-17.0  1.0-15.0  1.5-13.0  2.0-11.0 alkaline earth salt of sulfate synthetic, film-forming 0.0 0.0 0.0 0.0 0.0 polymers Alkali salt and/or 0.01-5.5  0.02-4.5  0.03-4.0  0.04-3.5  0.05-3.0  alkaline earth salt of chloride optional components ad. 100 ad. 100 ad. 100 ad. 100 ad. 100 and water

TABLE-US-00006 Component Formula 26 Formula 27 Formula 28 Formula 29 Formula 30 Sucrose  0.5-15.0  1.0-13.0  2.0-10.0 3.0-8.0 3.5-6.0 Alkali salt and/or 0.01-20.0  0.5-17.0  1.0-15.0  1.5-13.0  2.0-11.0 alkaline earth salt of sulfate synthetic, film-forming 0.0 0.0 0.0 0.0 0.0 polymers Alkali salt and/or 0.01-5.5  0.02-4.5  0.03-4.0  0.04-3.5  0.05-3.0  alkaline earth salt of chloride optional components ad. 100 ad. 100 ad. 100 ad. 100 ad. 100 and water

TABLE-US-00007 Component Formula 31 Formula 32 Formula 33 Formula 34 Formula 35 Sucrose  0.5-15.0  1.0-13.0  2.0-10.0 3.0-8.0 3.5-6.0 Magnesium sulfate 0.01-20.0  0.5-17.0  1.0-15.0  1.5-13.0  2.0-11.0 synthetic, film-forming 0.0 0.0 0.0 0.0 0.0 polymers Alkali salt and/or 0.01-5.5  0.02-4.5  0.03-4.0  0.04-3.5  0.05-3.0  alkaline earth salt of chloride optional components ad. 100 ad. 100 ad. 100 ad. 100 ad. 100 and water

TABLE-US-00008 Component Formula 36 Formula 37 Formula 38 Formula 39 Formula 40 Sucrose  0.5-15.0  1.0-13.0  2.0-10.0 3.0-8.0 3.5-6.0 Magnesium sulfate 0.01-20.0  0.5-17.0  1.0-15.0  1.5-13.0  2.0-11.0 synthetic, film-forming 0.0 0.0 0.0 0.0 0.0 polymers Sodium chloride 0.01-5.5  0.02-4.5  0.03-4.0  0.04-3.5  0.05-3.0  optional components ad. 100 ad. 100 ad. 100 ad. 100 ad. 100 and water

TABLE-US-00009 Component Formula 41 Formula 42 Formula 43 Formula 44 Formula 45 Sucrose  0.5-15.0  1.0-13.0  2.0-10.0 3.0-8.0 3.5-6.0 Magnesium sulfate 0.01-20.0  0.5-17.0  1.0-15.0  1.5-13.0  2.0-11.0 synthetic, film-forming 0.0 0.0 0.0 0.0 0.0 polymers Sodium chloride 0.01-5.5  0.02-4.5  0.03-4.0  0.04-3.5  0.05-3.0  Surfactant 0.05-3.5  0.10-2.5  0.15-2.0  0.2-1.5 0.2-1.0 optional components ad. 100 ad. 100 ad. 100 ad. 100 ad. 100 and water

TABLE-US-00010 Component Formula 46 Formula 47 Formula 48 Formula 49 Formula 50 Sucrose  0.5-15.0  1.0-13.0  2.0-10.0 3.0-8.0 3.5-6.0 Magnesium sulfate 0.01-20.0  0.5-17.0  1.0-15.0  1.5-13.0  2.0-11.0 synthetic, film-forming 0.0 0.0 0.0 0.0 0.0 polymers Sodium chloride 0.01-5.5  0.02-4.5  0.03-4.0  0.04-3.5  0.05-3.0  nonionic surfactant 0.05-3.5  0.10-2.5  0.15-2.0  0.2-1.5 0.2-1.0 optional components ad. 100 ad. 100 ad. 100 ad. 100 ad. 100 and water

TABLE-US-00011 Component Formula 51 Formula 52 Formula 53 Formula 54 Formula 55 Sucrose  0.5-15.0  1.0-13.0  2.0-10.0 3.0-8.0 3.5-6.0 Magnesium sulfate 0.01-20.0  0.5-17.0  1.0-15.0  1.5-13.0  2.0-11.0 synthetic, film-forming 0.0 0.0 0.0 0.0 0.0 polymers Sodium chloride  0.01-5.5 0.02-4.5  0.03-4.0  0.04-3.5  0.05-3.0  PEG-60 Hydrogenated  0.05-3.5 0.10-2.5  0.15-2.0  0.2-1.5 0.2-1.0 Castor Oil optional components ad. 100 ad. 100 ad. 100 ad. 100 ad. 100 and water

[0051] While at least one exemplary embodiment has been presented in the foregoing detailed description, it should be appreciated that a vast number of variations exist. It should also be appreciated that the exemplary embodiment or exemplary embodiments are only examples, and are not intended to limit the scope, applicability, or configuration of the various embodiments in any way. Rather, the foregoing detailed description will provide those skilled in the art with a convenient road map for implementing an exemplary embodiment as contemplated herein. It being understood that various changes may be made in the function and arrangement of elements described in an exemplary embodiment without departing from the scope of the various embodiments as set forth in the appended claims.