ADDITIVE MANUFACTURING OF METALENSES
20230022275 · 2023-01-26
Assignee
Inventors
Cpc classification
B33Y10/00
PERFORMING OPERATIONS; TRANSPORTING
B33Y80/00
PERFORMING OPERATIONS; TRANSPORTING
International classification
G02B1/00
PHYSICS
B33Y10/00
PERFORMING OPERATIONS; TRANSPORTING
Abstract
A method of manufacturing an optical element is disclosed. The method comprises the steps of forming a layer of first material on a substrate, forming a plurality of cavities in the layer of first material by an imprinting process, and forming a layer of second material in the plurality of cavities to form an optical meta-surface. Also disclosed is an optical element manufactured according to the method, and an optical device comprising the optical element, and an optical apparatus such as a cellular telephone, a camera, an image-recording device, or a video recording device.
Claims
1. A method of manufacturing an optical element, the method comprising the steps of: forming a layer of first material on a substrate; forming a plurality of cavities in the layer of first material by an imprinting process; and forming a layer of second material in the plurality of cavities to form an optical meta-surface.
2. The method of claim 1, wherein the imprinting process comprises: directly imprinting the plurality of cavities into the layer of first material; or imprinting a pattern corresponding to the plurality of cavities into a mask layer formed on the layer of first material, and subsequently etching the layer of first material to form the plurality of cavities.
3. The method of claim 1, wherein the step of forming the layer of second material comprises selectively growing or selectively depositing the second material.
4. The method of claim 3 comprising a subsequent step of removing the layer of first material from the substrate such that the layer of second material defines a plurality of columns, pillars, ridges, fins and/or mesas extending from the substrate.
5. The method of claim 1, wherein the step of forming the layer of second material comprises application of a coating to the layer of first material.
6. The method of claim 5, wherein the layer of second material forms: a substantially planar surface over the layer of first material and the plurality of cavities; and/or a layer of substantially uniform thickness over the layer of first material; and/or a layer conforming to a profile of the cavities in the layer of first material.
7. The method of claim 1 comprising a subsequent step of forming a layer of a third material over the layer of the second material, wherein: the third material has a refractive index different from the second material; and/or the layer of a third material conforms to a profile of the layer of the second material.
8. The method of claim 1, wherein the second material has a refractive index greater than the refractive index of the first material.
9. The method of claim 1, wherein the second material has a refractive index greater than 2.
10. The method of claim 1 wherein the plurality of cavities are formed in a substantially concentric arrangement and/or the plurality of cavities are arranged in a pattern of substantially concentric groups.
11. The method of claim 1, wherein at least one of: the layer of second material has a thickness of less than 100 nanometers; the plurality of cavities are arranged with less than 500 nanometers separations; the plurality of cavities have varying orientations in a plane defined by the substrate.
12. The method of claim 1, comprising a preceding step of forming a seed layer on the substrate, and optionally wherein the seed layer comprises the second material.
13. The method of claim 1, wherein the step of forming the layer of second material comprises at least one of: atomic layer deposition; chemical vapor deposition; physical vapor deposition; and/or epitaxial growth.
14. The method of claim 1, wherein the first and/or second material comprises gallium nitride, silicon nitride, or a titanium oxide and, when dependent upon claim 8, wherein the third material comprises gallium nitride, silicon nitride, or a titanium oxide.
15. An optical element manufactured according to the method of claim 1.
16. The optical element of claim 15, configured as a metalens.
17. The optical element of claim 15, wherein the optical element is configured for operation in at least a portion of a visible light range and/or a near infrared range.
18. An optical device comprising at least one optical element according to claim 15, the optical device further comprising a radiation sensor and/or a radiation source, wherein the at least one optical element is configured for use with the radiation sensor and/or the radiation source.
19. An apparatus comprising an optical device according to claim 18, wherein the apparatus is at least one of: a cellular telephone, a camera, an image-recording device; and/or a video recording device.
Description
BRIEF DESCRIPTION OF DRAWINGS
[0050] These and other aspects of the present disclosure will now be described, by way of example only, with reference to the accompanying drawings, which show:
[0051]
[0052]
[0053]
[0054]
[0055]
[0056]
[0057]
[0058]
DETAILED DESCRIPTION OF DRAWINGS
[0059]
[0060] In a first step a layer of first material 105 is formed on a substrate 110. The layer of first material 105 may comprise a curable material. For example, the curable material may be an Ultra Violet (UV) radiation curable material or a thermally curable material.
[0061] In an optional preceding step, a seed layer may formed on the substrate 110. The seed layer may be formed, for example, by atomic layer deposition; chemical vapor deposition, physical vapor deposition and/or epitaxial growth. The seed layer may comprise a material suitable for a second material to be formed on, e.g. epitaxially grown on, or the like, wherein the second material is described in more detail below. The seed layer may comprise the second material. In another method, the substrate 110 may be provided as an ‘epi-ready’ substrate e.g. a substrate 110 that has been pre-treated with a seed layer.
[0062] In this particular embodiment, the substrate 110 comprises silicon. In another embodiment the substrate 110 may comprise, for example, fused silica, sapphire, or any glass such as a silica-based glass.
[0063] The first material may comprise a polymer, e.g. a thermoplastic polymer or the like.
[0064] The layer of first material 105 may be formed or deposited on the substrate 110 by spin-coating the substrate 110. In some embodiments, the layer of first material 105 may be deposited, such as by evaporation, onto the substrate 110. In some embodiments, the substrate 110 may be dipped or otherwise submerged in the first material, wherein the first material is in a liquid state, to form the layer of first material 105 on the substrate 110.
[0065] The layer of first material 105 may be applied to the substrate 110 in a liquid state. For example, the first material may be heated until the first material transitions to a liquid state, prior to application of the layer of first material 105 to the substrate 110.
[0066] The layer of first material 105 may comprise a resist material.
[0067] The layer of first material 105 may be formed on a portion of a surface, e.g. an upper surface, of the substrate 110. In some embodiments, the layer of first material 105 may be formed on all, or substantially all, of a surface of the substrate 110.
[0068] In a next step also depicted in
[0069] The plurality of cavities 115 may be formed by directly imprinting the plurality of cavities 115 into the layer of first material 105. For example, the plurality of cavities 115 may be formed by a process of imprinting, e.g. a process of nanoimprint lithography as described in more detail below.
[0070] In one example embodiment, the plurality of cavities 115 may be formed by a process of thermoplastic nanoimprint lithography. That is, the layer of first material 105 is coated onto the substrate 110, and then a mold (not shown) comprising a predefined topological pattern is pressed onto the layer of first material 105. The layer of first material 105 is then heated directly and/or heated via the substrate 110 and/or heated via the mold, such that the layer of first material 105 is softened. The topological pattern on the mold is then pressed into the softened layer of first material 105, thus transferring a pattern corresponding to the predefined topological patterns of the mold to the layer of first material 105. As shown in
[0071] In another example embodiment, the plurality of cavities 115 are formed by a process of photo-nanoimprint lithography. That is, the layer of first material 105 is coated onto the substrate 110, wherein the layer of first material 105 comprises a photo-curable material. At this stage, the layer of first material 105 may be in a substantially malleable, softened, or liquid state. Then, the mold comprising the predefined topological patterns is pressed onto the layer of first material 105. The layer of first material is subsequently cured by exposure to radiation, such as Ultra Violet (UV) radiation. The mold may, for example, be transparent to radiation at wavelengths suitable for curing the layer of first material 105. After curing of the first material, the mold may be separated from the layer of first material 105.
[0072] As shown in
[0073] In an example embodiment, the residual layer 120 may be removed from the substrate 110 by a plasma descum process, such as a descum process employing an oxygen plasma or a high power argon plasma. As a result of the descum process, portions of the substrate 110 corresponding to the plurality of cavities 115 will be exposed, as shown in
[0074] The plurality of cavities 115 may be formed in a defined arrangement, e.g. with defined geometries and orientations, such that a resultant meta-surface formed from the cavities (as described in more detail below with respect for Figures lc and 1d) may have a desired effect upon incident radiation. For example, in one embodiment, the plurality of cavities 115 may be provided in a substantially concentric arrangement and/or the plurality of cavities 115 may be arranged in a pattern of substantially concentric groups.
[0075] In one example embodiment, the plurality of cavities 115 may be arranged with less than 1 micrometer separations. In another embodiment, the plurality of cavities 115 may be arranged with less than 500 nanometer separations. In one example embodiment, the layer of first material 105 may have a thickness of less than 500 nanometers. In another embodiment, the layer of first material 105 may have a thickness of less than 100 nanometers.
[0076] In a next step shown in
[0077] In one embodiment, the layer of second material 125 comprises gallium nitride. In other embodiments, the layer of second material 125 may, for example, comprise silicon, silicon dioxide, silicon nitride, titanium oxide, or the like.
[0078] The first and/or second material may be transparent, or substantially transparent to radiation with wavelengths in a visible light range and/or a near infrared range, e.g. approximately 380 to 740 nanometers. Additionally and/or alternatively, the first and/or second material may be transparent, or substantially transparent to radiation with wavelengths in the UV, near infrared, short, mid or long wavelength infrared, or far infrared range. In a particular embodiment, dimensions of the plurality of cavities 115, e.g. lateral and/or vertical dimensions and/or spacing between cavities may be smaller than a wavelength of radiation to which the first and/or second material is transparent.
[0079] In one embodiment, the layer of second material 125 is formed by a process of selective growth. As shown in
[0080] The process of selective growth of the layer of second material 125 may comprise a process of selective chemical vapor deposition. In other embodiments, other deposition processes may be used. For example, the process of selective growth of the layer of second material 125 may alternatively, or additionally, comprise a process of physical vapor deposition and/or epitaxial growth.
[0081] In a further optional step shown in
[0082] Advantageously, the process of imprinting the layer of first material 105 to form a plurality of cavities 115, together with a subsequent selective growth of a layer of second material 125 in the plurality of cavities 115 results in a plurality of columns, pillars, ridges, fins and/or mesas extending from the substrate 110 with extremely well-defined sidewalls. That is, the sidewalls of any columns, pillars, ridges, fins and/or mesas may for example be at, or close to, substantially 90 degrees relative to a surface of the substrate 110. That is, the sidewalls of any columns, pillars, ridges, fins and/or mesas may be substantially vertically oriented relative to a horizontal plane of an upper surface of the substrate 110.
[0083] Beneficially, by adhering to the method described with respect to and/or depicted in
[0084] In yet further embodiments (not shown) additional coatings or layers may be subsequently deposited over the layer of second material 125, wherein the additional coatings and/or layers may comprise a refractive index that is substantially different from the refractive index of the second material.
[0085] The optical element depicted in
[0086]
[0087] In a first step a layer of first material 205 is formed on a substrate 210. The layer of first material 205 may comprise a curable material. For example, the curable material may be an Ultra Violet (UV) radiation curable material or a thermally curable material.
[0088] In a next step also depicted in
[0089] In a next step, a residual layer 220 may be removed from the substrate 210, for example by a process of plasma descum or the like.
[0090] The steps shown in
[0091] In a next step shown in
[0092] In some embodiments, the second material has a substantially different refractive index than the refractive index of the first material. For example, in a one embodiment the second material may have a refractive index that differs from a refractive index of the first material by at least 1. In some embodiments, the second material may have a refractive index that differs from a refractive index of the first material by 1.5, 2, 2.5 or more.
[0093] The layer of second material 225 may be at least partially formed by, for example, atomic layer deposition, chemical vapor deposition, physical vapor deposition and/or epitaxial growth. Additionally and/or alternatively, the layer of second material 225 may be at least partially formed by spin-coating the layer of second material 225 onto the layer of first material 205.
[0094] In contrast to the embodiment described with respect to
[0095] The planar surface 230 may be particularly suited to mounting of further optical components, as will be described in more detail with reference to
[0096] The optical element depicted in
[0097]
[0098] The steps shown in
[0099] In a next step shown in
[0100] The layer of second material 325 may be formed by, for example, atomic layer deposition, chemical vapor deposition, physical vapor deposition and/or epitaxial growth. Again, in contrast to the embodiment described with respect to
[0101] In one embodiment, the layer of second material 325 may be substantially uniformly formed on the both the layer of first material 305 and in the plurality of cavities 315 formed in the layer of first material 305. That is, the layer of second material 325 may comprise a substantially uniform thickness.
[0102] The layer of second material 325 may comprise a plurality of cavities 330 corresponding to the plurality of cavities 315 in the layer of first material 325. That is, due to the layer of second material substantially conforming to the geometric profile of the layer of first material 325, the layer of second material 325 comprises cavities, as shown in
[0103] In an optional additional step, a layer of third material 335 may be formed over the layer of the second material 325, as shown in
[0104] The third material may be selected to comprise a refractive index different from the second and/or first material. For example, in some embodiments, the third material may have a refractive index that differs from a refractive index of the second and/or first material by 1, or more.
[0105] The planar surface 340 may be particularly suited to mounting of further optical components, as will be described in more detail with reference to
[0106] The optical element depicted in
[0107]
[0108] In an optional first step depicted in
[0109] In a next step depicted in
[0110] As depicted in
[0111] The layer of first material 405 may be formed or deposited on the substrate 410 (or seed layer 450) by spin-coating the substrate 410. In some embodiments, the layer of first material 405 may be deposited, such as by evaporation, on the substrate 410 (or seed layer 450), for example by atomic layer deposition, chemical vapor deposition, physical vapor deposition and/or epitaxial growth.
[0112] The mask layer 455 may be formed or deposited on the layer of first material 405 by spin-coating the layer of first material 405. Alternatively, the mask layer 455 may be deposited on the layer of first material 405, for example by atomic layer deposition, chemical vapor deposition, physical vapor deposition and/or epitaxial growth.
[0113] As depicted in
[0114] As depicted in
[0115] In subsequent steps depicted in
[0116] The remaining steps of selective growth of a layer of second material 425 as depicted in
[0117] The optical element depicted in
[0118] The optical element 570 may be coupled to and/or combined with a further optical component 575, as shown in
[0119] The further optical component 575 may for example be a Micro-Lens Array (MLA), a diffuser, a Diffractive Optical Element (DOE), a Fresnel lens, a refractive lens, or the like.
[0120] In a further example embodiment shown in
[0121]
[0122]
[0123] The example optical device 700 comprises a radiation source 710. The radiation source 710 may comprise a light emitting diode.
[0124] The radiation source 710 and the optical element 705 are supported by a supporting member 715. It will be appreciated that in other embodiments, the supporting member 715 may have a different configuration. For example, the supporting member 715 may comprise one or more spacer elements for spacing the radiation source 710 from the optical element 705.
[0125] In yet further embodiments, the radiation source 710 and the optical element 705 may be directly coupled, e.g. held immediately adjacent one another by the supporting member 715. In yet further embodiments, the optical device 700 may not comprise a supporting member 715, and instead the radiation source 710 and the optical element 705 may be directly coupled, such as by adhesion or otherwise. In yet further embodiments, the optical element 705 may be formed directly upon the radiation source 710.
[0126] The radiation source 710 may be configured to emit radiation 720. In the example embodiment of
[0127] The optical element 705 may alter the incident radiation 720, resulting in emitted radiation 725 emitted by the optical device 700. For example, the optical element 705 may be configured to alter a phase of incident radiation 720. In other embodiments the optical element 705 may be configured to additionally or alternatively at least one of filter, focus or disperse incident radiation 720.
[0128]
[0129] The example optical device 750 comprises a radiation sensor 760. The radiation sensor 760 may comprise, for example, a photodiode. The radiation sensor 760 may comprise an active pixel sensor. The radiation sensor 760 may comprise an array of sensors.
[0130] The radiation sensor 760 and the optical element 765 are supported by a supporting member 765. It will be appreciated that in other embodiments, the supporting member 765 may have a different configuration. For example, the supporting member 765 may comprise one or more spacer elements for spacing the radiation sensor 760 from the optical element 755.
[0131] In yet further embodiments, the radiation sensor 760 and the optical element 755 may be directly coupled, e.g. held adjacent one another by the supporting member 765. In yet further embodiments, the optical device 750 may not comprise a supporting member 765, and instead the radiation sensor 760 and the optical element 755 may be directly coupled, such as by adhesion or otherwise. In yet further embodiments, the optical element 755 may be formed directly upon the radiation sensor 760.
[0132] The optical element 705 may be configured to alter radiation 725 incident upon the optical element 705. For example, the optical element 705 may be configured to alter radiation 725, such that radiation 770 incident upon the radiation sensor 760 exhibits different characteristics from the radiation 775 incident upon the optical element 705. For example, the optical element 755 may be configured to alter a phase of incident radiation 775. In other embodiments, the optical element 705 may alternatively or additionally be configured to at least one of filter, focus or disperse the incident radiation 775. In a particular embodiment, the optical element 755 may be configured to focus radiation 775 such that a focal point of radiation 770 is incident upon the radiation sensor 760.
[0133]
[0134] The example optical device 800 comprises a radiation source 810. The radiation source 810 may comprise a light emitting diode.
[0135] The example optical device 800 comprises a radiation sensor 840. The radiation sensor 840 may comprise, for example, a photodiode. The radiation sensor 840 may comprise an active pixel sensor. The radiation sensor 840 may comprise an array of sensors.
[0136] The radiation source 810, the radiation sensor 840, and/or the optical element 805 may be supported by a supporting member 815. It will be appreciated that in other embodiments, the supporting member 815 may have a different configuration. For example, the supporting member 815 may comprise one or more spacer elements for spacing the radiation source 810 and/or the radiation sensor 840 from the optical element 805.
[0137] The radiation source 810 may be configured to emit radiation 820. In the example embodiment of
[0138] The optical element 805 may alter the incident radiation 820, resulting in emitted radiation 825 emitted by the optical device 800. For example, the optical element 805 may be configured to alter a phase of incident radiation 820. In other embodiments the optical element 805 may be configured to additionally or alternatively at least one of filter, focus or disperse incident radiation 820.
[0139] Additionally or alternatively, the optical element 805 may reflect at least a portion of the incident radiation. A reflected portion 830 of the incident radiation may be sensed by the radiation sensor 840.
[0140] Additionally or alternatively, the optical element 805 may be configured to alter radiation 835 incident upon the optical element 805 from outside the optical device 800. For example, the optical element 805 may be configured to alter radiation 835, such that radiation 830 incident upon the radiation sensor 840 exhibits different characteristics from the radiation 835 incident upon the optical element 805 from outside the optical device 800. For example, the optical element 805 may be configured to alter a phase of incident radiation 835. In other embodiments, the optical element 805 may alternatively or additionally be configured to at least one of filter, focus or disperse the incident radiation 835. In a particular embodiment, the optical element 805 may be configured to focus radiation 835 such that a focal point of radiation 830 is incident upon the radiation sensor 840.
[0141]
[0142] That is, in embodiments of the disclosure, a plurality of optical elements may be formed on a common substrate, by forming a plurality of optical meta-surfaces on the common substrate. The plurality of optical meta-surfaces may comprise one or more optical meta-surfaces with the same characteristics. The plurality of optical meta-surfaces may comprise one or more optical meta-surfaces with the different characteristics.
[0143] For purposes of example only,
[0144] For purposes of example only, first and second optical elements 855, 860 are depicted as disposed, e.g. formed, on a lower surface of the common substrate 865. It will be appreciated that one or more meta-surfaces may alternatively and/or additionally be disposed, e.g. formed, on an upper surface of the common substrate 865. Similarly, the optical elements 705, 755, 705 depicted in
[0145]
[0146] The optical device 905 is communicably coupled to processor circuitry 910. The processor circuitry 910 is configured to receive a signal from the optical device 905 and/or provide a signal and/or power to the optical device 905. The apparatus 900 is, for purposes of example only, a cellular phone. It will be appreciated that, in other examples, the apparatus 900 may be a digital camera, a security camera, a laptop or tablet device, an image recording device, or the like.
[0147] The applicant discloses in isolation each individual feature described herein and any combination of two or more such features, to the extent that such features or combinations are capable of being carried out based on the specification as a whole in the light of the common general knowledge of a person skilled in the art, irrespective of whether such features or combinations of features solve any problems disclosed herein, and without limitation to the scope of the claims. The applicant indicates that aspects of the disclosure may consist of any such individual feature or combination of features. In view of the foregoing description it will be evident to a person skilled in the art that various modifications may be made within the scope of the disclosure.
[0148] The skilled person will understand that in the preceding description and appended claims, positional terms such as ‘above’, ‘along’, ‘side’, etc. are made with reference to conceptual illustrations, such as those shown in the appended drawings. These terms are used for ease of reference but are not intended to be of limiting nature. These terms are therefore to be understood as referring to an object when in an orientation as shown in the accompanying drawings.
[0149] Although the disclosure has been described in terms of particular embodiments as set forth above, it should be understood that these embodiments are illustrative only and that the claims are not limited to those embodiments. Those skilled in the art will be able to make modifications and alternatives in view of the disclosure, which are contemplated as falling within the scope of the appended claims. Each feature disclosed or illustrated in the present specification may be incorporated in any embodiments, whether alone or in any appropriate combination with any other feature disclosed or illustrated herein.
TABLE-US-00001 LIST OF REFERENCE NUMERALS 105 layer of first material 450 seed layer 110 substrate 455 mask layer 115 plurality of cavities 460 plurality of cavities 120 residual layer 570 optical element 125 layer of second material 40 575 optical component 205 layer of first material 580 optical component 210 substrate 600 first step 215 plurality of cavities 605 subsequent step 220 residual layer 610 subsequent step 225 layer of second material 45 700 optical device 230 planar surface 705 optical element 305 layer of first material 710 radiation source 310 substrate 715 supporting member 315 plurality of cavities 720 radiation 325 layer of second material 50 725 radiation 330 plurality of cavities 750 optical device 335 layer of third material 755 optical element 340 planar surface 760 radiation sensor 405 layer of first material 765 supporting member 410 substrate 55 770 radiation 415 plurality of cavities 775 radiation 420 residual layer 800 optical device 425 layer of second material 805 optical element 810 radiation source 855 first optical element 840 radiation sensor 10 860 second optical element 815 supporting member 865 common substrate 820 incident radiation 870 radiation sensor 825 emitted radiation 875 radiation source 830 reflected portion 900 apparatus 835 radiation 15 905 optical device 850 optical device 910 processor circuitry