Fabric with degradable sensor
10613047 ยท 2020-04-07
Assignee
Inventors
- Ozgur Cobanoglu (Inegol-Bursa, TR)
- Jitka Eryilmaz (Inegol-Bursa, TR)
- Ozgur Akdemir (Inegol-Bursa, TR)
- Deniz Iyidogan (Inegol-Bursa, TR)
- Onur Yukselen (Inegol-Bursa, FR)
Cpc classification
G06K19/0717
PHYSICS
International classification
Abstract
A fabric comprising at least one conductive element to define at least one portion of an electric circuit, and a sensor coupled to said conductive element, wherein the sensor comprises a degradable element configured to at least partially degrade in preset conditions to change an electric feature of said sensor. An article comprising the fabric and a process for monitoring the life-cycle of the fabric are also disclosed.
Claims
1. A fabric comprising at least one conductive element defining at least a portion of an electric circuit, and a sensor coupled to said conductive element, wherein the sensor comprises a degradable element configured to provide a plurality of degrees of degradation of the degradable element itself in preset conditions to change an electric feature of said sensor.
2. The fabric according to claim 1, wherein the fabric is a woven or knitted fabric.
3. The fabric according to claim 1, wherein the conductive element comprises conductive yarn.
4. The fabric according to claim 1, wherein said preset conditions comprise at least one of a cleaning cycle, a heat treatment and wearing conditions.
5. The fabric according to claim 1, wherein said degradable element is configured to reduce its mass or dimension when put in contact with a liquid, to vary said electric feature.
6. The fabric according to claim 5, wherein the change of said electric feature of said sensor upon said degradation in said preset condition comprises a change between 1% and 5%.
7. The fabric according to claim 1, wherein said degradable element comprises at least one of a resistor and a dielectric portion of a capacitor interposed between two conductive elements.
8. The fabric according to claim 1, wherein said degradable element comprises a core of an inductor that defines the inductance of said inductor or includes a conductive element wound around said degradable element.
9. The fabric according to claim 1, wherein said degradable element comprises a piezoelectric element.
10. The fabric according to claim 9, wherein the change of the electric feature upon said degradation comprises a change of 10% to 50%.
11. The fabric according to claim 4, wherein the degradable element is configured to provide a first degree of degradation when the fabric is worn by a user, and a second degree of degradation at said cleaning cycle or at said heat treatment.
12. The fabric according to claim 11, wherein the degradable element is further configured to provide a third degree of degradation due to an undesired event being different from said preset condition.
13. An article comprising a fabric according to claim 1.
14. The article according to claim 13, further comprising a controller coupled to said sensor to monitor the change of said electric feature.
15. The article according to claim 14, wherein said controller is disposed within a button of said article.
16. The article according to claim 13, wherein said article is a garment.
17. The article according to claim 16, wherein the garment comprises at least one seam, and the sensor is disposed within said at least one seams.
18. The article according to claim 17, wherein said garment is a pair of pants and said controller is disposed within a button of said garment.
19. The article according to claim 18, wherein said sensor is disposed within at least one of an outer lateral seam extending in a longitudinal direction along a wearer's leg and an inner medial seam extending in said longitudinal direction along said wearer's leg.
20. A process for monitoring life-cycle of a fabric, said process comprising: (a) providing a fabric with at least one conductive element defining at least one portion of an electric circuit, and a sensor coupled to said conductive element, said sensor having a degradable element configured to at least partially degrade in preset conditions, whereby degradation of said element changes an electric feature of said sensor; (b) monitoring said electric feature and storing said monitored electric feature; (c) evaluating at least one of a value of said degradation of said electric feature and a number of degradation events as a function of said monitored and stored data; (d) determining status of said fabric as a function of the evaluation.
21. The process according to claim 20, wherein said step (c) comprises the steps of: (c1) evaluating a function of the monitored electric feature as a function of time; (c2) evaluating a derivative of the function of the monitored electric feature of step (c1) (c3) counting peaks of the derivative function, wherein each said peak is associated with one occurrence of said degradation event.
22. The process according to claim 20, wherein said sensor comprises at least one of resistor, an inductor, a capacitor and a piezoelectric element.
23. An electric circuit comprising at least one conductive element defining at least one portion of said electric circuit and a sensor coupled to said conductive element, the sensor including a degradable element configured to provide a plurality of degrees of degradation of the degradable element itself in preset conditions to change an electric feature of said sensor, said circuit being suitable to be inserted into a fabric.
24. A fabric comprising at least one conductive element to define at least one portion of an electric circuit, and a sensor coupled to said conductive element, wherein the sensor comprises a degradable element configured to provide a plurality of degrees of degradation in preset conditions to change an electric feature of said sensor, wherein said preset conditions comprise at least one of a cleaning cycle, a heat treatment and wearing conditions and wherein the degradable element is configured to provide a first degree of degradation when the fabric is worn by a user, and a second degree of degradation at said cleaning cycle or heat treatment.
25. The fabric according to claim 24, wherein the degradable element is provided with a third degree of degradation at an undesired event, different from said preset condition.
Description
DESCRIPTION OF THE DRAWING
(1) Exemplary and non-limiting embodiments will be now discussed with reference to the enclosed figures, in which:
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DETAILED DESCRIPTION OF THE EMBODIMENTS
(22) With reference to the figures, an article 11 (shown schematically in
(23) Preferably, a controller 10 can be coupled to the electric circuit 3 to evaluate the variation of such an electric feature.
(24) The fabric 1 is preferably a woven or knitted fabric. Conductive elements 2 can thus be conductive yarns 2a, 2b that are part of the woven or knitted fabric, i.e. they can be inserted in the fabric as yarns of the woven or knitted structure of the fabric itself.
(25) In a preferred embodiment, fabric 1 is a denim fabric for trousers. In any case, fabric 1 can be a generic fabric.
(26) In
(27) Conductive yarns can comprise e.g. steel or copper or silver wires, and they can be e.g. monofilament, or they can be blends of multiple fibers forming the final yarn.
(28) Alternative conductive elements can be used. In the exemplary embodiment of
(29) According to a further embodiment, shown in
(30) In general, conductive elements allow transmission of an electric signal along a portion of the fabric. In more detail, conductive elements are coupled to degradable elements, so as to form a portion of an electric closed path.
(31) In more detail, the conductive element(s) 2, 2a, 2b, 2c is/are disposed within/coupled to the fabric 1 so as to form a closed path, i.e. an electric circuit 3, preferably together with the controller 10. The controller 10 can be inserted within the fabric 1, or it can be an element external to the fabric 1.
(32) As an example, a controller 10 can be inserted within a button which is configured to be coupled to the fabric, as disclosed in pending application EP 15179147.2 in the name of the present applicant. The conductive elements(s) 2, 2a, 2b, 2c is/are disposed so as to close an electric path with the external controller 10, when the latter is coupled to the fabric 1 in the final garment. The electric controller 10 comprises known means to generate and/or evaluate an electric signal, and to monitor an electric feature of the electric circuit 3.
(33) As an example, in
(34) The electric circuit 3 comprises two conductive yarns 2a, 2b. The yarns 2a, 2b can be inserted within the fabric 1 as per above disclosed. The fabric 1 is not shown for clarity. A degradable element 4a is interposed between the yarns 2a, 2b. The electric circuit is closed by a controller 10.
(35) The electric circuit 3 may be more complex than what shown. As shown for example in
(36) According to an embodiment, the electric circuit 3 can comprise a pull-up or pull-down resistance 7, to avoid short circuits and to limit external disturbances. In general, the sensor 12 is able to generate a signal towards and/or from the degradable element 4, for example a degradable resistor 4a as per
(37) In the particular embodiment of
(38) R_ini being the initial value of the resistance of the resistor 4a (i.e. before any degradation) and R_fin being the larger expected final resistance value of the resistor 4a at the end of its operative life time, the voltage divider resistor 7a has preferably a resistance value R_div defined by the geometric average of R_ini and R_fin. In other words the value of the resistance of the voltage divider resistor 7a can be chosen as per the following formula:
R.sub.div={square root over ((R.sub.ini*R.sub.fin))}
(39) The above mentioned preferred value of the voltage divider resistor 7a guarantees the maximum dynamic range at the input of the ADC 5. The above disclosed voltage divider is particularly useful during measurement the resistance value of the resistor 4a.
(40) A resistor 7a may be used to form a voltage divider also in combination with a degradable sensor having a degradable inductor 4c, as shown in
(41) Also, a voltage divider may be used without a (pull up/pull down) resistor, as shown in
(42) A pull up/pull down resistor 7 is also shown in combination with a degradable piezoelectric sensor in an exemplary embodiment in
(43) According to an embodiment, the sensor 12 can be placed within seams 11a, 11b of the article 11 (see
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(45) In particular,
(46) Furthermore, even if not shown in detail, further seams may be provided on the article 11, e.g. at the top portion of the pants, i.e. at the portion of the pants usually configured to house a belt. The sensor 12 may be placed within any of these seams, according to the needs. It is further noted that seams 11a, 11b are used to produce the article, so that the sensor can be placed within a pre-existing seam of the article. Such a seam may be provided with an area having greater dimension (e.g. greater width) with respect to the other areas of the seams, in order to house a sensor in the greater area. Also, in some embodiments, a sensor may be placed within a seam that is created ad hoc for the sensor. In other words, a seam that have no structural function can be provided on the article with the only purpose to house a sensor. A seam may be thus formed on an article in order to form a pocket where a sensor may be housed.
(47) Also, the controller 10 can be placed within a seam 11a, 11b of an article 11. The controller 10 can be connected to the sensor by means of conducting elements (e.g. conducting yarns such as steel yarns) that do not degrade.
(48) As before mentioned, various kinds of degradable elements can be used in different embodiments of the present invention. Embodiments with water degradable elements and piezoelectric elements will be now discussed in detail.
(49) With reference to
(50) The water degradable resistor 4 is preferably made of polyether and/or polyester based polyurethanes.
(51) The water degradable resistor 4a partially reduces its mass/dimensions each time the fabric 1 is washed. This is schematically shown in
(52) Each time the water soluble resistor reduces its mass/dimension, i.e. each time the water soluble resistor loses part of its material, the relevant electric feature (i.e. the resistance) is changed.
(53) A water degradable resistor (and more in general a water degradable element, as the water degradable elements 42b and 41c subsequently discussed) is preferably configured to vary the relevant electric feature (e.g. resistance in the present case of a resistor) of about 1% to 5% at each washing cycle. As mentioned, in fact, the resistance of the resistor 4a is dependent on the mass/dimensions of the resistor 4a itself. In particular, the resistance increases with a decrease of the mass/dimensions of the resistor 4a. In fact, when the resistor loses mass (both by a reduction of the external dimension of the resistor, or by losing a filler of the resistor), the electric path that is traversed by the electric current narrows, thus raising the resistance of the resistor.
(54) As better discussed later, a change in the resistance of the resistor 4a in the sensor 12 can be sensed by the controller 10, in order to evaluate the life-cycle of the fabric 1, and in particular to evaluate the history of washing cycles on the fabric 1.
(55) Water degradable elements can be used not only as a resistor. As an example, in
(56) In a further embodiment, shown schematically in
(57) During a washing cycle, the water degradable core 41c partially reduces its mass/dimensions, so that the inductance of the inductor 4c is changed, e.g. lowered.
(58) More in general, different water degradable elements can be used in different embodiments of the present invention, provided that the partial degradation (e.g. by erosion caused by hydrolysis) of the water degradable element causes a sensible variation within the electric circuit 3, i.e. it changes the value of an electric features of the electric circuit 3.
(59) In the above disclosed embodiments, the electric feature changed by the water degradable element are respectively the resistance (in
(60) As mentioned, the conductive elements are not limited to conductive yarns.
(61) With reference to the embodiment of
(62) In particular, the degradable element 4 connects the two metal elements 2c so as to allow transmission of an electric signal between the metal elements 2c.
(63) Such an electric signal can be generated by a controller 10 (not shown in
(64) Water degradable elements were disclosed. However, different degradable elements can be configured to reduce their mass/dimensions when put in contact with different fluids (i.e. other than water), e.g. tetrachloroethylene, or other solvents used in dry cleaning. Moreover, in further embodiments of the present invention, degradable elements 4 that do not reduce their mass/dimensions when they are put in contact with a liquid can be used.
(65) As an example, in
(66) The piezoelectric degradable element 4d of the embodiment is made of a polyvinylidene difluoride (PVDF), in particular, of a semi-crystalline poly(vinylidene fluoride) polymer. The piezoelectric degradable element 4d generates an electric signal when it is subjected to mechanical stimulation, e.g. when the fabric carrying the piezoelectric degradable element is bent, stretched, pressed, wrinkled, sheared, stressed, released/relaxed, etc.
(67) A SEM (scanning electron microscope) image of a PVDF family member is shown in
(68) The strength of this signal is dependent on the polarization (i.e. the orientation of the electric dipoles 41d of
(69) As a result, when the fabric 1 is heated during a cleaning cycle (e.g. due to contact with hot water), the piezoelectric degradable element 4d partially loses polarization, and thus the strength of the electric signal generated by the piezoelectric degradable element 4d is lowered.
(70) As before, the piezoelectric degradable element 4d can be made of a material that does not to completely lose polarization when heated during a single cleaning cycle.
(71) In other words, the signal generated by the piezoelectric degradable element is preferably varied after a heat treatment. This variation is preferably comprised between 5% and 95%, more preferably between 10 and 50%.
(72) In
(73) In other words, electric dipoles 41d of the piezoelectric degradable element 4d are completely aligned at the left, partially aligned in the middle, and not aligned at the right of
(74) The material of the piezoelectric element 4d can be chosen to allow counting of the occurrence of heat treatments. Different piezoelectric elements can be used to count the occurrences of different events, in particular heat treatments.
(75) Different degradable elements can be used as well in other embodiments of the present invention.
(76) In general, as mentioned, a degradable element 4 is configured to partially degrade during a preset condition, i.e. at the occurrence of a predetermined event, so as to change an electric feature of the electric circuit 3 to which the degradable element 4 is coupled.
(77) According to further embodiments of the invention, the degradable element 4 can be configured to degrade not only during the predetermined events. As an example, the degradable element 4 can degrade also during normal use of the fabric 1, e.g. when the garment comprising fabric 1 is worn by a user.
(78) Preferably, the degradation rate (i.e. the speed of degradation) during normal use is different from degradation during the predetermined event. In particular, degradation during a preset event is greater (and preferably also faster) than degradation during normal use. In other words, the percentage of degradation during normal use is lower than the percentage of degradation during the predetermined event. Degradation is normally detected as a change in the signal generated by the sensor.
(79) An example of such an embodiment is shown in
(80) In particular, sweat simulations 6 (i.e. simulations of a normal use) and washing cycles simulations 8 were carried out on a fabric 1. Sweat simulation were carried out by immersion of the fabric into a pH 5.5 solution prepared with histidine monohydrochloride monohydrate, sodium phosphate and sodium chloride.
(81) Phases M of measuring the resistance of the water degradable resistor 4a were carried out before and after the sweat simulations 6 and the washing cycles simulations 8. As shown, two cycles of sweat simulations 6 and washing cycles simulations were carried out. After that, the fabric was placed at rest, i.e. it was not worn by a used nor subjected to particular treatment.
(82) In more detail, with reference also to
(83) As mentioned, the result of the test of
(84) Between times B and C and D and E, a fast degradation is shown. This fast degradation is due to washing cycles. In particular, it can be noted that washing cycle between time B and time C was longer than washing cycle between time D and time E. After time E, the resistance of the water degradable water resistor 4a is substantially constant. This is due to non-use of the fabric.
(85) The behavior is not limited only to a water degradable resistor 4a. As an example, the water degradable capacitor 4b and inductor 4c can be configured to show similar behavior, e.g. a first degree of degradation during normal use, and a second degree of degradation during a heat treatment.
(86) Piezoelectric degradable element 4d can also show a similar behavior. As an example, the heat emitted by a user body can cause a slow degradation of the polarization of the piezoelectric degradable element 4d.
(87) Furthermore, in other embodiments, the degradable element can have a third degree of degradation, other than the degradation during normal use and the degradation during a heat treatment/washing cycle. In particular, the third degree of degradation is preferably configured to show the occurrence of an undesired event.
(88) The third degree of degradation is typically different from the degree of degradation during the preset condition. In other words, the percentage of degradation during an undesired event is different (typically greater and/or faster) than the percentage of degradation during the preset condition.
(89) As an example, a piezoelectric degradable element can lose a great amount of polarization if the fabric 1 is heated at a too high temperature. In an embodiment, the piezoelectric element undergoes a glass transition at a certain temperature (which is a temperature that should not be applied to the fabric 1), so as to totally lose polarization. In other words, a degradable element can be totally degraded during a single undesired event.
(90) With reference to the embodiments previously disclosed, a water degradable element can be highly degraded (e.g. greatly eroded or dissolved) if the fabric is placed in water for a too long period.
(91) In general, embodiments of the present invention can have a degradable element with only one degree of degradation, i.e. degradation at a preset event. Different embodiments can have a degradable element with two degrees of degradation (i.e. degradation at a predetermined event and degradation during normal use or during an undesired event).
(92) Further embodiments can have a degradable element with all the three degrees of degradation previously discussed.
(93) Embodiments with one degradable element 4 have been shown. It is however possible to have a greater number of degradable elements 4. Furthermore, degradable elements of different kinds can be used in the same embodiment, to monitor different events. As an example, a water degradable element can be used to count washing cycles, while a piezoelectric degradable element can be used to monitor heat treatments.
(94) With particular reference to
(95) As before mentioned, an ADC 5 (
(96) The variation of the monitored data (i.e. the electric feature of the electric circuit 3) is then used to evaluate the number of occurrences of a predetermined event.
(97) Various analytic methods can be used for the purpose, e.g. real-time and on-line fast data analysis on the controller, or off-line data mining carried out e.g. by means of a PC.
(98) In the shown embodiment, with particular reference to
(99) A threshold value can be established to evaluate the number of significant peaks p1 and p2. In other words, every time that the derivative function exceeds the threshold value, the controller counts one peak, i.e. it counts the occurrences of a predetermined event.
(100) In the shown embodiment, two washing cycles have been carried out, i.e. between times B and C, and D and E of
(101) A further threshold value TV2, greater than threshold value TV, can be chosen in order to count the occurrences of undesired events. Thanks to this, if a peak p1 is between TV and TV2, the controller 10 will count an occurrence of a predetermined event. On the contrary if a peak is above both TV and TV2, an occurrence of an undesired event will be counted. In the shown embodiment, no undesired events were carried out on the fabric 1. As a result no peaks of the derivative function above TV2 are present.
(102) Other methods can be used to evaluate the number of occurrences of predetermined events. As an example, tests can be carried out on different sensors 12, to evaluate the change in the relevant electrical feature at the occurrence of one or more events (e.g. washing cycles) or in the whole life-cycle of the sensors 12.
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(105) On the contrary, the sensor of the sample that was subjected to washings changed sensibly its resistance value, in fact a total variation of over 600 k is shown in
(106)
(107) The sensors 12a, 12b, 12c and 12d where put in a strong chemical bath, to simulate the whole life of the sensors 12a, 12b, 12c and 12d.
(108) As can be seen, sensor 12a is a provided with a particularly high sensitivity to the event (i.e. it provides a sensibly great and fast variation of the electric feature), but it is provided with lower lifetime with respect to the other sensors 12b and 12d. In fact it can be seen that the curve of sensor 12a in
(109) In general, from the results of these or similar tests, it is possible to configure the controller 10 to evaluate the response of each of the sensor 12a, 12b, 12c and 12d, e.g. to predict the variation of the electric feature (i.e. the height of the steps of
(110) Furthermore, from these results, it is possible to predict the end of life of the sensors 12a, 12b, 12c and 12d, that is when there is substantially no variation in the electric feature of the sensor 12a, 12b, 12c and 12d in response to an event (washing cycle), i.e. when, at their end, the curves of
(111) In general, the controller 10 can be configured to recognize the variation of the value of the electric feature in response to certain events, e.g. a washing cycle. Further analytic methods can be carried out to evaluate the normal use carried out on the fabric. As an example, a small variation of the resistance that happens in a long time, e.g. the small variation between times C and D of
(112) In general, the evaluation of the monitored data (e.g. the resistance of