Elastic adhesive composition and an elastic composite made with the same

Abstract

This invention claims hot melt adhesive compositions that can be used to form elastic composites that are useful in disposable absorbent articles. The compositions have good elastic recovery and high peel adhesion at a viscosity of less than about 20,000 cps at 177 C. The low viscosity makes it possible to apply the adhesive at a high line speed and target application to only those areas requiring elastic performance.

Claims

1. An elastic composite comprising: a first and second substrate; and a hot melt adhesive composition between the first and second substrates thereby permanently bonding the first and second substrates to each other and providing elasticity in the bonded area, said hot melt adhesive comprising: at least 15% of s styrene block copolymer with a melt flow rate of at least 15 g/10 minutes (190 C., 2.16 kgs) and a diblock content of no greater than 10% by weight, and from 5% by weight to 30% by weight plasticizer, wherein the hot melt adhesive composition has a viscosity of no greater than about 20,000 cps at 350 F., wherein the first and second substrate are selected from the group consisting of a nonwoven and a polymer film, and further wherein the hot melt adhesive has a set 1.sup.st cycle after 50% hysteresis when tested according to the 2-Peak Hysteresis Test Method of no more than 12%.

2. The elastic composite of claim 1 wherein the hot melt adhesive composition has a set 1.sup.st cycle after 50% hysteresis of no more than 10%.

3. The elastic composite of claim 1 wherein the hot melt adhesive composition has a viscosity of no greater than 5,000 cps at 350 F.

4. The elastic composite of claim 1 wherein the hot melt adhesive composition further comprises a tackifying agent.

5. The elastic composite of claim 1 wherein the styrene block copolymer has an unsaturated mid-block.

6. The elastic composite of claim 1 wherein the first and second substrate are nonwoven.

7. The elastic composite of claim 6 wherein the nonwoven comprising the first and second substrates is airlaid, carded and hydroentangled.

8. The elastic composite of claim 6 wherein the first and second substrate are nonwovens extensible to greater than 100% in the cross web direction.

9. A disposable article comprising the elastic composite of claim 1.

10. The disposable article of claim 9 wherein the elastic composite is used in an application selected from the group consisting of ear, waist band, and belly band and side panel.

11. The disposable article of claim 9 selected from the group consisting of diaper, adult incontinence product, feminine hygiene product and medical bandage.

12. A hot melt adhesive composition that can be used to create a bonded, elasticized region, comprising: from 50% to 70% by weight one or more styrene block copolymers, wherein the one or more styrene block copolymers comprises at least 20% by weight of a styrene-isoprene-styrene block copolymer with a melt flow rate of at least 15 g/10 minutes (190 C., 2.16 kgs), and a diblock content of no greater than 10% by weight, a tackifying agent and, from 5% by weight to 30% by weight plasticizer, wherein the adhesive composition has a viscosity of no greater than 20,000 cps at 350 F.

13. The hot melt adhesive composition of claim 12 with a viscosity of no greater than 15,000 cps at 350 F.

14. The hot melt adhesive of claim 12 wherein the average styrene content of the styrene block copolymer is at least 30% by weight.

15. The hot melt adhesive composition of claim 12 wherein the one styrene block copolymer has a MFR (190 C./2.2 kg) of at least 50 g/10 minutes.

16. An elastic composite comprising: a substrate, and the hot melt adhesive composition of claim 12 bonded to the substrate; wherein the hot melt adhesive provides elasticity to the bonded area.

17. The hot melt adhesive of claim 12 wherein the hot melt adhesive composition is free of end block resin that has a melting point greater than 110 C.

18. The elastic composite of claim 1 wherein the styrene block copolymer is styrene-isoprene-styrene.

19. The elastic composite of claim 1 wherein the first and second substrate stretch with the hot melt adhesive composition.

20. The elastic composite of claim 6 wherein the nonwoven comprising the first and second substrates is selected from the group consisting of nonwoven extensible to greater than 100% in the cross-web direction and post treated nonwoven.

Description

DETAILED DESCRIPTION

(1) Applicants have discovered hot melt adhesive compositions that can be used to form elastic composites that are useful in disposable articles (e.g. disposable absorbent articles). The compositions have good elastic recovery and high peel adhesion and have a viscosity of no greater than about 20,000 cps at 177 C. The low viscosity makes it possible to apply the adhesive at a high line speed and target application to only those areas requiring elastic performance.

(2) Elastic Composite

(3) The elastic composite can include a first substrate and a hot melt adhesive composition. The hot melt adhesive composition imparts elasticity to the first substrate.

(4) Alternately, the elastic composite can include a first substrate, a second substrate and a hot melt adhesive composition. The hot melt adhesive composition is present between the first and second substrate, permanently bonding the substrates to each other and providing elasticity in the bonded area.

(5) At least one of the substrates is selected from the group consisting of nonwoven and polymer film.

(6) Any nonwoven can be used. The nonwoven can be an elastic nonwoven (e.g. core and shell type). The nonwoven can contain fibers made from one or more polymers e.g. PET (polyethylene terephthalate), PBT (polybutylene terephthalate), nylon, polypropylene and polyethylene), one or more natural fibers (e.g. rayon cellulose, cotton cellulose, hemp and viscose) or combinations thereof. The nonwoven can be formed by a number of different methods, including e.g. airlaid, wetlaid, spunbound or meltblown. The fibers can be carded (e.g. run through a comb) so that they are oriented in a particular direction. The webs can be bonded together in any manner including e.g. hydroentangled, chemical bonded, needle punched or thermally bonded. In one embodiment, the nonwoven is comprised of a blend of polypropylene and PET fibers which are airlaid, carded and hydroentangled.

(7) Any polymer film can be used. The polymer film can be selected from the group consisting of polyethylene, polypropylene, polyethylene copolymers, polypropylene copolymers, and PET.

(8) The first and second substrates can be nonwoven. The nonwoven can have a basis weight of less than 40 grams per square meter (gsm), less than 35 gsm, or even less than about 30 gsm. The nonwoven can be extensible to greater than 100% in the cross-web direction.

(9) Various post treatments, such as treatment with grooved rolls activation can be used to adjust the mechanical properties (e.g. extensibility) of the composite.

(10) The adhesive can be applied to the first and or second substrate using a variety of application methods including slot coating, non-contact coating, spraying including, e.g., spiral spraying and random spraying, screen printing, foaming, engraved roller, gravure roller, extrusion and meltblown.

(11) The adhesive can be applied to one substrate.

(12) Alternately, the adhesive can be applied to the first substrate and then contacted by the second substrate to form the composite. Pressure or tension can be used to aid in forming the bonded composite. The composite can be formed within a disposable article manufacturing process. Alternatively, the composite is formed prior to the disposable article manufacturing process.

(13) Adhesive Composition

(14) The adhesive composition is a hot melt adhesive. The adhesive can be a pressure sensitive adhesive. The adhesive composition can be light in color and can have good thermal stability. The adhesive can have an initial Gardner Color after manufacturing of less than about 3, or even less than about 2. Alternately, the adhesive can be pigmented to an opaque color such as e.g. pink, blue, white, etc.

(15) The adhesive composition has low viscosity at application temperature. The viscosity is no greater than about 20,000 cps at around 177 C., no greater than about 15,000 cps at around 177 C., no greater than about 10,000 cps at around 177 C., no greater than about 7,000 cps at around 177 C., no greater than about 5,000 cps at around 177 C., from about 500 cps to about 20,000 cps at around 177 C., or even from about 1,000 cps to about 15,000 cps at around 177 C. The adhesive composition gives a set after 50% hysterisis of no more than about 20%, no more than about 12%, or even no more than about 10%.

(16) The adhesive composition can have a Force Relaxation of no greater than 4.75 newtons, no greater than 4.50 newtons, or even no greater than 4.25 newtons.

(17) The adhesive composition provides good adhesion when tested according to the Peel Force Test Method. In some embodiments, the adhesive has peel adhesion of greater than about 100 grams/inch, greater than about 200 grams/inch, or even greater than about 300 grams/inch. In other embodiments the substrates tear when peeled SF (substrate failure).

(18) The adhesive composition can have a viscosity curve with a Viscosity Ratio (Viscosity @ 149 C. (cps)/Viscosity @ 177 C.) that is no greater than about 7.5, no greater than about 6, no greater than about 5, or even no greater than about 4. A low viscosity ratio can indicate improved machining at high line speeds as the adhesive does not gain viscosity quickly as it cools.

(19) The adhesive composition can include a tackifying resin with at least some aromatic content and a naphthenic oil.

(20) Styrene Block Copolymer

(21) First Styrene Block Copolymer

(22) The hot melt adhesive composition includes a first styrene block copolymer with a melt flow rate of at least about 15 g/10 minutes (190 C., 2.16 kgs), at least about 20 g/10 minutes (190 C., 2.16 kgs), at least about 30 g/10 minutes (190 C., 2.16 kgs), at least about 50 g/10 minutes (190 C., 2.16 kgs) or even from about 15 to about 200. The first styrene block copolymer has a diblock content of no greater than about 10% by weight, no greater than about 5% by weight, no greater than about 3% by weight, or even no greater than about 1% by weight.

(23) The composition can include one or more than one first styrene block copolymers with a melt flow rate of at least about 15 g/10 minutes (190 C., 2.16 kgs) and a diblock content of no greater than about 10% by weight.

(24) The first styrene block copolymer is present at, at least about 10% by weight, at least about 15% by weight, at least about 20% by weight, from about 10% to about 70% by weight, or even from about 15% to about 65% by weight.

(25) The first styrene block copolymer includes an aromatic vinyl polymer block and a conjugated diene polymer block, a hydrogenated conjugated diene polymer block, or a combination thereof. The blocks can be arranged in a variety of configurations including, e.g., linear, branched, radial, star and combinations thereof. The aromatic vinyl polymer block can be derived from a variety of aromatic vinyl compounds including, e.g., styrene, alpha-methylstyrene, beta-methylstyrene, o-, m-, p-methylstyrene, t-butylstyrene-2,4,6-trimethylstyrene, monofluorostyrene, difluorostyrene, monochlorostyrene, dichlorostyrene, methoxystyrene, 1,3-vinylnaphthalene, vinylanthracene, indene, acenaphthylene, and combinations thereof. The diene polymer block can be derived from a variety of diene-containing compounds including, e.g., isoprene, butadiene, hexadiene, 2,3-dimethyl-1,3-butadiene, 1,3-pentadiene, and hydrogenated versions thereof, and combinations thereof.

(26) Useful first styrene block copolymers include, e.g., triblock, multi-arm, and radial copolymers including, e.g., styrene-butadiene-styrene (SBS), styrene-isoprene-styrene (SIS), styrene-butadiene-isobutylene-styrene (SBBS), styrene-isoprene-butadiene-styrene (SIBS), styrene-ethylene/butene-styrene (SEBS), styrene-ethylene/propylene-styrene (SEPS), styrene-ethylene-ethylene/propylene-styrene (SEEPS), and combinations thereof.

(27) The first styrene block copolymer can have a styrene content of at least about 18% by weight, at least about 25% by weight, at least about 30% by weight, no greater than about 35% by weight, no greater than about 40% by weight, from about 30% to about 40% by weight, from about 30% to about 37% by weight, from about 18% by weight to about 35% by weight, from about 25% by weight to about 35% by weight, or even from about 30% to about 35% by weight.

(28) The first styrene block copolymer can have an unsaturated mid-block, alternately the mid-block can be saturated i.e. hydrogenated. The first styrene block copolymer can be selected from the group consisting of SIS, SBS, SIBS, and SBBS.

(29) The first styrene block copolymer can be the only polymer present in the adhesive.

(30) Useful first styrene block copolymers include for example KRATON MD 1648 commercially available from Kraton Polymers US LLC (Houston, Tex.).

(31) The composition can include additional styrene block copolymers. Useful additional styrene block copolymers include VECTOR 4411 and VECTOR 6241 available from TSRC Corporation (Houston, Tex.), SOLPRENE 411 (a high molecular weight radial SBS block copolymer) available from Dynasol (Houston, Tex.). The adhesive composition includes a total styrene block copolymer content (including the first styrene block copolymer and any others) of at least about 35% by weight, at least about 40% by weight, from about 35% by weight to about 60% by weight, or even from about 50% by weight to about 70% by weight.

(32) Tackifying Agent

(33) The adhesive includes a tackifying agent. The tackifying agent can be fluid or solid at room temperature. Suitable classes of tackifying agents include, e.g., aromatic, aliphatic and cycloaliphatic hydrocarbon resins, mixed aromatic and aliphatic modified hydrocarbon resins, aromatic modified aliphatic hydrocarbon resins, and hydrogenated versions thereof; terpenes, modified terpenes and hydrogenated versions thereof; natural rosins, modified rosins, rosin esters, and hydrogenated versions thereof; low molecular weight polylactic acid; and combinations thereof. Examples of useful natural and modified rosins include gum rosin, wood rosin, tall oil rosin, distilled rosin, hydrogenated rosin, dimerized rosin and polymerized rosin. Examples of useful rosin esters include e.g., glycerol esters of pale wood rosin, glycerol esters of hydrogenated rosin, glycerol esters of polymerized rosin, pentaerythritol esters of natural and modified rosins including pentaerythritol esters of pale wood rosin, pentaerythritol esters of hydrogenated rosin, pentaerythritol esters of tall oil rosin, and phenolic-modified pentaerythritol esters of rosin.

(34) Useful tackifying agents are commercially available under a variety of trade designations including, e.g., the ESCOREZ series of trade designations from Exxon Mobil Chemical Company (Houston, Tex.) including ESCOREZ 5400 (1% aromatic content), ESCOREZ 5415, ESCOREZ 5600 (9.8% aromatic content), ESCOREZ 5690 (10% aromatic content), ESCOREZ 5615 (9.9% aromatic content), the EASTOTAC series of trade designations from Eastman Chemical (Kingsport, Tenn.) including EASTOTAC H-100R and EASTOTAC H-100L, and the WINGTACK series of trade designations from Cray Valley HSC (Exton, Pa.) including WINGTACK 86, WINGTACK EXTRA, and WINGTACK 95 and the PICCOTAC and KRISTALEX series of trade designations from Eastman Chemical Company (Kingsport, Tenn.) including, e.g., PICCOTAC 8095 and KRISTALEX 3100.

(35) The adhesive can be free from end block resin that has a melting point greater than about 110 C., greater than about 120 C., or even greater than about 130 C.

(36) The adhesive composition can include at least one tackifying agent with aromatic content. The tackifying agent can have an aromatic content of greater than 5%, greater than 20%, greater than 50%, from about 5% to about 20% by weight, or even from about 7.5% to about 15% by weight. The aromatic content is measured by Nuclear Magnetic Resonance (NMR) spectroscopy.

(37) The composition can include a tackifying agent with a melt point of less than 100 C., or even less than 95 C.

(38) The adhesive composition can include at least about 20% by weight, at least about 25% by weight, from about 10% by weight to about 60% by weight, from about 15% by weight to about 50% by weight, or even from about 20% by weight to about 45% by weight tackifying agent.

(39) Plasticizer

(40) The adhesive composition can include a plasticizer. Alternatively, the adhesive can be free of a plasticizer (i.e. contain no plasticizer). Suitable plasticizers include, e.g., naphthenic oils, paraffinic oils (e.g., cycloparaffin oils), mineral oils, phthalate esters, adipate esters, olefin oligomers (e.g., oligomers of polypropylene, polybutene, and hydrogenated polyisoprene), polybutenes, polyisoprene, hydrogenated polyisoprene, polybutadiene, benzoate esters, animal oil, plant oils (e.g. castor oil, soybean oil (e.g. high oleic soy oil), derivatives of oils, glycerol esters of fatty acids, polyesters, polyethers, lactic acid derivatives and combinations thereof.

(41) Useful commercially available plasticizers include GALSOL 550 and CALSOL 5550, naphthenic oils from Calumet Specialty Products Partners, LP (Indianapolis, Ind.), KAYDOL OIL mineral oil from Sonneborn (Tarrytown N.Y.) PARAPOL polybutene from Exxon Mobil Chemical Company (Houston, Tex.), OPPANOL polyisobutylene from BASF (Ludwigsjhafen, Germany), KRYSTOL 550 mineral oil from Petrochem Carless Limited (Surrey, England), PURETOL 35 and 15 both mineral oils from Petro Canada Lubricants Inc. (Mississauga, Ontario), PLENISH from Pioneer Dupont, and TPC 5230, polyisobutylene available from TPC Group (Houston, Tex.).

(42) The plasticizer can be a naphthenic oil. Alternately, the plasticizer includes aromatic or naphthenic groups.

(43) The plasticizer can be present in the adhesive composition in an amount of at least about 5% by weight, at least about 10% by weight, at least about 15% by weight, at least about 18% by weight, no greater than about 10% by weight, no greater than about 15% by weight, from about 5% to about 30% by weight, or even from about 15% to about 25% by weight.

(44) Wax

(45) The adhesive composition can include a wax. Useful classes of wax include, e.g., paraffin waxes, microcrystalline waxes, high density low molecular weight polyethylene waxes, by-product polyethylene waxes, polypropylene waxes, Fischer-Tropsch waxes, oxidized Fischer-Tropsch waxes, functionalized waxes such as acid, anhydride, and hydroxy modified waxes, animal waxes, vegetable waxes (e.g. soy wax) and combinations thereof. Useful waxes are solid at room temperature and preferably have a Ring and Ball softening point of from 50 C. to 170 C. Useful waxes are commercially available from a variety of suppliers including EPOLENE N and C series of trade designations from Westlake Chemical Corporation (Houston, Tex.) including e.g. EPOLENE N-21 and the LICOCENE series of trade designations from Clariant International Ltd. (Muttenz, Switzerland) including e.g. TP LICOCENE PP 6102.

(46) The adhesive composition can include no greater than about 8.0% by weight, no greater than about 5% by weight, from about 1% by weight to about 7.5% by weight, or even from about 1% to about 5% by weight wax.

(47) Additional Polymers

(48) The adhesive composition optionally includes additional polymers e.g. single-site catalyzed polyooefins, amorphous poly-alpha olefins, polyethylene homopolymers/copolymers and polypropylene homopolymers/copolymers.) Useful additional polymers include VISTAMAXX 6102 (propylenelethylene copolymer available from ExxonMobil Chemical (Houston, Tex.) and REXTAC 2730 (an amorphous poly-alpha olefin) available from Rextac LLC (Odessa, Tex.).

(49) The adhesive composition includes a total polymer content (including SBC and additional polymers) of at least about 35% by weight, at least about 40% by weight, from about 35% by weight to about 60% by weight, or even about 50% by weight to about 70% by weight.

(50) Additional Components

(51) The adhesive composition optionally includes additional components including, e.g., stabilizers, antioxidants, adhesion promoters, ultraviolet light stabilizers, corrosion inhibitors, odor absorbers/neutralizers, colorants (e.g., pigments and dyes), fragrances, fillers (e.g. nano particles, clay, talc), surfactants, wetness indicators, superabsorbents, coextrusion coatings, processing aids and combinations thereof.

(52) Useful antioxidants include, e.g., pentaerythritol tetrakis[3,(3,5-di-tert-butyl-4-hydroxyphenyl)propionate], 2,2-methylene bis(4-methyl-6-tert-butylphenol), phosphites including, e.g., tris(p-nonylphenyl)-phosphite (TNPP) and bis(2,4-di-tert-butylphenyl)4,4-diphenylene-diphosphonite, di-stearyl-3,3-thiodipropionate (DSTDP), and combinations thereof. Useful antioxidants are commercially available under a variety of trade designations including, e.g., the IRGANOX series of trade designations including, e.g., IRGANOX 1010, IRGANOX 565, and IRGANOX 1076 hindered phenolic antioxidants and IRGAFOS 168 phosphite antioxidant, all of which are available from BASF Corporation (Florham Park, N.J.), and ETHYL 702 4,4-methylene bis(2,6-di-tert-butylphenyl). When present, the adhesive composition preferably includes from about 0.1% by weight to about 2% by weight antioxidant.

(53) Disposable Article

(54) The adhesive compositions and elastic composites of this invention can be incorporated into any suitable article including personal care garments, medical garments and industrial worker garments.

(55) The elastic composite of this invention is useful in a variety of applications and constructions to improve comfort and fit including e.g., disposable absorbent articles including, e.g., diapers, training paints, swim wear, absorbent underpants, adult incontinence products, sanitary napkins, medical dressings (e.g., wound care products and bandages), surgical pads, medical gowns, caps, gloves, drapes, face masks, laboratory coats, coveralls, meat-packing products, and components of absorbent articles including, e.g., an absorbent element, absorbent cores, impermeable layers (e.g., backsheets), tissue (e.g., wrapping tissue), acquisition layers and woven and nonwoven web layers (e.g., top sheets, absorbent tissue).

(56) The elastic composite of this invention is useful for elasticizing many areas of disposable articles including leg cuffs, waist portions, belly bands, side panels and fastening tabs/ears. The elastic composite of this invention can further be use to elasticize any portion of the disposable article or even the entire disposable article.

EXAMPLES

(57) Test Procedures

(58) Test procedures used in the examples and throughout the specification, unless stated otherwise, include the following.

(59) Viscosity Test Method

(60) Viscosity is determined in accordance with ASTM D-3236 entitled, Standard Test Method for Apparent viscosity of Adhesives and Coating Materials, (Oct. 31, 1988), using a Brookfield Thermosel viscometer Model RVDV 2 and a number 27 spindle. The results are reported in centipose (cps).

(61) Melt Flow Rate

(62) Melt Flow Rate was run according to ASTM D 1238 at the conditions stated.

(63) Test Lamination Preparation

(64) Test laminations were prepared by continuous slot coating the elastic adhesive composition between two nonwoven* substrates at an application temperature of 177 F., a nip pressure of 15 pounds per square inch (PSI), and a run speed of at least 20 ft/min. Laminations were prepared with an adhesive coatweight of 100 gms (Controls 1-2, Ex. 3-5) and 130 gsm (Ex. 1-2) and the width of the adhesive was at least 3 inches. A sufficient amount of laminate is prepared such that at least 60 inches of representative lamination can be collected for testing. *For Controls 1-2 and Examples 1-3, the nonwoven used is carded, hydroentangled and comprises 50/50 (PET/PP). It has a basis weight of 28 g/m.sup.2 and a cross direction tensile strength of 15 Newtons/5 cm.*For Examples 4 and 5, the nonwoven used is carded, hydroentangled and comprises 50/50 (PET/PP). It has a basis weight of 25 g/m.sup.2 and a cross direction tensile strength of 12 Newtons/5 cm.

(65) Peel Force Test Method

(66) Test laminates were prepared by coating adhesive between two substrates according to the Test Lamination Preparation method above. Peel force is determined using ASTM D1876-01 entitled; Test Method for Determining Peel Resistance of Adhesive (T-Peel Test Method), with the exception that the test is run at a rate of 12 inches per minute, instead of 10 in per minute, over a period of 10 seconds, and 7 replicates are run instead of the 10 specified in ASTM D1876. The samples are run on an INSTRON type-test instrument. The test samples are 1 inch in width and at least 4 inches in length. The average peel force over 10 seconds of peeling is recorded, and the results are reported in grams. The initial peel force is measured at least 24 hours after the laminate is prepared.

(67) 2-Peak Hysteresis Test Method

(68) Test laminates were prepared by coating adhesive between two substrates according to the Test Lamination Preparation method above. Test samples are prepared by cutting the laminates in cross-web direction, with 1 inch in width and at least 3 inches in length. The test is conducted at least 24 hours after the non woven laminate is prepared.

(69) The strips prepared are extended to a certain strain (e.g. 50%, 100%, 150% or 200%) and then retracted to their original dimension. Subsequently the specimen goes through a second extension-retraction cycle with the same deformation. The cross head speed is set to 20 inches per minute. There is no holding time between extension and retraction. The samples are run on an INSTRON type-test instrument with at least 3 replicates. The permanent set after each cycle, peak load/stress at maximum deformation, and percent energy loss between each cycles are recorded.

(70) 1-Peak Hysteresis Test Method

(71) Testing is performed using an INSTRON type-test instrument with a cross head speed of 20 inches per minute, for both extension and retraction. The test specimen is two inches in width. Grip separation is also set to two inches. A sample test set normally consists of five replicates. The elastic is elongated by the grips until a force of 10 Newtons is reached. At that point the specimen is placed in a hold for 30 seconds and then allowed to retract to the point where the specimen returns to the two inch initial gap setting. The data collected is the percent elongation (mm/mm and/or percent) at which the specimen 10 Newtons. During the 30 second hold, the force will diminish over this time, and the magnitude of the loss in force is reported as force relaxation in Newtons (N). After the 30 second hold time has passed, the specimen is returned to the two inch gap. The percent (%) set of the specimen is measured by the distortion of the two inch specimen length, determined by the % elongation of the specimen immediately after the cross head returns to the original gap as the three on the elastic approaches zero.

(72) Polymer Descriptions

(73) Polymer Example 1 is a <1 weight % diblock, SIS tri-block co-polymer containing 30% by weight styrene and having a MFR of 168 g/10-min (190 C., 2.16 kgs).

(74) Kraton MD 1648 is a <10 weight % diblock, selectively hydrogenated SBS co-polymer containing 20% by weight styrene and having a MFR of 30 g/10-min (190 C., 2.16 kgs).

(75) Vector 4411A is a <1 weight % diblock, SIS tri-block co-polymer containing 44% by weight styrene and having a MFR of 9 g/10-min (190 C., 2.16 kgs).

(76) Vector 6241A is a <1 weight % diblock, SBS tri-block co-polymer containing 43% by weight styrene and having a MRF of 5.0 g/10-min (190 C., 2.16 kgs).

(77) TABLE-US-00001 TABLE ONE Control Control 1 2 Ex. 1 Ex. 2 Ex. 3 Ex. 4 Ex. 5 VECTOR 4411 46.5 23 VECTOR 6241 46.5 20 KRATON MD 45 59.5 1648 Polymer 26 23 59.5 Example 1 Avg. Styrene 44 43 35.7 37 30 20 20 Content of SBC (weight %) ESCOREZ 5690 29.75 29.75 31.5 29.75 ESCOREZ 5615 ESCOREZ 5400 40 ESCOREZ 5415 29.5 30 CALSOL 550 23.25 23.25 22 23.25 PURETOL 35 25 10 IRGANOX 1010 0.5 0.5 0.5 0.5 0.5 0.5 0.5

(78) TABLE-US-00002 TABLE TWO Control 1 Control 2 Ex. 1 Ex. 2 Ex. 3 Ex. 4 Ex. 5 Viscosity (cps) @149 C. (300 F.) 35,150 37,800 17,800 11,500 43,000 5,400 34,500 @163 C. (325 F.) 14,250 18,850 8,850 5,750 23,200 3,290 17,300 @177 C. (350 F.) 7,050 12,050 5,925 3,480 13,350 2,300 10,200 Viscosity Ratio 4.99 3.11 3.00 3.30 3.22 2.35 3.38 @149 C./@177 C. 2-Peak Hysteresis Testing 50% hysteresis Set 1.sup.st cycle (%) 6 5 9 7 9 5 2 Set 2.sup.nd cycle 7 6 11 9 10 8 4 (%) Energy loss (%) 35.1 34.5 41.6 35 34.9 57.1 50 100% hysteresis Set 1.sup.st cycle (%) 16 14 26 20 23 15 9 Set 2.sup.nd cycle (%) 18 16 30 23 26 25 12 Energy loss (%) 46.9 45.6 57.3 51.0 51.1 67.9 61 150% hysteresis Set 1.sup.st cycle(%) 26 23 49 36 41 30 15 Set 2.sup.nd cycle (%) 28 27 54 40 45 50 21 Energy loss (%) 56.2 54.4 67.2 62.4 61.9 76 70.2 1-Peak Hysteresis Testing Extension at 10N 122.9 40.7 120 127 (%) Force Relaxation 4.5 3.9 6.4 5.0 (N) Set (%) 25.1 10.9 26 11 Adhesion Average peel 68 272 Substrate Substrate Substrate Substrate Substrate (gram force) failure failure failure failure* failure* *Bonds were pulled by hand