METHOD AND DEVICE FOR PREPARING GRAPHENE AND HYDROGEN GAS BY CONVERTING WASTE PLASTICS WITH JOULE HEAT

Abstract

A method and a device for preparing graphene and hydrogen gas by converting waste plastics with Joule heat are provided according to the present application. The method uses the Joule heat generated when a strong current passes through the mixed plastic material mixed with conductive additive, as the reaction driving energy. By Joule heating, carbon-carbon bonds and carbon-hydrogen bonds are broken, amorphous carbon is converted into sp.sup.2 hybridized high-purity graphene, and hydrogen atoms are converted into hydrogen gas. The reaction device used by the method is mainly composed of three parts: an airtight reaction chamber, a gas collecting system and a power control system.

Claims

1. A device for preparing graphene and hydrogen gas by converting plastic waste with Joule heat, comprising an airtight reaction chamber, a gas collecting system and a power control system, wherein the airtight reaction chamber comprises: a central quartz chamber configured to hold a conductive mixture, two refractory, gas permeable and conductive auxiliary electrodes arranged on the left and right sides of the conductive mixture, and two hollow electrodes inserted from the left and right sides of the conductive mixture, wherein a gas inlet pipeline is arranged outside the airtight reaction chamber and configured to transport inert protective gas into the airtight reaction chamber; the gas collecting system comprises: a filter cold trap configured to filter off solid particles and a waxy by-product and connected with an outer part of the hollow electrodes, a pressure-resistant gas collecting pipeline, a gas collecting unit, and a gas pressure control unit arranged on the pressure-resistant gas collecting pipeline and connected to the gas collecting unit, wherein the gas inlet pipeline of the airtight reaction chamber, the filter cold trap, and the pressure-resistant gas collecting pipeline of the gas collecting system are connected by a three-way valve, and the hollow electrodes, the filter cold trap, the three-way valve, and the pressure-resistant gas collecting pipeline together form an airtight passage; wherein the power control system is configured to regulate an output voltage, an on-off state, an on-off time and an on-off mode of a circuit according to resistance of the conductive mixture in the airtight reaction chamber.

2. The device for preparing graphene and hydrogen gas by converting plastic waste with Joule heat according to claim 1, wherein each of the hollow electrodes is closely attached to the corresponding refractory, gas permeable and conductive auxiliary electrode, a refractory silicone seal ring is provided between each of the hollow electrodes and the corresponding refractory, gas permeable and conductive auxiliary electrode, and has a distance of 10-20 mm from the corresponding refractory, gas permeable and conductive auxiliary electrode, and a gas barrier structure is formed by each refractory silicone seal ring together with an outer wall of the central quartz chamber and the corresponding hollow electrode, to restrict gas in the central quartz chamber to entering or exiting only from a passage inside each of the hollow electrodes.

3. The device for preparing graphene and hydrogen gas by converting plastic waste with Joule heat according to claim 1, wherein the hollow electrodes are made of a conductive refractory material of graphite or copper.

4. The device for preparing graphene and hydrogen gas by converting plastic waste with Joule heat according to claim 1, wherein the refractory, gas permeable and conductive auxiliary electrodes are prepared by weaving and compacting copper foam or fine copper wires.

5. The device for preparing graphene and hydrogen gas by converting plastic waste with Joule heat according to claim 1, wherein the power control system comprises: two copper connection webbings tightly wrapped on the left and right sides of the hollow electrodes, two high-voltage cables connected with the two copper connection webbings, a circuit control unit, and a high-voltage capacitor bank with a capacity of 50 mF-300 mF, wherein the two high-voltage cables are respectively connected to anode and cathode of the high-voltage capacitor bank, and the circuit control unit is arranged on one of the high-voltage cables connected to the high-voltage capacitor bank.

6. A method for preparing graphene and hydrogen gas by converting plastic waste with Joule heat by using the device according to claim 1, comprising: S1: pretreating plastic waste to obtain plastic powder with a particle size of about 0.1-2.0 mm, well-mixing the plastic powder with 5-20 wt % of carbon black added as a conductive additive to form a conductive mixture, controlling a resistance of the conductive mixture to 0.1-100Ω, and filling the conductive mixture into the central quartz chamber; S2: opening the gas inlet pipeline and closing the gas collecting pipeline by turning the three-way valve before reaction, introducing argon gas or nitrogen gas as inert protective gas into the reaction chamber, and collecting the gas generated during the reaction by closing the gas inlet pipeline and opening the gas collecting pipeline; and S3: during the reaction, charging the high-voltage capacitor bank to 50-1000V by the power control system according to the mass and resistance of the conductive mixture, and controlling the on-off state, the on-off time of 50-1000 ms, and the frequency of on-off switching of one of the high-voltage cables at the positive pole of the high-voltage capacitor bank by the circuit control unit.

7. The method according to claim 6, wherein in step S2, the gas pressure of the airtight passage is controlled by the gas pressure control unit to be within a range of 0-0.5 Mpa, and when the gas pressure is higher than a set value, the gas enters the gas collecting unit for storage through an exhaust hole of the gas pressure control unit.

8. The method according to claim 6, wherein the plastic waste includes LDPE, HDPE, PP, PS, and PET.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0024] The present application will be described in more detail below on the basis of embodiments and with reference to the accompanying drawings.

[0025] FIG. 1 is a schematic view of a device according to the present application.

DETAILED DESCRIPTION OF THE DISCLOSURE

[0026] Technical solutions in the embodiments of the present application are clearly and completely described hereinafter in conjunction with the drawings in the embodiments of the present application. Apparently, the embodiments described in the following are only some embodiments of the present application, rather than all embodiments. Based on the embodiments in the present application, all of other embodiments, made by the person of ordinary skill in the art without any creative efforts, fall into the scope of protection of the present application.

First Embodiment

[0027] As shown in FIG. 1, a device for preparing graphene and hydrogen gas by converting waste plastics with Joule heat is provided, which includes an airtight reaction chamber, a gas collecting system and a power control system.

[0028] The airtight reaction chamber includes a central quartz chamber 1 configured to hold a conductive mixture of waste plastics, two refractory, gas permeable and conductive auxiliary electrodes 2 arranged on the left and right sides of the conductive mixture, and two hollow electrodes 5 inserted from the left and right sides of the conductive mixture.

[0029] A gas inlet pipeline 8 for transporting inert protective gas into the airtight reaction chamber is provided outside the airtight reaction chamber.

[0030] The gas collecting system includes a filter cold trap 6, a pressure-resistant gas collecting pipeline 9, a gas collecting unit 11, and a gas pressure control unit 10 arranged on the pressure-resistant gas collecting pipeline 9 and connected to the gas collecting unit 11. The gas inlet pipeline 8 of the airtight reaction chamber, the filter cold trap 6, and the pressure-resistant gas collecting pipeline 9 of the gas collecting system are connected by a three-way valve 7. The hollow electrodes 5, the filter cold trap 6, the three-way valve 7, and the pressure-resistant gas collecting pipeline 9 together form an airtight passage. Each of the two hollow electrodes 5 is closely attached to the corresponding refractory, gas permeable and conductive auxiliary electrode 2, a refractory silicone seal ring 4 is provided between each of the hollow electrodes 5 and the corresponding refractory, gas permeable and conductive auxiliary electrode 2, and has a distance of 10-20 mm from the corresponding refractory, gas permeable and conductive auxiliary electrode 2, and each silicone sealing ring 4 forms a gas barrier structure together with an outer wall of the central quartz chamber 1 and the corresponding hollow electrode 5, ensuring that the gas in the central quartz chamber 1 can only enter and exit from a passage inside each of the two hollow electrodes 5.

[0031] The filter cold trap 6 is configured to filter off solid particles and waxy by-products, and is connected with an outer part of the hollow electrode 5.

[0032] The power control system is configured to regulate an output voltage, an on-off state, an on-off time and an on-off mode of the circuit according to the resistance of the conductive mixture in the airtight reaction chamber.

[0033] Each of the two hollow electrodes 5 is made of a conductive refractory material such as graphite or copper. Each refractory, gas permeable and conductive auxiliary electrode 2 is prepared by weaving and compacting copper foam or fine copper wires.

[0034] The power control system includes two copper connection webbings 15 tightly wrapped on the left and right sides of the two hollow electrodes 5, two high-voltage cables 14 connected with the two copper connection webbings 15, a circuit control unit 13, and a high-voltage capacitor bank 12 with a capacity of 50 mF-300 mF. The two high-voltage cables 14 are respectively connected to the anode and cathode of the high-voltage capacitor bank 12, and the circuit control unit 13 is arranged on one of the high-voltage cables 14 connected to the high-voltage capacitor bank 12.

Second Embodiment

[0035] A method for preparing graphene and hydrogen gas by converting waste plastics with Joule heat by means of the device provided by the first embodiment is further provided according to this embodiment, which includes the following steps:

[0036] S1: pretreating plastic waste to be processed, such as LDPE, HDPE, PP, PS, and PET, to obtain plastic powder with a particle size of 0.1-2.0 mm, well-mixing the plastic powder with 5-20 wt % of carbon black added as a conductive additive to form a conductive mixture, controlling a resistance of the conductive mixture to 0.1-100Ω, and filling the conductive mixture into the central quartz chamber 1;

[0037] S2: opening the gas inlet pipeline 8 and closing the gas collecting pipeline 9 by turning the three-way valve 7 before reaction, introducing inert protective gas argon or nitrogen into the reaction chamber, and then collecting the gas generated during the reaction by closing the gas inlet pipeline 8 and opening the gas collecting pipeline 9; wherein the gas pressure of the airtight passage is controlled by the gas pressure control unit 10 to be within the range of 0-0.5 Mpa, and when the pressure is higher than a set value, the gas enters the gas collecting unit 11 for storage through an exhaust hole of the gas pressure control unit 10.

[0038] S3: charging the high-voltage capacitor bank to 50-1000V by the power control system according to the mass and a resistance of the conductive mixture during the reaction, and controlling the on-off state, the on-off time of 50-1000 ms, and the frequency of on-off switching of the high-voltage cable at the positive pole of the high-voltage capacitor bank 12 by the circuit control unit 13.

[0039] Although the present application has been described with reference to the preferred embodiments, various improvements can be made to it and the components therein can be replaced with equivalents, without departing from the scope of the present application. In particular, as long as there is no structural conflict, the various technical features mentioned in the various embodiments can be combined in any manner. The present application is not limited to the specific embodiments disclosed herein, but includes all technical solutions falling within the scope of the claims.