Apparatus and a method for treatment of mined material with electromagnetic radiation
10597750 ยท 2020-03-24
Assignee
Inventors
- Georgios Dimitrakis (Nottingham, GB)
- Samuel Kingman (Burton on Trent, GB)
- Christopher Dodds (Nottingham, GB)
- Andrew Batchelor (Nottingham, GB)
- Aled Jones (Nottingham, GB)
Cpc classification
B02C19/18
PERFORMING OPERATIONS; TRANSPORTING
C22B4/00
CHEMISTRY; METALLURGY
International classification
B02C19/18
PERFORMING OPERATIONS; TRANSPORTING
C22B4/00
CHEMISTRY; METALLURGY
Abstract
The present disclosure provides an apparatus for treatment of mined material. The apparatus comprises a source for generating electromagnetic radiation and a microwave inlet region for exposing fragments of the mined material to the electromagnetic radiation. Further, the apparatus comprises a reflective structure adjacent the microwave inlet region and providing, or surrounding, a passage for guiding the fragments of the mined material to the microwave inlet region. The reflective structure is arranged to attenuate penetration of the electromagnetic radiation from the microwave inlet region into the passage during throughput of the fragments of the mined material.
Claims
1. An apparatus for treatment of mined material, the apparatus comprising: a source for generating electromagnetic radiation; a radiation inlet; a radiation inlet region at the radiation inlet and being arranged for exposing fragments of the mined material to the generated electromagnetic radiation; a tubular circular passage with a smooth surface facing the fragments of the mined material for guiding the fragments of the mined material to the radiation inlet region; and a reflective structure separate from the passage and surrounding at least a portion of the passage, the reflective structure being arranged to attenuate penetration of the electromagnetic radiation from the radiation inlet region into the passage during throughput of the fragments of the mined material, wherein the reflective structure comprises a metallic tube that comprises a plurality of a succession of circular first zones and circular second zones, and wherein the first zones have an average inner diameter that is smaller than that of the second zones and are arranged such that the metallic tube has an inner diameter that undulates in a direction along the tube such that the metallic tube has a corrugated wall portion that produces a reflected electromagnetic radiation towards the radiation inlet region, wherein the reflective structure has a dimensional periodicity of protruding sections of the second zones of the corrugated wall portion which produces reflected electromagnetic radiation that includes the wavelength of the electromagnetic radiation to which the fragments are exposed, and wherein the reflective structure produces an electric field with electric field intensity which increases towards the radiation inlet region at a rate of 15 dB/m or greater.
2. The apparatus of claim 1, wherein the reflective structure is arranged such that the electric field intensity associated with the electromagnetic radiation decreases at a rate of at least 15 dB/m in a direction from the radiation inlet region into the passage.
3. The apparatus of claim 1, wherein the reflective structure comprises an inner conduit that has at least a wall portion formed from a material that is transparent for the electromagnetic radiation and that is positioned to provide the passage.
4. The apparatus of claim 1 wherein the radiation inlet region comprises an inner conduit that comprises at least a wall portion that is formed form a material that is transparent for the electromagnetic radiation and is at least partially positioned at the radiation inlet region.
5. The apparatus of claim 3 wherein the material that is transparent for the electromagnetic radiation has a relative dielectric permittivity *j (: real part of the relative dielectric permittivity; : imaginary part of the relative dielectric permittivity) and wherein is less than 0.1.
6. The apparatus of claim 3 wherein the material that is transparent for the electromagnetic radiation has a relative dielectric permittivity *j (: real part of the relative dielectric permittivity; : imaginary part of the relative dielectric permittivity) and wherein is in the range of 120.
7. The apparatus of claim 1 wherein the reflective structure is positioned superjacent the radiation inlet region.
8. The apparatus of claim 1 wherein the apparatus is arranged for throughput of a packed bed of the fragments of the mined material by gravity.
9. The apparatus of claim 1 wherein the reflective structure is arranged such that an electric field intensity associated with the electromagnetic radiation increases towards the radiation inlet region at a rate of 30 dB/m or greater region into the passage.
10. The apparatus of claim 1 wherein the source is arranged to generate microwave radiation.
11. The apparatus of claim 10 wherein the apparatus is arranged such that the microwave radiation causes heating of the fragments of the mined material in the passage and an associated power-density in at least some heated portions of fragments of the mined material is at least 110.sup.9 W/cm.sup.3 when the fragments of the mined material are put through the apparatus in the form of a packed bed.
12. The apparatus of claim 10 wherein the apparatus is arranged such that the microwave radiation causes heating of the fragments of the mined material in the passage and an associated power-density in at least some heated portions of fragments of the mined material are put through the apparatus in the form of a packed bed.
13. The apparatus of claim 1 wherein a length of the reflective structure is arranged such that microwave radiation propagating along a portion of the length will traverse an environment in which dielectric properties change periodically.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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DETAILED DESCRIPTION OF SPECIFIC EMBODIMENTS
(14) Referring initially to
(15) The fragments of the mined material are then directed by conveyor belt 104 into a chute that comprises chute portions 106, 108 and 112. The chute provides a vertical passage through which the fragments of the mined material fall by gravity in the form of a packed bed. The chute portion 106 is a conduit that surrounds the falling fragments of the mined material and the chute portion 108 guides the fragments of the mined material through a microwave inlet region 110. The apparatus 100 comprises a microwave generator (not shown) that is arranged to generate high-intensity microwave radiation. The microwave inlet region 110 is positioned such that the fragments that flow in the form of a packed bed are exposed to the microwave radiation. The chute portion 112 directs the fragments of the mined material to an area for further processing.
(16) The microwave generator generates microwave radiation which by interaction with the fragments of the mined material (such as an ore) induces the microwave absorbing phase such that a resulting power-density in the microwave absorbent phase of the ore is in the region of 10.sup.6-10.sup.14 W/m.sup.3. Different types of materials have different receptiveness for microwave radiation (depending on their dielectric properties) and different thermal expansion coefficients. For example, minerals, silicates or similar that form rock have a thermal expansion coefficient that is different to that of copper or iron containing minerals and also absorb different amount of energy when exposed to the microwaves. Consequently, when for example copper-containing minerals are surrounded by gangue and are exposed to such treatment, micro cracks form due to the differential expansion between the hot mineral and the cold gangue. The micro-cracks form around the boundaries of the hot mineral phase enclosed in the gangue, which facilitates material separation.
(17) The effectiveness of the microwave treatment in inducing micro-cracks depends on the value and rate of development of a temperature differential that is created within the fragments of the mined material during the exposure of the fragments to the microwave radiation. Consequently, pre-heating of the fragments at a position before the treatment region of the chute portion 108 results in a lower temperature differential and consequently in lower effectiveness of the microwave treatment process.
(18) Embodiments of the present invention provide a microwave applicator and confining chokes. The confining chokes are arranged to restrict via reflection the propagation of the electromagnetic radiation from the microwave inlet region 110 into a passage within the chute portion 106 and thereby attenuate the propagation further into the chute portion 106 by 15 dB, 30 dB or more such that a large percentage of the radiation power is confined over a set distance within the treatment region. The confining chokes are effective to provide an abrupt change in electric field intensity of the electromagnetic radiation as fragments of the mined materials (ores) move through the chokes into the microwave inlet region 110. The highly localised increase in temperature due to the abrupt change in electrical field intensity results in uneven thermal expansion that in turn provides a higher degree of fracture. A further benefit of the confining chokes is that the loss of energy through the chute portion 106 is reduced, which increases the energy available in the treatment region and consequently further increases the efficiency.
(19) Consequently, the chute portion 106 comprises a reflective structure (the above-mentioned choke) that is arranged to reflect a portion of microwave radiation that propagates from the treatment region within and immediately adjacent the microwave inlet region 110 into the chute portion 106. The back reflection of the microwave radiation reduces propagation of the microwave radiation through the chute portion 106. The reflective structure of the chute portion 106 is arranged such that the electric field intensity decreases at a rate of 15 dB/m (typically at least 20 or 30 dB/m) in a direction from the microwave inlet region 110 into the chute portion 106. The fragments of the mined material experience a corresponding increase in electric field intensity at a rate of at least 15 dB/m, typically at least 20 or 30 dB/m (the increase in power density may be of at least 30 dB, 40 or 60 dB within the heated microwave absorbent phase of the fragments dependent on the ore) to cause structural alternations of the fragments of the mined material. Consequently, the volume of the ore that is exposed to high power microwaves is reduced resulting in an increase in power density inside the exposed ore body.
(20) The microwave inlet region 110 is defined by a chute portion that has a microwave inlet through which the generated microwave radiation is directed into the microwave inlet region such that the falling packed bed of the fragments of the mined material are exposed to the generated microwave radiation. The chute 106 comprises in this embodiment an inner conduit or liner that is surrounded by the reflective structure and is arranged to guide the packed bed of the fragments of the mined material through the reflective structure to the microwave inlet region 110. The inner conduit or liner comprises a material that is transparent for the microwave radiation such that the microwave radiation can be reflected by the surrounding chokes. The chute portion 108 guides the packed bed of the fragments of the mined material through the microwave inlet region 110 and has a window that is transparent for the microwave radiation such that the microwave radiation can within the microwave inlet region 110 be directed to the falling packed bed of the fragments of the mined material. Alternatively, the entire inner conduit may be composed of the microwave transmissive material. The reflective structure and the chute portions will be discussed further below in more detail.
(21) The microwave transparent material has selected dielectric properties. A dielectric material has a relative dielectric permittivity *=j that has a real part and an imaginary part j(). A suitable microwave transmissive material has a relative dielectric permittivity that has a real part in the range of 0.5-50, 1-20 or 5-10 and an imaginary part (the dielectric loss factor) in the range of 0.0001-0.1. For example, the microwave transparent material may be Al.sub.2O.sub.3, ALN, ALB, quartz or another suitable dielectric material.
(22) In general, the inner conduit (or inner liner) provides an inner surface that does not have any pockets, undulations or recesses in which falling fragments of the mined material may accumulate (and consequently the particles of the mined material experience a smooth surface).
(23) The microwave radiation to which the mined material is exposed in the apparatus 100 is continuous (but may in a variation of the described embodiment also be pulsed) and the apparatus 100 is arranged such that the exposure time of the falling packed bed is 0.05 to 1 second. The power density is of the order of 110.sup.7 W/m.sup.3-110.sup.13 W/m.sup.3 in the heated phase within the ore.
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(29) In this embodiment, the chute 106 comprises a succession of corrugations 406 that form a metallic tube having a wall profile that undulates in a direction along the tube. The chute portion further comprises an outer metallic shell that is not shown in
(30) The chute portion 106 has an inner liner 407 that is transparent for the microwave radiation and has the above-defined dielectric properties. In this embodiment, the inner liner 407 is composed of a suitable ceramics material or alumina. If heating of the inner liner 407 is unlikely, the inner liner may also be composed of a suitable plastics material. The inner liner 407 has an inner diameter of 200 mm. The inner liner 407 has a wall thickness that is selected such that back reflection of microwaves into the microwave generator is reduced. For the purpose of a simulation of the source 401 and the load 404 are assumed to have an inner diameter of 300 mm. The conduit 106 has a total length of 1200 mm. It will be appreciated that the corrugated choke may alternatively also be provided in another suitable form. For example, the circular corrugations may be replaced by arc-like portions.
(31) It was again assumed for purposes that of the microwave filed distribution that the inner liner 407 has dielectric properties of *=9j0 and the chute portions are filled with ore having dielectric properties of *=4j0.
(32) In the embodiment illustrated in
(33) Referring now to
(34) Similar to the chute portion 106, the chute portion 550 also comprises a plurality of circular corrugations 554 that together form a corrugated choke and reflect microwave radiation back into the applicator 552. In this embodiment, the chute portion 550 comprises six of such corrugations, but may alternatively also comprise any other number of corrugations. The corrugated choke of the chute portion 550 is a tubular arrangement that is formed form a metallic material and has a largely uniform wall thickness and an undulating inner and outer diameter. A cylindrical liner formed form a material that is substantially transparent for the microwave radiation (such as glass, plastics, or ceramics) is positioned within the corrugated choke. Further, the cute portion 550 has an outer metallic shell that is not shown.
(35) In contrast to the chute portion 106, the corrugations 554 of the chute portion 550 have a diameter that changes along the chute portion 550.
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(39) The corrugations 808 of the reflective structures 802 and 804 decrease in diameter in a direction away from the microwave inlet region 806. The component 800 is arranged such that the microwave absorbent phase of the fragments of mined material that are directed through the conduit 802 to the microwave inlet region experience an increase in power density (dependent on the type of the ore) at a rate of at least 30, 40 or 60 dB/m or more. This significant increase in power density over a relatively short distance is schematically indicated in plot 820 shown in
(40) Also shown in
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(42) Alternatively, the entire chute portion 844 may be composed of a material that is transparent for the microwave radiation. Further, in a variation of the described embodiment the reflective structures 842 and 846 may comprise an inner liner (such as a tube) that is composed of a material that is transparent for the microwave radiation.
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(44) The conduit 872 is arranged such that the microwave radiation can be directed through a wall portion of the conduit 872 at the microwave inlet region 878. Further, as the conduit 872 comprises a material that is transparent for microwave radiation, the alternating ring like zones 880 and 882 can function in the above-defined manner and reduce a penetration of the microwave radiation into the conduit 872 form the microwave inlet region 878.
(45) It will be appreciated that the reflective structures shown in
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(49) The microwave radiation is generated by a microwave radiation source (not shown) that is coupled to the microwave inlet portion 1106. The conduits 1102 and 1104 comprise further corrugated reflective structures 1114 and 1116, which are arranged to reduce propagation of microwave radiation away from the microwave inlet portion 1106 further. In addition, the conduits 1102 and 1104 have absorbent microwave chokes 1118 and 1120, respectively, which ensure that there is no leakage of microwave radiation out of the component 1100.
(50) The component 1100 also comprises a tube 1122 that is positioned within the microwave inlet portion 1106, the reflective structure 1108 and the reflective structure 1110. The tube 1122 is formed from a material that is transparent to microwave radiation (and which has the above-described dielectric properties). Further, the component 1100 comprises a steel encasing 1124 that encloses a portion of the microwave inlet portion 1106 and the corrugated reflective structures 1108 and 1110.
(51) In this embodiment the reflective corrugated structures 1108 and 1110 have identical properties, but are rotated about a central transversal axis through the microwave inlet portion 1106 by 180. Consequently, the reflective structure 1108 results in a steep increase in electrical field (or power density) as experienced by the fragments and the reflective structure 1110 results in a steep decrease in electric field intensity (or power density) as experienced by the falling particles.
(52) The reflective structure 1108 increases the efficiency of the microwave treatment by confining the electric field (and power density). Both reflective structures 1108 and 1110 reduce loss of electric field intensity (and power density) from the treatment region to the conduits, which increase the efficiency of the microwave treatment and reduces power consumptions.
(53) Referring now to
(54) It will be appreciated by a person skilled in the art that the components 1400 and 1450 may alternatively be provided in various related forms. For example, the components may comprise sections in which the passage has a substantially uniform diameter and that are adjacent sections in which the diameter changes. Further, the components 1400 and 1450 may not have an inner liner, but the zones of the reflective structure may be arranged to provide the passage that has a diameter that changes in the above-described manner. The extent of the change in the diameter of the passage depends on a number of factors including but not limited to a target throughput for the apparatus, the mineralogy and composition of the mined material, the size of the fragments including the fragment size distribution, the packing density in the bed, the power intensity and other characteristics of the microwave radiation.
(55) It is to be appreciated that various variations of the described embodiments are possible. For example, the apparatus 100 may be arranged to generate microwave radiation having any suitable frequency. Further, the chute portion 106 may not necessarily be arranged vertically and may have any suitable cross-sectional shape, diameter and length. Further, the chute portion 106 may have any number of ring or arc-like zones. In addition, it is to be appreciated that the described apparatus may not necessarily comprise reflective microwave choke structures, but may in a variation of the described embodiments also comprise absorbing microwave choke structures, which may designed such the fragments of the mined material experience an increase of electric filed intensity (and a corresponding increase in power density) at the described high rate.