ARRANGEMENT FOR ANTI-FOULING OF A PROTECTED SURFACE
20200087799 ยท 2020-03-19
Inventors
Cpc classification
C23F13/06
CHEMISTRY; METALLURGY
B08B17/02
PERFORMING OPERATIONS; TRANSPORTING
C23F2213/31
CHEMISTRY; METALLURGY
C23F13/04
CHEMISTRY; METALLURGY
International classification
C23F13/04
CHEMISTRY; METALLURGY
B08B17/02
PERFORMING OPERATIONS; TRANSPORTING
Abstract
An arrangement is provided for anti-fouling of a surface (30) of a marine structure (50) when in contact a liquid like seawater. The arrangement has floating electrodes and a power source (130) coupled to conductors in contact with the liquid, which conductors are distributed across the marine structure for providing an electrical potential across a protected area (40) of the surface. The floating electrodes (110) are arranged on the surface covering a protected area. Each floating electrode has a conductive layer being electrically isolated from the surface, and a dielectric layer (112) separating the conductive layer and the liquid. The power source is arranged to generate voltage pulses for charging and discharging the floating electrodes due to changes in the electrical potential for generating charging and discharging currents in the liquid at the dielectric layer. Effectively, such currents prevent or at least reduce biofouling.
Claims
1. An arrangement for anti-fouling of a surface, the arrangement comprising: a power source, the power source having a first pole and a second pole, wherein the first pole is coupled to a first conductor, wherein the first conductor is in contact with a liquid, wherein the second pole is coupled to a second conductor, wherein the second conductor is in contact with the liquid, wherein the first conductor and the second conductor is distributed across a marine structure, wherein the marine structure includes the surface, wherein the first conductor and the second conductor provide an electrical potential across a protected area of the surface; and one or more floating electrodes, wherein the one or more floating electrodes cover the protected area, wherein each floating electrode comprises a conductive layer, wherein the conductive layer is electrically isolated from the surface and a dielectric layer; wherein the power source is arranged to generate voltage pulses, wherein the voltage pulses are arranged to charge and discharge.
2. The arrangement according to claim 1, wherein the power source is arranged to generate the voltage pulses, wherein the voltage pulses have rising or falling slopes, wherein the rising or falling slopes change at a required rate of volts per second such that charging or discharging currents are anti-fouling.
3. The arrangement according to claim 1, wherein the power source is arranged to generate the voltage pulses having rising and falling slopes, wherein the rising or falling slopes are generated by switching a DC voltage on and off;
4. The arrangement according to claim 2, wherein the power source is arranged to generate the voltage pulses having a limited duration between the rising and falling slopes, wherein the duration is limited to enabling the charging current to charge the floating electrodes and to limit subsequent discharging of the floating electrodes due to leakage current.
5. The arrangement according to claim 1, wherein the first conductor is arranged for constituting an anode, wherein the second conductor is arranged for constituting a cathode, wherein the second conductor comprises conductive parts of the marine structure in direct contact with the liquid; wherein the power source is arranged to yield impressed current cathodic protection of the marine structure by generating an average DC component between the anode and the cathode.
6. The arrangement according to claim 5, wherein the power source is arranged to generate the average DC component by pulse width modulation of the voltage pulses.
7. The arrangement according to claim 5, wherein the power source is arranged to generate the average DC component by providing a continuous DC offset voltage added to the voltage pulses.
8. The arrangement according to claim 1, wherein the conductive layer is isolated from the marine structure by a coating layer.
9. The arrangement according to claim 1, wherein the arrangement comprises a foil of isolating material, wherein the foil comprises a plurality of the conductive layers positioned next to each other plurality.
10. The arrangement according to claim 9, wherein the conductive layers are isolated from the liquid by the isolating material constituting the dielectric layer.
11. The arrangement according to claim 9, wherein the one or more conductive layers are embedded in the isolating material close to the liquid to form the dielectric layer, wherein the dielectric layer has a limited thickness, wherein the isolating material constitutes a separation layer between the conductive layer and the surface of the marine structure, wherein the separation layer has a thickness well above the limited thickness.
12. A marine structure comprising: an arrangement, the arrangement comprising: a power source, the power source having a first pole and a second pole, wherein the first pole is coupled to a first conductor, wherein the first conductor is in contact with a liquid, wherein the second pole is coupled to a second conductor, wherein the second conductor is in contact with the liquid, wherein the first conductor and the second conductor is distributed across a marine structure, wherein the marine structure includes the surface, wherein the first conductor and the second conductor provide an electrical potential across a protected area of the surface; and one or more floating electrodes, wherein the one or more floating electrodes cover the protected area, wherein each floating electrode comprises a conductive layer, wherein the conductive layer is electrically isolated from the surface and a dielectric layer; wherein the power source is arranged to generate voltage pulses, wherein the voltage pulses are arranged to charge and discharge, wherein the first conductor and the second conductor are distributed across the marine structure, wherein the first conductor and the second conductor are arranged to provide for providing an electrical potential across a protected area of the surface; wherein the power source has the first pole coupled to the first conductor and the second pole coupled to the second conductor; and wherein the one or more floating electrodes are attached on the surface of the marine structure, wherein the one or more floating electrodes cover the protected area.
13. The marine structure according to claim 12, wherein a plurality of the floating electrodes comprises a pattern of the conductive layers, wherein the pattern of the conductive layers is shaped in complementary forms, wherein each complementary form constitutes a floating electrode separated by interruptions from adjacent floating electrodes, wherein the interruptions provide electrical isolation, wherein the interruptions are and relatively small with respect to the floating electrodes.
14. (canceled)
15. A method of operating an arrangement, wherein the arrangement comprises: a power source, the power source having a first pole and a second pole, wherein the first pole is coupled to a first conductor, wherein the first conductor is in contact with a liquid, wherein the second pole is coupled to a second conductor, wherein the second conductor is in contact with the liquid, wherein the first conductor and the second conductor is distributed across a marine structure, wherein the marine structure includes the surface, wherein the first conductor and the second conductor provide an electrical potential across a protected area of the surface; and one or more floating electrodes, wherein the one or more floating electrodes cover the protected area, wherein each floating electrode comprises a conductive layer, wherein the conductive layer is electrically isolated from the surface and a dielectric layer; wherein the power source is arranged to generate voltage pulses, wherein the voltage pulses are arranged to charge and discharge, wherein the one or more floating electrodes are located on a surface of the marine structure, wherein the marine structure is in contact with a liquid containing biofouling organisms, wherein each floating electrode comprises a conductive layer, wherein the conductive layer is electrically isolated from the surface, wherein a dielectric layer to separates the conductive layer and the liquid, wherein the first conductor and the second conductor is distributed across the marine structure, wherein the first conductor and the second conductor are arranged to provide an electrical potential across the protected area the method comprising: generating voltage pulses between the first conductor and the second conductor, wherein the voltage pulses are arranged to charge and discharge.
16. The arrangement according to claim 1, wherein the power source is arranged to generate the voltage pulses having rising and falling slopes, wherein the power source is arranged to generate the voltage pulses, wherein the voltage pulses have ramps constituting the rising slopes, wherein the ramps limit the amount of charging current for charging the floating electrodes, wherein the voltage pulses have falling slopes by switching the voltage off.
17. The arrangement according to claim 1, wherein the conductive layer is isolated from the liquid by a coating layer, wherein the coating layers consist of the dielectric layer.
18. The arrangement according to claim 1, wherein the arrangement comprises tiles of isolating material, wherein the tiles are in sheet form, wherein the tiles comprise one or more conductive layers positioned next to each other.
19. The arrangement according to claim 9, wherein the conductive layers are isolated from the protected surface by the isolating material.
20. The arrangement according to claim 10, wherein the one or more conductive layers are embedded in the isolating material close to the liquid to form the dielectric layer, wherein the dielectric layer has a limited thickness, wherein the isolating material constitutes a separation layer between the conductive layer and the surface of the marine structure, wherein the separation layer has a thickness well above the limited thickness.
21. The marine structure according to claim 12, wherein a plurality of the floating electrodes comprises partly overlapping floating electrodes, wherein the conductive layers of the overlapping floating electrodes are separated by isolating material, wherein the isolating material provides electrical isolation between overlapping parts of the partly overlapping floating electrodes.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0044] These and other aspects of the invention will be apparent from and elucidated further with reference to the embodiments described by way of example in the following description and with reference to the accompanying drawings, in which
[0045]
[0046]
[0047]
[0048]
[0049] The figures are purely diagrammatic and not drawn to scale. In the Figures, elements which correspond to elements already described may have the same reference numerals.
DETAILED DESCRIPTION OF THE EMBODIMENTS
[0050] In the following, the present invention will be explained with reference to an application scenario, in which it is used
[0051]
[0052] The power source has a first pole 131 coupled to a first conductor 121 in contact with the liquid, for example a metal electrode extending into the liquid. The power source also has a second pole 132 coupled to a second conductor 122 in contact with the liquid. In the Figure, the marine structure is show to be covered by a coating layer or paint layer 60. The second conductor is formed by a bare area of the marine structure, e.g. a rudder of a ship. For example, for a fully painted ship, propellers are usually unpainted and have an electric connection towards the inner hull. The hull is coupled to one pole of the power source at ground or minus potential and thus also the propellers are at that potential. Instead of, or in addition to, using existing parts of the marine structure, the second conductor may also have one or more metal electrodes extending into the liquid. In use, the first and second conductors are positioned distributed across the marine structure. The power source generates a voltage difference between the conductors so as to provide an electrical potential across the protected area 40. The electrical potential is further elucidated with reference to
[0053] The floating electrodes 110 are arranged covering the protected area. Each floating electrode has a conductive layer being electrically isolated from the surface, the Figure showing four of such electrodes. In practice a large number of electrodes will be positioned on the surface to be protected. In the example embodiment, isolation from the marine structure is formed by the paint layer 60, and by the conductive layer being embedded in an isolating material 111. The isolating material also forms a dielectric layer 112 which separates the conductive layer and the liquid.
[0054] Optionally, the conductive layer may be applied as a metallic layer to the surface as follows. Before applying the metallic layer, the surface is isolated by a coating layer or paint layer on the surface of the marine structure. Then conductive shapes are provided on the coating or paint, e.g. metal foils glued on the isolated surface. Optionally, a pattern of shapes may be formed by spraying a conductive paint while using a mask that provides interruptions between the shapes. Also, a metallic layer may be provided first and subsequently locally interrupted to form isolated patches. Finally, the conductive layer may be isolated from the liquid by a further coating or paint layer of isolating material constituting the dielectric layer.
[0055] The power source is arranged to generate voltage pulses for charging and discharging the floating electrodes due to changes in the electrical potential for generating charging and discharging currents in the liquid at the dielectric layer, as elucidated now.
[0056]
[0057] The Figure shows the electrical potential across the protected area by grey arrows 230 indicating current flowing from the first to the second conductors via the liquid. Also, the Figure shows lines 231 having the same potential, also called iso-potential lines. In the example, the potential at the anodes is shown as 30 Volt, and the potential at the cathodes is shown a 0 Volt. In between the conductors, a potential of 15 Volt is indicated near floating electrodes 210 (only a few shown). The electrodes are formed by metal layers covered by an isolating layer 211, e.g. another paint layer or coating sprayed on the metal layers, which isolating layers form a dielectric layer separating the metal layers from the conductive liquid. So, the floating electrodes, in combination with the dielectric layer and the liquid, form capacitors.
[0058] After the start of a voltage pulse, e.g. by a switch connecting to DC voltage to the anodes, the floating electrodes are charged. The potential of the electrodes is indicated as x Volt. The hull is coupled to the cathodes and remains at 0 Volt, as indicated by a dashed arrow. If effectively a low capacitance is formed between the hull and the floating electrodes, the electrodes will be charged to almost 15 Volt. Actually, the value of x depends on the ratio of said capacitance to the liquid and the capacitance of the electrodes to the ship's hull. If both dielectric layers are of equal effective thickness, the potential of 15 Volt in the liquid will charge the capacitor to 7.5 Volt. By providing a relatively thin top cover layer and a relatively thick paint layer on the hull, the potential will be higher, proportional to the ratio of both capacitances.
[0059] It is assumed that the power source can deliver the current required for charging the capacitors. However, in practice the current from the power source may be limited, and also the liquid may have some resistance. So, the capacitors will be charged by a voltage pulse have a slope according to a time constant, as illustrated in
[0060] After the voltage pulse ends, e.g. by switching off a DC power source or according to a pulse duration determined by the power source, the electrical potential across the marine structure will be zero, and the floating electrodes will discharge. The charging and discharging currents will flow via the liquid and the first and second conductors. In particular, the charging and discharging currents will also flow at the dielectric layer, i.e. at the surface of the isolating material where the dielectric layer contacts the liquid. By the charging and/or discharging currents occurring at that surface bio fouling at that surface is prevented, or at least reduced.
[0061] To counter natural corrosion of the steel hull most ships are coated or painted and in addition often equipped with passive or active cathodic protecting systems such that the ship hull remains protected against natural corrosion when the protective coat or paint fails locally. Passive systems use sacrificial Zinc, Aluminum or Iron anodes that dissolve electro-chemically over time. To protect the unpainted propellers and unpainted sections of the hull from corroding, an electric current (DC) may be sent to these parts, called impressed current. Since seawater wets all these parts, a seawater wet anode at a positive potential may be used to reach all these parts. Such active systems impress a DC current in using anodes made of MMO-Ti (mix metal oxides) coated Titanium or Pt/Ti (Platinum coated Titanium). For active systems impressing a DC current into the sea water (ICCP) careful monitoring is required as too large currents may dissolve the hull locally at enhanced rates. Obviously, anti-fouling solutions should not render the cathodic protection system to fail. Hence, the ship's hull may act as one terminal, and the sea water may serve as a high conductivity medium closing the electric circuit to the other conductor terminal.
[0062] In practice, once the capacitors are charged the current consumption drops to zero. An ICCP system providing current via the same anodes and cathodes can also be used to charge the floating capacitors, e.g. by using a switch to create pulses. Adjustment for changing conditions may be done by, for example, averaging using pulse width modulation or duty-cycle adaption to provide the required DC component and to charge the capacitors sufficiently to yield a pH change. When using a switch to switch off the anodes and the anodes are open, the capacitors will discharge towards the naked propellers. The current now flowing out of the capacitor may alter the pH at the surface to reduce bio-fouling. It is noted that, in a system that also provides ICCP, the discharge current direction is equal to the ICCP current direction. Hence ICCP corrosion protection is not opposed.
[0063]
[0064] In an embodiment, the power source is arranged to generate the voltage pulses having rising and falling slopes by switching a DC voltage on and off. A power switch, e.g. a power FET or electromechanical switch, may be connected in series between a pole of the power source and the conductor in contact with the liquid. In practice, the speed of building up the electrical potential on the floating electrode depends on the total available load current and the total surface of all floating electrodes on the marine structure, and the effective resistance of the path via the liquid. The resistance of seawater is low, e.g. a few tenths of an Ohm, and depends on the salt level and temperature of the seawater. The power source may be designed to provide large currents, so as to enable the capacitors to be charged quickly, i.e. the speed only being limited by the resistance of the seawater. The power source may be provided, at the output, with a large electrolytic capacitor or super capacitor to provide large currents during the short charging interval.
[0065] For example, assuming the resistance is 1 Ohm, and the total surface of floating electrodes on a large vessel is 15.000 m.sup.2, and the capacitance per m.sup.2 is between 1-10 mF, charging may take between 0.15 and 1.5 sec. Discharging may take about the same period, for e large vessel about 0.6-6 sec. For small structures a much higher frequency may apply, as the total capacitance is much lower, e.g. 100 Hz to 1 kHz for 15 m.sup.2.
[0066] A relatively slow charging cycle may be executed using a DC power source having a switch to connect and disconnect the power. The switch may be a mechanical switch or relay, or an electronic switch, e.g. a power FET. Also, low frequency AC pulses may be used. To avoid generation of hydrogen at bare parts of the marine structure that are used as conductor for the charge currents, the floating capacitors will be charged to a few volts only, e.g. 4 Volt. A corresponding slope is then about 4 V/0.2 sec=20 V/sec.
[0067] In an embodiment, the power source is arranged to generate the voltage pulses having ramps constituting the rising slopes, the ramp limiting the amount of charging current for charging the floating electrodes, and the voltage pulses having falling slopes by switching the voltage off. In the embodiment, the charging currents may be smaller than the discharging currents. For example, the power source is provided with a current limiter on the output so as to limit the total charging current. Effectively a voltage pulse so limited will have a ramp as rising slope. By switching the power to zero volt, or directly connecting the second conductor to the first conductor, e.g. said anode to the hull, the discharge currents will be only limited by the impedance of the liquid. Effectively, the total charging current is limited while the discharge currents may be larger.
[0068] In an embodiment, the power source is arranged to generate the voltage pulses having a limited duration between the rising and falling slopes. Effectively the pulse need only be long enough to charge the floating electrodes, as a longer pulse only requires additional power due to current flowing from the first conductor to the second conductor, as shown by current arrows 230 in
[0069] In an embodiment of the arrangement for anti-fouling, the first conductor is arranged for constituting an anode and the second conductor comprises conductive parts of the marine structure in direct contact with the liquid for constituting a cathode; and the power source is further arranged to yield impressed current cathodic protection of the marine structure by generating an average DC component between the anode and the cathode. For example, by generating of voltage pulses of an appropriate length and subsequent pauses between pulses, a required average DC component is generated. Effectively, anti-fouling and ICCP are combined by using a single power source and the same conductors as anode and cathode, and by controlling the pulse widths and voltage of the pulses. So, the power source may be arranged to generate the average DC component for ICCP by pulse width modulation of the voltage pulses. Alternatively, or additionally, the power source may be arranged to generate the average DC component by providing a continuous DC offset voltage added to the voltage pulses.
[0070] In an embodiment of the arrangement, the floating electrodes are embedded in a foil of isolating material. The foil may comprise a multitude of the conductive layers positioned next to each other. The foil may be glued to the surface to be protected, which surface is first provided with an isolating layer, e.g. a paint layer or a further foil. Optionally, the arrangement comprises tiles of isolating material in sheet form. A tile may have one conductive layer, isolated at the edges of the tile. Also, the tile may have a multitude of the conductive layers positioned next to each other. Multiple tiles may be glued to a surface to be protected. Optionally, such foils or tiles may overlap during mounting. Where conductive layers overlap, effectively some capacitances in series are formed, while charging and discharging currents still occur at the front capacitor. In the foils and/or tiles, the conductive layers may be isolated from the liquid by the isolating material constituting the dielectric layer. Also, the conductive layers may be isolated from the protected surface by the isolating material. The conductive layers may be embedded in the isolating material close to the liquid to form the dielectric layer having a limited thickness. The isolating material may further constitute a separation layer between the conductive layer and the surface of the marine structure. The separation layer has a thickness well above the limited thickness. The capacitance between the floating electrode and the liquid will then be well above the capacitance between the floating electrode and the marine structure.
[0071] A marine structure may have a surface to be protected when in contact with a liquid containing bio fouling organisms. The marine structure may be provided with an arrangement as described above to be protected from bio-fouling. The first and second conductors are distributed across the marine structure for, in use when powered, providing an electrical potential across the protected area of the surface. The power source has the first pole coupled to the first conductor and the second pole coupled to the second conductor. The floating electrodes are attached on the surface of the marine structure covering the protected area.
[0072]
[0073] The floating electrodes may be formed by a metallic layer, or any other conductive layer, having interruptions 405 in between respective floating electrodes. In the conductive layer, hexagons are shown as an example of complementary forms. A form of the respective isolated floating electrodes is called complementary, if the adjacent parts of neighboring forms are shaped so that small interruptions 405 are in between electrodes. Other examples may be squares or rectangles, or triangles. Each floating electrode is separated by interruptions from adjacent floating electrodes. The interruptions 405 provide electrical isolation and are relatively small with respect to the floating electrodes. On the interruptions, the protection may be less effective, as locally no currents are generated. So, the interruptions are to be made as small as possible. Also, the sides may be undulating or saw-tooth lie in a complementary way, to avoid straight lines of interruptions of isolated material.
[0074] Optionally, the floating electrodes may partly overlap so as to avoid said interruptions (as seen in top view) while still being isolated (in cross section) by an intermediate layer of isolating material. Due to the intermediate layer, the conductive layers of the overlapping floating electrodes are separated by isolating material. The isolating material provides electrical isolation between overlapping parts of the partly overlapping floating electrodes. Optionally, the intermediate layer may be relatively thick with respect to the dielectric layers.
[0075] A method for installing the above arrangements has the following steps, applied to a marine structure to be protected from fouling when in contact with a liquid containing bio fouling organisms. In a first step, the surface of the marine structure that is to be protected may be painted or coated with is isolating layer. In a next step, the one or more floating electrodes may be applied to the surface of the marine structure for covering the protected area of the surface. Also, the first and second conductors may be distributed across the marine structure for providing an electrical potential across the protected area. In a further step, the power source may be provided in or on the marine structure. Finally, the power source is to be connected, e.g. by coupling the first pole to the first conductor, and coupling the second pole to the second conductor.
[0076] A method of operating any of the above arrangements has the following steps. Before operation starts, the arrangement is mounted to a marine structure, and the floating electrodes are located on the surface of the marine structure to be protected from fouling for covering a protected area of the surface. Each floating electrode has a conductive layer which is electrically isolated from the surface and a dielectric layer to separate the conductive layer and the liquid. Also, the first and second conductors are distributed across the marine structure for, when powered, providing an electrical potential across the protected area.
[0077] In operation, the marine structure is in contact with a liquid containing bio fouling organisms. The method involves generating voltage pulses between the first and second conductors for charging and discharging the floating electrodes due to changes in an electrical potential across the protected area for generating charging and discharging currents in the liquid at the dielectric layer.
[0078] It will be clear to a person skilled in the art that the scope of the invention is not limited to the examples discussed in the foregoing, but that several amendments and modifications thereof are possible. While the invention has been illustrated and described in detail in the figures and the description, such illustration and description are to be considered illustrative or exemplary only, and not restrictive. The invention is not limited to the disclosed embodiments. The drawings are schematic, wherein details that are not required for understanding the invention may have been omitted, and not necessarily to scale.
[0079] Variations to the disclosed embodiments can be understood and effected by a person skilled in the art in practicing the claimed invention, from a study of the figures, the description and the attached claims. In the claims, the word comprising does not exclude other steps or elements, and the indefinite article a or an does not exclude a plurality. The term comprise as used in this text will be understood by a person skilled in the art as covering the term consist of. Hence, the term comprise may in respect of an embodiment mean consist of, but may in another embodiment mean contain/include at least the defined species and optionally one or more other species. Any reference signs in the claims should not be construed as limiting the scope of the invention.
[0080] Elements and aspects discussed for or in relation with a particular embodiment may be suitably combined with elements and aspects of other embodiments, unless explicitly stated otherwise. Thus, the mere fact that certain measures are recited in mutually different dependent claims does not indicate that a combination of these measures cannot be used to advantage.
[0081] In a general sense, it is a basic function of the anti-fouling arrangement according to the invention to keep a protected surface free from biofouling. Hence, the invention is applicable in all situations involving a fouling risk, which are situations in which the protected surface is intended to be immersed, at least during a part of the lifetime thereof, in a fouling liquid containing biofouling organisms. Seawater is a well-known example of such a fouling liquid. A marine structure may have a surface on which the above described anti-fouling arrangement is applied for anti-fouling of the surface when immersed in a fouling liquid containing bio fouling organisms. Similarly, a method for installing the above arrangement includes the step of attaching the arrangement to a surface of a marine structure and providing the power source coupled to the respective conductors.
[0082] Finally, use of the above arrangement is foreseen, in particular use of the arrangement installed on a surface of a marine structure for anti-fouling of the surface when immersed in a fouling liquid containing bio fouling organisms. The use requires the floating electrodes to be charged and discharged by the power source as described above. For example, the arrangement according to the invention may be applied on a vessel's hull. Other examples of a protected surface include the exterior surface of box coolers, surfaces of subsea off-shore equipment, interior walls of water reservoirs like ballast tanks of vessels, and filter surfaces of filter systems in desalination plants.
[0083] Summarizing, an arrangement is provided for anti-fouling of a surface of a marine structure when in contact a liquid like seawater. The arrangement has floating electrodes and a power source coupled to first and second conductors in contact with the liquid, which conductors are distributed across the marine structure for providing an electrical potential across a protected area of the surface. The floating electrodes are arranged on the surface covering a protected area. Each floating electrode has a conductive layer being electrically isolated from the surface, and a dielectric layer separating the conductive layer and the liquid. The power source is arranged to generate voltage pulses for charging and discharging the floating electrodes due to changes in the electrical potential for generating charging and discharging currents in the liquid at the dielectric layer. Effectively, such currents prevent or reduce biofouling.