Catalytic or electrocatalytic generation of chlorine dioxide

Abstract

The present invention concerns an electrode element having a valve metal substrate, a first catalyst component applied to said substrate, said first catalyst component suitable for evolving oxygen from an aqueous solution under anodic polarization, a second catalyst component suitable for generating chlorine dioxide from a chlorate solution in acidic environment; said first and second catalyst component being electrically insulated from each other. The inventions also concern an electrolytic cell having such an electrode element and a process for the generation of chlorine dioxide on a catalyst component an electrochemical cell comprising such an electrode element.

Claims

1. An electrode element consisting of an integral electrode comprising two distinct catalyst components arranged in a single piece comprising: a valve metal substrate, wherein the valve metal substrate is a titanium rod; a first catalyst component applied to said substrate, said first catalyst component suitable for evolving oxygen from an aqueous solution under anodic polarization; a second catalyst component suitable for generating chlorine dioxide from a chlorate solution in acidic environment, the second catalyst component is supported on a support and wrapped around the first catalyst component; a spacer arranged between the first catalyst component and the second catalyst component supported on the support, thereby electrically insulating from each other said first and second catalyst components.

2. The electrode element according to claim 1, wherein the support is a ceramic support.

3. The electrode element according to claim 1, wherein the support is a metallic support.

4. An electrolytic cell comprising at least one electrode element as described in claim 3 and a power supply, wherein said second catalyst component is connected to said power supply.

5. The electrode element according to claim 1, wherein said first catalyst component comprises noble metal oxides.

6. The electrode element according to claim 1, wherein said second catalyst component is a mixture of noble metal oxides selected from the group consisting of ruthenium oxide, iridium oxide, palladium oxide, rhodium oxide and platinum oxide, optionally comprising a valve metal oxide.

7. The electrode element according to claim 1, wherein said second catalyst component is in the form of a sheet, a mesh or a porous material.

8. An electrolytic cell comprising at least one electrode element as described in claim 1.

9. The electrode element according to claim 1, wherein the first catalyst component comprises mixed oxides of iridium and tantalum in a 2:1 molar ratio.

10. The electrode element according to claim 1, wherein the second catalyst component comprises ruthenium oxide and rhodium oxide in a 1:2 molar ratio.

11. A process for the generation of chlorine dioxide on a catalyst component comprising the steps of: providing an electrochemical cell comprising at least one cathode and at least one electrode element as described in claim 1 as anode; filling said cell with an aqueous feedstock containing a chlorate solution; electrolyzing said feedstock by passing an electric current between the cathode and the anode thereby forming oxygen and acidity on the surface of said first catalyst component and thereby acidity in close contact with the surface of said second catalyst layer; and stripping and recovering the chlorine dioxide generated on said second catalytic layer.

Description

EXAMPLE

(1) An electrochemical cell comprising a 0.5 cm-diameter coated titanium rod as the anode was prepared. The coating of the anode consisted of 10 g/m.sup.2 of mixed oxides of iridium and tantalum in a 2:1 molar ratio. A coated titanium expanded mesh serving as support for the second catalyst element was wrapped around the rod with a spacer arranged therebetween to provide for electrical insulation. The coating of the titanium mesh consisted of 10 g/m.sup.2 of RuO.sub.2/RhO.sub.2 in a 1:2 molar ratio. A 2M NaClO.sub.3 solution was supplied as the electrolyte feedstock. The reaction was carried out at a temperature of 61 C. and at an anode current density of 50 mA/cm.sup.2.

(2) The test was run for 5 hours. A sample was taken every one hour and characterised in a UV/VIS Spectrophotometer (Hach DR 5000). The FIGURE shows the increase in chlorine dioxide concentration as a function of time.

(3) The previous description shall not be intended as limiting the invention, which may be used according to different embodiments without departing from the scopes thereof, and whose extent is solely defined by the appended claims.

(4) Throughout the description and claims of the present application, the term comprise and variations thereof such as comprising and comprises are not intended to exclude the presence of other elements, components or additional process steps.

(5) The discussion of documents, acts, materials, devices, articles and the like is included in this specification solely for the purpose of providing a context for the present invention. It is not suggested or represented that any or all of these matters formed part of the prior art base or were common general knowledge in the field relevant to the present invention before the priority date of each claim of this application.