A CONTROL SYSTEM AND METHOD FOR CONTROLLING A MICRO-GRID
20240030742 ยท 2024-01-25
Inventors
- Sean Crawford CHAPMAN (Pisa, IT)
- Jan-Justus SCHMIDT (Pisa, IT)
- Nikolay V. KRASKO (Saint-Petersburg, RU)
- Nikita AFANASENKO (Saint-Petersburg, RU)
Cpc classification
C25B9/65
CHEMISTRY; METALLURGY
H02J3/28
ELECTRICITY
C25B15/023
CHEMISTRY; METALLURGY
International classification
H02J15/00
ELECTRICITY
H02J3/38
ELECTRICITY
H02J3/28
ELECTRICITY
C25B15/023
CHEMISTRY; METALLURGY
Abstract
A control system for a micro-grid comprising a plurality of electrolysers and one or more primary power sources, the control system being configured, under control of a processor, to: determine power available from the one or more primary power sources; and generate control signals configured to cause available power to be directed to one or more of said plurality of electrolysers; wherein, the control system is configured to be communicably connectable to in-situ diagnostic means associated with each of the electrolysers of said plurality of electrolysers for measuring a respective performance parameter, the control system being configured, under control of said processor, to receive signals from said in-situ diagnostic means and determine therefrom at least one performance parameter associated with said plurality of electrolysers.
Claims
1. A control system for a micro-grid comprising a plurality of electrolysers and one or more primary power sources, the control system being configured, under control of a processor, to: determine power available from the one or more primary power sources; and generate control signals configured to cause available power to be directed to one or more of said plurality of electrolysers; wherein the control system is configured to be communicably connectable to in-situ diagnostic means associated with each of the electrolysers of said plurality of electrolysers for measuring a respective performance parameter, the control system being configured, under control of said processor, to receive signals from said in-situ diagnostic means and determine therefrom at least one performance parameter associated with said plurality of electrolysers.
2. A control system as claimed in claim 1, configured to derive any one or more of: polarisation curves; ohmic resistance, and; EIS using data received from said in-situ diagnostic means, preferably wherein the polarisation curves are generated at predetermined intervals.
3. (canceled)
4. A control system as claimed in claim 1, wherein each electrolyser is allocated unique identifier data.
5. A control system as claimed in claim 1, configured to obtain or determine any one or more of the following performance parameters from the in-situ diagnostic means in respect of each of one or more said plurality of electrolysers: cumulative run time of each modular device, cumulative down time of each modular device, capacity at which the modular device has been run at whilst running, Temperature of the device, Pressure of the device, Voltage/potential of the device, and Data pertaining to the balance of plant such as Electrolyte flow electrolyte level conductivity of said electrolyte pump performance.
6. A control system as claimed in claim 1, wherein any one or more of the performance parameters is measured at predetermined intervals and/or upon a pre-determined trigger, preferably wherein a trigger includes one or both of a change of power supply and a forecast change of conditions.
7. (canceled)
8. A control system as claimed in claim 1, wherein each electrolyser has a Weighted Run Time (WRT) associated to it.
9. A control system according to claim 1, further configured, under control of the processor, to perform power balancing in respect of said plurality of electrolysers.
10. A control system as claimed in claim 1, configured to receive output signals from each of said plurality of electrolysers, and being configured, under control of the processor, to predict an output of each electrolyser and to compute a predicted output based on an allocated distribution of power to said plurality of electrolysers.
11. A microgrid comprising a plurality of electrolysers, one or more primary sources of power, in-situ diagnostic means associated with each of the electrolysers for measuring respective performance parameter, and a control system as claimed in claim 1, the control system being communicably connectable to the in-situ diagnostic means.
12. A microgrid as claimed in claim 11, wherein at least one of the primary power sources is a renewable energy source or a grid connection.
13. A microgrid as claimed in claim 11, additionally comprising one or more secondary power sources, preferably wherein at least one of the secondary power sources is a renewable energy source or a grid connection.
14. (canceled)
15. A microgrid as claimed in any of claim 11, wherein each electrolyser is an AEM electrolyser operating with a dry cathode.
16. A microgrid as claimed in claim 11, further comprising one or more alternative loads, preferably wherein the alternative load is any one or more of: one or more batteries; electrochemical energy storage devices; capacitors; appliances, or grid.
17. (canceled)
18. A microgrid as claimed in claim 11, further comprising means, communicably coupled to the control system, for measuring the power available from the one or more primary power sources.
19. A microgrid as claimed in claim 11, wherein the one or more primary power sources comprise renewable energy sources, the microgrid further comprising forecasting means, communicably coupled to the control system, for forecasting the power expected to be available from the one or more primary power sources, preferably wherein the forecasting means comprise any one or more of: Weather forecasting; Windspeed forecasting; Cloud cover; and Tidal states.
20. (canceled)
21. A microgrid as claimed in claim 11, wherein the electrolysers are adapted to run at different capacities.
22. A microgrid as claimed in claim 11, wherein the electrolysers have passive charge/discharge circuitry for use by the in-situ diagnostic means for measuring respective voltage transience and include means for using said transience for fitting pre-determined equivalent circuit parameters.
23. A microgrid as claimed in claim 11, wherein the power from the one or more primary power sources is AC or DC, and the one or more electrolysers are powered by either AC or DC.
24. A microgrid as claimed in claim 11, including means for the handling and use of hydrogen output from said electrolysers, such as a dryer, hydrogen storage means or a fuel cell.
25. A method for operating/controlling a bank of electrolytic cells, the electrolytic cells and other components forming a micro-grid, the method comprising the following steps: allocating a unique identifier to each of the one or more electrolytic cells, said electrolytic cells being the primary load for the microgrid; and, at intervals repeating the steps of: determining/estimating power output from one or more sources of power; determining which and how many of the electrolytic cells are available for operation; determining a set point for the or each available electrolytic cell; directing said power to one or more electrolytic cells, and monitoring the activity of each of the electrolytic cells; measuring in-situ diagnostic data and logging the results in association with unique identifier data for each electrolytic cell; measuring actual power output and comparing it to expected power output; and repeating the above steps at regular pre-determined intervals, and reducing a set point of one or more of said electrolytic cells in the event that power output is insufficient or operation of one or more of the electrolytic cells is not required.
Description
[0139] To help understanding of the invention, a specific embodiment thereof will now be described by way of example only and with reference to the accompanying drawings, in which:
[0140]
[0141]
[0142]
[0143]
[0144]
[0145]
[0146]
[0147]
[0148]
[0149] Referring to
[0150] In the example grid illustrated schematically in
[0151] In the event that hydrogen is required, or the battery charge is low, power may be used from an alternative power source 17, such as a larger regional or national grid. The alternative power source 17 may also be connected such that it could power the fuel cell 16 or alternative load 18 if needed. The presence of an alternate load 18 is preferable to a power sink (not shown), which could be used but would result in a true waste of energy, which is clearly undesirable.
[0152] The Electrolyser bank 14 is beneficially adapted to utilise in-situ diagnostics as described herein and depicted in later figures. Such in-situ diagnostics are used to adapt the control philosophy of the micro-grid in real time at predetermined intervals.
[0153]
[0154] The control/gateway 23 is communicably connected to relevant devices, as denoted by the dashed lines. Means for forecasting power generation 24 are provided. For example, an irradiance sensor could be used for this purpose if the renewable power source 21 comprises or includes PV panels.
[0155] In
[0156]
[0157]
[0158] Referring to
[0159] As discussed above, means for in-situ diagnostics are provided. Such means may record any one or more of the following: [0160] cumulative run time of an electrolytic cell or group of electrolytic cells; [0161] cumulative down time of an electrolytic cell or group of electrolytic cells; [0162] capacity at which an electrolytic cell or group of electrolytic cells has been run at whilst running; [0163] Temperature of an electrolytic cell or group of cells, [0164] Pressure of an electrolytic cell or cells, [0165] Voltage/potential of an electrolytic cell or cells; and [0166] Data pertaining to the balance of plant such as [0167] Electrolyte flow [0168] electrolyte level [0169] conductivity of said electrolyte [0170] pump performance.
[0171] The above list is not necessarily exhaustive, any reasonable performance or operating condition from which the status of a component may be determined or inferred may be used, in addition or alternatively.
[0172] It is envisaged that, based on the previously monitored operating conditions and outputs, means are provided to predict outputs extrapolated from the previous operating conditions.
[0173] Where appropriate, such measurements may be taken at pre-determined intervals by the in-situ diagnostic means, which may optionally be amended by the user. Additionally, triggers may be given for the instigation of diagnostics. Such triggers could be a change of power supply, forecast change of conditions or any other conceivable trigger.
[0174] It is envisaged that the above information may be used by a control system according to an aspect of the invention to determine a weighted run time (WRT) for each electrolytic cell in a bank, the WRT taking into account factors such as, but not limited to run time, power supplied whilst running, and down time.
[0175] There are a variety of ways in which the WRT may be used to control the operation of the micro-grid as a whole. Priority may be given to the cell with the lowest WRT, however it may be preferable to prioritise another device depending on the State of Health, discussed below, should the in-situ diagnostics show or indicate an issue with a device having a lower WRT than other devices. This may be supplemented by the polarisation curve or other diagnostic techniques. A device may have reduced priority even with a lower WRT if in need of maintenance, or a potential issue has been detected.
[0176] In another embodiment, extra weighting may also be given to the time elapsed since the electrolyser or electrolytic cell was last in operation. Certain electrolytic cells may degrade if not operated frequently, or not purged between operations, or stored improperly. For example, electrolysers may run the risk of a membrane drying, corrosion or embrittlement if left for too long without running.
[0177] Preferably the electrolyser with the lowest WRT, based on any one or more of the above factors will be given preference to be the first modular device to receive power. As discussed above wherein multiple modular devices may be partially powered, it is envisaged that the system control means is adapted to direct power, and be able to alter the power supplied to the or each modular device based on the WRT and/or other in-situ diagnostics discussed above.
[0178] It is envisaged that the power from the one or more power sources can be either AC, or DC. It is also envisaged that the bank of modular devices will operate with AC, or DC. Accordingly, if power is not generated in the required form, any of the following devices may be used: Inverter, rectifier, transformer or other requisite component to ensure compatibility between the loads and power sources and intermediary components. Indeed, such components may be required in more than one location. Such devices may have optional connections to the control system.
[0179] It is envisaged that a user, the user being a person, such as but not necessarily the manager of the system, may wish to monitor the performance of the system being managed remotely. A computer can be used to access a dashboard, or app, either displaying performance related data. In some embodiments, it is envisaged that forecast performance data may also be included.
[0180] In the preferred embodiment, wherein the modular devices are electrolysers, it is envisaged that the system will further comprise any of the following: means for storing hydrogen, means for drying hydrogen, hydrogen refuelling stations, a fuel cell or other device/process requiring hydrogen.
[0181] Power balancing means, preferably fast acting power balancing means are provided. In the event an excess of power is supplied a power sink may be provided to protect the components.
[0182] Means for measuring output of each electrolyser and computing means for predicting said output based on a supply of power may also be used to control the system and loads within said system. For example, if an electrolyser is producing less than the expected amount of hydrogen for a given power supply, this implies an issue with that stack. An additional control device such as PID controller may be employed.
[0183] The optional features disclosed for the system embodiments described above may be included and controlled by the method of operating such a microgrid substantially as described above.
[0184] The available power from the primary source can be calculated as follows:
Power available=output from primary sourceefficiency of transmission
It should be noted that the efficiency of transmission also accounts for the efficiency of inversion, should it be required such as DC/AC, or vice versa.
[0185] In order to better control the distribution of power to a plurality of electrolytic cells, it is envisaged that forecasting of power output from the one or more power sources may be performed. Where renewable sources are used, this could involve analysis of weather forecasts, with machine learning employed to correlate such forecasts to actual available power. Additionally, in an embodiment wherein PV panels are used, should output drop during daylight hours it may be possible to attribute this to passing clouds. Optical sensors, or even user input may be used to inform the system. In such instances a temporary reduction as opposed to transitioning to standby mode may be preferred.
[0186] It is envisaged that alternative power sources may be employed to allow for the operation of the bank of primary loads i.e. the electrolysers to allow for continued production of hydrogen, or equivalent output.
[0187] It is envisaged that the alternative load may be a battery bank, which can also be used as a buffer to ensure a smooth, relatively consistent power supply. Alternatively, appliances or devices in the microgrid may be alternative loads such as air conditioning, refrigeration, lights and more. Yet another alternative load could be a connection to a larger grid, or other micro-grid to allow for the maximisation of use of product.
[0188] By regularly measuring the available power it will occur that the power available is not sufficient to power the same number of electrolysers at the same capacity. The WRT or equivalent can then be used to reallocate power and ramp up or down loads as appropriate. If a forecast indicates that the change is short term then secondary loads or power sinks may be utilised. Such an approach helps to minimize cycling on and off of devices, which helps to increase their longevity.
[0189] Other methods of determining a stack's State of Health (SoH), a supplement or alternative to the WRT, generally include fitting the stack to an equivalent circuit model. In the simplest cases said model including resistor and capacitor components, but generally also adapted to include mass transport contributions as well. An example being Randles circuit, which includes a Warburg element to represent mass transport effects. Additionally, constant phase elements, a more general kind of capacitor element, to reflect porous electrodes may be included.
[0190] Equivalent circuit fitting of impedance spectra is possible for electrochemical stacks, but to obtain more useful data it is envisaged that fitting such a stack to equivalent circuits either requires electrochemical impedance spectroscopy (EIS) or another circuit through which the stack can passively charge/discharge. The passive charge/discharge circuitry having requisite switches and resistors to allow passive charging and discharging of the stack. Upon charging and discharging, the resulting voltage transience can be used, with a sufficient sampling rate, wherein said sampling rate is pre-determined, to fit the stack to an equivalent circuit. For the avoidance of doubt, the measured voltage transience may be combined with means for using said transience for fitting pre-determined equivalent circuit parameters. Characteristics of the stack voltage transience can be directly correlated with performance parameters that need to be identified (i.e. ohmic resistance, kinetic activity characteristics, and even mass transport/low frequency behaviour). This arguably increases the hardware complexity but allows for specific determination of parameters associated with individual cell components. EIS generally requires potentiostats which are expensive, however, one such potentiostat may be used to a plurality of electrolysers or strings of electrolysers. A DC bias is applied to the stack with an AC component (+/1% of the DC bias) such that the frequency of the AC perturbation is swept from kHz to mHzthe impedance is measured at each frequency and this data can be used to fit the stack to an equivalent circuit model. If using a potentitostat, it would be connected to the electrochemical cell, stack or string by known means not described herein.
[0191] In another embodiment, the external dedicated passive discharge circuit can be fully bypassed, only using the discharging voltage transience of the electrolyser during shutdown via the power supply. The idle discharge profile of the stack is affected by many of the electrochemical observables stated prior, along with added information of potential gas or electrolyte leakages to the dry cathode. The existence of trace amounts of 02 in the primarily H2 line can show up as characteristic voltage responses, especially when one gaseous species is consumed to completion. Such a mixed potential is well known in the fuel cell community, but can be expanded to any catalytic layers that are at least partially active to both HOR and ORR. In this way, the quality of Hydrogen in the H2 gas processing line can be inferred, albeit indirectly so, in parallel with the electrochemical and mechanical sealing state of health of said electrolyser.
[0192] The ideal case, simplifying the hardware requirements while still obtaining useful information, involves simply looking at the changes in polarization curve data where the below equation separates the three dominating sources of losses: kinetic, ohmic, and mass transport.
[0193] Yet another diagnostic method includes measuring V, or the change of polarization curve diagnostic. The polarization curve, or voltage versus applied current graph, gives us information of the different kinds of efficiency losses in an electrolyser cell/stackkinetic, ohmic, and mass transport. Nominally, electrolysers are dominated by kinetic and ohmic losses, the former being a logarithmic V vs I relationship, and the latter being linear between V and I. Though mass transport losses are present in the worst cases, generally it can be taken as the difference between the raw polarization curve data and the kinetic+ohmic fitting data. The kinetic part having two fitting coefficients, these being Tafel slope and exchange current density, which are dependent on the electrochemical reactions of the cell and reflect the state of health of each electrode's catalyst layer. The ohmic part only has one fitting coefficient, this being DC resistance, factors impacting this including membrane state of health and increasing contact resistance due to corrosion. Lastly, mass transport generally has two fitting coefficients, a logarithm prefactor, and the limiting current density, both of which give us an idea of the degree of resistance of water getting to the catalyst layer and/or gases leaving the electrodesmass transport losses mainly arise from the GDL, CL, and/or the membrane.
[0194] Consider that nonlinear curve fitting with five free parameters is practically rather difficult in our case and there are time constraints if done too regularly, although improved processing power may go some way to mitigating thiswith an associated cost. Ignoring mass transport fitting now and focusing on the kinetic and ohmic allows for simplification. For the fitting procedure and improving accuracy and stability, the ohmic part may be measured and fixed such that the nonlinear curve fitting is only correcting for the two kinetic parameters in the first and only log term. In embodiments wherein one of the fitting parameters is stable, say the Tafel slope, this may be set at a fixed point in the control software/methodology reducing the variable. However, it is preferred to fix something that can be measured quickly such as the DC resistance or other suitable parameter. Deviation from the fitted polarization curve of purely ohmic+kinetic contributions with respect to the measured values can be attributed to mass transport limitation onset, which can also be used to properly define a maximum capacity value.
[0195] Some methods for measuring the ohmic part mentioned above include EIS or current interrupt which require a potentiostat or an impedance meter to read the impedance at a fixed high frequency (e.g. 1 kHz). As before a single potentiostat may be centralized and used for multiple stacks. It should be noted that distinguishing between a logarithm and a linear part of a curve is not easily done if there is not enough data, this is normally more pronounced at especially at a very low current density which require a long time to remove the capacitive contribution. It is envisaged that the means may be adapted to conduct more measurements at lower current densities to ensure adequate data, lower current densities being half or less than maximum operating capacity. Measuring the resistance by direct methods (e.g. EIS, current interrupt, impedance meter) removes this numerical issue allowing for a fast recording of the polarization curve, requiring less points for a accurate numerical fitting regardless of linear or logarithmic tendencies.
[0196] In a preferred embodiment of the present invention means are provided to create a polarization curve at pre-determined intervals such as every 1-1000 hours, 10-100 hours, 100-500 hours, or anywhere suitable within that range. Repeated creation of polarisation curves allows for time rates of change to be determined for each of the fitted voltage loss parameters for a given electrolyser module. With this knowledge, modules can be loaded with a corresponding weight factor in order to increase the lifetime of the aggregate system, in conjunction with catching individual module issues before catastrophic failure, as voltage gains in some cases start with reversible losses that eventually become irreversible. This data may be incorporated with the/a WRT to attribute a SoH.
[0197] For embodiments wherein the electrolytic cells are used to generate a product which is consumed, it is envisaged that the control means may be adapted to direct the requisite power to one or more of the cells at a rate to produce only what is to be consumed. This may be predetermined, input by a user or set by another mechanism. Alternatively, when the storage for the product is full, control means may facilitate the supply of power to generate no more than can be safely stored.
[0198] It is envisaged that demand side response (DSR) may be used in the event of unexpected power fluctuations. Such instances may result from damage to components, unexpected changes in weather conditions, or changing requirements of operating the electrolytic cells. Alternatives include utilising a power sink or other curtailing means.
[0199] There is an optional additional step of the above-described method wherein the collected data is made viewable to a user via a computing means connected to an app, web based or otherwise.
[0200] If demand for generated product surpasses that possible from the primary power, the control system may be configured to cause power from the alternative power source or battery bank to be directed as required, so as to supplement the primary power source. If there is no means to store the product, the available power can be routed to alternative loads including the battery bank, depending upon demand. Alternatively, if the battery or bank thereof is low then power may be redirected to it. It is envisaged that a predetermined threshold may be implemented to ensure that the batteries do not drop below a certain percentage charge (to increase their longevity) or a set amount of power as defined by the user or designer of the system.
[0201] This section outlines a specific example embodiment of a system in accordance with the present invention.
Example Calculation of WRT Hours
[0202] Generally a basic WRT can be calculated using the basic formula of:
WRT=Percentage powerhours at said power
[0203] As an electrolyser may run with varied inputs, the calculation may have to be repeated for each steady state. Yet another option is to integrate to account for operation during ramp up and down of the electrolyser.
EL.sub.1 Running at 100% for 100 hoursWRT=100 hours
EL.sub.2 Running at 50% for 100 hoursWRT=50 hours
EL.sub.3 Running at 30% for 200 hoursWRT=60 hours
[0204] Using WRT alone, in the above example Priority may be given to EL.sub.2, having the lowest WRT despite having been operated half as many hours as EL.sub.3 and for the same number of hours as EL.sub.1. As an electrolyser may run at various load capacities for differing hours, the sum of these may be calculated.
[0205] The WRT may be further supplemented by the forecast means, and optionally a temperature sensor. Electrolysers need time to ramp up to be operational. It is not desirable for power to be wasted during this ramp up process, utilisation of temperature sensors allows for more accurate control by either providing heating where required and prioritising devices closer to the pre-determined operable range.
[0206]
[0207]
[0208] Referring now to
[0209] Referring now to
[0210] The invention is not intended to be restricted to the details of the above described embodiment. For instance, any plurality of modular devices may be controlled in a manner as described in the above disclosed invention.
[0211] The present invention is not intended to be limited to AEM electrolysers, and other types of electrolyser may be used in a system according to the present invention.
[0212] Transformers may be used where required without deviating from the spirit of the present invention. As such they are not necessarily discussed in full as the individual of ordinary skill would be familiar with how to install them.
[0213] In the preferred embodiment, the electrolysers are AEM electrolysers. However, this is not necessarily intended as a limiting feature, as any bank of electrolysers may be controlled or used as disclosed herein.