Fuel additive
10584293 ยท 2020-03-10
Assignee
Inventors
Cpc classification
C10L1/1616
CHEMISTRY; METALLURGY
C10L1/1881
CHEMISTRY; METALLURGY
C10L1/1802
CHEMISTRY; METALLURGY
International classification
C10L1/222
CHEMISTRY; METALLURGY
Abstract
The invention pertains to a novel additive for fuels comprising iso-propanol in an amount of from 60-70 Vol.-%, diesel and gasoline each in an amount of from 10-20 vol.-% and water in an amount of from 1-5 vol.-%. In another aspect the composition comprises Iso-propanol in an amount of from 60-70 vol.-%, lineseed oil in an amount of from 15-25 vol.-%, gasoline fuel in an amount of from 10-20 vol.-%, and water in an amount of from 1-5 vol.-%. The invention further relates to the use of the said additive in reducing carbon monoxide (CO) and unburnt hydrocarbons (HC) levels from emissions of combustion engines.
Claims
1. A composition comprising iso-propanol in an amount of from 60-70 vol.-%, diesel fuel in an amount of from 10-20 vol.-%, gasoline fuel in an amount of from 10-20 vol.-%, and water in an amount of from 1-5 vol.-%.
2. A composition comprising iso-propanol in an amount of from 60-70 vol.-%, lineseed oil in an amount of from 15-25 vol.-%, gasoline fuel in an amount of from 10-20 vol.-%, and water in an amount of from 1-5 vol.-%.
3. The composition of claim 1, wherein the amount of iso-propanol is in the range of from 65-70 vol.-%.
4. The composition of claim 1, wherein the amount of diesel and/or gasoline is in a range of from 13-17 vol.-% each.
5. The composition of claim 2, wherein the amount of lineseed oil is between 18 vol.-% and 22 vol. %.
6. The composition of claim 1, wherein the amount of water is between 1.5 and 3 vol. %.
7. The composition according to claim 2, wherein the lineseed oil is present in admixture with diesel.
8. The composition according to claim 1, wherein urea is provided in an amount of between 1 and 5%.
9. A fuel comprising the composition according to claim 1.
10. The fuel according to claim 9, wherein the fuel is selected from diesel, gasoline, AvGasoline, MoGasoline, kerosene, or heating oil.
11. A method for preparing fuel, providing lower CO and HC emissions, comprising the step of adding the composition according to claim 1 to the fuel in a ratio of 1:8,000-to 1:12,000.
12. The method of claim 11, wherein the composition is added to the fuel in an amount of 1:10,000.
13. A method for reducing carbon monoxide and hydrocarbons levels in exhaust gases of combustion engines, comprising the step of adding the composition according to claim 1 to a fuel in a ratio of 1:8,000 to 1:12,000.
14. The method according to claim 13, wherein the amount of carbon dioxide in exhaust gases is reduced by at least 15% and/or wherein the amount of hydrocarbons in exhaust gases is reduced by at least 30%.
15. The fuel according to claim 9, wherein the composition is contained in a ratio of from 1:8,000 to 1:12,000, preferably 1:10,000.
16. The fuel according to claim 9, wherein the fuel is selected from diesel or gasoline, AvGasoline, MoGasoline, kerosene, or heating oil.
17. The composition of claim 2, wherein the amount of iso-propanol is in the range of from 65-70 vol.-%.
18. The composition of claim 2, wherein the amount of diesel and/or gasoline is in a range of from 13-17 vol.-% each.
19. The composition of claim 2, wherein the amount of water is between 1.5 and 3 vol. %.
20. The composition according to claim 2, wherein urea is provided in an amount of between 1 and 5%.
21. The composition of claim 5, wherein the amount of lineseed oil is between 19 and 21 vol.-%.
22. The composition of claim 6, wherein the amount of water is between 2 vol.-% and 3 vol.-%.
23. The composition according to claim 8, wherein urea is provided in an amount of between 2 and 4% by weight and most preferred between 2.5 and 3.5% of weight.
24. The composition according to claim 8, wherein urea is provided in an amount of between 2.5 and 3.5% of weight.
25. The fuel according to claim 15, wherein the composition is contained in a ratio of 1:10,000.
26. The composition of claim 19, wherein the amount of water is between 2 vol.-% and 3 vol.-%.
27. The composition according to claim 20, wherein urea is provided in an amount of between 2 and 4% by weight.
28. The composition according to claim 20, wherein urea is provided in an amount of between 2.5 and 3.5% of weight.
29. A fuel comprising the composition according to claim 2.
30. The fuel according to claim 29, wherein the composition is contained in a ratio of from 1:8,000 to 1:12,000.
31. A method for preparing fuel, providing lower CO and HC emissions, comprising the step of adding the composition according to claim 2 to the fuel in a ratio of 1:8,000- to 1:12,000.
32. The method of claim 31, wherein the composition is added to the fuel in an amount of 1:10,000.
33. A method for reducing carbon monoxide and hydrocarbons levels in exhaust gases of combustion engines, comprising the step of adding the composition according to claim 2 to a fuel in a ratio of 1:8,000 to 1:12,000.
Description
EXAMPLE I
(1) An AUDI Q7, 4.2 l, petrol engine, built in 2013 and equipped with a catalyst, fulfilling the EU exhaust gases requirements was subjected to a drive cycle EPA US 06. The drive length was 12 km.
(2) The car has been filled with conventional gasoline, ROZ 95 and subjected to the test while determining the amount of CO and HC, which is set to 100% as reference.
(3) Prior to starting an experiment with a fuel, the car was depleted from the previous fuel, refueled with the new fuel and run for 15 minutes at idle speed with the respective new fuel to warm the motor and fill all lines and the engine with the respective fuel to be tested.
(4) Experiments have been carried out with additives according to the invention (embodiments 1-3, 6-8) and with additives, wherein the amount of individual components are not within the limits indicated or where a fuel component was replaced by another component (embodiments 4-5).
(5) The respective compositions have been added to fuel in a ratio of roughly 1:10.000 prior to filling the car.
(6) The exhaust gases were analyzed for C and HC and the amount of CO and HC determined with the fuel+additive was indicated in percentage reduction as compared to the reference.
(7) Additives:
(8) TABLE-US-00001 1. M 1 Isoprop. = 65%, D = 17%, B = 16% W = 2%. 2. M 2 Isoprop. = 65%, D = 17%, B = 15%, W = 3%. 3. M 3 Isoprop. = 70%, D = 14%, B = 14% W = 2%. 4. M 4 Isoprop. = 55%, D = 20%, B = 22%, W = 3%. 5. M 5 Isoprop. = 65%, D = 15%, B = 15%, W = 5%. 6. M 6 Isoprop. = 65%, techn. lineseed B = 12%, W = 3%. oil = 20%, 7. M 7 Isoprop. = 65%, techn. lineseed B = 10%, W = 5% oil = 20%, 8. M 8 Isoprop. = 65%, techn. lineseed B = 16%, W = 2%. oil = 17%, Isoprop. = isopropanol; D = diesel; B = gasoline; W water.
(9) The following results have been obtained:
(10) TABLE-US-00002 1. CO 39%, HC 28%. 2. CO 37%, HC 27%. 3. CO 32%, HC 24%. 4. CO 18%, HC 15%. 5. CO 29%, HC 21%. 6. CO 38%, HC 28%. 7. CO 33%, HC 25%. 8. CO 39%, HC 28%.
(11) As may be seen, all compositions produced an decreased level of CO. However, in case the amount of isopropanol exceeds the lower level of 60 vol.-% or the amount of water exceeds the upper limit of 3 vol.-% the amount of HC is increased. Good results are also achieved when replacing diesel with technical lineseed oil.
EXAMPLE II
(12) A similar experiment has been carried out with a Hyundai i30, built in 2010, diesel engine, and equipped with a catalyst, fulfilling the EU exhaust gases requirements was subjected to a drive cycle. The drive length as 11 km. The following additive has been prepared:
(13) TABLE-US-00003 Isopropanol 660 ml Diesel 160 ml Benzin 160 ml Water 20 ml Urea 3 ml
(14) The additive has been added to the diesel fuel in a ratio of 1:10.000.
(15) Exhaust gases have been determined according to 70/220/EWG i.d.F. 98/69/B/EG.
(16) The following results have been obtained as compared to the reference (diesel without additive);
(17) TABLE-US-00004 City Countryside CO 73% 16% HC 45% 31%.