Abstract
A LED including an epitaxial stacked layer, a first electrode and a second electrode is provided. The epitaxial stacked layer includes a first type doped semiconductor layer, a light emitting layer and a second type doped semiconductor layer. The epitaxial stacked layer has a first mesa portion and a second mesa portion to form a first type conductive region and a second type conductive region respectively. The first electrode is disposed on the first mesa portion. The second electrode is disposed on the second mesa portion. The second electrode contacts the first type doped semiconductor layer, the light emitting layer and the second type doped semiconductor layer located at the second mesa portion. Moreover, a manufacturing method of the LED is also provided.
Claims
1. A micro light emitting diode, comprising: an epitaxial stacked layer, comprising a first type doped semiconductor layer, a light emitting layer and a second type doped semiconductor layer, the light emitting layer being located between the first type doped semiconductor layer and the second type doped semiconductor layer, and the first type doped semiconductor layer and the second type doped semiconductor layer being opposite in electrical property, wherein the epitaxial stacked layer has a first mesa portion and a second mesa portion to form a first type conductive region and a second type conductive region respectively, and the first mesa portion and the second mesa portion are connected through the second type doped semiconductor layer; an insulation layer disposed on a side surface of the epitaxial stacked layer and a part of a top surface of the epitaxial stacked layer to expose the first mesa portion and the second mesa portion, a material of the insulation layer comprising a combination of two stacked materials with different refractive indexes and having reflection function; a first electrode, electrically connected to the epitaxial stacked layer, and disposed on the first mesa portion; and a second electrode, electrically connected to the epitaxial stacked layer, and disposed on the second mesa portion, wherein the second electrode contacts the first type doped semiconductor layer, the light emitting layer and the second type doped semiconductor layer located at the second mesa portion and a material of the first electrode or the second electrode comprises gold, tin or alloys thereof, wherein the first electrode has a first surface exposed to external, the second electrode has a second surface exposed to external, and at least a part of the first surface and at least a part of the second surface are in a same horizontal plane.
2. The micro light emitting diode as claimed in claim 1, wherein the epitaxial stacked layer has a first recess portion and a second recess portion, the first recess portion defines the first mesa portion and the second mesa portion and exposes a part of the second type doped semiconductor layer, and the second mesa portion has the second recess portion, the second recess portion defines a first sub mesa portion and a second sub mesa portion in the second mesa portion, and the second recess portion exposes the second type doped semiconductor layer, a part of the first type doped semiconductor layer and a part of the light emitting layer in the second mesa portion.
3. The micro light emitting diode as claimed in claim 1, wherein a part of the first type doped semiconductor layer, a part of the light emitting layer and a part of the second type doped semiconductor layer in the first mesa portion constitute a first diode, a part of the first type doped semiconductor layer, a part of the light emitting layer and a part of the second type doped semiconductor layer in the first sub mesa portion constitute a second diode, a part of the first type doped semiconductor layer, a part of the light emitting layer and a part of the second type doped semiconductor layer in the second sub mesa portion constitute a third diode, wherein a positive terminal of the first diode is coupled to the first electrode, and a negative terminal of the first diode is coupled to a negative terminal of the second diode and a negative terminal of the second diode.
4. The micro light emitting diode as claimed in claim 1, further comprising a current spreading layer, wherein the first electrode or the second electrode is electrically connected to the epitaxial stacked layer through the current spreading layer.
5. The micro light emitting diode as claimed in claim 1, further comprising a substrate, wherein the epitaxial stacked layer, the first electrode and the second electrode are disposed at a same side of the substrate.
6. The micro light emitting diode as claimed in claim 5, wherein the insulation layer is extended to a surface of the substrate from the side surface of the epitaxial stacked layer.
7. The micro light emitting diode as claimed in claim 5, wherein the epitaxial stacked layer further includes an unintentionally doped semiconductor layer, and the unintentionally doped semiconductor layer is located between the second type doped semiconductor layer and the substrate.
8. The micro light emitting diode as claimed in claim 1, wherein the second electrode covers a part of the insulation layer.
9. The micro light emitting diode as claimed in claim 1, wherein the first electrode directly contacts the first type doped semiconductor layer on the first mesa portion.
10. The micro light emitting diode as claimed in claim 1, wherein a diagonal length of the micro light emitting diode ranges between 10 m and 100 m.
11. A manufacturing method of a micro light emitting diode, comprising: providing a substrate; forming an epitaxial stacked layer on the substrate, wherein the epitaxial stacked layer includes a first type doped semiconductor layer, a light emitting layer and a second type doped semiconductor layer, the light emitting layer is located between the first type doped semiconductor layer and the second type doped semiconductor layer, and the first type doped semiconductor layer and the second type doped semiconductor layer are opposite in electrical property; etching the epitaxial stacked layer to make the epitaxial stacked layer have a first mesa portion and a second mesa portion to form a first type conductive region and a second type conductive region respectively; forming an insulation layer on a side surface of the epitaxial stacked layer and a part of a top surface of the epitaxial stacked layer to expose the first mesa portion and the second mesa portion, wherein a material of the insulation layer comprises a combination of two stacked materials with different refractive indexes and has reflection function; and respectively forming a first electrode on the first mesa portion in the first type conductive region and forming a second electrode on the second mesa portion in the second type conductive region, wherein the first electrode and the second electrode are electrically connected to the epitaxial stacked layer, wherein the second electrode contacts the first type doped semiconductor layer, the light emitting layer and the second type doped semiconductor layer of the second mesa portion, wherein the first electrode has a first surface exposed to external, the second electrode has a second surface exposed to external, and at least a part of the first surface and at least a part of the second surface are in a same horizontal plane, and a material of the first electrode or the second electrode comprises gold, tin or alloys thereof.
12. The manufacturing method of the micro light emitting diode as claimed in claim 11, wherein the step of etching the epitaxial stacked layer comprises: etching a part of the first type doped semiconductor layer, a part of the light emitting layer and a part of the second type doped semiconductor layer to make the epitaxial stacked layer have a first recess portion and a second recess portion, wherein the first recess portion defines the first mesa portion and the second mesa portion to form the first type conductive region and the second type conductive region respectively, and the second recess portion defines a first sub mesa portion and a second sub mesa portion in the second mesa portion.
13. The manufacturing method of the micro light emitting diode as claimed in claim 11, wherein the step of etching the epitaxial stacked layer to make the epitaxial stacked layer have the first mesa portion and the second mesa portion comprises: etching the epitaxial stacked layer to expose a part of the substrate.
14. The manufacturing method of the micro light emitting diode as claimed in claim 13, wherein after the step of etching the epitaxial stacked layer to expose a part of the substrate.
15. The manufacturing method of the micro light emitting diode as claimed in claim 11, wherein before the step of respectively forming the first electrode and the second electrode on the first mesa portion and the second mesa portion, the manufacturing method further comprises: forming a current spreading layer on the epitaxial stacked layer.
16. A manufacturing method of micro light emitting diodes, comprising; providing a substrate; forming an epitaxial stacked layer on the substrate, wherein the epitaxial stacked layer comprises a first type doped semiconductor layer, a light emitting layer and a second type doped semiconductor layer, the light emitting layer is located between the first type doped semiconductor layer and the second type doped semiconductor layer, and the first type doped semiconductor layer and the second type doped semiconductor layer are opposite in electrical property; etching the epitaxial stacked layer to make the epitaxial stacked layer to form a plurality of sub epitaxial stacked layers separated from each other, wherein each of the sub epitaxial stacked layers comprises a part of the first type doped semiconductor layer, a part of the light emitting layer and a part of the second type doped semiconductor layer; etching each of the sub epitaxial stacked layers to make each of the sub epitaxial stacked layers have a first mesa portion and a second mesa portion to form a first type conductive region and a second type conductive region respectively; forming an insulation layer on a side surface of the epitaxial stacked layer and a part of a top surface of the epitaxial stacked layer to expose the first mesa portion and the second mesa portion, wherein a material of the insulation layer comprises a combination of two stacked materials with different refractive indexes and has reflection function; and forming a plurality of first electrodes on the first mesa portions in the first type conductive regions, and forming a plurality of second electrodes on the second mesa portions in the second type conductive regions, wherein each of the first electrodes is electrically connected to the corresponding sub epitaxial stacked layer, and each of the second electrodes is electrically connected to the corresponding sub epitaxial stacked layer, so as to form a plurality of micro light emitting diodes on the substrate, wherein the first electrode has a first surface exposed to external, the second electrode has a second surface exposed to external, and at least a part of the first surface and at least a part of the second surface are in a same horizontal plane, and a material of the first electrode or the second electrode comprises gold, tin or alloys thereof, wherein in each of the micro light emitting diodes, the second electrode contacts the first type doped semiconductor layer, the light emitting layer and the second type doped semiconductor layer of the corresponding second mesa portion.
17. The manufacturing method of the micro light emitting diodes as claimed in claim 16, wherein the step of etching each of the sub epitaxial stacked layers further comprises: etching a part of the first type doped semiconductor layer, a part of the light emitting layer and a part of the second type doped semiconductor layer in each of the sub epitaxial stacked layers to make each of the sub epitaxial stacked layers have a first recess portion and a second recess portion, wherein the first recess portion defines the first mesa portion and the second mesa portion to form the first type conductive region and the second type conductive region respectively, and the second recess portion defines a first sub mesa portion and a second sub mesa portion in the second mesa portion.
18. The manufacturing method of the micro light emitting diodes as claimed in claim 17, wherein an area of an orthogonal projection of the first mesa portion is substantially the same to an area of an orthogonal projection of the second mesa portion.
19. The manufacturing method of the micro light emitting diodes as claimed in claim 16, wherein after the step of forming the micro light emitting diodes on the substrate, the manufacturing method further comprises: providing a temporary substrate; selecting at least a part of the micro light emitting diodes on the substrate as a predetermined detaching portion, and detaching the micro light emitting diodes in the predetermined detaching portion from the substrate; and transferring the detached micro light emitting diodes in the predetermined detaching portion to the temporary substrate.
20. The manufacturing method of the micro light emitting diodes as claimed in claim 19, wherein any of the micro light emitting diodes in the predetermined detaching portion on the temporary substrate is a first micro light emitting diode, wherein the first micro light emitting diode is located adjacent to a second micro light emitting diode of the micro light emitting diodes in a first direction, and the first micro light emitting diode and the second micro light emitting diode have a first gap there between, the first micro light emitting diode is located adjacent to a third micro light emitting diode of the micro light emitting diodes in a second direction different to the first direction, and the first micro light emitting diode and the third micro light emitting diode have a second gap there between.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) The accompanying drawings are included to provide a further understanding of the invention, and are incorporated in and constitute a part of this specification. The drawings illustrate embodiments of the invention and, together with the description, serve to explain the principles of the invention.
(2) FIG. 1A is a top view of a micro light emitting diode (LED) according to an embodiment of the invention.
(3) FIG. 1B is a cross-sectional view of FIG. 1A along a section line A-A.
(4) FIG. 1C is an equivalent circuit diagram of the LED of FIG. 1A connected to an external power.
(5) FIG. 2A to FIG. 2K are flowcharts illustrating a process for manufacturing the LED of the embodiment of FIG. 1A and FIG. 1B.
(6) FIG. 3A is a top view of a LED according to another embodiment of the invention.
(7) FIG. 3B is a cross-sectional view of FIG. 3A viewing along a section line B-B.
(8) FIG. 4A is a top view of a LED according to still another embodiment of the invention.
(9) FIG. 4B is a cross-sectional view of FIG. 4A viewing along a section line C-C.
(10) FIG. 5A is a top view of a LED according to still another embodiment of the invention.
(11) FIG. 5B is a cross-sectional view of FIG. 5A viewing along a section line D-D.
(12) FIG. 6A is a top view of a LED according to still another embodiment of the invention.
(13) FIG. 6B is a cross-sectional view of FIG. 6A viewing along a section line E-E.
(14) FIG. 7A is a top view of a LED according to still another embodiment of the invention.
(15) FIG. 7B is a cross-sectional view of FIG. 7A viewing along a section line F-F.
(16) FIG. 8A is a top view of a LED according to still another embodiment of the invention.
(17) FIG. 8B is a cross-sectional view of FIG. 8A viewing along a section line G-G.
(18) FIG. 9A to FIG. 20A are top views of a manufacturing process of a LED of according to another embodiment of the invention.
(19) FIG. 9B to FIG. 20B are cross-sectional views of the manufacturing process of FIG. 9A to FIG. 20A.
(20) FIG. 21 is a schematic diagram of a LED in a heating state according to an embodiment of the invention.
(21) FIG. 22A to FIG. 26A are top views of a manufacturing process of a LED of according to still another embodiment of the invention.
(22) FIG. 22B to FIG. 26B are cross-sectional views of the manufacturing process of FIG. 22A to FIG. 26A.
DESCRIPTION OF EMBODIMENTS
(23) FIG. 1A is a top view of a micro light emitting diode (LED) according to an embodiment of the invention. FIG. 1B is a cross-sectional view of FIG. 1A along a section line A-A. FIG. 1C is an equivalent circuit diagram of the LED of FIG. 1A connected to an external power.
(24) Referring to FIG. 1A, in the present embodiment, the LED 100 is, for example, a flip-chip LED. A size of the LED 100 is, for example, in a micro-scale. In detail, a length of a diagonal W of the LED 100, for example, ranges between 1 micrometer (m) and 100 m, preferably, the length of the diagonal W of the LED 100 ranges between 10 m and 50 m. Referring to FIG. 1B, the LED 100 includes an epitaxial stacked layer 110, a first electrode 120, a second electrode 120, a current spreading layer 140, an insulation layer 150 and a substrate 160, and functions of the above components are described in detail below.
(25) In the present embodiment, the epitaxial stacked layer 110 includes a first type doped semiconductor layer 112, a light emitting layer 114, a second type doped semiconductor layer 116 and an unintentionally doped semiconductor layer 118. The light emitting layer 114 is located between the first type doped semiconductor layer 112 and the second type doped semiconductor layer 116. The first type doped semiconductor layer 112, the light emitting layer 114 and the second type doped semiconductor layer 116 are stacked on the unintentionally doped semiconductor layer 118. In detail, the epitaxial stacked layer 110 has a first mesa portion Mes1 and a second mesa portion Mes2, and the epitaxial stacked layer 110 has a first recess portion D1 and a second recess portion D2. The first recess portion D1 defines the first mesa portion Mes1 and the second mesa portion Mes2 to form a first type conductive region and a second type conductive region respectively. The first mesa portion Mes1 and the second mesa portion Mes2 are connected to each other through the second type doped semiconductor layer 116 in the epitaxial stacked layer 110. The second mesa portion Mes2 has the second recess portion D2, and the second recess portion D2 defines a first sub mesa portion SMes1 and a second sub mesa portion SMes2. Moreover, the second recess portion D2 exposes the second type doped semiconductor layer 116 in the second mesa portion Mes2. In the present embodiment, the first mesa portion Mes1, the first sub mesa portion SMes1 and the second sub mesa portion SMes2 all have a part of the first type doped semiconductor layer 112, a part of the light emitting layer 114 and a part of the second type doped semiconductor layer 116.
(26) In the present embodiment, the first type doped semiconductor layer 112 is different to the second type doped semiconductor layer 116. To be specific, the first type doped semiconductor layer 112 and the second type doped semiconductor layer 116 are opposite in electrical property. The first type doped semiconductor layer 112 is one of a P-type doped semiconductor layer and an N-type doped semiconductor layer, for example, the P-type doped semiconductor layer, where a material of the P-type doped semiconductor layer is, for example, p-GaN. The second type doped semiconductor layer 116 is the other one of the P-type doped semiconductor layer and the N-type doped semiconductor layer, for example, the N-type doped semiconductor layer, where a material of the N-type doped semiconductor layer is, for example, n-GaN. The light emitting layer 114 is, for example, a multiple quantum well (MQW) comprising alternately stacking multi-layer of well layers and multi-layer of barrier layers or a recombination area for the recombination of holes of the first type doped semiconductor layer 112 and electrons of the second type doped semiconductor layer 116. In the present embodiment, the well layer in the MQW is, for example, InGaN, and the barrier layer in the MQW is, for example, GaN. Since the well layer has a lower energy band gap compared with that of the barrier layer, the barrier layer may limit the electrons and the holes to recombine in the well layer to emit photons. In other embodiments, the light emitting layer 114 is, for example, a single quantum well (SQW), which is not limited by the invention. Moreover, a material of the unintentionally doped semiconductor layer 118 is, for example, unintentionally doped u-GaN, which is not limited by the invention. In overall, the epitaxial stacked layer 110 of the present embodiment is, for example, a semiconductor structure of nitride. In other embodiments, the material of the unintentionally doped semiconductor layer 118 is, for example, AlN.
(27) In the present embodiment, the first electrode 120 is electrically connected to the epitaxial stacked layer 110, and is disposed on the first mesa portion Mes1 of the epitaxial stacked layer 110. The first electrode 120 has a first surface S1 exposed to external. The first electrode 120 is, for example, a P-type electrode. The first electrode 120 is, for example, a metal electrode, and a material thereof is, for example, Au, Ni, Pt, Sn, Al, Ti, Al/Cu alloy, Sn/Ag/Cu alloy, Au/Sn alloy, Sn alloy or alloys thereof, which is not limited by the invention.
(28) In the present embodiment, the second electrode 130 is electrically connected to the epitaxial stacked layer 110, and is disposed on the second mesa portion Mes2 of the epitaxial stacked layer 110. The second electrode 130 is, for example, an N-type electrode. The second electrode 130 has a second surface S2 exposed to external and a third surface S3 opposite to the second surface S2. The second electrode 130 directly contacts the first type doped semiconductor layer 112, the light emitting layer 114 and the second type doped semiconductor layer 116 located on the second mesa portion Mes2 through the third surface S3. In detail, the third surface S3 is divided into three portions including a first portion S21, a second portion S32 and a third portion S33. The second electrode 130 directly contacts the first type doped semiconductor layer 112, the light emitting layer 114 and a part of the second type doped semiconductor layer 116 located on the first sub mesa portion SMes1 through the first portion S31 of the third surface S3. The second electrode 130 directly contacts the second type doped semiconductor layer 116 located on the second mesa portion Mes2 and exposed by the second recess portion D2 through the second portion S32 of the third surface S3. The second electrode 130 directly contacts the first type doped semiconductor layer 112, the light emitting layer 114 and a part of the second type doped semiconductor layer 116 located on the second sub mesa portion SMes2 through the third portion S33 of the third surface S3. The second electrode 130 is, for example, a metal electrode, and a material thereof is, for example, Au, Ni, Pt, Sn, Al, Ti, Al/Cu alloy, Sn/Ag/Cu alloy, Au/Sn alloy, Sn alloy or alloys thereof, which is not limited by the invention.
(29) Referring to FIG. 1B, in the present embodiment, at least a part of the first surface S1 of the first electrode 120 and at least a part of the second surface S2 of the second electrode 130 are in a same horizontal plane. In other words, at least a part of the first surface S1 and at least a part of the second surface S2 are substantially aligned. Therefore, when the LED 100 of the present embodiment is bonded to an external substrate (for example, a thin-film transistor substrate in a display panel), it is not liable to encounter a tilt problem, and through the aforementioned design, the manufacturing yield is further improved. In an embodiment of the invention, the metal electrodes of the first electrode 120 and the second electrode 130 include a material of tin, such that when the LED 100 of the present embodiment is bonded to the external substrate (for example, the thin-film transistor substrate in the display panel), the LED 100 may be directly and electrically bonded to a circuit on the external substrate, or a circuit metal electrode on the external substrate includes a material of tin, such that when the LED 100 of the present embodiment is bonded to the external substrate (for example, the thin-film transistor substrate in the display panel), the LED 100 may be directly and electrically bonded to the circuit on the external substrate. Through the above design, usage of extra solder material consumed in bonding of the LED 100 and the external substrate is decreased.
(30) In the present embodiment, the current spreading layer 140 is disposed between the first electrode 120 and the first mesa portion Mes1. The first electrode 120 is electrically connected to the epitaxial stacked layer 110 through the current spreading layer 140. A material of the current spreading layer 140 is, for example, indium tin oxide (ITO) or indium zinc oxide (IZO) or a transparent conductive material such as a transparent metal layer, etc., or a metal material having a reflecting function such as Au, Ni, Pt, Sn, Al, Ti, W/Au alloy, Al/Cu alloy, Sn/Ag/Cu alloy, Sn alloy or alloys thereof, which is not limited by the invention.
(31) In the present embodiment, the insulation layer 150 is disposed on a side surface SS of the epitaxial stacked layer 110 and a part of a top surface TS of the epitaxial stacked layer 110 to expose the first mesa portion Mes1 and the second mesa portion Mes2. The insulation layer 150 and the first electrode 120, the second electrode 130 have gaps there between. A material of the insulation layer 150 is, for example, an insulation material or a combination of two stacked materials with different refractive indexes, which has a protection or reflection function, so that the insulation layer 150 is also regarded as a protective layer. The insulation layer 150 is, for example, made of SiO.sub.2, or Si.sub.3N.sub.4 or TiO.sub.2, which is not limited by the invention.
(32) In the present embodiment, the substrate 160 is, for example, a sapphire substrate (Al.sub.2O.sub.3). In other embodiments, the substrate 160 may be a silicon substrate, a silicon carbide substrate (SiC) or other substrate suitable for growing the epitaxial stacked layer 110. The epitaxial stacked layer 110, the first electrode 120 and the second electrode 130 are disposed at a same side of the substrate 160. To be specific, the unintentionally doped semiconductor layer 118, the second type doped semiconductor layer 116, the light emitting layer 114 and the first type doped semiconductor layer 112 of the epitaxial stacked layer 110 are sequentially stacked on the substrate 160.
(33) Referring to FIG. 1B and FIG. 1C, in the present embodiment, since the first type doped semiconductor layer 112 and the second type doped semiconductor layer 116 are opposite in electrical property, a part of the first type doped semiconductor layer 112, a part of the light emitting layer 114 and a part of the second type doped semiconductor layer 116 in the first mesa portion Mes1 may be regarded as a first diode Dio1. A part of the first type doped semiconductor layer 112, a part of the light emitting layer 114 and a part of the second type doped semiconductor layer 116 in the first sub mesa portion SMes1 may be regarded as a second diode Dio2. A part of the first type doped semiconductor layer 112, a part of the light emitting layer 114 and a part of the second type doped semiconductor layer 116 in the second sub mesa portion SMes2 may be regarded as a third diode Dio3. The LED 100 of the present embodiment is equivalent to be connected to an external power Vs (shown in FIG. 1C), and a positive electrode of the external power Vs is coupled to the first electrode 120 of the LED 100. A positive terminal T.sub.p1 of the first diode Dio1 is coupled to the first electrode 120, and a negative terminal T.sub.N1 of the first diode Dio1 is coupled to a negative terminal T.sub.N2 of the second diode Dio2 and a negative terminal T.sub.N3 of the third diode Dio3. A negative electrode of the external power Vs, a positive terminal T.sub.P2 of the second diode Dio2 and a positive terminal T.sub.P3 of the third diode are regarded to be grounded. A resistance of the components in the LED 100 may be equivalent to a resistance R.
(34) Referring to FIG. 1B and FIG. 1C, when the external power Vs supplies a current i to the LED 100, since the current i is a forward bias for the first diode Dio1 of the first mesa portion Mes1, and the current i is a reverse bias for the second diode Dio2 of the first sub mesa portion SMes1 and the third diode Dio3 of the second sub mesa portion SMes2, the current i is not liable to flow to the second electrode 130 from the top surfaces of the first sub mesa portion SMes1 and the second sub mesa portion SMes2. In detail, the current i sequentially passes through the first electrode 120, the current spreading layer 140, the first type doped semiconductor layer 112 (i.e. the P-type doped semiconductor layer 112), the light emitting layer 114, the second type doped semiconductor layer 116 (i.e. the N-type doped semiconductor layer 116), and then enters the second electrode 130 through the second portion S32 of the third surface S3 of the second electrode 130 (i.e. the part of surface of the second electrode 130 that directly contacts the second type doped semiconductor layer 116), and then the current i leaves the LED 100 from the second electrode 130. In other words, the portion of the second electrode 130 that contacts the first type doped semiconductor layer 112 on the second mesa portion Mes2 (i.e. the first sub mesa portion SMes1 and the second sub mesa portion SMes2) has a current barrier function, and the portion of the second electrode 130 that contacts the second type doped semiconductor layer 116 on the second mesa portion Mes2 has a current conducting function.
(35) According to the above description, in the LED 100 of the present embodiment, through the design of contacting the second electrode 130 with the first type doped semiconductor layer 112, the light emitting layer 114 and the second type doped semiconductor layer 116 located at the second mesa portion Mes2, compared to the structure of the prior art where the protective layer is evaporated and etched in the hole, the LED of the invention has a simple structure and a higher manufacturing yield, and an area of the second electrode 130 is not limited.
(36) FIG. 2A to FIG. 2K are flowcharts illustrating a process for manufacturing the LED of the embodiment of FIG. 1A and FIG. 1B. The method for manufacturing the LED 100 of the invention is described in detail below.
(37) Referring to FIG. 2A, the substrate 160 is provided. The substrate 160 is, for example, a growth substrate used for growing the epitaxial stacked layer 110.
(38) Referring to FIG. 2B, the epitaxial stacked layer 110 is forming on the substrate 160, where the epitaxial stacked layer 110 includes the first type doped semiconductor layer 112, the light emitting layer 114, the second type doped semiconductor layer 116 and the unintentionally doped semiconductor layer 118 (a function thereof is to serve as a low temperature nucleation layer or a buffer layer, and a main component thereof is GaN or AlN) or a buffer layer formed by a non-epitaxial growing process, for example, GaN, AlN, SiC or a combination thereof including a carbon material or a carbon covalent bond. The light emitting layer 114 is located between the first type doped semiconductor layer 112 and the second type doped semiconductor layer 116. The first type doped semiconductor layer 112 and the second type doped semiconductor layer 116 are opposite in electrical property. In detail, the unintentionally doped semiconductor layer 118 is first formed on the substrate 160. Then, the second type doped semiconductor layer 116 is formed on the unintentionally doped semiconductor layer 118. Then, the light emitting layer 114 is formed on the second type doped semiconductor layer 116. Finally, the first type doped semiconductor layer 112 is formed on the light emitting layer 114. The aforementioned method for growing the epitaxial stacked layer 110 is, for example, a metal organic chemical vapor deposition (MOCVD) method, though the invention is not limited thereto.
(39) Referring to FIG. 2C, a sacrificial layer SL is formed on the epitaxial stacked layer 110. A material of the sacrificial layer SL is, for example, SiO.sub.2, TiO.sub.2 or a combination of two stacked materials with different refractive indexes, which is not limited by the invention.
(40) Referring to FIG. 2D, a patterned photoresist layer PPR is formed on the sacrificial layer SL.
(41) Referring to FIG. 2E, a part of the sacrificial layer SL is etched. The sacrificial layer SL is, for example, etched through dry chemical etching, wet chemical etching, physical etching or a combination thereof to transfer a pattern of the patterned photoresist layer PPR to the sacrificial layer SL to form a patterned sacrificial layer PSL and expose a part of the epitaxial stacked layer 110.
(42) Referring to FIG. 2F, the epitaxial stacked layer 110 is etched to expose a part of the second type doped semiconductor layer 116 to form the first recess portion D1 and the second recess portion D2. To be specific, a part of the first type doped semiconductor layer 112, a part of the light emitting layer 114 and a part of the second type doped semiconductor layer 116 are etched to form the first mesa portion Mes1 and the second mesa portion Mes2 of the epitaxial stacked layer 110, and the second mesa portion Mes2 further has the first sub mesa portion SMes1 and the second sub mesa portion SMes2, where the patterned sacrificial layer PSL and the patterned photoresist layer PPR serve as a barrier layer of etching. In detail, in the etching process of FIG. 2F, the first recess portion D1 is formed to define the first mesa portion Mes1 and the second mesa portion Mes2, and the second recess portion D2 is formed to define the first sub mesa portion SMes1 and the second sub mesa portion SMes2 of the second mesa portion Mes2. In the etching process, the pattern of the patterned sacrificial layer PSL and the patterned photoresist layer PPR may be transferred to define a pattern of the first mesa portion Mes1 and the second mesa portion Mes2. In the present embodiment, the etching process is implemented through the dry chemical etching or the physical etching, and only the patterned sacrificial layer PSL may be taken as the barrier layer of etching to define the first mesa portion Mes1 and the second mesa portion Mes2, and the second recess portion D2 is formed to define the first sub mesa portion SMes1 and the second sub mesa portion SMes2 of the second mesa portion Mes2, though the invention is not limited thereto.
(43) Referring to FIG. 2G, the patterned photoresist layer PPR and the patterned sacrificial layer PSL are removed to expose the first mesa portion Mes1 and the second mesa portion Mes2.
(44) Referring to FIG. 2H, a part of the first type doped semiconductor layer 112, a part of the light emitting layer 114, a part of the second type doped semiconductor layer 116 and a part of the unintentionally doped semiconductor layer 118 are etched to expose a part of the substrate 160. In detail, in the manufacturing method of FIG. 2H, referring to the process of FIG. 2F, a patterned sacrificial layer and a patterned photoresist layer or a patterned sacrificial layer is taken as a barrier layer of etching to form a part of the first type doped semiconductor layer 112, a part of the light emitting layer 114, a part of the second type doped semiconductor layer 116 and a part of the unintentionally doped semiconductor layer 118 and expose a part of the substrate 160.
(45) Referring to FIG. 2I, the insulation layer 150 is formed on the side surface SS of the epitaxial stacked layer 110 and a part of the top surface TS of the epitaxial stacked layer 110 to expose the first mesa portion Mes1 and the second mesa portion Mes2. The method for forming the insulation layer 150 is, for example, plasma-enhanced chemical vapour deposition (PECVD) or E-gun evaporation or alternatively, a photolithography photoresist lift-off or an etching manner is used, wherein an insulation layer is formed on the patterned photoresist layer and the epitaxial stacked layer 110 through the PECVD or the E-gun evaporation, and then the patterned photoresist layer is removed through photoresist lift-off, so as to form the insulation layer 150 on the epitaxial stacked layer 110 and a part of the substrate 160, however, the invention is not limited thereto.
(46) Referring to FIG. 2J, the current spreading layer 140 is formed on the first mesa portion Mes1, where the current spreading layer 140 contacts the first type doped semiconductor layer 112 located at the first mesa portion Mes1. The current spreading layer 140 is, for example, formed through E-gun evaporation or sputtering. In detail, a method for forming the current spreading layer 140 is to form the patterned photoresist layer on the epitaxial stacked layer 110 by using a photolithography photoresist lift-off or an etching manner, and the current spreading layer 140 is formed on the patterned photoresist layer is formed on the epitaxial stacked layer 110 through the PECVD or the E-gun evaporation, and then the patterned photoresist layer is removed through photoresist lift-off, so as to form the current spreading layer 140 on the epitaxial stacked layer 110.
(47) Referring to FIG. 2K, the first electrode 120 and the second electrode 130 are formed on the first mesa portion Mes1 and the second mesa portion Mes2, respectively. The first electrode 120 and the second electrode 130 are electrically connected to the epitaxial stacked layer 110. Till now, manufacturing of the LED 100 of the embodiment of FIG. 1A and FIG. 1B is substantially completed.
(48) It should be noticed that reference numbers of the components and a part of contents of the aforementioned embodiment are also used in the following embodiment, wherein the same reference numbers denote the same or like components, and descriptions of the same technical contents are omitted. The aforementioned embodiment can be referred for descriptions of the omitted parts, and detailed descriptions thereof are not repeated in the following embodiment.
(49) FIG. 3A is a top view of a LED according to another embodiment of the invention. FIG. 3B is a cross-sectional view of FIG. 3A viewing along a section line B-B.
(50) Referring to FIG. 3A and FIG. 3B, the LED 100a of the embodiment of FIG. 3A and FIG. 3B is substantially similar to the LED 100 of the embodiment of FIG. 1A and FIG. 1B, and a main difference there between is that in the present embodiment, the substrate 160 of the LED 100a is, for example, a patterned substrate 160, and is, for example, a patterned sapphire substrate (PSS).
(51) FIG. 4A is a top view of a LED according to still another embodiment of the invention. FIG. 4B is a cross-sectional view of FIG. 4A viewing along a section line C-C.
(52) Referring to FIG. 4A and FIG. 4B, the LED 100b of the embodiment of FIG. 4A and FIG. 4B is substantially similar to the LED 100 of the embodiment of FIG. 1A and FIG. 1B, and a main difference there between is that in the present embodiment, the insulation layer 150 of the LED 100b further extends to the surface of the substrate 160 from the side surface SS of the epitaxial stacked layer 110. In other words, the insulation layer 150 covers partial surface of the substrate 160.
(53) FIG. 5A is a top view of a LED according to still another embodiment of the invention. FIG. 5B is a cross-sectional view of FIG. 5A viewing along a section line D-D.
(54) Referring to FIG. 5A and FIG. 5B, the LED 100c of the embodiment of FIG. 5A and FIG. 5B is substantially similar to the LED 100 of the embodiment of FIG. 1A and FIG. 1B, and a main difference there between is that in the present embodiment, the first electrode 120 and the second electrode 130 of the LED 100c respectively cover a part of the insulation layer 150. In other words, a part of the insulation layer 150 is disposed between the first electrode 120 and the epitaxial stacked layer 110 and between the second electrode 130 and the epitaxial stacked layer 110.
(55) FIG. 6A is a top view of a LED according to still another embodiment of the invention. FIG. 6B is a cross-sectional view of FIG. 6A viewing along a section line E-E.
(56) Referring to FIG. 6A and FIG. 6B, the LED 100d of the embodiment of FIG. 6A and FIG. 6B is substantially similar to the LED 100 of the embodiment of FIG. 1A and FIG. 1B, and a main difference there between is that in the present embodiment, the first electrode 120 of the LED 100d directly contacts the first type doped semiconductor layer 122 of the first mesa portion Mes1.
(57) FIG. 7A is a top view of a LED according to still another embodiment of the invention. FIG. 7B is a cross-sectional view of FIG. 7A viewing along a section line F-F.
(58) Referring to FIG. 7A and FIG. 7B, the LED 100e of the embodiment of FIG. 7A and FIG. 7B is substantially similar to the LED 100 of the embodiment of FIG. 1A and FIG. 1B, and a main difference there between is that in the present embodiment, the current spreading layer 140 of the LED 100e is disposed at the second mesa portion Mes2, a part of the first sub mesa portion SMes1 and a part of the second sub mesa portion SMes2, where the current spreading layer 140 electrically contacts the second type doped semiconductor layer 116 located at the second mesa portion Mes2.
(59) FIG. 8A is a top view of a LED according to still another embodiment of the invention. FIG. 8B is a cross-sectional view of FIG. 8A viewing along a section line G-G.
(60) Referring to FIG. 8A and FIG. 8B, the LED 100g of the embodiment of FIG. 8A and FIG. 8B is substantially similar to the LED 100 of the embodiment of FIG. 1A and FIG. 1B, and a main difference there between is that the first electrode 120 covers the current spreading layer 140. In other words, the current spreading layer 140 is located within a projection area of the first electrode 120 projected to the epitaxial stacked layer 110. The first surface S1 of the first electrode 120 exposed to external has different horizontal heights, and the second surface S2 of the second electrode 130 exposed to external has different horizontal heights. At least a part of the first surface S1 and at least a part of the second surface S2 are in a same horizontal plane.
(61) FIG. 9A to FIG. 20A are top views of a manufacturing process of a LED of according to another embodiment of the invention. FIG. 9B to FIG. 20B are cross-sectional views of the manufacturing process of FIG. 9A to FIG. 20A. FIG. 21 is a schematic diagram of a LED in a heating state according to an embodiment of the invention. FIG. 22A to FIG. 26A are top views of a manufacturing process of a LED of according to still another embodiment of the invention. FIG. 22B to FIG. 26B are cross-sectional views of the manufacturing process of FIG. 22A to FIG. 26A.
(62) The manufacturing process of FIG. 9A, FIG. 9B, FIG. 10A and FIG. 10B is similar to that of FIG. 2A and FIG. 2B, and detail thereof is not repeated.
(63) Referring to FIG. 11A and FIG. 11B, the epitaxial stacked layer 110 is etched to expose a part of the surface of the substrate 160, such that the epitaxial stacked layer 110 forms a plurality of sub epitaxial stacked layers 110S separated from each other. Each of the sub epitaxial stacked layers 110S includes a part of the first type doped semiconductor layer 112, a part of the light emitting layer 114, a part of the second type doped semiconductor layer 116 and a part of the unintentionally doped semiconductor layer 118.
(64) Referring to FIG. 12A and FIG. 12B, a part of the first type doped semiconductor layer 112, a part of the light emitting layer 114 and a part of the second type doped semiconductor layer 116 in each of the sub epitaxial stacked layers 110S are etched to make each of the sub epitaxial stacked layers 110S have the first recess portion D1 and the second recess portion D2. The first recess portion D1 defines the first mesa portion Mes1 and the second mesa portion Mes2 and exposes the second type doped semiconductor layer 1160 to form the first type conductive region and the second type conductive region respectively. The second mesa portion Mes2 has the second recess portion D2. The second recess portion D2 defines the first sub mesa portion SMes1 and the second sub mesa portion SMes2 in the second mesa portion Mes2. The second recess portion D2 exposes the second type doped semiconductor layer 116, a part of the first type doped semiconductor layer 112 and a part of the light emitting layer 114 in the second mesa portion Mes2. In the present embodiment, an area and a shape of an orthogonal projection of the first mesa portion Mes1 are substantially the same to an area and a shape of an orthogonal projection of the second mesa portion Mes2. The first recess portion D1 is located between the first type conductive region and the second type conductive region.
(65) Referring to FIG. 13A and FIG. 13B, a plurality of the first electrodes 120 are formed on the first mesa portions Mes1 in the first type conductive regions respectively. A plurality of the second electrodes 130 are formed on the second mesa portions Mes2 in the second type conductive regions respectively. Each of the first electrodes 120 is electrically connected to the corresponding sub epitaxial stacked layer 110S, and each of the second electrodes 130 is electrically connected to the corresponding sub epitaxial stacked layer 110S, so as to form a plurality of the LEDs 100g on the substrate 160. In each of the LEDs 100g, the second electrode 130 contacts the first type doped semiconductor layer 112, the light emitting layer 114 and the second type doped semiconductor layer 116 located on the second mesa portion Mes2, and each of the second electrodes 130 wraps each of the second recess portions D2. Certainly, in other embodiments, the LEDs 100g may also be added with the aforementioned current spreading layer or insulation layer, etc., which is not limited by the invention.
(66) Referring to FIG. 14A and FIG. 14B, a temporary substrate S is provided. An adhesive layer is, for example, configured on the temporary substrate S.
(67) Referring to FIG. 15A and FIG. 15B, the LEDs 100g on the substrate 160 are inversely disposed on the temporary substrate S.
(68) Referring to FIG. 16A and FIG. 16B, at least a part of the LEDs 100g on the substrate 160 disposed on the temporary substrate S is selected as a predetermined detaching portion PDP. An amount of the LEDs 100g in the predetermined detaching portion PDP is, for example, four, which are, for example, a first LED 100g1, a second LED 100g2, a third LED 100g3 and a fourth LED 100g4. In other embodiments, the amount of the LEDs 100g in the predetermined detaching portion PDP may also be greater than four or less than four, which is not limited by the invention.
(69) Referring to FIG. 17A and FIG. 17B, the predetermined detaching portion PDP is detached from the other portion of the substrate 160, and a detaching method is, for example, a laser lift-off method, a photochemical reaction method or a photophysical reaction method.
(70) Referring to FIG. 18A and FIG. 18B, the substrate 160 is removed to complete transferring the LEDs 100g in the predetermined detaching portion PDP to the temporary substrate S. Any of the LEDs 100g in the predetermined detaching portion PDP on the temporary substrate S is the first LED 100g1. The first LED 100g1 is located adjacent to the second LED 100g2 of the LEDs 100g in a first direction X1, and the first LED 100g1 and the second LED 100g2 have a first gap G1 there between. The first LED 100g1 is located adjacent to the third LED 100g3 of the LEDs 100g in a second direction X2 different to the first direction X1, and the first LED 100g1 and the third LED 100g3 have a second gap G2 there between. In detail, the first LED 100g1 is located adjacent to the third LED 100g3 in the first direction X1, and located adjacent to the second LED 100g2 in the second direction X2. The fourth LED 100g4 is located adjacent to the third LED 100g3 in the second direction X2, and located adjacent to the second LED 100g2 in the first direction X1. The first direction X1 is, for example, perpendicular to the second direction X2, and in other embodiments, the first direction X1 and the second direction X2 may also include a non-90 degree angle, which is not limited by the invention. In the present embodiment, the first gap G1 is greater than the second gap G2, and in other embodiments, the first gap G1 may be equal to the second gap G2, which is not limited by the invention. The first gap G1 and the second gap G2 may be designed to correspond to each other according to a corresponding package or module design match of the LED. Moreover, a length of an orthogonal projection of any LED on the temporary substrate S in the first direction X1 is greater than or equal to a length of the orthogonal projection of the LED on the temporary substrate S in the second direction X2. In other embodiments, the first gap G1 between the first LED 100g1 and the second LED 100g2 is greater than or equal to the second gap G2 between the first LED 100g1 and the third LED 100g3. A shape of any LED 100g on the temporary substrate S may be a rectangle or a square, which is not limited by the invention.
(71) Referring to FIG. 19A and FIG. 19B, a permanent substrate PS is provided, and the permanent substrate PS has a plurality of predetermined bonding positions PBP thereon, and the predetermined bonding positions PBP have gaps corresponding to the first gap G1 and the second gap G2 of the LEDs 100g there between. The predetermined bonding positions PBP have a plurality of predetermined bonding electrodes PE disposed corresponding to the first electrodes 120 and the second electrodes 130 of the LEDs 100g.
(72) Referring to FIG. 20A and FIG. 20B, the LEDs 100g in the predetermined detaching portion PDP on the temporary substrate S shown in FIG. 18A and FIG. 18B are transferred to the permanent substrate PS, and a plurality of the first electrodes 120 and a plurality of the second electrodes 130 of the LEDs 100g are electrically connected to the predetermined bonding electrodes PE on the permanent substrate PS. During the aforementioned process of transferring the LEDs to the permanent substrate, a heating process, a pressurization process or a combination thereof may be added. Referring to FIG. 21, after the LEDs 100g are heated by the heating process, the first electrodes 120 and the second electrodes 130 thereof form semi-arc shapes. The first electrodes 120 and the second electrodes 130 with a plurality of semi-arc shapes in the LEDs 100g are bonded to the predetermined bonding electrodes PE on the permanent substrate PS through eutectic or welded bonding. The semi-arc shaped first electrodes 120 and second electrodes 130 may be directly bonded and electrically connected to the predetermined bonding electrodes PE on the permanent substrate PS.
(73) Referring to FIG. 16A and FIG. 16B and referring to FIG. 22A and FIG. 22B, at least a part of the LEDs 100g on the substrate 160 is selected as the predetermined detaching portion PDP, and the part of substrate 160 carrying the predetermined detaching portion PDP is sliced from the other part of the substrate 160, and a slicing method thereof is, for example, a laser slicing method, a photochemical reaction method or a photophysical reaction method, so as to form a plurality of traces on the substrate 160. A splitting device is adopted to separate the predetermined detaching portion PDP from the other part of the substrate 160 along the traces.
(74) Referring to FIG. 23A and FIG. 23B, the LEDs 100g on the sliced predetermined detaching portion PDP are transferred to the temporary substrate S.
(75) Referring to FIG. 24A and FIG. 24B, the substrate 160 carrying the sliced predetermined detaching portion PDP is detached, and a detaching method is, for example, a laser lift-off method, a photochemical reaction method or a photophysical reaction method, so as to detach the substrate 160 carrying the predetermined detaching portion PDP from the LEDs 100g in batches or in one time.
(76) Referring to FIG. 25A and FIG. 25B, the substrate 160 is removed to complete transferring the LEDs 100g in the predetermined detaching portion PDP to the temporary substrate S. Any of the LEDs 100g in the predetermined detaching portion PDP on the temporary substrate S is the first LED 100g1. The first LED 100g1 is located adjacent to the second LED 100g2 of the LEDs 100g in the first direction X1, and the first LED 100g1 and the second LED 100g2 have the first gap G1 there between. The first LED 100g1 is located adjacent to the third LED 100g3 of the LEDs 100g in the second direction X2 different to the first direction X1, and the first LED 100g1 and the third LED 100g3 have the second gap G2 there between.
(77) Referring to FIG. 26A and FIG. 26B, the permanent substrate PS of FIG. 19A and FIG. 19B is provided, and the LEDs 100g in the predetermined detaching portion PDP on the temporary substrate S are transferred to the permanent substrate Ps and are electrically connected to the predetermined bonding electrodes PE on the permanent substrate PS, and the process thereof is similar to the process mentioned in the embodiments of FIG. 19A, FIG. 19B, FIG. 20A, FIG. 20B and FIG. 21, and detail thereof is not repeated.
(78) In summary, in the LED of the invention, through the design of contacting the second electrode with the first type doped semiconductor layer, the light emitting layer and the second type doped semiconductor layer located on the second mesa portion, compared to the structure of the prior art where the protective layer is evaporated and etched in the hole, the LED of the invention has a simple structure and a higher manufacturing yield, and the area of the second electrode is not limited. Moreover, the aforementioned LED may be manufactured according to the manufacturing method of the LED of the invention, so that the manufacturing method of the LED of the invention has a simple manufacturing flow and higher manufacturing yield.
(79) It will be apparent to those skilled in the art that various modifications and variations can be made to the structure of the invention without departing from the scope or spirit of the invention. In view of the foregoing, it is intended that the invention cover modifications and variations of this invention provided they fall within the scope of the following claims and their equivalents.
