Oxygen candle

Abstract

Provided is an oxygen candle starting device, comprising a pull line column (17) and a percussion cap (15), wherein a pull line hole (155) is provided in the pull line column in an axial direction of the pull line column, a percussion cap cavity (154) is provided inside one end of the pull line column, a fire-preventing cavity is provided inside the other end of the pull line column, and the pull line hole passes through the fire-preventing cavity and the percussion cap cavity; the percussion cap is mounted in the percussion cap cavity, and sand grains (16) are packaged in the fire-preventing cavity. Further provided is an oxygen candle comprising the oxygen candle starting device and an oxygen generator, wherein the oxygen generator comprises an agent loading housing, with a through hole being provided in the top of the agent loading housing, a gas outlet being provided in the bottom thereof, and a filter being mounted at the gas outlet; and the percussion cap of the oxygen candle starting device is in contact with an oxygen candle agent via the through hole, the oxygen generator is connected to the agent loading housing in a sealed manner, and the filter is connected to the gas outlet in a sealed manner. The oxygen candle employs a pull-type starting device, and the starting structure for an existing oxygen candle is simplified, thereby preventing a false start caused by the falling-off of a steel needle and improving the reliability.

Claims

1. An oxygen candle starting device, comprising a pull line column and a percussion cap, wherein a pull line hole is provided in the pull line column in an axial direction of the pull line column, a percussion cap cavity is provided inside one end of the pull line column, and a fire-preventing cavity is provided inside the other end of the pull line column, the pull line hole passes through the fire-preventing cavity and the percussion cap cavity; the percussion cap is mounted in the percussion cap cavity, and sand grains are packaged in the fire-preventing cavity.

2. The oxygen candle starting device according to claim 1, wherein the percussion cap comprises a tension spring, which passes through the pull line hole.

3. The oxygen candle starting device according to claim 1, wherein the fire-preventing cavity is packaged by a rubber plug, the rubber plug is mounted via a jack bolt, and the pull line hole passes through the rubber plug and the jack bolt.

4. An oxygen candle, comprising an oxygen candle starting device and an oxygen generator, wherein the oxygen candle starting device is the oxygen candle starting device according to claim 1 wherein the oxygen generator comprises an agent loading housing, with a through hole being provided in the top of the agent loading housing, a gas outlet being provided in the bottom of the agent loading housing, and a filter being mounted at the gas outlet; the percussion cap of the oxygen candle starting device is in contact with the oxygen candle agent via the through hole, the oxygen generator is connected to the agent loading housing in a sealed manner, and the filter is connected to the gas outlet in a sealed manner.

5. The oxygen candle according to claim 4, wherein the oxygen candle agent is loaded in the agent loading housing, and a heat-insulating cotton is provided between the inner wall of the agent loading housing and the oxygen candle agent.

6. The oxygen candle according to claim 4, wherein the filter comprises a filter housing, with an air inlet being provided in the top of the filter housing, a gas outlet being provided on the bottom and a filter layer being mounted in the filter housing, and the filter housing is connected to the agent loading housing in a sealed manner.

7. The oxygen candle according to claim 4, wherein the filter housing comprises an upper cover and a lower housing, wherein an air inlet is provided in the upper cover, and a gas outlet is provided in the bottom of the lower housing.

8. The oxygen candle according to claim 7, wherein a moisture-proof cotton is provided between the upper cover and the filter layer, and a moisture-proof cotton is provided between the filter layer and the bottom of the lower housing.

9. The oxygen candle according to claim 7, wherein a carrier plate web is provided between the upper cover and the oxygen generator, wherein the carrier plate web is provided with vent holes and convex parts.

10. The oxygen candle according to claim 4, wherein the oxygen candle agent is loaded in the agent loading housing, and the oxygen candle agent comprises an absorbing inflammable layer, a heating layer and a main candle layer, wherein the heating layer is provided between the absorbing inflammable layer and the main candle layer; the main candle layer is made of, in mass percentage, 90%˜96% chlorate, 1.5%˜5% catalyst, 0˜3% fuel, 1.5%˜2.5% bonding agent and 0.5%˜1.5% stabilizing agent; the heating layer is made of, in mass percentage, 70%˜80% chlorate, 5%˜15% catalyst, 5%˜12% fuel and 3.0%˜6.0% bonding agent; the absorbing inflammable layer is made of, in mass percentage, 5%˜15% fuel, 80%˜90% barium chromate, 3%˜5% bonding agent and 0˜1% chlorate; the catalyst is a combination of more than two of cobalt oxide, MnO.sub.2 and titanium oxide, and the main candle layer has a catalyst dosage that is 4˜5 times of that of the heating layer; the fuel is a mixture of one or more of magnesium powder, titanium powder, cobalt powder and zirconium powder; the chlorate is sodium chlorate or potassium chlorate; the bonding agent is a combination of one or more of kaolin, glass fiber, ceramic fiber and diatomite; and the stabilizing agent is a combination of one or more of potassium perchlorate, sodium perchlorate and micro silicon powder.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) FIG. 1 is a structural representation of an oxygen candle according to the invention;

(2) FIG. 2 is a partly enlarged view of a percussion cap according to one embodiment of the invention;

(3) FIG. 3 is a structural representation of a filter according to one embodiment of the invention;

(4) FIG. 4 is an enlarged view of the structure between the oxygen generator and the filter; and

(5) FIG. 5 is an enlarged view of the structure of the carrier plate in FIG. 4.

DETAILED DESCRIPTION OF THE EMBODIMENTS

(6) The percussion cap of the invention may employ percussion cap with a column structure (for example, a cylinder). For example, in the structure diagram of the percussion cap shown in FIG. 2, the percussion cap consists of a percussion cap housing 153, a percussion cap agent 152 and a tension spring 151. The percussion cap housing 153 is a cylindrical housing for protecting the percussion cap agent 152, with the upper bottom face being provided with a small hole and the lower bottom face being opened. The percussion cap housing 153 is placed in a percussion cap cavity 154 of the pull line column. The tension spring 151 passes through the percussion cap agent 152 and a pull line hole 155. The percussion cap cavity 154 is a cylindrical cavity similar to the percussion cap housing 153. The pull line hole 155 is a hole the same as that on the upper bottom face of the percussion cap housing 153, which can be adapted for the smooth pull-out of the tension spring. Under the action of an external force, friction is generated between the tension spring and the percussion cap agent at the moment the tension spring is pulled straight, so that the percussion cap is ignited.

(7) The tension spring 151 of the invention passes through the fire-preventing sand. When the percussion cap is ignited, the fire-preventing sand plays the role of heat damping and prevents post torching. Further, the rubber plug blocks the gas from escaping. The material of the rubber plug may be one selected from butyronitrile rubber, chloroprene rubber, styrene butadiene rubber and fluororubber.

(8) The heat-insulating cotton of the invention may employ a silicon dioxide aerogel heat-insulating cotton for reduing heat loss, and the housing temperature of the oxygen candle may be greatly lowered.

(9) The carrier plate web between the oxygen candle agent and the filter layer of the invention lowers the oxygen flow resistance. Stainless steel may be selected as the material of the carrier plate web, mainly for lowering the airflow resistance.

(10) The filter layer of the invention may employ a hybrid-type filter layer, which may consist of a catalyst and an alkali metal peroxide (for example, sodium peroxide). A filter material prepared by a heating and grinding hybrid process can effectively absorb harmful gases such as CO and CO.sub.2, etc.

(11) The technical solutions in the embodiments of the invention will be described clearly and fully below in conjunction with the drawings in the embodiments of the invention. Apparently, the embodiments described are only a part of the embodiments of the invention, rather than being the whole embodiments. All the other embodiments obtained by one of ordinary skills in the art based on the embodiments of the invention without creative work pertain to the protection scope of the invention.

Embodiment 1

(12) As shown in FIG. 1 and FIG. 2, the oxygen candle starting device of this embodiment includes a pull line column 17 and a percussion cap 15, wherein a pull line hole 155 is provided in the pull line column in an axial direction of the pull line column, a percussion cap cavity 154 is provided inside one end of the pull line column 17, and a fire-preventing cavity is provided inside the other end of the pull line column, and the pull line hole passes through the fire-preventing cavity and the percussion cap cavity. The percussion cap 15 is mounted in the percussion cap cavity, and fire-preventing sand 16 is packaged in the fire-preventing cavity.

(13) The percussion cap consists of a percussion cap housing 153, a percussion cap agent 152 and a tension spring 151. The percussion cap housing 153 is a cylindrical housing for protecting the percussion cap agent 152, with the upper bottom face being provided with a small hole and the lower bottom face being opened. The percussion cap housing 153 is placed in the percussion cap cavity 154 of the pull line column, and the tension spring 151 passes through the percussion cap agent 152 and the pull line hole 155. The percussion cap cavity 154 is a cylindrical cavity similar to the percussion cap housing 153. The pull line hole 155 is a hole the same as that on the upper bottom face of the percussion cap housing 153, which can be adapted for the smooth pull-out of the tension spring.

(14) For easy operation, in some embodiments, a circular handle 11 is provided at the end part of the tension spring.

(15) In some specific embodiments, the fire-preventing cavity is packaged by a rubber plug 13, and the rubber plug is mounted via a jack bolt 12, wherein the pull line hole passes through the rubber plug and the jack bolt.

(16) For the selection of the parameters, the specific dimensions of the percussion cap may be selected as follows: a copper cylinder having a diameter D=5±0.01 mm, with the upper bottom face being opened and the lower bottom face being provided with a small hole of 0.5±0.01 mm in diameter; the percussion cap agent is loaded on the lower bottom face of the percussion cap housing, and a small hole with the same size as that of the lower bottom face is provided. Optionally, the tension spring has a diameter of 5 mm, the wire diameter d=0.5±0.01 mm, and one end of thereof is connected to a pulling ring, and the other end thereof is wound by 3˜5 turns. The material of the tension spring is one selected from copper wire or iron wire.

Embodiment 2

(17) As shown in FIG. 1, the oxygen candle of this embodiment includes an oxygen candle starting device, an oxygen generator and a filter.

(18) The oxygen generator is mounted below the oxygen candle starting device, and they are connected in a sealed manner. The filter is mounted below the oxygen generator, and similarly, they are connected in a sealed manner.

(19) The oxygen generator includes an agent loading housing 22, wherein a through hole is provided in the top of the agent loading housing 22, a gas outlet is provided in the bottom of the agent loading housing 22, and a filter is mounted at the gas outlet. The percussion cap of the oxygen candle starting device is in contact with the oxygen candle agent via the through hole. The pull line column of the oxygen candle starting device is connected to the agent loading housing in a sealed manner, and the filter is connected with all the gas outlets in a sealed manner. The bottom of the pull line column may be welded to the agent loading housing to achieve a sealing effect.

(20) In some more specific embodiments, an oxygen candle agent 18 is mounted inside the agent loading housing, and a heat-insulating cotton 20 is provided between the inner wall of the agent loading housing and the oxygen candle agent.

(21) The filter of this embodiment includes a filter housing 23, with an air inlet being provided in the top of the filter housing, a gas outlet 24 being provided in the bottom thereof and a filter layer 21 being mounted in the filter housing, wherein the filter housing and the agent loading housing are connected in a sealed manner.

(22) In use, the tension spring 151 in FIG. 1 of the invention is pulled out via the pulling ring. Friction is generated between the tension spring and the percussion cap agent, and the heat generated ignites the agent. Heat damping is performed by the fire-preventing sand on the high-energy flame generated momentarily, and the oxygen candle body is ignited to release high-concentration oxygen.

(23) In some embodiments, as shown in FIG. 3, the filter housing 23 includes an upper cover 130 and a lower housing 118. The upper cover is provided with an air inlet, and the bottom of the lower housing is provided with a gas outlet 24. In a preferred solution, as shown in FIG. 4, a moisture-proof cotton 117 is provided between the upper cover 130 and the filter layer 21, and a moisture-proof cotton is provided between the filter layer and the bottom of the lower housing. In a more preferred solution, as shown in FIG. 4 and FIG. 5, a carrier plate web 19 is provided between the upper cover 130 and the oxygen generator. Vent holes 191 are provided on the carrier plate web 19, and the carrier plate web is provided with convex parts 193. In a more preferred solution, a heat-insulating cotton 192 may be provided between the carrier plate web 19 and the oxygen generator.

(24) The high-concentration oxygen momentarily generated by the oxygen candle passes through the carrier plate web, as shown in FIG. 4, whereby the resistance on the gas flowing to the filter layer is effectively lowered. The momentarily generated high-concentration oxygen passes through the heat-insulating cotton 192, then passes through the carrier plate web 19 having holes 191 and convex parts 193, and enters the filter layer along the upper cover 130 of the filter layer. The harmful gas components contained in the gas is absorbed by the filter layer, and oxygen is released along the gas outlet.

(25) According to an experiment on the embodiment of the invention, the oxygen candle with a drawing-type structure meets the standard of AQ-1057s.

(26) Specific experiment results:

(27) TABLE-US-00001 detection item detection method detection result standard starting force spring tension 40N AQ-1057 machine trigger rate group experiment all 100% AQ-1057 started drop fall from height of intact structure AQ-1057 performance 3 m no oxygen released spontaneously rolling rolling impact test intact structure AQ-1057 experiment chamber no oxygen released spontaneously air tightness U-type pressure 15 Pa AQ-1057 gauge under 1 Kpa, pressure drop within 1 min no greater than 30 Pa

Embodiment 3

(28) The absorbing inflammable layer has a total weight of 10 g, and the ratio of each component (mass percentage) is as follows: chlorate 0.2%, magnesium powder 10%, barium chromate 85% and kaolin 4.8%.

(29) The heating body layer has a total weight of 52.1 g, with a ratio (mass percentage) of: sodium chlorate 73%, cobaltosic oxide 4%, manganese dioxide 6%, iron powder 5%, cobalt powder 7% and kaolin 5%.

(30) The main candle layer has a total weight of 300.05 g, with a ratio (mass percentage) of: sodium chlorate 95%, potassium perchlorate 0.5%, cobaltosic oxide 0.7%, manganese dioxide 0.8%, cobalt powder 1.0% and kaolin 2.0%. First of all, the chlorate is dried at 120° C. in an infrared oven for 30-60 min and then agitated and mixed uniformity with other weighed materials by a ball mill and a double worm mixer, a certain amount of NaCrO.sub.4 aqueous solution with a concentration of 0.5˜2% is added and mixed fully, and an oxygen-generating block with φ=20 mm and H=23 mm is prepared by moulding and demoulding and then dried at 120° C. in an infrared drying oven for 1 h.

(31) Experiment Result: the oxygen candle can be normally started, the catalyst is compounded by Co.sub.3O.sub.4/MnO.sub.2, the oxygen candle combusts stably without flowing, and it is detected that each performance index meets the standard of AQ-1057.

(32) TABLE-US-00002 detection item detection method detection result standard oxygen release wet flowmeter 6.0 L AQ-1057 oxygen purity multi-component  >95% — gas infrared analyzer oxygen release wet flowmeter 2.3 L AQ-1057 in the first 30 s oxygen release wet flowmeter 4.9 L AQ-1057 in the first 50 s nitrogen oxide nitrogen oxide 0 ppm AQ-1057 detecting tube carbon monoxide carbon monoxide 79 ppm AQ-1057 detecting tube chlorine chlorine 0 ppm AQ-1057 detecting tube carbon dioxide Co.sub.2 infrared 0.16% (v/v) AQ-1057 analyzer −20° C./60° C. — started normally AQ-1057 housing temperature thermometer 125° C. AQ-1057 reaction temperature temperature 195.4° C. — recorder effective oxygen — 41.5% — release/weight ratio

Embodiment 4

(33) The absorbing inflammable layer has a total weight of 15 g, with a ratio (mass percentage) of: chlorate 0.5%, magnesium powder 10%, barium chromate 84.5% and kaolin 5%;

(34) The heating body layer has a total weight of 59.12 g, with a ratio (mass percentage) of: sodium chlorate 76%, cobaltosic oxide 5%, manganese dioxide 5%, iron powder 3%, cobalt powder 6% and kaolin 5%.

(35) The main candle layer has a total weight of 285 g, with a ratio (mass percentage) of: sodium chlorate 95.5%, potassium perchlorate 0.7%, cobaltosic oxide 0.7%, manganese dioxide 0.9%, cobalt powder 0.5% and kaolin 1.7%. First of all, the chlorate is dried at 120° C. in an infrared oven for 30˜60 min and then agitated and mixed uniformity with other weighed materials by a ball mill and a double worm mixer, a certain amount of NaCrO.sub.4 aqueous solution with a concentration of 0.5˜2% is added and mixed fully, and an oxygen-generating block with φ=20 mm and H=23 mm is prepared by moulding and demoulding and then dried at 120° C. in an infrared drying oven for 1 h.

(36) Experiment Result: the oxygen candle can be normally started, the catalyst is compounded by Co.sub.3O.sub.4/MnO.sub.2, the oxygen candle combusts stably without flowing, and it is detected that each performance index meets the standard of AQ-1057.

(37) TABLE-US-00003 detection item detection method detection result standard oxygen release wet flowmeter 5.9 L AQ-1057 oxygen purity multi-component >95% gas infrared analyzer oxygen release wet flowmeter 2.4 L AQ-1057 in the first 30 s oxygen release wet flowmeter 5.0 L AQ-1057 in the first 50 s nitrogen oxide nitrogen oxide 0 ppm AQ-1057 detecting tube carbon monoxide carbon monoxide 76 ppm AQ-1057 detecting tube chlorine chlorine 0 ppm AQ-1057 detecting tube carbon dioxide CO.sub.2 infrared 0.14% (v/v) AQ-1057 analyzer −20° C./60° C. — started normally AQ-1057 housing temperature thermometer 130° C. AQ-1057 reaction temperature temperature 200.1° C. — recorder effective oxygen —  39% — release/weight ratio

Embodiment 5

(38) The absorbing inflammable layer has a total weight of 10 g, with a ratio (mass percentage) of: zirconium powder 8%, barium chromate 83% and kaolin 9%;

(39) The heating body layer has a total weight of 48.5 g, with a ratio (mass percentage) of: sodium chlorate 77%, cobaltosic oxide 6%, manganese dioxide 5.5%, iron powder 4%, magnesium powder 2.5% and kaolin 5%.

(40) The main candle layer has a total weight of 300.01 g, with a ratio (mass percentage) of: sodium chlorate 94.4%, potassium perchlorate 1.0%, cobaltosic oxide 0.9%, manganese dioxide 1.2%, magnesium powder 1.0% and kaolin 1.4%. First of all, the chlorate is dried at 120° C. in an infrared oven for 30˜60 min and then agitated and mixed uniformity with other weighed materials by a ball mill and a double worm mixer, a certain amount of NaCrO.sub.4 aqueous solution with a concentration of 0.5˜2% is add and mixed fully, and an oxygen-generating block with φ=20 mm and H=23 mm is prepared by moulding and demoulding and then dried at 120° C. in an infrared drying oven for 1 h.

(41) Experiment Result: the oxygen candle can be normally started, the catalyst is compounded by Co.sub.3O.sub.4/MnO.sub.2, the oxygen candle combusts stably without flowing, and it is detected that each performance index meets the standard of AQ-1057.

(42) TABLE-US-00004 detection item detection method detection result standard oxygen release wet flowmeter 5.9 L AQ-1057 oxygen purity multi-component >95% — gas infrared analyzer oxygen release wet flowmeter 2.1 L AQ-1057 in the first 30 s oxygen release wet flowmeter 3.5 L AQ-1057 in the first 50 s nitrogen oxide nitrogen oxide 0 ppm AQ-1057 detecting tube carbon monoxide carbon monoxide 77 ppm AQ-1057 detecting tube chlorine chlorine 0 ppm AQ-1057 detecting tube carbon dioxide CO.sub.2 infrared 0.15% (v/v) AQ-1057 analyzer −20° C./60° C. — started normally AQ-1057 housing temperature thermometer 120° C. AQ-1057 reaction temperature temperature 194.8° C. recorder effective oxygen —  41% — release/weight ratio

Embodiment 6

(43) The ratio of each component in the absorbing inflammable layer is the same as that of Embodiment 3.

(44) The ratio of each component in the heating body layer is the same as that of Embodiment 1.

(45) The main candle layer has a total weight of 295 g, with a ratio (mass percentage) of: sodium chlorate 93.5%, potassium perchlorate 1.5%, cobaltosic oxide 1.1%, manganese dioxide 1.3%, magnesium powder 1.1% and kaolin 1.5%. First of all, the chlorate is dried at 120° C. in an infrared oven for 30˜60 min and then agitated and mixed uniformity with other weighed materials by a ball mill and a double worm mixer, a certain amount of NaCrO.sub.4 aqueous solution with a concentration of 0.5˜2% is add and mixed fully, and an oxygen-generating block with φ=20 mm and H=23 mm is prepared by moulding and demoulding and then dried at 120° C. in an infrared drying oven for 1 h.

(46) Experiment Result: the oxygen candle can be normally started, the catalyst is compounded by Co.sub.3O.sub.4/MnO.sub.2, the oxygen candle combusts stably without flowing, and it is detected that each performance index meets the standard of AQ-1057.

(47) TABLE-US-00005 detection item detection method detection result standard oxygen release wet flowmeter 5.6 L AQ-1057 oxygen purity multi-component >95% gas infrared analyzer oxygen release wet flowmeter 2.1 L AQ-1057 in the first 30 s oxygen release wet flowmeter 3.9 L AQ-1057 in the first 50 s nitrogen oxide nitrogen oxide 0 ppm AQ-1057 detecting tube carbon monoxide carbon monoxide 63 ppm AQ-1057 detecting tube chlorine chlorine 0 ppm AQ-1057 detecting tube carbon dioxide CO.sub.2 infrared 0.20% (v/v) AQ-1057 analyzer −20° C./60° C. — started normally AQ-1057 housing temperature thermometer 126° C. AQ-1057 reaction temperature temperature 196.6° C. — recorder effective oxygen —  40% — release/weight ratio

Embodiment 7

(48) The ratio of each component in the absorbing inflammable layer is the same as that of Embodiment 2.

(49) The ratio of each component in the heating body layer is the same as that of Embodiment 3.

(50) The main candle layer has a total weight of 320 g, with a ratio (mass percentage) of: sodium chlorate 92.6%, potassium perchlorate 1.2%, cobaltosic oxide 1.0%, manganese dioxide 1.5%, cobalt powder 1.5%, magnesium powder 1.0% and kaolin 2.2%. First of all, the chlorate is dried at 120° C. in an infrared oven for 30˜60 min and then agitated and mixed uniformity with other weighed materials by a ball mill and a double worm mixer, a certain amount of NaCrO.sub.4 aqueous solution with a concentration of 0.5˜2% is add and mixed fully, and an oxygen-generating block with φ=20 mm and H=23 mm is prepared by moulding and demoulding and then dried at 120° C. in an infrared drying oven for 1 h.

(51) Experiment Result: the oxygen candle can be normally started, the catalyst is compounded by Co.sub.3O.sub.4/MnO.sub.2, the oxygen candle combusts stably without flowing, and it is detected that each performance index meets the standard of AQ-1057.

(52) TABLE-US-00006 detection item detection method detection result standard oxygen release wet flowmeter 5.8 L AQ-1057 oxygen purity multi-component  >95% — gas infrared analyzer oxygen release wet flowmeter 2.2 L AQ-1057 in the first 30 s oxygen release wet flowmeter 3.6 L AQ-1057 in the first 50 s nitrogen oxide nitrogen oxide 0 ppm AQ-1057 detecting tube carbon monoxide carbon monoxide 70 ppm AQ-1057 detecting tube chlorine chlorine 0 ppm AQ-1057 detecting tube carbon dioxide CO.sub.2 infrared 0.15% (v/v) AQ-1057 analyzer −20° C./60° C. started normally AQ-1057 housing temperature thermometer 118° C. AQ-1057 reaction temperature temperature 195.9° C. — recorder effective oxygen — 39.5% — release/weight ratio

(53) The above formulation examples 1, 2, 3, 4, 5 are prepared in the process below.

(54) First of all, a certain amount of main candle body is added to the lower part of the cavity of a forming mould; next, a heating body layer well mixed is added for prepressing; then, the components of an inflammable layer is added for shaping and demoulding. The oxygen candle as formed is placed into a baking oven at a constant temperature of 120° C. for 30 min, and an intact oxygen-generating device is equipped, then the oxygen-generating device is placed at a constant temperature of −20° C., 25° C. and 60° C. for 2 h respectively to detect whether the oxygen candle can be started successfully.

(55) The oxygen-generating agent in the oxygen candle according to the invention has a decomposition temperature lower than 200° C., and the temperature rise of the housing is less than 130° C. According to the oxygen release and the change of the oxygen candle before and after combustion, the effective oxygen release/weight ratio is 39%-41%.

(56) The above embodiments will not limit the scope of the invention, and any modification, equivalent substitution and improvement made within the principles of the above embodiments without creative work will pertain to the protection scope of the invention.