FIVE-POINT DECONVOLUTION INTERPRETATION METHOD FOR QUANTIFICATION OF URANIUM ORES BY GAMMA SPECTRUM LOGGING
20230228906 · 2023-07-20
Inventors
- Bin Tang (Fuzhou, CN)
- Xiongjie Zhang (Fuzhou, CN)
- Haitao Wang (Fuzhou, CN)
- Zhifeng Liu (Fuzhou, CN)
- Yan Zhang (Fuzhou, CN)
- Renbo Wang (Fuzhou, CN)
- Lijiao Zhang (Fuzhou, CN)
- Rui Chen (Fuzhou, CN)
- Fan Huang (Fuzhou, CN)
- Shumin Zhou (Fuzhou, CN)
- Jinhui Qu (Fuzhou, CN)
Cpc classification
Y02E30/30
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
International classification
Abstract
A five-point deconvolution method for quantification of uranium ores by energy spectrum logging disclosed by the invention refers to: carry out γ spectrum logging along the borehole to obtain logging curves in multiple energy zones, using these logging curves and energy spectrum features, inversion calculate the distribution of uranium content along the borehole; the main features are: first, realize the subdivision interpretation of layered strata; second, realize multi-element stripping for energy spectrum logging; third, realize subdivision interpretation by the five-point deconvolution methods; fourth, on-site uranium ores quantification under fast spectral logging conditions can be realized; the invention also discloses two types of algorithm flows of “first stripping, then subdividing” and “first subdividing, then stripping” and the formula for solving the uranium/thorium/potassium content of the unit layer.
Claims
1. A five-point deconvolution interpretation method for quantification of uranium ores by γ spectrum logging specifically refers to: carry out γ spectrum logging along the borehole to obtain logging curves in multiple energy zones, using these logging curves and energy spectrum features, inversion calculate the distribution of uranium content along the borehole; divide 7 energy zones according to the energy range of natural γ-ray, and collect them into 7 logging curves according to the count rate of each energy zone at each measuring point; according to the five-point deconvolution method for quantification of uranium ores by energy spectrum logging, inversion calculate the algorithm flow, calculation formula for solving unit layer uranium, thorium and potassium content involved in the distribution of strata uranium content along the borehole.
2. The five-point deconvolution interpretation method for quantification of uranium ores by γ spectrum logging of claim 1: (1) The selection of detector: select a γ detector with excellent comprehensive performance, especially a detector with an energy resolution of 3.5%@662 keV or better; the total count rate of the energy spectrum measured by the detector at the center point of the saturated uranium layer with a content of 100 ppm cannot be lower than 1000 cps; (2) The division scheme of the energy zone, the determination of the energy range and the acquisition of the energy spectrum logging curves: All count rates in the energy zone are involved in the quantitative calculation of subdivision interpretation and element stripping, thereby realizing fast energy spectrum logging; according to the full spectrum and the coverage characteristic peaks thereof, select 7 energy zones, also known as 7 energy sections, subdivide the strata into “unit layers”, and construct the relationship between energy zones, unit layers and energy spectrum logging curves, the selected 7 energy zones are: The 0th energy zone, referred to as the total energy zone, has an energy range of [0.0 MeV, 2.8 MeV]; it reflects the counting effect of all characteristic peaks of uranium, thorium and potassium, as well as other energy peaks and Compton continuum, and obtain the total count rate of energy spectrum logging at a certain measuring point; this energy zone is not involved in uranium ore quantification, and is only used to evaluate whether the total count rate of the energy spectrum of the logging instrument meets the standard; The 1st energy zone has an energy range of [0.4 MeV, 2.8 MeV], it reflects the counting effect of all the characteristic peaks in the high-energy zone of uranium, thorium and potassium, as well as other energy peaks and Compton continuum, and is the energy zone used for the quantification of uranium ores in the current γ total logging; this energy zone covers the largest characteristic peak of thorium at 2.615 MeV, recorded as thorium characteristic spectrum 2. The 2nd energy zone has an energy range of [0.4 MeV, 2.3 MeV], it reflects the counting effect of part of the characteristic peaks in the high-energy zone of uranium, thorium and potassium, as well as other energy peaks and Compton continuum; this energy zone covers the characteristic peak of uranium at 2.20 MeV, recorded as uranium characteristic spectrum 3; The 3rd energy zone has an energy range of [0.4 MeV, 2.0 MeV], it reflects the counting effect of part of the characteristic peaks in the high-energy zone of uranium, thorium and potassium, as well as other energy peaks and Compton continuum; this energy zone covers the largest characteristic peak of uranium at 1.765 MeV, recorded as uranium characteristic spectrum 2; The 4th energy zone has an energy range of [0.4 MeV, 1.7 MeV], it reflects the counting effect of part of the characteristic peaks in the high-energy zone of uranium, thorium and potassium, as well as other energy peaks and Compton continuum; this energy zone covers the thorium characteristic peak of 2.615 MeV and the double escape peak of 1.595 MeV, recorded as thorium characteristic spectrum 1; The 5th energy zone has an energy range of [0.4 MeV, 1.55 MeV], it reflects the counting effect of part of the characteristic peaks in the high-energy zone of uranium, thorium and potassium, as well as other energy peaks and Compton continuum; this energy zone covers the sole characteristic peak of potassium 1.461 MeV, recorded as potassium characteristic spectrum; The 6th energy zone has an energy range of [0.4 MeV, 1.35 MeV], it reflects the counting effect of part of the characteristic peaks in the high-energy zone of uranium, thorium and potassium, as well as other energy peaks and Compton continuum; this energy zone covers multiple characteristic peaks of uranium/thorium, recorded as uranium characteristic spectrum 1; By default, the depth coordinate of each measurement point of the energy spectrum logging is 4, and the 7 energy spectrum logging curves constructed by the 7 energy spectrum count rates of each measurement point are recorded as:
{N.sub.i(Z.sub.j)}, wherein i=0,1, . . . ,6; j=1,2, . . . In the formula, subscript i is the number of 7 energy zones; subscript j=1, 2, . . . is the number of the measurement points, also the number of the unit layers; N.sub.i(Z.sub.j) represents the count rate of the energy spectrum obtained at the j-th measurement point in the i-th energy zone; (3) Using the two technical schemes of “first subdividing, then stripping” or “first stripping, then subdividing” to calculate the logging curves, the contents of uranium, thorium and potassium in each unit layer can be obtained at the same time.
3. The five-point deconvolution interpretation method for quantification of uranium ores by γ spectrum logging of claim 2, the technical scheme of “first subdividing, then stripping” is: “First subdividing” is processing subdivision interpretation according to the first formula of Equation (1), that is, first obtain the intermediate variable N.sub.i′(Z.sub.j), which is called the saturation count rate; the physical meaning of the saturation count rate is: when a saturated ore layer is constructed from rocks with uranium, thorium and potassium content of q.sub.k(Z.sub.j), the count rate at the center of the ore layer is N.sub.i′(Z.sub.j); “Then stripping” is processing element stripping according to the second formula of Equation (1), which is using the saturation count rate N.sub.i′(Z.sub.j) to obtain the content q.sub.k(Z.sub.j) of uranium, thorium and potassium elements in each unit layer; however, in the second formula, the value range of k is smaller than the value range of i, that is, the unknown variable q.sub.k(Z.sub.j) to be solved is less than the number of equations, and it is a singular equation that will have no solution if the equation is directly solved, which needs to be solved by the “least square method”;
4. The five-point deconvolution interpretation method for quantification of uranium ores by γ spectrum logging of claim 2, the technical scheme of “first stripping, then subdividing” is: “First stripping” is processing the element stripping according to the first formula of Equation (2), that is, first obtaining the intermediate variable q.sub.k′(Z.sub.j); the variable is called saturation content, and the physical meaning is: when the content of uranium, thorium and potassium elements in a saturated ore layer is q.sub.k′(Z.sub.j), the count rate at the center point of the ore layer will be N.sub.i(Z.sub.j); however, in the first formula, the value range of k is smaller than the value range of i, that is, the unknown variable q.sub.k′(Z.sub.j) to be solved is less than the number of equations, and it is a singular equation that will have no solution if the equation is directly solved, which needs to be solved by the “least square method”; “Then subdividing” refers to the subdivision interpretation according to the second formula of Equation (2), that is, the content q.sub.k(Z.sub.j) of uranium, thorium and potassium in each unit layer is calculated using the intermediate variable q.sub.k′(Z.sub.j);
Description
4. BRIEF DESCRIPTION OF ACCOMPANY DRAWINGS
[0047] In order to illustrate the technical schemes of the invention more clearly, the following briefly introduces the accompanying drawings needed in the embodiments. Obviously, the drawings in the following description are only some embodiments of the invention, and for those skilled in the art, other drawings can also be obtained from these drawings without any creative effort.
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5. SPECIFIC EMBODIMENT OF THE INVENTION
[0063] The technical schemes in the embodiments of the application will be clearly and completely described hereinafter with reference to the drawings in the embodiments of the application. Obviously, the described embodiments are only a part of the embodiments of the application, rather than all the embodiments. Based on the embodiments in this application, all other embodiments obtained by those of ordinary skill in the art without creative work shall fall within the protection scope of this application.
[0064] In order to make the above objects, features and advantages of the application more clearly understood, the application will be described in further detail below with reference to the drawings and specific embodiments.
[0065] The embodiment mainly provides a logging method for determining the content of natural radioactive elements such as uranium, thorium and potassium in layered uranium ore or layered strata by using γ energy spectrum logging, comprising the following content: the γ energy spectrum curve of the saturated ore bed containing uranium/thorium/potassium and its central measuring point, schematic diagram of energy peak and energy zone division scheme (as shown in
[0066] The invention discloses the technical scheme, algorithm formula and software flow of two types of “uranium ore energy spectrum logging five-point deconvolution method”: “first stripping, then subdividing” and “first subdividing, then stripping”, specifically:
[0067] The technical scheme of using high-resolution γ energy spectrum to determine 7 energy zones and their energy spectrum count rate
[0068] Basic principles of energy peak identification and selection
[0069] For the saturated ore layer with high uranium/thorium content and moderate potassium content, the energy spectrum measured at the central measuring point is shown in
[0070] the characteristic peaks, including: the characteristic peaks of thorium are 2.615 MeV, 1.623 MeV, 1.621 MeV, 1.588 MeV; the characteristic peaks of uranium are 2.20 MeV, 1.765 MeV, 1.408 MeV, 1.401 MeV, 1.238 MeV, 1.12 MeV; the characteristic peaks of potassium are 1.461 MeV.
[0071] the escape peaks, including: single escape peak 2.105 MeV formed by thorium characteristic peak 2.615 MeV, double escape peak 1.595 MeV; single escape peak 1.255 MeV formed by uranium characteristic peak 1.765 MeV
[0072] the overlapping peaks, including: in the above energy peaks, 1.595 MeV, 1.588 MeV, 1.621 MeV, 1.623 MeV overlap each other; 1.255 MeV, 1.238 MeV overlap each other; 1.401 MeV, 1.408 MeV overlap each other.
[0073] As shown in
[0074] Software design flow chart of five-point deconvolution method for γ energy spectrum logging of uranium ore quantification
[0075] According to the two types of “five-point deconvolution method for uranium ore energy spectrum logging” that “first stripping, then subdividing” and “first subdividing, then stripping” and their formulas, the software flow disclosed by the invention is shown in
[0076] 1. The Basic Structure of γ Energy Spectrum Logging Tool
[0077] γ energy spectrum logging tool is an instrument and equipment that converts the measured γ rays of different energies into nuclear pulse amplitude distribution (often called γ energy spectrum). The γ energy spectrum logging tool consists of seven parts (the basic structure is shown in
[0078] γ detector 1; multi-channel pulse amplitude analyzer 2; communication and auxiliary circuits 3; headstall 4; stainless steel probe housing 5; logging cable 6; rock mass 7; encoder disc 8; control and data processing platform 9; power and winch control platform 10.
[0079] Select a γ detector with excellent comprehensive performance, especially a detector with an energy resolution of 3.5% @662 keV or better. The detector can measure the total count rate of the energy spectrum above 1000 cps at the center point of the saturated uranium ore with a content of 100 ppm. For example, choose LaBr3(Ce) crystal detector.
[0080] In the embodiment, the depth interval is 10 cm, and the simulated γ energy spectrum logging instrument measures and saves the borehole γ energy spectrum data at a constant speed. The embodiment results of the γ energy spectrum curve at the center point of the ore layer are shown in
[0081] 2. Determination of γ Energy Range and Acquisition of γ Energy Spectrum Logging Curve
[0082] The key factors that cause the change of the energy spectrum of each measuring point include: the type and content of radioactive elements contained in the ore layer, interaction of rays with strata, detectors and other media in their boreholes. The characteristic peaks reflect the γ-rays of inherent energy released by uranium, thorium and potassium. Escape peaks and Compton continuum are caused by the interaction between rays and medium, and are secondary reflections of characteristic peaks. The interaction between the ray and the medium will also weaken the characteristic peaks and escape peaks, strengthen the Compton continuum, and then cover up the inherent characteristics of the γ-ray emitted by the uranium/thorium/potassium, which is an unfavorable factor for the resolution of element types and element content.
[0083] According to the energy zone division scheme provided by the invention, each measured γ energy spectrum is decomposed into 7 energy zones, wherein:
[0084] The 0th energy zone, represented by E.sub.0, has an energy range of [0.0 MeV, 2.8 MeV]; it reflects the counting effect of all characteristic peaks of uranium, thorium and potassium, as well as other energy peaks and Compton continuum, and obtain the total count rate of energy spectrum logging at a certain measuring point. This energy zone is not involved in uranium ore quantification, and is only used to evaluate whether the total count rate of the energy spectrum of the logging instrument meets the standard. The 1st energy zone, represented by E.sub.1, has an energy range of [0.4 MeV, 2.8 MeV], it reflects the counting effect of all the characteristic peaks in the high-energy zone of uranium, thorium and potassium, as well as other energy peaks and Compton continuum, and is the energy zone used for the quantification of uranium ores in the current γ total logging. This energy zone covers the largest characteristic peak of thorium at 2.615 MeV, recorded as thorium characteristic spectrum 2. The 2nd energy zone, represented by E.sub.2, has an energy range of [0.4 MeV, 2.3 MeV], it reflects the counting effect of part of the characteristic peaks in the high-energy zone of uranium, thorium and potassium, as well as other energy peaks and Compton continuum. This energy zone covers the characteristic peak of uranium at 2.20 MeV, recorded as uranium characteristic spectrum 3. The 3rd energy zone, represented by E.sub.3, has an energy range of [0.4 MeV, 2.0 MeV], it reflects the counting effect of part of the characteristic peaks in the high-energy zone of uranium, thorium and potassium, as well as other energy peaks and Compton continuum. This energy zone covers the largest characteristic peak of uranium at 1.765 MeV, recorded as uranium characteristic spectrum 2. The 4th energy zone, represented by E.sub.4, has an energy range of [0.4 MeV, 1.7 MeV], it reflects the counting effect of part of the characteristic peaks in the high-energy zone of uranium, thorium and potassium, as well as other energy peaks and Compton continuum. This energy zone covers the thorium characteristic peak of 2.615 MeV and the double escape peak of 1.595 MeV, recorded as thorium characteristic spectrum 1. The 5th energy zone, represented by E.sub.5, has an energy range of [0.4 MeV, 1.55 MeV], it reflects the counting effect of part of the characteristic peaks in the high-energy zone of uranium, thorium and potassium, as well as other energy peaks and Compton continuum. This energy zone covers the sole characteristic peak of potassium 1.461 MeV, recorded as potassium characteristic spectrum. The 6th energy zone, represented by E.sub.6, has an energy range of [0.4 MeV, 1.35 MeV], it reflects the counting effect of part of the characteristic peaks in the high-energy zone of uranium, thorium and potassium, as well as other energy peaks and Compton continuum. This energy zone covers multiple characteristic peaks of uranium/thorium, recorded as uranium characteristic spectrum 1.
[0085] Sum the data for each energy zone, subtract the background to get the net count N.sub.i. Let the depth coordinate of each measuring point be 4, where j=1, 2, . . . is the serial number of the measuring point; the seven energy spectrum logging curves constructed from the seven energy interval count rates of each measuring point are recorded as:
{N.sub.i(Z.sub.j)}, wherein i=0,1, . . . ,6; j=1,2, . . .
[0086] Proceed the γ energy spectrum data of the borehole of the embodiment according to the above method, then obtain seven energy spectrum logging curves, as shown in the solid lines in
[0087] 3. Using the two technical schemes of “first subdividing, then stripping” or “first stripping, then subdividing” to calculate the logging curves, the contents of uranium, thorium and potassium in each unit layer can be obtained at the same time.
[0088] The technical scheme of “first subdividing, then stripping” is:
[0089] “First subdividing” is processing subdivision interpretation according to the first formula of Equation (1), that is, first obtain the intermediate variable N.sub.i′(Z.sub.j), which is called the saturation count rate; the physical meaning of the saturation count rate is: when a saturated ore layer is constructed from rocks with uranium, thorium and potassium content of q.sub.k(Z.sub.j), the count rate at the center of the ore layer is N.sub.i′(Z.sub.j);
[0090] “Then stripping” is processing element stripping according to the second formula of Equation (1), which is using the saturation count rate N.sub.i′(Z.sub.j) to obtain the content q.sub.k(Z.sub.j) of uranium, thorium and potassium elements in each unit layer; however, in the second formula, the value range of k is smaller than the value range of i, that is, the unknown variable q.sub.k(Z.sub.j) to be solved is less than the number of equations, and it is a singular equation that will have no solution if the equation is directly solved, which needs to be solved by the “least square method”;
[0091] In the formula,
[0092] Zj represents the sampling point of the borehole depth coordinate Z, i.e. the coordinates of the measuring point, and the subscript j=1, 2, . . . is the serial number of the measuring point;
[0093] ΔZ represents the sampling distance of the measuring point coordinates Z, which satisfies the condition of ΔZ Z.sub.j+1−Z.sub.j≈10 cm;
[0094] N.sub.i(Z.sub.j) represents the count rate of the i-th energy zone at the measuring point coordinate Z.sub.j, and the measuring points are connected in sequence; the obtained i-th energy spectrum logging curve is {N.sub.i(Z.sub.j)}, wherein i=1, 2, . . . , 6 is the serial number of the energy zone;
[0095] q.sub.k(Z.sub.j) represents the content of the k-th radioactive element contained in the unit layer corresponding to the coordinate Z.sub.1 of the measuring point, wherein k=1 is the uranium content, k=2 is the thorium content, and k=3 is the potassium content;
[0096] A.sub.tk is called the conversion factor, which means that when the saturated ore layer is constructed by the unit content of the k-th radioactive element, the count rate at its center point is A.sub.tk, hence each radioactive element k has its own conversion factor in each energy zone i; the conversion factor is a set of constants obtained by using the measured data of standard model wells;
[0097] α.sub.i is called a characteristic parameter, which is a parameter describing the characteristics of the strata, indicating that after the measuring point leaves the ore layer, its energy spectrum logging curve will drop rapidly according to the negative exponential law at the descending speed of α.sub.i, which is also the absorption probability of the gamma rays in the i-th energy zone being absorbed by the strata of unit thickness; the characteristic parameters are a set of constants obtained in real time using their own energy spectrum logging curves.
[0098] The technical scheme of “first stripping, then subdividing” is:
[0099] “First stripping” is processing the element stripping according to the first formula of Equation (2), that is, first obtaining the intermediate variable q.sub.k′(Z.sub.j); the variable is called saturation content, and the physical meaning is: when the content of uranium, thorium and potassium elements in a saturated ore layer is q.sub.k′(Z.sub.j), the count rate at the center point of the ore layer will be N.sub.i(Z.sub.j); however, in the first formula, the value range of k is smaller than the value range of i, that is, the unknown variable q.sub.k′(Z.sub.j) to be solved is less than the number of equations, and it is a singular equation that will have no solution if the equation is directly solved, which needs to be solved by the “least square method”;
[0100] “Then subdividing” refers to the subdivision interpretation according to the second formula of Equation (2), that is, the content q.sub.k(Z.sub.j) of uranium, thorium and potassium in each unit layer is calculated using the intermediate variable q.sub.k′(Z.sub.j);
[0101] In the formula, the physical meaning of each parameter is shown in Equation (1).
[0102] 4. Methods and Embodiments of Quantitative Interpretation of Uranium Ore
[0103] According to the technical scheme of “first subdividing, then stripping” provided by the invention, deconvolution calculation is performed on the obtained seven energy spectrum logging curves according to formula (3) respectively, and the saturated count rate N.sub.i′(Z.sub.j) of each ore layer is obtained. The calculation results are shown in the dotted lines in
[0104] It should be noted that formula (3) needs to obtain the characteristic parameter α.sub.1 respectively through the curves during calculation. The calculation method is the same as the calculation method of the characteristic parameter a in the subdivision interpretation technology of γ total amount of uranium ore.
[0105] At last, use the numerical solution of singular equations such as the “least square method”, and perform element stripping according to formula (4). That is, the content q.sub.k(Z.sub.j) of uranium, thorium and potassium elements in each unit layer is obtained by using the saturation count rate kVA and the interpretation results are shown in
[0106] It can be seen from
[0107] The above-mentioned embodiments are only the description of the preferred mode of the application, rather than limiting the scope of the application. Without departing from the design spirit of the application, various modifications and improvements made by those of ordinary skill in the art to the technical schemes of the application shall all fall within the protection scope determined by the claims of the application.