Liquid dispenser with framed refill receiving bay
10568467 ยท 2020-02-25
Assignee
Inventors
- Agnete Enga (Oslo, NO)
- Ivan Exposito Sanchez (Valencia, ES)
- Jamie Mark Nicholson (Brooklyn, NY, US)
- Kevin Richard Lozeau (Charlotte, NC, US)
- Srinivasan Krishnan (New Canaan, CT, US)
Cpc classification
A47K5/1204
HUMAN NECESSITIES
B05B11/1087
PERFORMING OPERATIONS; TRANSPORTING
B05B11/0054
PERFORMING OPERATIONS; TRANSPORTING
A47K5/1217
HUMAN NECESSITIES
International classification
Abstract
A liquid dispenser has a bay surrounded by a shaped frame that is sized to receive a shaped refill inserted at an acute angle of 75 degrees or less in relation to the dispenser's lateral central axis. This unique arrangement is designed to maintain consistent quality of liquids dispensed by preventing the substitution of product refills having different shapes whose contents are of uncertain quality. Refills may be readily manufactured and at low cost. Mechanical and motorized dispensers with optional proximity detection of a user's hand may be used with the inventive dispenser and refill arrangement. Liquid or foam may be dispensed depending on the design of the dispenser pump.
Claims
1. A liquid dispenser (10) for dispensing a fluid (80), comprising: a. a housing (20) having a height H and a central axis AA extending between side walls 43 parallel to a housing bottom floor (44) and disposed at the midpoint of the housing height H; wherein the housing includes a first housing wall (22), a second housing wall (42) opposite the first housing wall (22), a shaped inner frame (90) having a first inner frame side (92) and a shaped outer frame (24); wherein the outer frame (24) connects the first housing wall (22) with the second housing wall (42); b. wherein the housing contains a pump (26) configured for pumping the fluid (80), wherein the pump (26) is connected to a pump inlet conduit (28) and a pump outlet conduit (30); c. wherein the housing (20) contains a refill bay (70) defined by the shaped inner frame (90) and configured to receive a refill (60) comprising a refill reservoir (40) and a refill adapter (50) that is inserted into the refill bay (70) through the first inner frame side (92) at the rear of the dispenser along either the vector R or R wherein the vector R and the vector R.sup.1 are both in the same plane defined by the height H and the axis AA and wherein both vectors intersect the central axis AA on opposite sides at a point midway between the first housing wall (22) and the second housing wall (42); wherein the vector R intersects the central axis AA at an angle between 0 and 75 degrees and the vector R intersects the central axis AA at an angle between 0 and minus 75 degrees; and d. wherein the refill (60) includes an outlet interface (48) in fluid communication with the refill reservoir (40) and wherein the outlet interface (48) and a pump inlet conduit interface (53) are configured to sealingly engage with each other when the refill (60) is fully inserted into the refill bay (70), and wherein the refill is substantially surrounded by the outer frame, and wherein the refill (60) passes into the refill bay (70) on the opposite side of the dispenser (10) from where a dispenser outlet (12) is located, the dispenser outlet being located at the front of the dispenser.
2. The dispenser of claim 1 wherein the outer frame (24) and the inner frame (90) are spaced apart over an arc defined by at least a 120 degree angle of rotation around the central axis AA of a line P drawn perpendicular to the axis AA.
3. The dispenser of claim 1, wherein the angle is less than 10 degrees.
4. The dispenser according to claim 1 wherein the refill reservoir (40) is transparent or translucent.
5. The dispenser of according to claim 1 wherein the pump (26) has an entrainment mechanism which entrains air or gas into the fluid (80) prior to dispensing.
6. The dispenser according to claim 1 wherein the refill reservoir (40) is sealingly engaged via a liquid tight coupling (47) to the refill adapter (50) and the refill adapter 50 includes a refill interface (48) in fluid communication with the refill reservoir (40).
7. The dispenser according to claim 1 wherein the junction between the first housing wall (22) and the outer frame (24) and between the second housing wall (42) and the outer frame (24) comprise a smooth, three dimensional surface.
8. The dispenser according to claim 1 wherein the first housing wall (22) defines an open, transparent or translucent window (100) coinciding with at least a portion of the refill reservoir (40).
9. The dispenser according to claim 1 wherein the refill bay (70) is sized to receive the refill (60) in a pressing engagement with the inner frame (90).
10. The dispenser according to claim 1 wherein the refill bay (70) is sized to receive the refill assembly (60) in a pressing engagement via a plurality of protuberances (33) rigidly connected to the inside frame and extending into the refill bay.
11. The dispenser according to claim 1 wherein the refill bay (70) is further defined by a bulkhead (39) connected to the inner frame 90 opposite the first inner frame side (92).
12. A liquid dispenser kit comprising: a. A liquid dispenser according to claim 1; and b. a refill (60) containing a composition comprising: i. 1 to 60% by wt. of one or more lathering surfactant(s) selected from soap, synthetic anionic surfactant(s), amphoteric surfactant(s), nonionic surfactant(s), cationic surfactant(s) or a blend thereof; ii. 10 to 99% by wt. of water, and iii. 0.1 to 30% by wt. of one or more skin conditioning agent(s) selected from hydrophobic conditioning agent(s), hydrophilic conditioning agent(s) or a blend thereof.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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DETAILED DESCRIPTION OF THE INVENTION
(9) All publications and patent applications, patents, and other references mentioned herein are incorporated by reference in their entirety.
(10) Referring now to the drawings in which like figures represent like elements, in
(11) As depicted in
(12) In a preferred aspect, inner frame 90 depicted in
(13) Complementary shaped refill 60 is inserted into refill bay 70 along either vector R where vector R intersects central dispenser axis AA at dispenser midpoint M at angle or along vector R where vector R intersects central dispenser axis AA at dispenser midpoint M at angle as illustrated in
(14) Optionally, the dispenser 10 has a window 100 to allow a user to monitor the amount of fluid 80 remaining in refill 60.
(15) The window may be a simple aperture or include a transparent or translucent window preferably made of transparent or translucent plastic in whole or in part.
(16) In operation of the dispenser 10 illustrated in
(17) In one aspect of the invention is a liquid dispenser, including but not limited to:
(18) A liquid dispenser (10) for dispensing a fluid (80), including: a. a housing 20 having a height H and a central axis AA parallel to a housing bottom floor 44 and disposed at the midpoint of a housing height H; wherein the housing includes a first housing wall 22, a second housing wall 42 opposite the first housing wall 22, a shaped inner frame 90 having a first inner frame side 92 and a shaped outer frame 24; wherein the outer frame 24 connects the first housing wall 22 with the second housing wall 42; b. wherein the housing contains a pump 26 configured for pumping fluid (80), preferably in the range of 9 to 41 C. and 1 Atm., wherein the pump 26 is connected to a pump inlet conduit 28 and a pump outlet conduit 30; c. wherein housing 20 contains a refill bay 70 defined by shaped inner frame 90 and configured to receive a refill 60 that is inserted into refill bay 70 through first inner frame side 92 along either vector R or R which vectors are both in the same plane defined by height H and axis AA and wherein both vectors intersect central axis AA on opposite sides at a point midway between first housing wall 22 and second housing wall 42; wherein vector R intersects central axis AA at an angle between 0 and 75 degrees and vector R intersects central axis AA at an angle between 0 and minus 75 degrees; and d. wherein refill 60 includes outlet interface 48 in fluid communication with refill reservoir 40 and wherein the refill interface 48 and a pump inlet conduit interface 53 are configured to sealingly engage with each other when refill 60 is fully inserted into refill bay 70.
(19) Advantageously angle is between 0 and 70, 65, 60, 55, 50, 45, 40, 35, 30, 25, 20, 15, 10, 5, 2, 1, 0.5 or 0.1 degrees and angle is between 0 and minus 70, 65, 60, 55, 50, 45, 40, 35, 30, 25, 20, 15, 10, 5, 2, 1, 0.5 or 0.1 degrees.
(20) Advantageously the outer frame 24 and inner frame 90 are spaced apart over an arc defined by at least a 120 degree angle of rotation 3 around the central axis AA of a line P drawn perpendicular to axis AA. Preferably 3 is at least 150, 180, 210, 240, 270, 300, 330 or 360 degrees.
(21) Preferably refill 60 has a transparent or translucent refill reservoir 40. More preferably pump 26 has an entrainment mechanism which entrains air or gas into fluid 80. Most preferably refill reservoir 40 is sealingly engaged via a liquid tight coupling 47 to refill adapter 50 and refill adapter 50 includes refill interface 48 in fluid communication with refill reservoir 40, preferably the coupling comprises spout 49 and receptacle 51 or an equivalent liquid tight connection.
(22) Preferably the junction between wall 22 and outer frame 24 and between wall 42 and outer frame 24 comprise a smooth, three dimensional surface, preferably without noticeable boundaries or seams. Advantageously the first inner frame side 92 when viewed along central axis AA has a regular or irregular shape, more preferably wherein the first inner frame side shape is selected from a polygonal, circular, ovoidal, curved or curvilinear shape or a combination thereof.
(23) Preferably first housing wall 22 defines an open, transparent or translucent window 100 coinciding with at least a portion of refill reservoir 40, preferably with a vertical cross-section of refill reservoir 40.
(24) Advantageously refill 60 passes into refill bay 70 either on the side of the dispenser 10 where dispenser outlet 12 is located or on the opposite side of the dispenser 10 where dispenser outlet 12 is located. Preferably the refill bay 70 is sized to receive the refill 60 in pressing engagement with the inner frame 90, preferably refill 60 has a refill reservoir 40 whose volume is under 1 liter or 500 mls. More preferably refill bay 70 is sized to receive the refill assembly 60 in pressing engagement via a plurality of protuberances 33 rigidly connected to the inside frame and extending into the refill bay.
(25) Advantageously refill bay 70 is further defined by a bulkhead 39 connected to the inner frame 90 opposite the first inner frame side 92.
(26) In another aspect of the invention is a liquid dispenser kit including but not limited to:
(27) a. a liquid dispenser (10) for dispensing a fluid (80), including: i. housing 20 having a height H and a central axis AA parallel to a housing bottom floor 44 and disposed at the midpoint of a housing height H; wherein the housing includes a first housing wall 22, a second housing wall 42 opposite the first housing wall 22, a shaped inner frame 90 having a first inner frame side 92 and a shaped outer frame 24; wherein the outer frame 24 connects the first housing wall 22 with the second housing wall 42; ii. wherein the housing contains a pump 26 configured for pumping fluid (80), preferably in the range of 9 to 41 C. and 1 Atm., wherein the pump 26 is connected to a pump inlet conduit 28 and a pump outlet conduit 30; iii. wherein housing 20 contains a refill bay 70 defined by shaped inner frame 90 and configured to receive a refill 60 that is inserted into refill bay 70 through first inner frame side 92 along either vector R or R which vectors are both in the same plane defined by height H and axis AA and wherein both vectors intersect central axis AA on opposite sides at a point midway between first housing wall 22 and second housing wall 42; wherein vector R intersects central axis AA at an angle between 0 and 75 degrees and vector R intersects central axis AA at an angle between 0 and minus 75 degrees; and iv. wherein refill 60 includes outlet interface 48 in fluid communication with refill reservoir 40 and wherein the refill interface 48 and a pump inlet conduit interface 53 are configured to sealingly engage with each other when refill 60 is fully inserted into refill bay 70; and b. wherein refill 60 contains a composition including but not limited to: i. 1 to 60% by wt. of one or more lathering surfactant(s) selected from soap, synthetic anionic surfactant(s), amphoteric surfactant(s), nonionic surfactant(s), cationic surfactant(s) or a blend thereof; Preferably the lathering surfactants include a blend of soap(s) and synthetic anionic surfactant(s) in the concentration range of 5 to a maximum of 10, 15 and 20% by wt. Preferably the lathering surfactants include an amphoteric surfactant in the concentration range of 1 to a maximum of 5, 7, and 10% by wt. ii. 10 to 99% by wt. of water; and iii. optionally 0.1 to 30% by wt. of one or more skin conditioning agent(s) selected from hydrophobic conditioning(s), hydrophilic conditioning (s) or a bend thereof. Preferably hydrophilic conditioning agents in the total concentration range of 5 to 15 by wt. Preferably hydrophilic conditioning agents include polyols such as glycerin and propylene glycol. Preferably the hydrophobic conditioning agent(s) is/are less than 5, 4, 3, 2, 1, 0.5, 0.1, or 0.01% by wt. or may be absent.
Lathering Surfactant
(28) The inventive liquid dispenser kit contains a liquid cleansing composition with lathering surfactant(s). By a lathering surfactant is meant a surfactant, which when combined with water and mechanically agitated generates a foam or lather. Preferably, these lathering surfactants should be mild, which means that they must provide sufficient cleansing or detersive benefits but not overly dry the skin or hair, and yet meet the lathering criteria described above.
(29) A wide variety of lathering surfactants is useful herein and include those selected from anionic, nonionic, cationic, and amphoteric surfactants and mixtures thereof.
(30) Among the anionic lathering surfactants useful herein are the following non-limiting examples which include the classes of: (1) Alkyl benzene sulfonates in which the alkyl group contains from 9 to 15 carbon atoms, preferably 11 to 14 carbon atoms in straight chain or branched chain configuration. Especially preferred is a linear alkyl benzene sulfonate containing 12 carbon atoms in the alkyl chain. (2) Alkyl sulfates obtained by sulfating an alcohol having 8 to 22 carbon atoms, preferably 12 to 16 carbon atoms. The alkyl sulfates have the formula ROSO.sub.3-M.sup.+ where R is the C.sub.8-22 alkyl group and M is a mono- and/or divalent cation. (3) Paraffin sulfonates having 8 to 22 carbon atoms, preferably 12 to 16 carbon atoms, in the alkyl moiety. These surfactants are commercially available as Hostapur SAS from Hoechst Celanese. (4) Olefin sulfonates having 8 to 22 carbon atoms, preferably 12 to 16 carbon atoms. Most preferred is sodium C.sub.14-C.sub.16 olefin sulfonate, available as Bioterge AS 40 (5) Alkyl ether sulfates derived from an alcohol having 8 to 22 carbon atoms, preferably 12 to 16 carbon atoms, ethoxylated with less than 30, preferably less than 12, moles of ethylene oxide. Most preferred is sodium lauryl ether sulfate formed from 1 or 2 moles average ethoxylation, commercially available as e.g. Standopol ES-2. (6) Alkyl glyceryl ether sulfonates having 8 to 22 carbon atoms, preferably 12 to 16 carbon atoms, in the alkyl moiety. (7) Fatty acid ester sulfonates of the formula: R.sup.1CH(SO.sub.3-M+)CO.sub.2R.sup.2 where R.sup.1 is straight or branched alkyl from C.sub.8- to C.sub.18, preferably C.sub.12 to C.sub.16, an R.sup.2 is straight or branched alkyl from C.sub.1 to C.sub.6, preferably primarily C.sub.1, and M+ represents a mono- or divalent cation. (8) Secondary alcohol sulfates having 6 to 18, preferably 8 to 16 carbon atoms. (9) Fatty acyl isethionates having from 10 to 22 carbon atoms, with sodium cocoyl isethionate being preferred. (10) Dialkyl sulfosuccinates wherein the alkyl groups range from 3 to 20 carbon atoms each. (11) C10 to C14 Acyl glycinates. Most preferred is sodium or potassium cocoyl glycinate. (12) Alkanoyl sarcosinates corresponding to the formula RCON(CH.sub.3)CH.sub.2CH.sub.2CO.sub.2M wherein R is alkyl or alkenyl of 10 to 20 carbon atoms and M is a water-soluble cation such as ammonium, sodium, potassium and trialkanolammonium. Most preferred is sodium lauroyl sarcosinate. (13) Alkyl lactylates wherein the alkyl groups range from 8 to 18 carbon atoms, with sodium lauryl lactylate sold as Pationic 138 C available from the Patterson Chemical Company as the most preferred. (14) Taurates having from 8 to 16 carbon atoms, with cocoyl methyl taurate being preferred. (15) Fatty acid soaps consisting of soluble soaps. Soluble soap is defined as a soap or soap blend having a Krafft point less than or equal to 40 C. The soluble soap(s) can be selected from the chain length of C6-C14 saturated fatty acid soap(s) and C16-C18 unsaturated and polyunsaturated fatty acid soap(s) or a combination of these fatty acid soaps. These soluble soaps can be derived from coco fatty acid, Babasu fatty acid, palm kernel fatty acid and any other source of unsaturated fatty acid including tallow and vegetable oils and their mixtures.
(31) Nonionic lathering surfactants suitable for the present invention include C.sub.10-C.sub.20 fatty alcohol or acid hydrophobes condensed with from 2 to 100 moles of ethylene oxide or propylene oxide per mole of hydrophobe; C.sub.2-C.sub.10 alkyl phenols condensed with from 2 to 20 moles of alkylene oxides; mono- and di-fatty acid esters of ethylene glycol such as ethylene glycol distearate; fatty acid monoglycerides; sorbitan mono- and di-C.sub.8-C.sub.20 fatty acids; and polyoxyethylene sorbitan available as Polysorbate 80 and Tween 80 as well as combinations of any of the above surfactants.
(32) Other useful nonionic surfactants include alkyl polyglycosides, saccharide fatty amides (e.g. methyl gluconamides) as well as long chain tertiary amine oxides. Examples of the latter category are: dimethylododecylamine oxide, oleyldi(2-hydroxyethyl)amine oxide, dimethyloctylamine oxide, dimethyldecylamine oxide, dimethyltetradecylamine oxide, di(20-hydroxyethyl)tetradecylamine oxide, 3-didodecyoxy-2-hydroxypropyldi(3-hydroxypropyl)amine oxide, and dimethylhexadecylamine oxide.
(33) Suitable amphoteric or zwitterionic lathering surfactants for use in the present compositions include those broadly described as derivatives of aliphatic quaternary ammonium, phosphonium, and sulfonium compounds, wherein which the aliphatic radicals can be straight chain or branched, and wherein one of the aliphatic substituents contains 8 to 30 carbon atoms and another substituent contains an anionic water-solubilizing group, such as carboxy, sulfonate, sulfate, phosphate, phosphonate, and the like. Classes of zwitterionics include alkylamino sulfonates, alkyl betaines and alkylamido betaines, such as stearamidopropyldimethylamine, diethylaminoethylstearamide, dimethylstearamine, dimethylsoyamine, soyamine, myristylamine, tridecylamine, ethylstearylamine, N-tallowpropane diamine, ethoxylated (5 moles ethylene oxide) stearylamine, dihydroxy ethyl stearylamine, arachidylbehenylamine, and the like. Some suitable betaine surfactants include but are not limited to alkyl betaines, alkyl amidopropyl betaines, alkyl sulphobetaines, alkyl glycinates, alkyl carboxyglycinates, alkyl amphopropionates, alkyl amidopropyl hydroxysultaines, acyl taurates, and acyl glutamates, wherein the alkyl and acyl groups have from 8 to 18 carbon atoms. Non-limiting examples of preferred amphoteric surfactants include cocamidopropyl betaine, sodium cocoamphoacetate, disodium cocoamphodiacetate, cocamidopropyl hydroxysultaine, and sodium cocoamphopropionate, which are particularly suitable as mild-type cleansers for skin and hair.
(34) Hydrophilic Conditioning Agents
(35) Skin hydrophilic conditioning agents also known as hydrophilic emollients may be advantageously used in the present invention as benefit agents. The emollient composition may be a single agent component or it may be a mixture of two or more compounds one or all of which may have a conditioning aspect. In addition, the conditioning agent itself may act as a carrier for other components one may wish to add to the personal care implement.
(36) Hydrophilic emollients are preferably present in a concentration range of 2 to 20% by weight of the cleansing composition contained in the refill. The term emollient is defined as a substance which softens or improves the elasticity, appearance, and youthfulness of the skin (stratum corneum) by either increasing its water content, adding, or replacing lipids and other skin nutrients; or both, and keeps it soft by retarding the decrease of its water content.
(37) Useful examples of hydrophillic emollients (also known as humectants) include polyhydric alcohols, e.g. glycerine and propylene glycol, and the like; polyols such as the polyethylene glycols listed below and the like; saccharide(s) and/or polysaccharide(s) such as sucrose, sorbitol; and urea derivatives such as hydroxyethyl urea and the like may be advantageously used.
(38) Other useful examples of hydrophillic emollients include any of the following or blends thereof: alcaligenes polysaccharides; algae extract; aloe barbadensis leaf extract; Bacillus/rice bran extract/soybean extract ferment filtrate; black strap powder; diglycereth-7 malate; diglycerin; diglycol guanidine succinate; erythritol; fructose; glucose; glucoronolactone; glycereth-7 glycolate; glycerin; glyceryl dimaltodextrin; glycol; hesperetin laurate; 1,2,6-hexanetriol; honey; hydrogenated honey; hydrogenated starch hydrolysate; hydrolyzed wheat protein/PEG-20 acetate copolymer; hydroxypropyltrimonium hyaluronate; inositol; lactic acid; lacitol; maltitol; maltose; mannitol; mannose; methoxy PEG-7; methoxy PEG-10; methoxy PEG-16; methoxy PEG-25; methoxy PEG-40; methoxy PEG-100; PEG 4; PEG-6; PEG-7; PEG-8; PEG-9; PEG-10; PEG-12; PEG-14; PEG-16; PEG-18; PEG-20; PEG-32; PEG-40; PEG-45; PEG-55; PEG-60; PEG-75; PEG-90; PEG-75; PEG-90; PEG-100; PEG-135; PEG-150; PEG-180; PEG-200; PEG-220; PEG-240; PEG-800; PEG-15 butanediol; PEG-3-methyl ether; PEG-4 methyl ether; PEG-5 pentaerythrityl ether; polyglyceryl sorbitol; potassium dextrin octenylsuccinate; potassium PCA; PPG-6 sorbeth-245; PPG-6 sorbeth-500; propylene glycol; Rosa canina seed extract; sodium acetylated hyaluronate; sodium dextrin octenylsuccinate; sodium glucuronate; sodium PCA; sorbeth-6; sorbeth-20; sorbeth-30; sorbeth-40; sorbitol; sorbityl silanediol; sucrose; TEA dextrin octenylsuccinate; trehalose; triglycereth-7 citrate; trioxaundecanedioic acid; tripropylene glycol; urea; urea-d-glucuronic acid; xylitol; xylose and the like.
(39) Hydrophobic Conditioning Agents
(40) Hydrophobic conditioning agents are defined herein as either finely dispersed or emulsified oils and/or agents with very low water solubility as defined below and are optionally present at total levels of less than 20, 10, 5, 3, 2, 1, 0.5, 0.1 or 0.01% by wt. in the composition contained in the inventive kit and may be absent from the composition. These hydrophobic conditioning agents include but are not limited to the following: (a) silicone oils and modifications thereof such as linear and cyclic polydimethylsiloxanes; amino, alkyl, alkylaryl, and aryl silicone oils; (b) fats and oils including natural fats and oils (triglycerides) such as jojoba, soybean, sunflower, rice bran, avocado, almond, olive, sesame, persic, castor, coconut, mink oils; cacao fat; beef tallow, lard; hardened oils obtained by hydrogenating the aforementioned oils; and synthetic mono, di and triglycerides such as myristic acid glyceride and 2-ethylhexanoic acid glyceride; (c) waxes such as carnauba, spermaceti, beeswax, lanolin, and derivatives thereof; (d) hydrophobic plant extracts; (e) hydrocarbons such as petrolatum, polybutene, liquid paraffins, microcrystalline wax, ceresin, squalene, pristan and mineral oil; (f) higher alcohols such as lauryl, cetyl, stearyl, oleyl, behenyl, cholesterol and 2-hexydecanol alcohol; (g) esters such as cetyl octanoate, myristyl lactate, cetyl lactate, isopropyl myristate, myristyl myristate, isopropyl palmitate, isopropyl adipate, butyl stearate, decyl oleate, cholesterol isostearate, glycerol monostearate, glycerol distearate, glycerol tristearate, alkyl lactate, alkyl citrate and alkyl tartrate; (h) essential oils and extracts thereof such as mentha, jasmine, camphor, white cedar, bitter orange peel, ryu, turpentine, cinnamon, bergamot, citrus unshiu, calamus, pine, lavender, bay, clove, hiba, eucalyptus, lemon, starflower, thyme, peppermint, rose, sage, sesame, ginger, basil, juniper, lemon grass, rosemary, rosewood, avocado, grape, grapeseed, myrrh, cucumber, watercress, calendula, elder flower, geranium, linden blossom, amaranth, seaweed, ginko, ginseng, carrot, guarana, tea tree, jojoba, comfrey, oatmeal, cocoa, neroli, vanilla, green tea, penny royal, aloe vera, menthol, cineole, eugenol, citral, citronelle, borneol, linalool, geraniol, evening primrose, camphor, thymol, spirantol, penene, limonene and terpenoid oils; (i) mixtures of any of the foregoing components, and the like.
(41) Preferably hydrophobic conditioning agents have a very low solubility in water at 20 C. Preferably their water solubility is less than 0.5, 0.1, 0.05 or 0.01% by wt.
(42) The foregoing description illustrates selected aspects of the present invention. In light thereof variations and modifications will be suggested to one skilled in the art, all of which are within the scope and spirit of this invention.