Glass roll and method of processing glass roll
10562727 ยท 2020-02-18
Assignee
Inventors
- Yasuo Teranishi (Shiga, JP)
- Kaoru Mitsugi (Shiga, JP)
- Yoshinori Hasegawa (Shiga, JP)
- Michiharu Eta (Shiga, JP)
Cpc classification
International classification
B32B17/06
PERFORMING OPERATIONS; TRANSPORTING
Abstract
A roll-to-roll apparatus reliably reduces breakage of a glass film even in a case of sequentially performing predetermined processing on the glass film. Provided is a glass roll (1) formed by winding a glass film (2) into a roll, in which a resin film (4) is attached onto the glass film (2), and at least a part of the resin film (4) is arranged on a front side of an unwinding direction relative to a leading end portion in the unwinding direction of the glass film (2).
Claims
1. A processing method of sequentially performing predetermined processing by a roll-to-roll apparatus on a glass roll including a glass film wound into a roll, the processing method comprising: attaching a resin film onto the glass film such that at least a part of the resin film is in front of a leading end portion of the glass film relative to an unwinding direction of the glass film; and guiding the glass film into the roll-to-roll apparatus while the resin film is in the lead; wherein a length of the part of the resin film in front of the leading end portion of the glass film relative to the unwinding direction is equal to or larger than an entire length of a conveyance path for the glass film in the roll-to-roll apparatus.
2. The processing method according to claim 1, wherein at least a part of the resin film is arranged also on a rear side of the unwinding direction relative to a trailing end portion in the unwinding direction of the glass film.
3. The processing method according to claim 2, wherein the part of the resin film in front of the leading end portion is a first part, wherein a length of a second part the resin film behind the trailing end portion of the glass film relative to the unwinding direction is equal to or larger than the entire length of the conveyance path for the glass film in the roll-to-roll apparatus.
4. The processing method according to claim 1, wherein the part of the resin film in front of the leading end portion is a first part, wherein at least a second part of the resin film is behind a trailing end portion of the glass film in the unwinding direction of the glass film.
5. A processing method of sequentially performing predetermined processing by a roll-to-roll apparatus on a glass roll including a glass film wound into a roll, the processing method comprising: attaching a resin film onto the glass film such that at least a part of the resin film is in front of a leading end portion of the glass film relative to an unwinding direction of the glass film; and guiding the glass film into the roll-to-roll apparatus while the resin film is in the lead; wherein the glass film is conveyed by conveying rollers through the roll-to-roll apparatus during the processing in a non-linear manner with a plurality of directional changes such that the conveying rollers contact both surfaces of the glass film.
Description
BRIEF DESCRIPTION OF DRAWINGS
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DESCRIPTION OF EMBODIMENTS
(18) In the following, embodiments of the present invention are described with reference to the attached drawings.
(19)
(20) The glass film 2 is formed by an overflow downdraw method to have a thickness of from 1 m to 200 m (preferably, 10 m to 100 m). The reason why the glass film is set to have such a thickness is because, with the thickness within the above-mentioned numerical range, appropriate flexibility and strength can be imparted to the glass film 2 and no trouble arises at the time of winding. In other words, when the thickness of the glass film 2 is less than 1 m, handling of the glass film is troublesome because of lack of strength. When the thickness of the glass film 2 exceeds 200 m, satisfactory flexibility is not obtained, which leads to a problem in that a winding radius is extremely and inevitably increased.
(21) In this embodiment, a width of the glass film 2 is 12.5 mm or more, in particular, preferably 100 mm or more, more preferably 300 mm or more, and still more preferably 500 mm or more. Note that, the glass film 2 is used for a wide variety of devices including a small-screen display such as a mobile phone with a small size and a large-screen display such as a television set with a large size, and hence it is preferred that the width of the glass film 2 be finally selected as needed depending on a size of a substrate of a device to be used.
(22) As a glass composition of the glass film 2, there can be used various glass compositions of silicate glass and the like, such as silica glass and borosilicate glass. However, if is preferred to use non-alkali glass. The reason is as follows. When the glass film 2 contains an alkali component, a phenomenon, so-called white weathering, occurs so that the glass film is structurally rough. When the glass film 2 is curved, there is a risk in that the glass film is prone to break from a portion that is weathered over time. Note that, herein, the non-alkali glass includes glass that does not substantially contain an alkali component, specifically, glass containing an alkali, metal oxide of 1000 ppm or less (preferably, of 500 ppm or less, and more preferably, of 300 ppm or less).
(23) Further, in view of ensuring strength of the glass film 2, it is preferred that at least each end surface in a width direction of the glass film 2 include a cut surface which is cut by laser splitting. With this configuration, the each end surface in the width direction of the glass film 2 has a cross-section with high strength free from defects causing breakage, such as micro cracks. Specifically, when utilizing the laser splitting, without being subjected to polishing or the like after the cutting, the each end surface in the width direction of the glass film 2 is allowed to have an arithmetic average roughness Ra (compliant to JIS B0601:2001) of 0.1 m or less (preferably, 0.05 m or less). Here, the laser splitting refers to a method of cutting the glass film 2 in such a manner that an initial crack is caused to develop by utilizing thermal stress that is generated through expansion due to a heating action of laser and through contraction due to a cooling action of a refrigerant.
(24) A thickness and a width of the resin film 4 are not particularly limited. However, considering that the resin film is caused to pass through in the same roll-to-roll apparatus as the glass film 2, it is preferred that the resin film have substantially the same thickness and width as those of the glass film 2. Specifically, it is preferred that the thickness of the resin film 4 be from 1 to 200 m, and the width of the resin film 4 be 0.5 to 2 times (preferably 0.9 to 1.5 times) larger than the width of the glass film 2. Note that, the resin film 4 needs to have strength high enough to drag the glass film 2, and hence it is preferred to finally determine the thickness and the width in consideration of a material and the like of the resin film 4.
(25) As the resin film 4, there cars be used, for example, an ionomer film, a polyethylene film, a polypropylene film, a polyvinyl chloride film, a polyvinylidene chloride film, a polyvinyl alcohol film, a polyester film, a polycarbonate film, a polystyrene film, a polyacrylonitrile film, an ethylene vinyl acetate copolymer film, an ethylene-vinyl alcohol copolymer film, an ethylene-methacrylate copolymer film, a nylon (registered trademark) film (polyamide film), a polyimide film, and an organic resin film (synthetic resin film) such as cellophane. In addition, in view of ensuring both cushioning performance and strength, it is preferred that, as the resin, film 4, a foamed resin sheet such as a polyethylene foam sheet be used.
(26) Next, the roll-to-roll apparatus for performing predetermined processing on the glass roll 1 configured as described above, and the procedure for processing the glass film 2 by the apparatus are briefly described.
(27)
(28) Specifically, after the glass roll 1 is set in the unwinding section 11, the predetermined processing is performed successively while conveying rollers 13a to 13n sequentially convey, to a downstream side, the glass film 2 which is unwound from the glass roll 1 set in the unwinding section 11, and then the glass film 2 subjected to the predetermined processing is sequentially wound in the winding section 12. In this way, the glass roll 1 is produced again.
(29) In this embodiment, on the conveyance path between the unwinding section 11 and the winding section 12, in order from an upstream side of the conveyance path, there are arranged a cleaning chamber 14 which pools cleaning liquid (for example, water), a drying chamber 15 in which the glass film 2 dipped into the cleaning liquid of the cleaning chamber 14 is dried with hot air or the like, and a static elimination chamber 16 in which static electricity accumulated on the glass film 2 is eliminated. In order from the upstream side, a cleaning process, a drying process, and a static elimination process are performed on the glass film 2. Note that, in
(30) Further, as described above, in order for the roll-to-roll apparatus to perform the predetermined processing such as cleaning on the glass film 2, first, it is necessary to guide the glass film 2 unwound from the glass roll 1 set in the unwinding section 11 into the winding section 12, and to stretch the glass film 2 between the unwinding section 11 and the winding section 12. At this time, when the glass film 2 is guided into an inside of the roll-to-roll apparatus while the leading end portion in the unwinding direction of the glass film 2 is in the lead, the leading end portion of the glass film 2 is excessively and repeatedly brought into contact with/impact on apparatus components of the roll-to-roll apparatus, and hence the glass film 2 may break. In view of this, as illustrated in
(31) That is, the resin film 4 has higher fracture toughness in comparison with the glass film 2. Thus, even when the resin film is brought into contact with the apparatus components to have small flaws, the resin film does not break due to the small flaws. Therefore, when the glass film 2 is guided into the inside of the roll-to-roll apparatus while the resin film 4 is in the lead, it is possible to reliably reduce such a situation that the glass film 2 is flawed due to excessive contact with the apparatus components.
(32) Here, in view of preventing breakage of the glass film 2, it is preferred that a length of the resin film 4 (indicated by D1 of
(33) Note that, in the above-mentioned embodiment, description is made of the ease where the glass film 2 is wound around the roll core 3 into a roll, to thereby manufacture the glass roll 1. However, in view of protecting a surface of the glass film 2, it is preferred that, under a state in which the cushion sheet (not shown) is superposed on any one of surfaces of the glass film 2, the glass film 2 and the cushion sheet be wound around the roll core 3 together. In this case, it is preferred that the roll-to-roll apparatus have both such a configuration as to separate the cushion sheet from the glass film 2 before processing, and such a configuration as to superpose the cushion sheet on the glass film 2 and wind the cushion sheet and the glass film again after the processing (for example, see a winding section 19 and an unwinding section 20 for the resin film 4 illustrated in
(34) Further, in the above-mentioned embodiment, description is made of the case where the glass film 2 and the resin film 4 are coupled to each other by attaching the adhesive tapes 5 across the films. However, the glass film 2 and the resin film 4 may be coupled to each other by bonding the films with an adhesive. In this case, it is preferred that, as the adhesive, one that can separate a bonded portion between the glass film 2 and the resin film 4 again be used.
(35) Further, the glass film 2 and the resin film 4 may be coupled to each other by stretching the adhesive tapes 5 across the end portion of the glass film 2 and the end portion of the resin film 4 under a state in which both of the end portions are abutted on each other without being superposed on each other or under a state in which both of the end portions are opposed to each other with a gap.
(36)
(37) The roll-to-roll apparatus needs to keep constant tension between the unwinding section 11 and the winding section 12. When the resin film 4 is coupled on the trailing end portion in the unwinding direction of the glass film 2, the constant tension can act on the glass film 2 through the resin film 4 even after the trailing end portion of the glass film 2 is sent out of the unwinding section 11. Therefore, even after the trailing end portion of the glass film 2 is sent out of the unwinding section 11, it is possible to perform the predetermined processing, such as the above-mentioned cleaning, on the glass film 2. As a result, an unprocessed region included in the glass film 2 is reduced, and hence it is possible to achieve effective use of the glass film 2.
(38) Note that, in view of achieving effective use of the glass film 2, it is preferred that a length D2 of the resin film 4, which corresponds to a part on the rear side of the unwinding direction relative to the trailing end portion in the unwinding direction of the glass film 2, be equal to or larger than the entire length of the conveyance path provided in the inside of the roll-to-roll apparatus. With this configuration, it is possible to stably perform the processing such as the cleaning up to the trailing end portion in the unwinding direction of the glass film 2, and hence it is possible to more reliably achieve effective use of the glass film 2. Note that, at this time, it is more preferred that the length D1 of the resin film 4, which corresponds to the part on the front side of the unwinding direction relative to the leading end portion in the unwinding direction of the glass film 2, be equal to or larger than the entire length of the conveyance path provided in the inside of the roll-to-roll apparatus.
(39)
(40) In a case where a widthwise center line L1 of the glass film 2 and a widthwise center line L2 of the resin film 4 are not present on the same straight line, the roll-to-roll apparatus forcibly corrects displacement (inclination) of the glass film 2, and hence bending stress and torsional stress act on the portion of the glass film 2 coupled to the resin film 4. Consequently, there may arise a problem in that the glass film 2 breaks.
(41) In view of this, as illustrated in
(42) Specifically, as illustrated in
(43) Note that, in
(44) Further, in a case where the resin film 4 is coupled also to the trailing end portion in the unwinding direction of the glass film 2, it is preferred that the glass film 2 and the resin film 4 be coupled to each other with the elastic adhesive tapes 6 at both of the leading end portion and the trailing end portion in the unwinding direction of the glass film 2.
(45) Note that, examples of the elastic adhesive tape 6 include a tape that has a base member formed of a polyester film. Further, the elastic member that couples the glass film 2 and the resin film 4 to each other is not limited to the elastic adhesive tape 6, but may be an elastic adhesive.
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(47) Specifically, a widthwise center of the elastic adhesive tape 6 conforms to the widthwise center line L1 of the glass film 2 and the widthwise center line L2 of the resin film 4. Further, a width of the elastic adhesive tape 6 is smaller than widths of the glass film 2 and the resin film, and an intersection between the widthwise center line L1 of the glass film 2 and the widthwise center line L2 of the resin film 4 is included in a region where the elastic adhesive tape 6 is attached.
(48) With this configuration, the elastic adhesive tape 6 couples a region including the widthwise center line L1 of the glass film 2 to a region including the widthwise center line L2 of the resin film 4, and hence, even if an area of the coupled portion with the elastic adhesive tape 6 is reduced, it is possible to couple the films to each other in stable postures. Accordingly, owing to a reduction in size of the coupled portion, the stress can be reduced as much as possible, which acts on the glass film 2 by the elastic adhesive tape 6 absorbs the displacement between the widthwise center line L1 of the glass film 2 and the widthwise center line L2 of the resin film 4. Therefore, this is effective also in view of preventing breakage of the glass film 2. Further, the elastic adhesive tape 6 is positioned on the widthwise center lines of the glass film 2 and the resin film 4, and hence it is possible to suppress a deformation amount of the elastic adhesive tape 6, which is necessary to absorb the displacement between the widthwise center line L1 of the glass film 2 and the widthwise center line L2 of the resin film 4.
(49) Note that, in
(50)
(51) With this configuration, while protecting one surface of the glass film 2 with the resin film 4, the roll-to-roll apparatus can perform the predetermined processing on the other surface of the glass film 2.
(52) In this case, it is preferred that the glass film 2 be peelably bonded onto the resin film 4. In this case, the glass film 2 is attached onto the resin film 4, and hence, even if the glass film 2 breaks, etc., it is possible to prevent such a situation that glass fragments are scattered around. Further, such a situation is less likely to arise that the resin film 4 is cut halfway through the roll-to-roll apparatus due to breakage. Thus, even if such a situation arises that the glass film 2 is cut halfway through the roll-to-roll apparatus due to breakage, the constant tension can act on the glass film 2. Therefore, it is possible to prevent halfway stop of a roll-to-roll step.
(53) Further, an effective surface of the glass film 2, on which an electrode or the like is formed, needs to avoid direct contact with another member as much as possible, and hence it is preferred that the resin film 4 be attached on a surface opposite to the effective surface of the glass film 2.
(54)
(55) With this configuration, even the plurality of glass films 2 with short lengths, which are previously cut into fixed lengths, or the plurality of glass films 2 with short lengths, which are cut due to a defect and the like at a stage of not having predetermined lengths, can be packaged in a state of the glass roll 1. Further, by being packaged in the state of the glass roll 1, even the glass films 2 with short lengths can be subjected to the predetermined processing using a roll-to-roll method.
(56) Note that, in this case, sizes (mainly, lengths in a conveying direction) of the glass films 2 to be attached on one resin film 4 are not particularly limited. The glass films 2 may have different sizes.
(57)
(58) With this configuration, it is possible to protect the entire front and back surfaces of the glass film 2 with the resin films 4. Further, just before performing the predetermined processing by the roll-to-roll apparatus, by peeling off the resin film 4 attached on a surface that needs to be subjected to the predetermined processing such as the cleaning, it is possible to carry out the predetermined processing without any problem.
(59) Specifically, the following can be given as an example of the roll-to-roll apparatus used in this case. In addition to the configuration of the roll-to-roll apparatus illustrated in
(60) Note that, in a case of covering the entire front and back surfaces of the glass film 2 with the resin films 4 as described above, it is preferred that the resin film 4 on the effective surface side of the glass film 2 be not jointed to the glass film 2 through bonding or the like. This is because, when the resin film 4 is jointed on the effective surface side through bonding or the like, there is a fear in that foreign matters such as bonding components remain on the effective surface after the resin film 4 is peeled off from the effective surface of the glass film 2. That is, it is preferred that the resin film 4 on the effective surface side of the glass film 2 be jointed through bonding or the like only to the resin film 4 opposite to the effective surface of the glass film 2.
(61) Further, as illustrated in
(62) Note that, the present invention is not limited to the above-mentioned embodiments, and can be implemented in various modes. For example, in each of the above-mentioned embodiments, using the roll-to-roll apparatus illustrated in
(63) Further, as illustrated in
(64) Further, in the above-mentioned embodiments, description is made of the case where the glass film 2 is formed by the overflow downdraw method. However, the glass film 2 may be formed by a downdraw method such as a slot downdraw method or a redraw method. When using the downdraw method in this way, unlike a case of forming the glass film 2 by a float method, the surface of the glass film 2 is not contaminated by tin or the like. Thus, there is an advantage that the glass film 2 can be used under a state in which the surface of the glass film 2 remains unpolished. The glass roll 1 is targeted for the glass film 2 having a small thickness, and hence it is also very advantageous to use the glass film with a surface remaining unpolished in terms of reducing a risk of breakage of the glass film 2. Note that, in view of ensuring smoothness of the surface of the glass film 2, it is preferred to adopt the overflow downdraw method or the redraw method among the downdraw method.
INDUSTRIAL APPLICABILITY
(65) The present invention can be preferably used to a glass substrate used for a flat panel display, such as a liquid crystal display or an OLED display, and for a device such as a solar cell, and used to cover glass for an OLED lighting.
REFERENCE SIGNS LIST
(66) 1 glass roll 2 glass film 3 roll core 4 resin film 5 adhesive tape 6 elastic adhesive tape (elastic member) 11 unwinding section 12 winding section 14 cleaning chamber 15 drying chamber 16 static elimination chamber