Micro-encapsulated, improved vapor corrosion inhibitor

Abstract

The current invention relates to a micro-encapsulated, volatile vapor corrosion inhibitor (VCI), and method for the use of same. More particularly, it relates to a fluid composition, and microencapsulation of the fluid composition, that inhibits corrosion and tarnishing and that may be relatively non-toxic. The VCI is intended to be employed in varying concentrations depending on the intended application and deployed via microcapsules. The microcapsules may be adapted to release the VCI over time, or all at once. To effect this, the microcapsules may be adapted to be breached at varying times or at the same time. By adapting the microcapsules, or the method of breaching the microcapsules, the rate at which the VCI is released may be controlled.

Claims

1. A volatile vapor corrosion inhibitor comprising: a solution containing a volatile compound derived from a plant or plants within the Fabaceae plant family, and a corrosion inhibitor; and a microcapsule having a circumferential wall containing said solution.

2. The volatile vapor corrosion inhibitor of claim 1, further comprising a means for breaching a wall of said microcapsule.

3. The volatile vapor corrosion inhibitor of claim 1, further comprising a first surface, and wherein said microcapsule is attached to said first surface.

4. The volatile vapor corrosion inhibitor of claim 1, further comprising a plurality of said microcapsules, and wherein said microcapsules are adapted to be breached at varying times.

5. The volatile vapor corrosion inhibitor of claim 1, further comprising: a first surface, wherein said microcapsule is attached to said first surface; a second surface, said second surface attached to said first surface with an adhesive such that said microcapsule is held between said first and said second surface; and wherein when said second surface is pulled away from said first surface, the wall of said microcapsule is breached and said solution is exposed to an environment.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) FIG. 1 is a perspective view of an enclosed environment illustrating the use of the present invention.

(2) FIGS. 2a-2c are perspective views of various types of microcapsules.

(3) FIGS. 3a and 3b are perspective views of one embodiment of a deployment method for the VCI filled microcapsules.

(4) FIG. 4 is a side view of one embodiment of a deployment method for the VCI filled microcapsules.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT

(5) Referring to the figures, FIG. 1 illustrates how the improved VCI 10 inhibits corrosion. The improved VCI 10 uses a volatile compound, or carrier, derived from a plant or plants within the Amaryllidaceae plant family to cause vaporization. Volatility is due generally to phenols in the compound. Natural phenols such as found in the Amaryllidaceae plant family, can chemically interact with many other substances in the form of stacking. Stacking refers to attractive, non-covalent interactions between aromatic rings. Thus, as the compound vaporizes, it can interact with, and take other molecules with anti-corrosive properties. These anti-corrosive properties are in the form of an ionic bond formed with oxygen molecules. As oxygen molecules are thus engaged, they are not available to cause oxidation, or corrosion of the metallic object. An emitting substrate 20, which is loaded with the improved VCI 10 is placed in a container 100. As used herein, loaded is intended to mean that some amount of the improved VCI 10 is contained on or in the emitting substrate 20 in the microcapsules. Anti-corrosive ions (not shown) of the improved VCI 10 are carried into the gaseous phase with the carrier as a vapor. This vapor will come to an equilibrium that fills the interior 102 of the container 100. It is anticipated that varying sizes of emitting substrates 20 and amounts of improved VCI 10 will be used in conjunction with varying volumes of container 100 interiors 102. The vapor is intended to fill the interior 102 and coat the metal surfaces of articles 104 in the interior 102 to inhibit corrosion and oxidation. The improved VCI 10 inhibits corrosion of the surfaces 104, and/or blend with moisture and oxygen in the interior 102 to neutralize the primary components (i.e., moisture and oxygen) that cause corrosion.

(6) The emitting substrate 20 inside a container 100 that has a hollow interior space 102. An amount of VCI 10 in microcapsules are loaded on the emitting substrate 20. Over time, the improved VCI 10 vaporizes emitting improved VCI 10 ions (not shown) into the interior 102 of the container 100. These ions (not shown) come to an equilibrium filling (if there is sufficient amount of improved VCI 10 loaded on the emitting substrate 20) the interior 102. The ions (not shown) come in contact with a metallic object 104 in the interior 102. A layer of the ions (not shown) coats the metallic object 104 which inhibits corrosion of the metallic object 104.

(7) Dissolved, or vaporized, ions (not shown) from the improved VCI 10 in the emitting substrate 20 enter into a gaseous phase. Some of these ions (not shown) bond with the object 104, and form an ionic layer on the object 104. This layer on the metallic object 104 of the improved VCI 10 acts as an anti-corrosive.

(8) It is anticipated that the interior 102 may not be sealed from the outside environment. This may occur if the container 100 is temporarily opened, or if the container has apertures or is otherwise permeable to the outside environment. In these cases, objects 104 remaining in the container 100 after the container 100 is opened will be protected from corrosion if sufficient improved VCI 10 remains on the emitting substrate 20 such the corrosion inhibiting ion vapor again develops in the container 100 after it is closed. In the instance in which a container 100 has a more permanent aperture, then improved VCI 10 ions (not shown) will continually be dispersed into the atmosphere and lost to the outside environment. The improved VCI 10 will continue vaporizing from the emitting substrate 20, so ions (not shown) will continue to protect the object 104 from oxidation until to many ions (not shown) are lost to the outside environment.

(9) FIGS. 2a-2c illustrate a few embodiments of microcapsules. Each has a circumferential wall. FIG. 2a illustrates a simple, single walled spherical microcapsule. It has a first wall 40 that surrounds the VCI filled core 30. FIG. 2b illustrates a multiwalled microcapsule. It has a first wall 40, and a second wall 42 that surround the VCI filled core 30. FIG. 2c illustrates an irregularly shaped microcapsule. As with the spherically shaped microcapsules, it has a first wall 40 that surrounds the VCI filled core 30. It is anticipated that the microcapsules would be manufactured so as to allow for deployment of the VCI for a given application and that the present invention is not limited by the shape, method of manufacture, number of walls, nor material of the walls of the microcapsules.

(10) FIGS. 3a-3b illustrate a means for deploying the VCI filled microcapsules 60. In this first embodiment, used as an example herein, it is anticipated that the emitting substrate 20 will be constructed from either a single folded piece of paper (as shown in FIG. 3a), or two pieces of paper (as shown in FIG. 3b). Effectively, these are the same means. If a single folded piece of paper is used then the first fold 62 has a first surface 64 and the second fold 66 has a second surface 68. If two pieces of paper are used, then the first paper 70 has the first surface 64 and a second paper 72 has the second surface 68. In a first embodiment of use, microcapsules 60 containing either a standard VCI or the improved VCI are adhered to the first surface 64. The second surface 68 is attached to the first surface, sandwiching the VCI filled microcapsules, using an adhesive 74.

(11) FIG. 4 illustrates when the second surface 68 is attached to the first surface 64 with an adhesive 74, the VCI filled microcapsules 60 are sandwiched between the surfaces and generally fixed in place. When the first 64 and second 68 surfaces are pulled apart, the tearing action breaches the microcapsule walls 40 exposing the VCI, or improved VCI 10, to the environment. As the VCI, or improved VCI 10, vaporize, ions (not shown) are released. Presumably, if the user has placed the emitting substrate 20 in an enclosed environment 102, then the VCL ions (not shown) attempt to reach an equilibrium in the container. The VCL ions (not shown) provide anti-corrosive protection, keeping even the smallest piece of metal 104 coated and corrosion free. There is no need to clean the object 104 prior to use. Emitting substrates 20 may be fibrous products, without limitation, such as paper, cloth sheets, wood pulp, fiberboard, or paperboard chips.

(12) Likewise, the microcapsules 60 could be bonded to the first surface 64. In order to breach the microcapsule wall 40 and expose the VCI, or improved VCI 10, to the environment, then the user could employ a number of means including but not limited to: frictional force applied with a breaching member, pressure, shear forces, solvent action, enzyme action, chemical reactions, hydrolysis, or slow disintegration.

(13) The emitting substrate 20 may take the form of a printed paper. The printing will not affect the emitting substrate 20 and improved VCI 10 as a whole. Therefore, it is anticipated that marketing materials, such as a business card or magazine insert, could be printed, distributed with microcapsules 60 filled with the improved VCI 10. For example, and advertiser could give the emitting substrate/marketing material 20 to a client/customer, or potential client/customer. Because the emitting substrate/marketing material 20 would be more useful than ordinary marketing materials, the client would be enticed to use the emitting substrate/marketing material 20 in protecting some personal metallic object 104 and thus be repeatedly reminded of the advertiser.

(14) Although the invention has been described with reference to specific embodiments, this description is not meant to be construed in a limited sense. Various modifications of the disclosed embodiments, as well as alternative embodiments of the inventions will become apparent to persons skilled in the art upon the reference to the description of the invention. It is, therefore, contemplated that the appended claims will cover such modifications that fall within the scope of the invention.