System and Method for Transfering Liquid Argon to Bulk Transport Tanks

Abstract

A system and method is provided for transferring liquid argon from a bulk storage tank to a transport tank in which liquid argon is pumped through a tube arrangement within a heat exchanger and the tube arrangement is contacted by liquid nitrogen so that heat transfers from the liquid argon to the liquid nitrogen, thereby reducing the temperature, density and pressure of the liquid argon prior to exiting the heat exchanger and flowing into the transport tank.

Claims

1. A system for transferring liquid argon from a bulk storage tank to a transport tank comprising: a storage tank containing liquid nitrogen; and a heat exchanger including; a housing defining an interior chamber; a liquid argon tube arrangement disposed within the interior chamber and having an inlet configured for fluid communication with the bulk storage tank and an outlet configured for fluid communication with the transport tank; a liquid nitrogen tube arrangement in fluid communication with said liquid nitrogen bulk storage tank and disposed within the interior chamber in close proximity to the liquid argon tube arrangement, the liquid nitrogen tube arrangement including a plurality of openings positioned and arranged to direct liquid nitrogen from the liquid nitrogen tube arrangement onto the liquid argon tube arrangement; and a vent defined in the housing in communication with the interior chamber to vent gaseous nitrogen therefrom.

2. The system for transferring liquid argon of claim 1, wherein: said inlet is incorporated into said housing at or adjacent an upper portion of the housing; and said outlet is incorporated into said housing at or adjacent a lower portion of the housing

3. The system for transferring liquid argon of claim 1, wherein said liquid argon tube arrangement includes a first spiral tube extending from said inlet to said outlet.

4. The system for transferring liquid argon of claim 3, wherein said first spiral tube includes twenty coils between said inlet and said outlet.

5. The system for transferring liquid argon of claim 3, wherein said liquid nitrogen tube arrangement includes a second spiral tube that is substantially concentric with the first spiral tube.

6. The system for transferring liquid argon of claim 4, wherein said first spiral tube and said second spiral tube each include twenty coils.

7. The system for transferring liquid argon of claim 5, wherein said second spiral tube is configured and arranged to be radially inboard relative to said first spiral tube.

8. The system for transferring liquid argon of claim 1, wherein the nitrogen in said nitrogen storage tank is maintained at a temperature equal to or more than the temperature of the liquid argon in the bulk storage tank.

9. The system for transferring liquid argon of claim 8, wherein the nitrogen in said nitrogen storage tank is maintained at a temperature of about 250 F.

10. The system for transferring liquid argon of claim 9, wherein the nitrogen in said nitrogen storage tank is maintained at a pressure of about 100 psig.

11. The system for transferring liquid argon of claim 9, wherein the nitrogen in said nitrogen storage tank is maintained at a pressure between about 50 psig and 250 psig.

12. A system for transferring liquid argon from a bulk storage tank to a transport tank comprising: a storage tank containing liquid nitrogen; and a heat exchanger including an elongated tubular housing defining an interior chamber; a liquid argon tube arrangement disposed within the interior chamber and having an inlet configured for fluid communication with the bulk storage tank and an outlet configured for fluid communication with the transport tank; a liquid nitrogen inlet in fluid communication with said liquid nitrogen storage tank and opening to the interior chamber adjacent the bottom of the tubular housing; and an outlet for venting nitrogen vapor from the interior chamber at the top of the elongated tubular housing.

13. The system for transferring liquid argon of claim 12, wherein said liquid nitrogen inlet includes a spray nozzle directed toward said interior chamber to spray liquid nitrogen onto said liquid argon tube arrangement.

14. The system for transferring liquid argon of claim 11, wherein: said inlet is incorporated into said housing at or adjacent an upper portion of the housing; and said outlet is incorporated into said housing at or adjacent a lower portion of the housing.

15. The system for transferring liquid argon of claim 12, wherein said liquid argon tube arrangement includes a spiral tube extending from said inlet to said outlet.

16. The system for transferring liquid argon of claim 15, wherein said first spiral tube includes twenty coils between said inlet and said outlet.

17. The system for transferring liquid argon of claim 12, wherein said liquid argon tube arrangement includes a plurality of U-shaped tubes, each of said tubes including a U-shaped bend at one end and two elongated legs each having an opening at the opposite end of the U-shaped tube, with the opening at one of the elongated legs in communication with said inlet and the opening at the other of the elongated legs in communication with said outlet.

18. The system for transferring liquid argon of claim 17, wherein said two elongate legs of each of said U-shaped tubes has a length of 96 in.

19. The system for transferring liquid argon of claim 17, wherein said plurality of U-shaped tubes includes several tubes having a different bend radius.

20. The system for transferring liquid argon of claim 17, wherein said plurality of U-shaped tubes includes twenty-eight (28) tubes.

21. The system for transferring liquid argon of claim 17, wherein said housing includes a plurality of baffles distributed along the length of said tubular housing and configured to support said plurality of U-shaped tubes within said housing.

22. The system for transferring liquid argon of claim 21, wherein said plurality of baffles are distributed along the length of said tubular housing to define a serpentine flow path for liquid nitrogen flowing from the bottom of the housing to the vent.

23. The system for transferring liquid argon of claim 17, further comprising: a skirt supporting said tubular housing, said skirt defining an interior chamber separated by a baffle into an inlet chamber and an outlet chamber, said skirt incorporating said inlet in fluid communication with said inlet chamber and incorporating said outlet in fluid communication with said outlet chamber; and a support plate between said skirt and said tubular housing, wherein said support plate supports each of said plurality of U-shaped tubes with opening of said one leg of each of said tubes in fluid communication with said inlet chamber and the opening of said other leg of each of said tubes in fluid communication with said outlet chamber.

24. A method for transferring liquid argon from a bulk storage tank to a transport tank comprising: pumping liquid argon at a first temperature and first pressure through a tubing arrangement within a housing; contacting the tubing arrangement with liquid nitrogen within the housing, the liquid nitrogen at a second temperature such that heat energy is transferred from the liquid argon to the liquid nitrogen, whereby the temperature and pressure of the liquid argon is reduced and the liquid nitrogen changes to a gaseous state; discharging the liquid argon to the transport tank at the liquid argon lower temperature and pressure; and venting the gaseous nitrogen from the housing.

25. The method of claim 24 where the amount of liquid argon captured in the liquid argon tank is 25% more than in a standard transfer of liquid argon from a storage tank to a transport tank.

Description

DESCRIPTION OF THE DRAWINGS

[0009] FIG. 1 is a diagram of a system for transferring liquid argon from a bulk storage tank to a transport tank according to one embodiment of the present disclosure.

[0010] FIG. 2 is an enlarged view of argon and nitrogen tubing arrangements in a heat exchanger of the system shown in FIG. 1

[0011] FIG. 3 is a side view of a heat exchanger according to another embodiment of the present disclosure.

[0012] FIG. 4 is a top view of the heat exchanger shown in FIG. 3.

[0013] FIG. 5 is a cross-sectional view of the heat exchanger shown in FIG. 3.

[0014] FIG. 6 is a side cut-away view of the argon tubing arrangement for the heat exchanger shown in FIG. 3.

[0015] FIG. 7a, 7b are top views of baffles disposed within the heat exchanger shown in FIG. 3.

[0016] FIG. 8 is an enlarged cut-away view of the mounting flange of the heat exchanger shown in FIG. 3.

DETAILED DESCRIPTION

[0017] For the purposes of promoting an understanding of the principles of the disclosure, reference will now be made to the embodiments illustrated in the drawings and described in the following written specification. It is understood that no limitation to the scope of the disclosure is thereby intended. It is further understood that the present disclosure includes any alterations and modifications to the illustrated embodiments and includes further applications of the principles disclosed herein, to include the application to other cryogenic gases, as would normally occur to one skilled in the art to which this disclosure pertains.

[0018] One embodiment of the present system is depicted schematically in FIG. 1. A supply of liquid argon is stored within a bulk tank 10 at 100 psig and a temperature of 256 F. The bulk tank is constructed in a conventional manner to safely hold the liquefied argon under pressure, and may be insulated in a conventional manner. Liquid argon is supplied by tube 12 to internal pipes or a tube arrangement 14 within a heat exchanger unit 15. The liquid argon exits the heat exchanger unit 15 through an outlet tube 16 that supplies the liquid argon to a Department of Transportation (DOT) approved transport vehicle 18. As will be understood by one having skill in the art, the materials for the heat exchanger unit 15 are only limited in that such materials must be able to withstand cryogenic temperatures, i.e. 321 F. In one embodiment, the shell and outlet tubes of heat exchanger unit 15 are preferably oriented vertically to prevent adverse bending of the heat exchanger due to unequal temperature chances which sometimes happen if the heat exchanger is in a horizontal position.

[0019] In one embodiment, the heat exchanger unit includes a housing 15a defining an interior volume 15b. The housing may be formed of any suitable material capable of maintaining the interior volume substantially sealed except at pre-defined inlets and outlet. The inlet tube 12 and outlet tube 16 can be connected to the heat exchanger 15 by appropriate fittings to maintain a leak-proof transfer of the liquid argon from the inlet tube 12 to the internal tube arrangement 14, and from the tube arrangement to the outlet tube 16.

[0020] In one embodiment, the internal tube arrangement 14 includes a tube or pipe, such as a copper tube, that is wound within the interior volume 15b from the inlet tube 12 to the outlet tube 16, as illustrated in FIG. 2. The tube arrangement can thus include a number of turns, such as 20 turns, in the spiral configuration. The spiral configuration can start with the first loop 14a of the spiral having a diameter slightly less than the perimeter dimensions of the housing 15a. In one specific embodiment, the housing is a six foot cube, so the first loop 14a of the spiral tube arrangement 14 can have a diameter of about five feet. In some embodiments, the diameter of each successive loop can decrease to the last loop 14b that is connected to the outlet tube 16, which can have a diameter of about one foot.

[0021] In one feature of the present disclosure, a liquid nitrogen tank 20 is connected to the heat exchanger 15 by an inlet tube 22. In one embodiment, the inlet tube 22 is connected to a spray nozzle 24 mounted within the housing 15a. The spray nozzle 24 is configured and arranged to direct a spray of liquid nitrogen across the internal tube arrangement 14 carrying the liquid argon. A vent 26 is provided to vent the nitrogen as it changes state from liquid to gas.

[0022] The liquid nitrogen in the tank 20 is maintained at a temperature and pressure. In one embodiment, the temperature of the stored liquid nitrogen is at a lower temperature than the temperature of the liquid argon. In another embodiment, the temperature of the stored liquid nitrogen is at the same temperature or a higher temperature than the temperature of the liquid argon. It is to be understood that the temperature is generally dependent on the saturated pressure. Based on construction of typical bulk tanks, in many cases, the maximum temperature of the liquid nitrogen is about 254 F at 250 psig, which is the normal maximum allowable operating pressure (MAWP) of the bulk tanks. In the first illustrated embodiment, the liquid argon is stored at a temperature of 256 F. and warms slightly to a temperature of about-250 F. upon entering the heat exchanger 15. In this illustrated embodiment, the liquid nitrogen is stored at a temperature of 250 F. The liquid nitrogen is stored at a pressure of 100 psig so that as the nitrogen is depressurized upon exiting the nozzle 24 it will sufficiently cover the internal tube arrangement 14. As the nitrogen depressurizes its temperature decreases to about 320 F., which is significantly colder than the liquid argon flowing through the internal tube arrangement 14. This temperature is the boiling point of the nitrogen and results in a temperature where nitrogen can absorb the most heat. Thus, this temperature differential results in heat transfer from the liquid argon to the liquid nitrogen sprayed onto the tube arrangement, thereby reducing the temperature of the liquid argon by about 20 F. Spraying the nitrogen onto the internal tube arrangement reduces the Leidenfrost effect, which helps maintain the heat transfer from the liquid argon to the liquid nitrogen.

[0023] In another embodiment, the spray nozzle 24 is replaced by a spiral tube, such as spiral tube 24, which is concentrically disposed adjacent an internal spiral tube arrangement 14 for the liquid argon, as shown in FIG. 2. The liquid nitrogen spiral tube includes a series of small holes 24a in the tube directed toward the adjacent spiral tube arrangement 14 so that liquid nitrogen ejected from each hole is sprayed directly onto the argon tube 14. The end 24b of the tube can be capped. As one of skill in the art understands, varying the internal tube arrangement for the nitrogen gas so as to result in a further pressure decrease and corresponding temperature decrease so as to maximize the system is anticipated. The nitrogen sprayed from the tube again acts to draw thermal energy from the argon flowing through the tube arrangement 14 to thereby lower the temperature of the liquid argon. The holes 24a can be limited to portions of the spiral tube 24 that are in immediate proximity to portions of the argon tube arrangement 14, or can extend along substantially the entire length of the tube. In the illustrated embodiment, the liquid nitrogen spiral tube 24 is concentrically wound with the liquid argon spiral tube 14. In a specific embodiment, the liquid nitrogen tube 24 is wound at a smaller diameter than the liquid argon tube 14 so that the liquid nitrogen tube is generally radially inboard of the liquid argon tube. In this configuration, the openings 24a are arranged in the tube 24 to direct the liquid nitrogen generally radially outward toward the liquid argon tube 14. Alternatively, the liquid nitrogen tube can be wound at a larger diameter than the liquid argon tube, in which case the liquid nitrogen tube is generally radially outboard of the liquid argon tube. In this configuration, the openings in the liquid nitrogen tube are arranged to direct the liquid nitrogen generally radially inward.

[0024] It can be appreciated that the heat exchanger 15 of the present disclosure operates to lower the temperature of the liquid argon flowing from the bulk tank 10 to the transport tank 18. As the argon is cooled the pressure of the liquid argon within the tube arrangement 14 decreases by about 30-50 psig without any corresponding loss of liquid argon or any corresponding change of state of the liquid argon. The lower pressure of the liquid argon as it leaves the heat exchanger through the outlet tube 16 reduces, and in some cases eliminates, the losses that occur with argon in the conventional transfer process. In the conventional process the liquid argon is maintained substantially at its bulk storage pressure, 100 psig in the present example, but must be reduced to the DOT regulated pressure of 25 psig within the transport tank 18. In order to achieve this significant pressure reduction it is necessary to open a relief valve in the transport tank and relieve argon gas to the atmosphere. It can be appreciated that a 75 psig differential in the conventional system can require significant venting of argon gas, leading to the 30-50% loss of liquid argon. However, with the system and method of the present disclosure the liquid argon enters the transport tank 18 at a much lower pressure, nominally 30-50 psig or less. The pressure differential is no longer 75 psig, but in the range of 5-25 psig. It can thus be appreciated that this much reduced pressure differential means that significantly less argon gas must be vented to achieve the DOT regulated pressure within the transport tank 18. Moreover, the liquid argon increases in density as it cools. The greater density allows more liquid argon to flow into the transport tank 18 regardless of the constraints of the total volume of the transport tank 18.

[0025] In another embodiment shown in FIGS. 3-8, a heat exchanger 50 includes a vertical tubular housing 52 supported on a skirt 54 mounted on a platform 55. In some embodiments, the skirt is anchored with gussets 55a although the means of anchoring to the platform is not meant to be limiting. The elongated tubular housing 52 defines an interior chamber 53 that is supplied with liquid nitrogen through nitrogen inlet 74. As the nitrogen ascends within vertical housing 52 it gradually changes to the gaseous state, exiting the housing at the nitrogen vapor vent 76 at the top of the housing. An arrangement of baffles 70, 71 define an upward serpentine path for the nitrogen flowing within the tubular housing 52 from the bottom of the housing to the vent 76.

[0026] The skirt 54 defines an interior chamber 62 that is separated by a baffle 64 into an inlet chamber 62a, an outlet chamber 62b and left and right intermediate chambers 62c and 62d, respectively. The inlet chamber 62a is in fluid communication with a liquid argon inlet 58, while the outlet chamber 62b is in fluid communication with a liquid argon outlet 59. The tubular housing 52 is engaged to the skirt 54 at a mounting flange 56, with the flange positioned above the argon inlet and outlet. As shown in the detail view of FIG. 8, the mounting flange 56 includes a mounting plate 66 sandwiched between the mating flange elements 56a, 56b. The mounting flange includes an appropriate gasket or seal arrangement to provide a fluid and gas tight seal between the mounting plate 66 and the skirt chamber 62, and between mounting plate and the housing chamber 53.

[0027] A shown in FIG. 8, the mounting plate 66 includes a plurality of openings, such as openings 66a, 66b, to receive and support the argon tube arrangement that in one embodiment includes a plurality of U-shaped tubes 60 (FIG. 3). The lower ends 61a, 61b open into the respective inlet chamber 62a and outlet chamber 62b, that in turn communicate with the respective liquid argon inlet 58 and outlet 59. The tubes 60 pass through corresponding openings 70a and 71a in respective baffles 70, 71 to support the tubes along the entire length of the tubular housing 52. A number of tie bars (not shown) or other connectors can pass through openings 73 in the baffles 70, 71 and anchor the mounting flange 56 to provide stability to the tubular housing and argon tube arrangement 60.

[0028] Tubes 60 can be provided in a range of nested sizes, from the tubes 60a having a narrower lateral extent to the tubes 60b having a wider lateral extent. U-shaped tubes 60c and 60d are sized to nest between the narrower and wide tubes 60a, 60b. As depicted in the embodiment in FIG. 5, fourteen U-shaped tubes 50 can fit within the chamber 53 of the tubular housing 52. Each of the U-shaped tubes defines a bend radius R to the centerline (FIG. 6). In one specific embodiment, the bend radius can be about 0.95 in. for the smaller tube 60a, 1.6 in. for the tube 60d, 2.2 in. for the tube 60c and about 2.8 in. for the larger tube 60b. The differing bend radii allow the tubes to be arranged in a generally nested fashion, as depicted in FIG. 6. With this configuration, 28 tubes having a tube diameter of 0.625 in. can be arranged within an 8 in. diameter tubular housing 52including six tubes at each of the larger bend radii and eight tubes at each of the smaller bend radii. However, as is generally understood by the skilled artisan, the number of tubes is not meant to be limiting and different numbers of tubes can be used in different situations. The tubes 60 include generally straight legs 61 that can have a length in the specific embodiment of about 96 in. The tubular housing 52 is thus appropriately sized to encase the tubes 60. In a specific embodiment, fourteen baffles 70, 71 are provided to support the tubes within the housing. The baffles also increase the flow velocity and turbulence of the nitrogen within the housing by forcing the nitrogen to flow largely perpendicularly to the tubes, thus forcing the nitrogen to flow around the tubes, in a generally horizontal manner. The baffles thus increase the heat transfer rate between the argon in the tubes and the liquid nitrogen in the housing.

[0029] The liquid argon inlet 58 can be connected by way of a cryogenic pump to the liquid argon tank 10 (FIG. 1) and the argon outlet 59 can likewise be connected to the transport tank 18 in a known manner. Liquid argon is transferred (by pumping or by pressure differential) at 100 psig and 256 F. into the inlet chamber 62a and from there into each of the plurality of U-shaped tubes 60. The liquid argon is directed into the tubes at the inlet chamber 62a (FIG. 5) and then upward through the tubes to the U-shaped bend within the left intermediate chamber 62c. The argon then flows downward through the tubes to the bottom of the left intermediate chamber 62c, where the argon then passes into the U-shaped tubes in the right intermediate chamber 62d. The argon flows upward within the tubes in the intermediate chamber to the U-shaped bend, and then downward within the housing to the argon outlet 59.

[0030] The liquid nitrogen inlet 74 is connected by way of a cryogenic pump, in certain embodiments, to the liquid nitrogen tank 20 and is concurrently transferred through the nitrogen interior chamber 53 of the tubular housing 52. The temperature of the nitrogen at the inlet is automatically controlled to prevent the argon from freezing at its outlet. In this embodiment, the liquid nitrogen at the inlet is approximately the temperature/pressure of the bulk nitrogen tank, i.e. usually a temperature that is warmer than 300 F, even at a pressure of 25 psig. This is warmer than the freezing point of argon which is 308 F. The baffles 70, 71 interrupt the flow of nitrogen through the chamber so that the nitrogen is maintained in contact with the U-shaped tubes 60 carrying the liquid argon. In addition, the thermodynamic characteristics of the nitrogen changes as it moves upward within the housing, so that the nitrogen is warmer at the inlet and colder at the outlet to cool the argon without it freezing at its outlet. And although not meant to be limiting, the U-shaped argon tubes ensures that the entire length of the tubing is contacted by the liquid nitrogen, which upon entry into the chamber decreases in temperature in association with the corresponding decrease in pressure. As with the previous embodiments, as the nitrogen changes state it draws heat energy from the argon flowing through the U-shaped tubes 60, thereby reducing the temperature and pressure of the argon, while increasing the density of the liquid argon that exits the outlet 59 into the transport tank 20. The argon can thus enter the transport tank at 300 F. and at a pressure lower than the required DOT regulated pressure for transport. This translates to significant lower losses of argon to atmosphere as the transport tank is filled. And even though nitrogen is released into the atmosphere in the system, the overall cost savings are significant. The general cost of nitrogen is approximately 10 lower than the cost of an equivalent amount of argon. Additionally, there is a current argon shortage suggesting that the cost of argon will continue to climb. As nitrogen is almost 80% of our atmosphere and can be easily generated in house, it is unlikely to ever become limiting. In the embodiments where nitrogen is stored at a temperature higher or equal to the temperature of the argon, further cost savings are realized because the lower temperature does not have to be maintained in the nitrogen storage tank.

[0031] The present disclosure should be considered as illustrative and not restrictive in character. It is understood that only certain embodiments have been presented and that all changes, modifications and further applications that come within the spirit of the disclosure are desired to be protected.