Biodegradable and safe drinking straws from date palm leaves as substitute for plastic straws

Abstract

Biodegradable drinking straws from date palm leaves as a substitute for plastic straws. The straws are made by washing the palm tree leaves with a solution of ascorbic acid, 99% ethanol and water, cleaning the palm tree leaves with abrasive sheets, soaking the palm tree leaves, drying the palm tree leaves, heating the palm tree leaves to a temperature selected from a range of 60° C. to 140° C., rolling the palm tree leaves, binding the rolled palm tree leaves using biodegradable food grade adhesive, drying the rolled palm tree leaves.

Claims

1. A method for manufacturing a biodegradable drinking palm tree straw, the method comprising: washing palm tree leaves with a solution of ascorbic acid, 99% ethanol, and water; cleaning the palm tree leaves with abrasive sheets; soaking the palm tree leaves; drying the palm tree leaves; heating the palm tree leaves to a temperature selected from a range of 60° C. to 140° C.; rolling the palm tree leaves; binding the rolled palm tree leaves using biodegradable food grade adhesive; and drying the rolled palm tree leaves; wherein the palm tree leaves are washed twice with a 99% ethanolic solution under an ultrasonicator bath and subsequently once with water.

2. The method of claim 1, wherein the palm leaves are selected from the group consisting of date palm tree leaves, coconut palm tree leaves, and oil palm tree leaves.

3. The method of claim 1, wherein the palm tree leaves are date palm tree leaves.

4. The method of claim 1, wherein the concentration of ascorbic acid of the solution is less than 50% v/v.

5. The method of claim 1, wherein cleaning the palm tree leaves comprises: scrubbing the palm tree leaves with abrasive sheets, wherein the grade of the abrasive sheets ranges from 15 to 40 micron.

6. The method of claim 1, wherein during at least one of drying the palm tree leaves and drying the rolled palm tree leaves, the palm tree leaves are dried with hot air.

7. The method of claim 6, wherein the hot air has a temperature of 70° C. to 130° C. and is applied to the palm tree leaves for one to fifteen minutes.

8. The method of claim 6, wherein the hot air has a temperature of 80° C. to 120° C. and is applied to the palm tree leaves for five minutes.

9. The method of claim 1, wherein the palm tree leaves are subject to hydrothermal heating at a temperature within the range of 70° C. to 130° C.

10. The method of claim 9, wherein the palm tree leaves are subject to hydrothermal heating at a temperature in the range of 80° C. to 120° C.

11. The method of claim 1, wherein binding the rolled palm tree leaves utilizes synthetic and non-synthetic polymeric adhesives.

12. The method of claim 1, wherein binding the rolled palm tree leaves utilizes synthetic and non-synthetic polymeric adhesives bound with graphene oxide quantum dots (GOQDs).

13. The method of claim 1, wherein binding the rolled palm tree leaves utilizes non-synthetic polymeric adhesives bound with graphene oxide quantum dots (GOQDs).

14. The method of claim 1, wherein binding the rolled palm tree leaves utilizes synthetic polymeric adhesives bound with graphene oxide quantum dots (GOQDs).

15. The method of claim 1, wherein the rolled and bound palm tree leaves are dried for 1 to 24 hours.

16. The method of claim 1, wherein the bound palm tree leaves are dried for 8 hours.

17. The method of claim 1, wherein the bound palm tree leaves are dried at standard temperature and pressure.

Description

BRIEF DESCRIPTION OF THE FIGURES

(1) The invention can be better understood with reference to the following figures and description.

(2) FIG. 1 shows date palm dried leaves.

(3) FIG. 2 shows straw standard size options.

(4) FIG. 3 shows crush strength comparison among the different types of straw.

(5) FIG. 4 shows straws subjected to testing under milk, juice and water.

(6) FIG. 5 shows that paper straws become more soggy than palm straws.

DETAILED DESCRIPTION OF SPECIFIC EMBODIMENTS

(7) In a first embodiment of the present disclosure, a method is disclosed for manufacturing a biodegradable drinking palm tree straw, comprising the steps of (a) washing date palm tree leaves with less than 40% concentration solution of ascorbic acid, ethanol and water; (b) cleaning the leaves with different grade of abrasive sheets for softening of the leaves; (c) soaking of the leaves for 6 hour in water; (d) hot air blow dry the leaves in an oven; (e) hydrothermally heating the leaves at 80° C. to 120° C.; (f) Rolling followed by binding the leaves using synthetic or non-synthetic polymeric adhesives bound with Graphene Oxide Quantum Dots (GOQDs); (g) drying the leaves at standard temperature and pressure (STP) for 8 hours.

(8) In one embodiment of the present invention, the palm tree leaves utilized to make the straws can be date palm tree (Phoenix dactylifera), coconut palm tree (Cocos nucifera), oil palm tree (Elaeis guineensis), acai palm (Euterpe oleacea), zombie palm tree (Zombia antillarum), windmill palm tree (Trachycarpus fortune), foxtail palm tree (Wodyetia bifucata), king palm tree (Archontophoenix alexandrae), triangle palm tree (Dypsis decaryi), pygmy date palm tree (Phoenix roebellenii), cliff date palm tree (Phoenix rupicola), Senegal date palm tree (Phoenix reclinata), Ceylon date palm tree (Phoenix pusilla), wild date palm tree (Phoenix sylvestris), Cretan date palm (Phoenix theophrastii), dwarf date palm (Phoenix acaulis), and other Phoenix hybrid species.

(9) In a preferred embodiment of the present invention, the palm tree utilized to make the straws can be palm tree (Phoenix dactylifera), coconut palm tree (Cocos nucifera), oil palm tree (Elaeis guineensis).

(10) In a most preferred embodiment of the present invention, the palm tree utilized to make the straws is the date palm tree (Phoenix dactylifera).

(11) In one embodiment of the present invention, the palm tree leaves are washed with solution of ascorbic acid, 99% ethanol and water.

(12) In a preferred embodiment of the present invention, the solution of ascorbic acid, ethanol, and water contains less that 50% v/v ascorbic acid.

(13) In a most preferred embodiment of the present invention, the solution of ascorbic acid, ethanol, and water contains less that 40% v/v ascorbic acid.

(14) In one embodiment of the present invention, the raw leaves are washed with less than 40% v/v concentrated ascorbic acid, ethanol and water to remove dirt and any kind of microbial growth.

(15) In another embodiment of the present invention, the leaves are scrubbed using different grade of abrasive sheets and washed in ethanol twice under an ultrasonicator bath at a frequency of approximately 40/60 KHz for approximately 15 minutes, followed by a bath in deionized water (DI Water) for approximately 15 minutes. The abrasive sheets used have an abrasiveness range of 15 to 40 micron.

(16) In another embodiment, the leaves are washed in an ultrasonicator bath at a frequency of approximately 40/60 KHz for a time ranging from 5 to 30 minutes.

(17) In a preferred embodiment, the leaves are washed in an ultrasonicator bath at a frequency of approximately 40/60 KHz for a time ranging from 10 to 20 minutes.

(18) In a most preferred embodiment, the leaves are washed in an ultrasonicator bath at a frequency of approximately 40/60 KHz for approximately 15 minutes.

(19) In another embodiment, the water used to wash the leaves may be deionized water, distilled water, and/or reverse osmosis water.

(20) In a preferred embodiment, the water used to wash the leaves is deionized water.

(21) In another embodiment, the leaves are washed in a bath of purified water for a time ranging from 5 to 30 minutes.

(22) In a preferred embodiment, the leaves are washed in a bath of purified water for a time ranging from 10 to 20 minutes.

(23) In a most preferred embodiment, the leaves are washed in a bath of purified water for approximately 15 minutes.

(24) In another embodiment of the present invention, the leaves are soaked in water at standard temperature and pressure (STP).

(25) In another embodiment of the present invention, the leaves are exposed to hot air flow at e temperature ranging from 70° C. to 130° C. for a time ranging from 1 to 15 minutes.

(26) In a preferred embodiment of the present invention, the leaves are exposed to hot air flow at e temperature ranging from 80° C. to 120° C. for approximately 5 minutes.

(27) In another embodiment of the present invention, the leaves can be segregated into different containers depending on their length, thickness, and strength.

(28) In another embodiment of the present invention, the leaves are subjected to a hydrothermal heating to a temperature ranging from 60° C. to 140° C.

(29) In a preferred embodiment of the present invention, the leaves are subjected to a hydrothermal heating to a temperature ranging from 80° C. to 120° C.

(30) In another embodiment of the present invention, the palm tree leaves are rolled to form a straw, comprising an elongated drinking tube impermeable to fluids, including an exterior surface and an interior surface, having an approximately circular cross-section, a first end and a second end opposite the first end.

(31) In another embodiment of the present invention, the rolled palm tree leaves are bound with synthetic and/or non-synthetic polymeric adhesive.

(32) In one embodiment of the present invention, GOQDs are added to the adhesives.

(33) In a preferred embodiment of the present invention, GOQDs are dispersed and homogeneously mixed with the synthetic and/or non-synthetic polymeric adhesive.

(34) In another embodiment of the present invention, the rolled leaves are dried at STP for approximately for 5 to 24 hours.

(35) In a preferred embodiment of the present invention, the rolled leaves are dried at STP for approximately for 6 to 12 hours.

(36) In a most preferred embodiment of the present invention, the rolled leaves are dried at STP for approximately 8 hour.

EXPERIMENTAL EXAMPLES

(37) Material and Methods

(38) Collection of Date Palm Leaves

(39) The palm develops an average of 12 to 15 new leaves each year under natural growth conditions, and as a consequence, the same number can be assumed to be cut as part of the palm's maintenance. As this is applied to hundreds of thousands of trees, it may result in a large number of leaves becoming available each year. Leaflets vary in length from about 15 to 30 cm and in width from 1 to 3 cm (FIG. 1). The number of leaflets on one midrib may be in the range of 120 to 150. Dried leaves from Phoenix dactylifera (date palm) frond were collected from the farmland. Then the leaves undergone a thorough quality check for the selection of damage-free leaves from cracks, cuts & dimensions that well suit the application.

(40) Experimental Steps

(41) The experimental steps for manufacturing a straw utilizing date palm leaves include: (1) material collection of materials such as glue, dry leaves, etc. Straw is bound together with biodegradable food-grade glue that is completely secure when it gets in contact with beverages; (2) manufacturing the straw using the source of fab lab; (3) testing the straw to determine durability, aesthetic, reaction at cold and hot water; (4) testing product cytotoxicity since this product falls in food and beverage industry before commercializing into market; (5) long tipping test of straw in liquid to determine its shelf life. Also, determining storage condition (dry & cold), and packaging method to maintain the desired properties of the product.

(42) Synthesis Process of Date Palm Tree Straw

(43) The synthesis process of the date palm tree leaves straws includes the following steps: (a) Washing of the date palm tree leaves with less than 40% concentration solution of ascorbic acid, ethanol and water; (b) Cleaning the leaves with different grade of abrasive sheets for softening of the leaves; (c) Soaking of the leaves for 6 hour in water; (d) Hot air blow dry in an oven; (e) Hydrothermal heating of the leaves at 80° C. to 120° C.; (f) Rolling followed by binding of the leaves using synthetic or non-synthetic polymeric adhesives bound with GOQDs; (g) Room temperature drying of the leaves at standard temperature and pressure (STP) for 8 hours.

(44) Ascorbic acid also called Vitamin-C is an organic as well naturally occurring compound that has anti-microbial properties [10]. It is the most effective and safest way to eliminate the growth of any microbes on the date palm leaves. Moreover, using a combination of ethanol and ascorbic acid had greater antimicrobial effects [11]. The combination of ascorbic acid and ethanol not only certify the elimination of germs but also removes any kind of organic/inorganic contaminants (dirt, glue, etc.) making the date-palm leaves more hygienic to process for straws.

(45) Abrasive sheets were used to remove the top layer of the leaves, removing defects/discoloration, generating a pleasantly smooth finish while at the same time adding adhesion by increasing surface area through the development of small irregular rough lines/ridges/defects for the glue to stick properly. The abrasive sheets used have an abrasiveness range of 15 to 40 micron. Moreover, on boiling the leaves the naturally occurring wax in the leaves comes out and is segregated effectively in short time duration. It has a pleasant smell, good emulsification properties, and enhances better binding properties [12].

(46) The GOQDs synthesized were dispersed and homogeneously mixed with the synthetic or non-synthetic adhesive will remove the voids and air bubbles that generally occurred while applying glue to any surface. In addition, GOQDs will offer antibacterial [13], disinfection systems (healing and wound disinfection) [14], anti-bio fouling [15], bio-imaging markers (for monitoring of health condition) [16], humidity and pressure sensors [17], fluorescent polymers properties to the straws.

(47) The rolled leaves with synthetic and/or non-synthetic polymeric adhesives are dried at standard temperature and pressure for 8 hours to make sure that the glue has been dried properly and the leaf surfaces are gelled properly.

(48) The advantage of using an oven for the drying process involves (a) a drying oven allows estimating the amount of moisture contents (approximately) in the leaves and can uniformly heat the leaves; (b) It allows a larger volume of the samples to be dried at the same time, thus higher throughput can be achieved; (c) It is a simple, highly accurate, and most economical as well as repeatable process for heating.

(49) The synthesis techniques for the date palm tree straw involves cumbersome washing technique, which involves washing of the raw leaves with less than 40% concentrated ascorbic acid and to certify the removal of the dirt and any kind of microbial growth. It is followed by scrubbing of the leaves using different grade of abrasive sheets and two times washing in ethanol under ultrasonicator bath (Frequency ˜40/60 KHz) for 15 minutes as well as washing in deionized water (DI Water) for 15 minutes. The leaves are then exposed to fresh water for soaking at STP. Moreover, to attest the purity and to avoid any kind of contamination on the wet leaves, they are exposed to hot air (temperature 80° C. to 120° C.) for 5 minutes. This step assures the cleanliness as well as purity of the leaves. The leaves are then segregated into different boxes depending on their length, thickness as well as strength. Once, the leaves have been distributed into different boxes, the leaves of the individual boxes are subject to hydrothermal heating at 80° C. to 120° C. The completion of the hydrothermal steps will lead to secretion of the gluey or wax contents of the leaves from their surfaces, which along with selected combination of synthetic and/or non-synthetic polymeric adhesives are bonded to produce the end product. Finally, the rolled leaves with synthetic and/or non-synthetic polymeric adhesives are dried at STP for about 8 hours.

(50) Synthesis of Hybrid Adhesive

(51) The commercially available glue was mixed with Graphene Oxide Quantum Dots (GOQDs) to enhance its physical and chemical properties. The amount of GOQDs added to the glue was less than 50%.

(52) Synthesis of Graphene Oxide Quantum Dots from Date Palm Seeds

(53) In a typically proposed synthesis of graphene oxide quantum dots using carbonization of date seeds, 2 grams of dry date seeds were measured and baked for 8 h in hot air at 150° C., followed by crushing/grounding in a mortar and pestle for 2 hr to get a uniform distributed powder [13]. The dried date seed powder was then dissolved in 5 ml of deionized water and heated at 200° C. using a heating mantle [13]. On the appearance of the yellow color of the solution, the heating was stopped. The solution was then mixed with NaOH solution to get a PH 7 solution. The solution thus formed was liquidated and the remaining powder was vacuum dried at 60° C. Another proposed approach for the synthesis of GOQDs through sonochemical exfoliation is to mix the date seed powder in a 3:1 ratio of sulphuric acid and nitric acid followed by ultrasonication for 8-10 h [14]. The solution is then allowed to cool at room temperature and 100 ml ice of deionized water was added into it followed by drop wise addition of NaOH solution till the PH of the solution reaches 7 (neutral). The GOQDs synthesized was dispersed and homogeneously mixed with the synthetic or non-synthetic adhesive. This green and nontoxic approach of adding GOQDs to the adhesive and the date palm tree offers antibacterial [15], disinfection systems (healing and wound disinfection) [16], anti-bio fouling [17], bio-imaging markers (for monitoring of health condition) [18], humidity and pressure sensors [19], fluorescent polymers properties to the straws.

(54) Straw Size

(55) The size of the straw can be customized based on the type of application (Table 1). For instance, usual straw size that is used in restaurants, Cafeterias and hotels are of diameter 5.5 mm and length of 210 mm each. The straws from date palm can not only replace them, but also replace small straws that are used by beverage companies for packaged drinks.

(56) Testing Phase

(57) Toxicity, self-life, durability, environment friendly/sustainability are some of the factors which need to be evaluated for any products which are getting direct contact with sensory organs like mouth in day-to-day activity. Date palm tree leaves are low-cost, non-toxic, and opens up a scope for scalable production of straws as well as supports the sustainable development goals.

(58) Toxicity

(59) The toxic content of the straw itself is zero unless and until it is been chewed or swallowed completely. The date palm tree fruits comes under edible category subjected to processing and manufacturing. The leaves are biodegradable in nature and are non-toxic. The adhesive used is environmental friendly and as it falls under food grade category.

(60) Crush Strength Test

(61) The crush strength was determined by subjecting the various types of straws in use to a given loading (see FIG. 2). Date palm straw outperformed paper straws from China and was found to be almost as strong as current high-quality straws.

(62) Shelf-Life

(63) Under proper storage conditions, the shelf-life of the straws has been evaluated for 3 months under vacuum condition. Exposure to moisture will degrade the food products and organic products. However, these straws can remain in excellent condition if stored properly till they are used and discarded.

(64) Straw Longevity

(65) Unlike plastic or wax-coated paper straws, date palm leaf straws, are stable and on exposure to hot or cold liquids (see FIG. 3). It can withstand in hot drinks or cold for up to 35 and 50 minutes respectively. In the “hard lid” tests, the cooler temperatures caused by ice extended the life of all straws. Three separate common drinks, such as milk, juice, and water, in the same temperature range and liquid level were used to test the straws longevity. The straws prepared are quite stable for minimum of 30 minutes under hot liquid, while are unaffected more than 40 minutes on exposure to juice or water.

(66) Durability

(67) Date palm leaf straws can withstand for long time on being immersed in liquids. The palm straw exhibited more durability comparing the paper straw after removing them from respective liquids (see FIG. 4).

REFERENCES

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