Coating for hot-shaping core

Abstract

The invention concerns a method for coating a core (1) for producing a turbomachine part (2) by isostatic compacting, for example a leading-edge shield of a blade, the coating method comprising the steps of:—S1: covering the core (1) by means of a first solution comprising a first refractory component configured to oppose the diffusion of species, the first component comprising a metal oxide,—S2: covering the core (1) by means of a second solution comprising a second component designed to bind the first component in such a way as to form a homogeneous layer, the second component comprising a mineral binder;—S3: applying a heat treatment to the covered core (1) in such a way as to dry the solution and solidify the coating.

Claims

1. A process for coating a core for a manufacture of a turbomachine part by isostatic pressing, the coating process comprising the steps of: S1: Coating the core with a first solution comprising a first refractory component configured to oppose species diffusion, the first component comprising a metal oxide; S2: Coating the core with a second solution comprising a second component configured to bind the first component so as to form a homogeneous layer, the second component comprising an inorganic binder; and S3: Applying a heat treatment to the coated core so as to dry the solution and solidify the coating.

2. The coating process as claimed in claim 1, wherein steps S1 to S3 are repeated at least once.

3. The coating process as claimed in claim 1, wherein the first component comprises an oxide of a transition metal, and the second component comprises a colloid of a lanthanide.

4. The coating process as claimed in claim 1, wherein the first solution is aqueous, and the first component comprises an yttrium oxide filler in powder form.

5. The coating process as claimed in claim 1, wherein the second component comprises a cerium colloid binder.

6. The coating process as claimed in claim 1, wherein the heat treatment step S3 is carried out at a temperature comprised between 40° C. and 120° C. for a period comprised between 15 minutes and 60 minutes.

7. The coating process as claimed in claim 1, wherein the heat treatment step S3 is carried out at a temperature comprised between 70° C. and 90° C. for a period comprised between 25 and 35 minutes.

8. The process as claimed in claim 1, further comprising, between steps S1 and S2, a step S4 of heat treatment of the core.

9. The process as claimed in claim 8, wherein, during step S1, the solution comprises a mass proportion of water comprised between 40% and 60%, and a mass proportion of metal oxide comprised between 40% and 60%.

10. The coating process as claimed in claim 1, wherein the coating steps S1 and S2 are performed simultaneously by applying a single solution comprising the first component and the second component.

11. A manufacturing process for manufacturing a turbomachine blade, the blade comprising an internal cavity, a first sheet and a second sheet, wherein the process comprises the steps of: assembling the first sheet, the second sheet and a core comprising a coating made as claimed in claim 1; isostatically pressing the assembly at a temperature configured to soften the first sheet and the second sheet so as to promote their deformation; and extracting the core.

12. The manufacturing process as claimed in claim 11, wherein one among the first sheet and the second sheet comprises a first material; the core comprises a second material; the first material comprising a titanium alloy; and the second material comprising an alloy of a transition metal.

13. The manufacturing process as claimed in claim 12, wherein the second material comprises an alloy of yttrium.

Description

PRESENTATION OF THE FIGURES

(1) Other features and advantages of the invention will emerge from the following description, which is purely illustrative and non-limiting, and should be read in conjunction with the appended figures in which:

(2) FIG. 1 represents the various steps of a hot-shaping process for a turbomachine blade according to the invention; FIG. 1a represents the previously formed pressure-side sheet; FIG. 1b represents the pressure-side sheet in which the core 1 is positioned; FIG. 1c represents the suction-side sheet, positioned on the core 1, itself positioned on the pressure-side sheet. The whole constituting the assembly to be shaped; FIG. 1d represents a cross-section of the assembly, revealing the core 1, the pressure-side and suction-side sheets being fixed to each other prior to hot shaping; FIG. 1e represents a cross-section of the assembly, revealing the core 1 and the part 2 formed after the hot-shaping step; FIG. 1f represents the part 2 formed, with the core 1 in the cavity of the part 2; FIG. 1g represents the final part 2 after extraction of the core 1;

(3) FIG. 2 represents free enthalpies of formation of various oxide species.

DESCRIPTION OF ONE OR MORE EMBODIMENTS

(4) The invention relates to a process for coating a core 1 for the manufacture of a turbomachine blade by isostatic pressing, the coating process comprising the steps of: S1: Coating the core (1) with a solution comprising a first refractory component configured to oppose species diffusion, the first component comprising a metal oxide, S2: Coating the core (1) with a solution comprising a second component configured to bind the first component so as to form a homogeneous layer, the second component comprising an inorganic binder; S3: Applying a heat treatment to the coated core (1) so as to dry the solution and solidify the coating.

(5) The core 1 is thus coated with a non-permanent, anti-diffusion coating, which comprises a first component, or filler, which is refractory and thermodynamically very stable, anti-diffusing, and non-reactive with the material of the part 2, even at a temperature of the order of 1000° C., and a second component, or binder, which is inorganic, so as not to contaminate, during hot isostatic pressing, the material of the part 2.

(6) The process can optionally comprise a reiteration of steps S1 to S3, which allows the thickness of the coating obtained to be adapted according to need.

(7) “Binder” is conventionally understood to mean a product that serves to agglomerate solid particles in the form of powder or granules into a solid mass.

(8) Advantageously, the first component has a very negative free enthalpy of formation at 25° C. for the formation of its oxide. This oxide will therefore be extremely stable. Moreover, in order to be inert with respect to the material of the part 2 (titanium), the free enthalpy of formation of the oxide of the component will advantageously be lower than that of titanium oxide (TiO2), titanium being the main chemical element of the material of the part 2.

(9) Such a coating prevents interdiffusion of species between a part 2 and the core 1, which greatly limits the adhesion between the part 2 and the core 1 and promotes the removal and reuse of the core 1 during a subsequent manufacturing process of a part 2.

(10) Such a manufacturing process is shown in FIG. 1.

(11) In an embodiment, such a process may comprise a step, not shown, of cutting and then machining sheets intended to form the part 2.

(12) For example, in the case of a turbomachine blade, a first sheet comprises a sheet intended to form the pressure side of the blade, and a second sheet comprises a sheet intended to form the pressure side of the blade.

(13) Such a process can also include a hot shaping step, during which the sheets intended to form the pressure side and suction side are hot forged in order to give them a preform that approximates the shape of the core in order to simplify the assembly of the sheets around the core.

(14) An assembly step is then performed, during which the first sheet, the second sheet and the core 1 are positioned relative to each other and held together, as illustrated in FIGS. 1a to 1c.

(15) The pressure-side and suction-side sheets are fixed to each other, for example by welding at the lateral edges of said sheets, in order to guarantee the positioning of the sheets around the core and to ensure the tightness of the assembly, as illustrated in FIG. 1d.

(16) An isostatic pressing step is then carried out, during which the sheets and the core are heated to a temperature of the order of 800° C. to 1000° C. and compacted by an external pressure so as to join the sheets together by diffusion welding, to shape them around the core and thus to form the part 2, as illustrated in FIG. 1e, comprising an internal cavity with the exact geometry of the core.

(17) After hot isostatic pressing, the part 2 formed is obtained by removing the core. In an embodiment, an additional machining step can be performed, such as machining the leading edges in the case of a turbomachine blade.

(18) Preferentially, the machining step is carried out with the core 1 in the cavity of the part 2, as illustrated in FIG. 1f. This makes it possible to stiffen the assembly, in particular avoiding deformation of the part 2 under the machining forces, and to have integrated dimensional references, thus avoiding the need for complex machining tools.

(19) The core 1 is then removed, as illustrated in FIG. 1g, and can be reused in a production operation for another part 2. This greatly reduces the unit cost of manufacturing a part 2.

(20) In an embodiment, the first component comprises an yttrium oxide and optionally another oxide selected from one or a plurality of metal oxide powders, which may for example comprise an oxide or combination of oxides selected from: titanium oxide (TiO2), molybdenum oxide (MoO3), cerium oxide (CeO2), tin oxide (SnO2), zinc oxide (ZnO), cobalt oxide (Co2O3), alumina (Al2O3), mullite (3 Al2O3+2 SiO2), silica (SiO)

(21) In an embodiment, the first component comprises in particular one or a combination of transition metal oxides.

(22) In a preferential embodiment, the first component comprises yttrium oxide (Y2O3) powder. This makes it possible, in particular when the part 2 comprises titanium or a titanium alloy, to very greatly limit or even avoid contamination of the titanium during a thermal cycle according to the process.

(23) In an embodiment, the part 2 is made of a titanium alloy. FIG. 2 shows the free enthalpies of formation of various oxides. In this configuration, yttrium oxide appears to be the best candidate among the oxides shown, exhibiting a free enthalpy of formation much lower than the free enthalpy of formation of titanium oxide. Titanium being the main chemical element of the part 2, yttrium oxide will be inert towards titanium.

(24) In an embodiment, the second component comprises an inorganic colloid in an aqueous medium.

(25) “Colloid” is understood to mean a suspension of one or more substances, regularly dispersed in another substance, forming a system with two separate phases. In a fluid, it forms a homogeneous dispersion of particles whose dimensions range from nanometer to micrometer. These particles are therefore the size of a nanoparticle, although they are not specifically considered as such.

(26) Advantageously, the second component comprises a lanthanide colloid, for example one or a combination of colloids selected from an yttrium colloid, a titanium colloid (basic or acidic) and a cerium colloid.

(27) In a preferential embodiment, the part 2 is made of a titanium alloy, and the second component comprises a cerium colloid. This greatly limits or even prevents any contamination of the part 2 by cerium.

(28) In an embodiment, the solution used for coating thus comprises: An yttrium oxide (Y2O3) filler in powder form, A cerium colloid (CeO2) binder, Water.

(29) In an embodiment, the coating is deposited in two passes, the deposition process comprising: a first coating step during which a first solution comprising the first component is deposited on the core 1, a first step of heating the core 1, a second coating step during which a second solution comprising the second component is deposited on the core 1, and a second heating step.

(30) Optionally, the first solution comprises a mass proportion of water comprised between 40% and 60%, and a mass proportion of metal oxide comprised between 40% and 60%, preferentially a mass proportion of water comprised between 50% and 55%, and a mass proportion of metal oxide comprised between 45% and 50%, for example a mass proportion of water of 53% and a mass proportion of yttrium oxide (Y2O3) of 47%.

(31) Optionally, the second solution comprises a cerium colloid (CeO2).

(32) Advantageously, the first heating step is carried out at a temperature comprised between 40° C. and 120° C. for a period comprised between 15 minutes and 60 minutes, preferentially at a temperature comprised between 70° C. and 90° C. for a period comprised between 25 minutes and 35 minutes, for example at a temperature of 80° C. for a period of 30 minutes.

(33) Optionally, the second heating step is carried out at a temperature comprised between 40° C. and 120° C. for a period comprised between 15 minutes and 60 minutes, preferentially at a temperature comprised between 70° C. and 90° C. for a period comprised between 25 minutes and 35 minutes, for example at a temperature of 80° C. for a period of 30 minutes.

(34) Advantageously, the coating has a thickness comprised between 10 μm and 30 μm, for example 20 μm. This effectively isolates the core 1 from the part 2, by presenting a thickness that resists any wear or scratches that may occur during the operations of removing the core 1 when the part 2 is formed. Such a thickness also makes it possible to avoid modifying the dimensions of the core 1, and therefore of the cavity formed, too significantly.