USING A POLYOL MIXTURE COMPRISING PBD FOR CREATING A PU-BASED ARTIFICIAL TURF
20230016648 · 2023-01-19
Assignee
- Advanced Polymer Technologies Corp. (Harmony, PA, US)
- Synthetic Turf Resources Corp. (Dalton, GA, US)
Inventors
- Stephan SICK (Willich-Neersen, DE)
- Frank LUCARELLI (Zelienople, PA, US)
- Axel HINRICHS (Acworth, GA, US)
- Andreas SCHULZE-ISING (Sewickley, PA, US)
- Matthew Lee HENSON (Acworth, GA, US)
- Erin Anderson TIDWELL (Caulhoun, GA, US)
Cpc classification
C08G18/7671
CHEMISTRY; METALLURGY
C08G18/4063
CHEMISTRY; METALLURGY
Y10T428/23986
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
C08G18/6208
CHEMISTRY; METALLURGY
Y10T428/23993
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
C08G18/42
CHEMISTRY; METALLURGY
B05D1/26
PERFORMING OPERATIONS; TRANSPORTING
E01C13/08
FIXED CONSTRUCTIONS
D06N7/00
TEXTILES; PAPER
Y10T428/23979
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
International classification
E01C13/08
FIXED CONSTRUCTIONS
B05D1/26
PERFORMING OPERATIONS; TRANSPORTING
C08G18/42
CHEMISTRY; METALLURGY
C08G18/62
CHEMISTRY; METALLURGY
Abstract
A method of manufacturing an artificial turf includes creating fluid polyurethane mass. The creation including reacting first and second polyols with an isocyanate. The first polyol is a polyether polyol and/or a polyester polyol having at least 2 hydroxyl groups per molecule, the second polyol being polybutadien diol. The isocyanate including isocyanate monomers, isocyanate polymers or isocyanate prepolymers or a mixture thereof, the isocyanate monomers, isocyanate polymers and the isocyanate prepolymers having two or more isocyanate groups per molecule. The method further includes incorporating an artificial turf fiber into a carrier such that a first portion of the fiber protrudes to the front side of the carrier and that a second portion of the fiber is located at the back side of the carrier, adding the fluid polyurethane mass on the back side of the carrier, and hardening the fluid polyurethane mass.
Claims
1. (canceled)
2. An artificial turf, comprising: a polyurethane backing, the polyurethane being a reaction product of first and second polyols with an isocyanate, the first polyol being polyether polyol and/or polyester polyol having at least 2 hydroxyl groups per molecule, the second polyol being polybutadiene diol, the isocyanate comprising isocyanate monomers, isocyanate polymers or isocyanate prepolymers or a mixture thereof, the isocyanate monomers, the isocyanate polymers and the isocyanate prepolymers having two or more isocyanate groups per molecule; a carrier; and an artificial turf fiber incorporated into the carrier such that a first portion of the artificial turf fiber protrudes to a front side of the carrier and a second portion of the artificial turf fiber is located at a back side of the carrier, at least the second portion of the artificial turf fiber being incorporated into the polyurethane backing.
3. The artificial turf of claim 2, wherein the polyurethane backing is only on the back side of the carrier and only the second portion of the artificial turf fiber is incorporated into the polyurethane backing.
4. The artificial turf of claim 3, wherein the carrier is configured to prevent the polyurethane backing from penetrating and transgressing the carrier.
5. The artificial turf of claim 3, wherein the carrier is a closed mesh carrier.
6. The artificial turf of claim 2, wherein the polyurethane backing is formed from a non-foamed liquid polyurethane mass, the non-foamed liquid polyurethane mass being the reaction product of the first and second polyols with the isocyanate.
7. The artificial turf of claim 6, wherein the artificial turf is manufactured based on: creating the non-foamed liquid polyurethane mass, the creating including reacting the first and second polyols with the isocyanate; incorporating the artificial turf fiber into the carrier such that the first portion of the artificial turf fiber protrudes to the front side of the carrier and that the second portion of the artificial turf fiber is located at the back side of the carrier; adding the non-foamed liquid polyurethane mass on the back side of the carrier, the non-foamed liquid polyurethane mass thereby incorporating the second portion of the artificial turf fiber; and hardening the non-foamed liquid polyurethane mass on the back side of the carrier.
8. The artificial turf of claim 6, wherein the non-foamed liquid polyurethane mass has a density of more than 1000 g/l.
9. The artificial turf of claim 3, wherein the polybutadiene diol has an amount of 4.0-8.0% by weight of a combination of the first polyol and the isocyanate.
10. A method of manufacturing an artificial turf, the method comprising: creating a fluid polyurethane mass, the creating comprising reacting first and second polyols with an isocyanate, the first polyol being a polyether polyol and/or a polyester polyol having at least 2 hydroxyl groups per molecule, the second polyol being polybutadiene diol, the isocyanate comprising isocyanate monomers, isocyanate polymers or isocyanate prepolymers or a mixture thereof, the isocyanate monomers, the isocyanate polymers and the isocyanate prepolymers having two or more isocyanate groups per molecule; incorporating an artificial turf fiber into a carrier such that a first portion of the artificial turf fiber protrudes to a front side of the carrier and that a second portion of the artificial turf fiber is located at a back side of the carrier; adding the fluid polyurethane mass on the back side of the carrier, the fluid polyurethane mass thereby incorporating the second portion of the artificial turf fiber; and hardening the fluid polyurethane mass on the back side of the carrier.
11. The method of claim 10, the polybutadiene diol having an amount of 4.0-8.0% by weight of a combination of the first polyol and the isocyanate.
12. The method of claim 10, wherein the carrier is configured to prevent the fluid polyurethane mass from penetrating and transgressing the carrier when the fluid polyurethane mass is added on the back side of the carrier.
13. The method of claim 12, wherein the carrier is a closed mesh carrier.
14. The method of claim 10, wherein the fluid polyurethane mass is formed from a non-foamed liquid polyurethane mass, the non-foamed liquid polyurethane mass being a product of the first and second polyols reacting with the isocyanate.
15. The method claim 10, wherein incorporating the artificial turf fiber into the carrier comprises: tufting the artificial turf fiber into the carrier; or weaving the artificial turf fiber into the carrier.
16. The method of claim 10, the hardening of the fluid polyurethane mass comprising: heating the fluid polyurethane mass on the back side of the carrier to a temperature of 70-140° C.
17. The method of claim 10, further comprising generating the artificial turf fiber, the generation comprising: generating a polymer mixture; extruding the polymer mixture into a monofilament; quenching the monofilament; reheating the monofilament; and stretching the reheated monofilament to form the monofilament into the artificial turf fiber.
18. An artificial turf manufactured according to the method of claim 10.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0105] In the following embodiments of the invention are explained in greater detail, by way of example only, making reference to the drawings in which:
[0106]
[0107]
[0108]
[0109]
[0110]
[0111]
DETAILED DESCRIPTION
[0112] Like numbered elements in these figures are either equivalent elements or perform the same function. Elements which have been discussed previously will not necessarily be discussed in later figures if the function is equivalent.
[0113]
[0114] Polyether polyols are made by reacting epoxides like ethylene oxide or propylene oxide with the multifunctional initiator in the presence of a catalyst, often a strong base such as potassium hydroxide or a double metal cyanide catalyst such as zinc hexacyanocobaltate-t-butanol complex. Common polyether polyols are polyethylene glycol, polypropylene glycol, and poly(tetramethylene ether) glycol.
[0115] Polyesters are formed by condensation or step-growth polymerization of polyols and dicarboxylic acids (or their derivatives), for example diethylene glycol reacting with phthalic acid. Alternatively, the hydroxyl group and the carboxylic acid (or their derivatives) may be within the same molecule, as in the case of caprolactone. Polyether polyols and/or polyester polyols can be bought ready-made from various suppliers.
[0116] The isocyanate comprises isocyanate monomers, isocyanate polymers or isocyanate prepolymers or a mixture of isocyanate monomers, isocyanate polymers and isocyanate prepolymers. The isocyanate monomers, polymers and prepolymers have two or more isocyanate groups per molecule.
[0117] For example, the isocyanate can be methylene diphenyl diisocyanate (“MDI”). MDI is an aromatic diisocyanate. It exists in three isomers, 2,2′-MDI, 2,4′-MDI, and 4,4′-MDI. Embodiments of the invention may be based on any of said isomers, preferentially the 4,4′ isomer is used as the isocyanate. MDI reacts with the polyols (i.e., with the PBD and the polyether polyol or the polyester polyol) in the manufacture of the PU mass.
[0118] In step 104, one or more turf fibers are incorporated into a carrier, e.g. a textile or other material comprising perforations. For example, the incorporation may comprise weaving, spinning, twisting, rewinding, and/or bundling the a monofilament, e.g. a stretched monofilament, into the artificial turf fiber and then incorporating the fiber into the carrier. This technique of manufacturing artificial turf is known e.g. from United States patent application US 20120125474 A1.
[0119] In step 106, the liquid PU mass generated in step 102 is added on the backside of the backside of the carrier (see e.g.
[0120] In step 108, the liquid PU mass solidifies into a solid PU-based artificial turf backing that strongly fixes hydrophobic fibers without the need to create chemical bonds between the PU backing and the fiber material. For example, the PU mass on the backside of the carrier may be hardened at room temperature or in an oven.
[0121]
[0122] A first mixing unit is used for creating a first mixture comprising the polyether polyol or the polyester polyol (but not the hydrogenated PBD). For example, the first mixture comprises a polyether-polyol, e.g. a polyether-polyol having a number average molecular weight of about 4000 g/mol, e.g. a polyol based on polymerized propyleneoxide. The polyether polyol may be obtained e.g. in the form of a ready-made polyol.
[0123] Optionally, the first mixture comprises filler materials. Adding a filler may reduce cost and/or help to achieve a particular look or weight. Fillers can be, for example selected from the group ground limestone, precipitated calcium carbonate, china clay, cold fly ash, silicates and other inert material including non-reactive liquids. Moreover fillers with flame retardant and/or intumescent efficiency like aluminium trihydroxide or ammonium polyphosphate can be used or mixtures of the aforementioned fillers.
[0124] Moreover, the first mixture may comprise a catalyst for boosting the polyaddition reaction that generates the PU. The catalyst can be, for example, amine compounds and metal-organo complexes. Traditional amine catalysts have been tertiary amines such as triethylenediamine (TEDA, 1,4-diazabicyclo[2.2.2]octane or DABCO), dimethylcyclohexylamine (DMCHA), and dimethylethanolamine (DMEA).
[0125] Metal-organo complexes used as polyurethane catalysts can be based e.g. on mercury (e.g. mercury carboxylates), lead, tin (e.g. alkyl tin carboxylates and oxides), bismuth, and zinc (e.g. bismuth and zinc carboxylates).
[0126] The first mixture is then stored in a first tank 202, e.g. a day tank, i.e., a tank sized to provide a day's worth of usage.
[0127] The second mixture, i.e., the isocyanate monomer/polymer/prepolymers mixture, e.g. MDI, is stored in a second tank 204 that is preferentially also a day tank.
[0128] A further container 206 that is typically of a smaller size than the first and second tank comprises a third substance mixture. The third substance mixture comprises the PBD and optionally further substances such as a wetting agent, pale oil and/or one or more further additives. The one or more further additives can be, for example, flame retardants, pigments, extenders, cross linkers, blowing agents etc. The container 206 may be part of or coupled to a blender 208. The blender 208 receives the first mixture from the first container, receives the second mixture from the second container 204 and receives the PBD and the one or more optional substances (wetting agent, pale oil and/or further additives) from the further container 206. The blender 208 blends the first, second and third mixtures received from respective tanks and containers in amounts suited to generate a reaction mixture 210 whose substance concentrations are within the ranges specified herein for embodiments of the invention. For example, the first, second and third mixtures are blended such that the number of OH groups in the first polyol molecules in the first mixture in combination with the number of OH groups in the PBD molecules in the third mixture will roughly correspond (e.g. in a range of ratios ranging from “0.9:1” to “1:0.9”) to the number of NCO groups in the isocyanate molecules (monomers and prepolymers). The third mixture is added by the blender 208 to the reaction mixture 210 in such an amount that the PBD in the reaction mixture has a concentration range of 0.5-5% by weight of a combination of the first polyol and the isocyanate.
[0129] An example of a third mixture is given below:
TABLE-US-00001 % by weight of the third Description mixture in container 206 Hydrogenated 56% hydroxyl-terminated polybutadien (PBD): Conductivity additive & 16% pigments Pale oil 28%
[0130] The third mixture will be blended with the first and second mixture such that the PBD is contained in the reaction mixture/liquid PU mass in an amount of 0.5-5% of a combination of the first polyol and the isocyanate.
[0131] According to embodiments, the first and second mixtures in the first and second tanks are supplied as “two pack systems” or “two component systems” wherein the polyol part acts as the first mixture in the first tank and the polyisocyanates part acts as the second mixture in the second tank. While the first and second mixtures may be bought as ready-made two-component PU-generation systems, the third mixture in container 206 may be customized to specific needs of a customer, e.g. by adding a certain pigment to achieve a desired coloring effect or by adding a certain amount of PBD and/or oil and wetting agent in order to achieve a desired viscosity given a desired PU-density.
[0132] The blender 208 may be a low-pressure gear pump, which produce a desired mixing ration of the first, second and third mixtures. Ratio and material distribution are driven by a computer assisted equipment. Despite the viscosity of the PU mass 210, the PU mass penetrates deeply into the tufts of artificial grass, and wets the textile carrier and the monofilaments contained therein.
[0133] The reaction mixture 210 generated by the blender 208 is output to a container 212 that may have the form of a hose. The chamber 212 has an opening 214 that leads to a coater, e.g. a “knife over roll” coating assembly as depicted, for example, in
[0134] According to embodiments, the first polyol(s), the PBD and the isocyanate in total constitute at least 25%, according to other embodiments at least 40%, or even more than 95% of the total amount of the total reaction mix used for generating the liquid PU mass that—after a curing process—is used as the artificial turf backing. This means that the totality of fillers, wetting agents, pale oils and any further additives (e.g. extenders, cross linkers, surfactants, flame retardants, blowing agents, pigments, and so on) typically constitutes less than 75%, or less than 60%, or in further embodiments less than 5% by weight of the reaction mix used for generating the PU. An example would be a reaction mixture comprising about 20% isocyanate, 4% PBD, 20% first polyol, 2% catalyst, 3% additives like oils, dyes or flame retardants, and 51% filler material. In some example embodiments the reaction mixture does not comprise any filler material.
[0135] According to preferred embodiments, the liquid PU mass is a non-foam polyurethane, i.e., a PU that is (substantially) non-porous.
[0136] Polyols or polyhydroxylated compounds are known to absorb water and generally are the source for the introduction of water into the formulation. Moisture is introduced either in the polyhydroxylated compound or in some other ingredient, and this moisture can react with the isocyanate to produce urea linkages and carbon dioxide. The urea linkages are strong and desirable; however, the carbon dioxide causes bubbles to appear in the product. In many cases, the presence of bubbles in the product weakens the structure of the PU backing. Therefore, according to embodiments of the invention, the reaction conditions and educts are chosen such that a non-foamed liquid PU mass 210 is generated. The generation of “non-foamed” liquid PU masses is described, for example, in “Polyurethanes: Science, Technology, Markets, and Trends”, Mark F. Sonnenschein, ISBN: 978-1-118-73791-0.
[0137]
[0138] According to preferred embodiments, the liquid PU mass is a non-foam polyurethane, i.e., a PU that is (substantially) non-porous.
[0139] The high viscosity of the PU mass according to embodiments of the invention and the configuration and dimensions of the opening 214 and the speed of the PU mass flow through this opening are chosen such that a defined amount of PU mass builds up and accumulates in front of the front side of the knife 304. This ensures that the thickness of the PU backing of the generated piece of artificial turf is constant.
[0140] After the PU mass 210 was homogeneously applied on the back side of the carrier 308, it is hardened (increase of viscosity) by keeping the coated piece of artificial turf for about 10 minutes at room temperature. Typically, the PU backing is solid 30 minutes after its application on the carrier.
[0141] Preferentially, in order to sped up the solidification, the artificial turf is exposed to elevated temperatures around 100° C. Typically, after 90 seconds at elevated temperature, 90 to 95% of the PU mass is “cured” (is in solid state). For example, the coating assembly may automatically transport the coated piece of artificial turf in an oven.
[0142]
[0143] Thus, the monofilament is produced by feeding the polymer mixture 400 into an fiber producing extrusion line. The melt mixture is passing the extrusion tool, i.e., a spinneret plate or a wide slot nozzle, forming the melt flow into a filament or tape form, is quenched or cooled in a water spin bath, dried and stretched by passing rotating heated godets with different rotational speed and/or a heating oven. The monofilament or fiber may later be annealed online in a second step passing a further heating oven and/or set of heated godets.
[0144] According to embodiments, manufacturing an artificial turf fiber (which may comprise one or more monofilaments 412) comprises forming the stretched monofilament into a yarn. Multiple, for example 4 to 8 monofilaments, could be formed or finished into a yarn.
[0145] According to embodiments, the extrusion is performed at a pressure of 40-140 bars, more preferentially between 60-100 bars. The polymer mixture may be created by adding polymer granules to a solid polymer composition that is mixed and heated until all polymers are molten. For example, the polymer mixture may be heated to reach at the time of extrusion a temperature of 190-260° C., more preferentially 210-250° C.
[0146] According to embodiments, the stretching comprises stretching the reheated monofilament according to a stretch factor in the range of 1.1-8, more preferentially in the range of 3-7.
[0147] According to embodiments, the quenching is performed in a quenching solution having a temperature of 10-60° C., more preferentially between 25° C.-45° C.
[0148] According to embodiments, the incorporation of the artificial turf fiber into the carrier comprises tufting or weaving the artificial turf fiber into the carrier.
[0149] According to embodiments, the quenching solution, e.g. a water bath, has a temperature (right after the extrusion nozzle or hole(s)) of 10-60° C., more preferentially between 25° C.-45° C., and even more preferentially between 32° C.-40° C.
[0150] According to embodiments, the extrusion is performed at a pressure of 80 bar, the polymer mixture at time of extrusion has a temperature of 230° C., the stretch factor is 5 and the quenching solution, e.g. a water bath, has a temperature of 35° C.
[0151]
[0152] A “monofilament” as used herein is a filament generated by extruding a liquid polymer mixture through a single opening or is a slice of a polymer tape generated in accordance with the slit film technique.
[0153] After the inserting is done, as depicted in
[0154]
[0155]
[0156]
[0157]
[0158] The liquid PU mass 210 added in the coating process on the backside of the carrier surrounds and thereby mechanically fixes at least some portions of the monofilaments of the arranged artificial turf fibers. Then, the liquid PU mixture 210 solidifies into a PU-based artificial turf backing 210′ at room temperature or in an oven. The solid film acts as the artificial turf backing. In some examples, additional coating layers may be added on the bottom of the artificial turf backing.
LIST OF REFERENCE NUMERALS
[0159] 102-104 steps [0160] 202 first tank for first mixture [0161] 204 second tank for second mixture [0162] 206 container for third mixture [0163] 208 blender [0164] 210 PU mass [0165] 210′ solidified PU mass [0166] 212 hose of coating assembly [0167] 214 opening of hose [0168] 302 fibers protruding from carrier [0169] 304 knife [0170] 306 roll [0171] 308 carrier, e.g. textile mesh [0172] 400 polymer mixture for fiber creation [0173] 402 hydrophobic fiber polymer [0174] 404 additive [0175] 406 additive [0176] 408 plate [0177] 410 opening of extrusion nozzle [0178] 412 extruded monofilament [0179] 501 artificial turf fiber [0180] 502 cutting operation [0181] 503 fiber loop [0182] 504 fiber portion within carrier [0183] 506 fiber portion protruding to the back side of the carrier [0184] 600 artificial turf [0185] 602 fiber portion protruding to the front side of the carrier being embedded in the PU mass [0186] 604 fiber portion protruding to the front side of the carrier not being embedded in the PU mass