Process for the production of thermoplastic moulding compounds

Abstract

The invention relates to a process for the production of thermoplastic moulding compounds, in particular ABS, wherein at least a first reagent (11) and a second reagent (12) of the thermoplastic moulding compounds are fed to a gear pump (10) which comprises a housing and at least a first gear wheel that is rotatable relative to the housing about a first axis, and a second gear wheel that is rotatable relative to the housing about a second axis, wherein a loop conduit (29) is provided, and wherein the reagents (11, 12) are pressed in a loop through the loop conduit (29) and passing the gear wheels, whereby the reagents (11, 12) are dispersed to form a dispersion (15) in the gear pump (10). The invention also relates to a thermoplastic moulding compound that is produced by the inventive process.

Claims

1. A process for the production of acrylonitrile-butadiene-styrene (ABS), wherein: at least a first reagent (11) that contains or consists of styrene-acrylonitrile copolymer (SAN) and a second reagent (12) that contains or consists of poly-butadiene based rubber in the form of SAN grafted elastomer of the thermoplastic moulding compounds are fed to a gear pump (10) which comprises a housing and at least a first gear wheel that is rotatable relative to the housing about a first axis, and a second gear wheel that is rotatable relative to the housing about a second axis, wherein a loop conduit (29) is provided, wherein the cross sectional area of the loop conduit (29) is changeable by means of a loop valve (35) arranged at the loop conduit (29), and wherein the reagents (11, 12) are pressed in a loop through the loop conduit (29) and passing the gear wheels, whereby the reagents (11, 12) are dispersed to form a dispersion (15) in the gear pump (10).

2. The process according to claim 1, wherein the first reagent (11) styrene-acrylonitrile copolymer (SAN) is fed to the gear pump (10) in molten state.

3. The process according to claim 2, wherein the first reagent (11) styrene-acrylonitrile copolymer (SAN) is heated above melting temperature.

4. The process according to claim 1, wherein the second reagent (12) rubber is fed to the gear pump (10) as relatively fine powder having an average particle size of 10 to 1000 micrometer.

5. The process according to claim 1, wherein the second reagent (12) rubber is fed to the gear pump (10) in molten state.

6. The process according to claim 1, wherein at least one solvent is added to the reagents (11, 12).

7. The process according to claim 6, wherein the reagents (11, 12) and the at least one solvent are first mixed to form a pre-mix, and the pre-mix is fed to the gear pump (10).

8. The process according to claim 7, wherein the pre-mix is fed directly to the gear pump (10).

9. The process according to claim 7, wherein the pre-mix is stored temporarily and is later fed to the gear pump (10).

10. The process according to claim 1, wherein the dispersion (15) is processed further to form moulding compounds.

11. The process according to claim 1, wherein the reagents (11, 12) are pressed in loops through the loop conduit (29) from 10 times to 1000 times.

12. The process according to claim 1, wherein the first reagent (11) and the second reagent (12) are fed to a mixing vessel (50), and wherein within the mixing vessel (50) a premixing of the reagents (11, 12) proceeds to form a premix, and wherein the resultant premix is then fed through an incoming valve (65) to an inlet (42) of the gear pump (10), and wherein the reagents (11, 12) and the dispersion (15) are fed through the loop conduit (29) back to the mixing vessel (50), and wherein the loop conduit (29) connects an outlet (44) of the gear pump (10) to the mixing vessel (50).

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) In the drawings:

(2) FIG. 1 shows a schematic drawing of a first embodiment of a system for the production of moulding compounds, in particular ABS-compositions.

(3) FIG. 2 shows a schematic drawing of a second embodiment of a system for the production of moulding compounds.

(4) FIG. 3 shows a schematic drawing of a third embodiment of a system for the production of moulding compounds.

(5) In FIG. 1, a schematic drawing of a first embodiment of a system for the production of moulding compounds, in particular for the production of acrylonitrile-butadiene-styrene (ABS), is shown schematically. The system comprises a gear pump 10 that has an inlet 42 to which reagents 11, 12 can be fed.

(6) For the production of acrylonitrile-butadiene-styrene (ABS), in particular a first reagent 11 and a second reagent 12 are fed to the inlet 42 of the gear pump 10, wherein in particular the first reagent 11 is styrene-acrylonitrile-copolymer (SAN), and the second reagent 12 is rubber, e.g. polybutadiene-rubber.

(7) The second reagent 12 rubber is specifically a SAN grafted elastomer, with the elastomer preferably being a polybutadiene based rubber. Hence, the second reagent can be a SAN grafted rubber.

(8) Within the gear pump 10, the first reagent 11 and the second reagent 12 that are fed to the inlet 42 are dispersed to form a dispersion 15. The resultant dispersion 15 is then further processable to form moulding compounds, in particular to form acrylonitrile-butadiene-styrene (ABS).

(9) The gear pump 10 comprises a first gear wheel rotatable about a first axis and a second gear wheel rotatable about a second axis. The gear wheels have teeth that are in contact with each other, so that when one of the gear wheels rotates, the other gear wheel rotates, too. When rotating, the gear wheels rotate in opposite directions. The axes about that the gear wheels rotate are running parallel to one another. An electric motor is provided to drive one of the gear wheels.

(10) The gear pump 10 comprises a housing in which the gear wheels are arranged. At a first front end of the housing, there is an opening which forms the inlet 42 of the gear pump 10.An outlet 44 is formed by an opening at a second front end of the housing of the gear pump 10.

(11) The system further comprises a loop conduit 29. The loop conduit 29 connects the outlet 44 to the inlet 42. The loop conduit 29 can be arranged within the housing of the gear pump 10 or outside the housing of the gear pump 10.

(12) A loop valve 35 is arranged at the loop conduit 29. With the loop valve 35, the cross sectional area of the loop conduit 29 is changeable. With the loop valve 35, the loop conduit 29 also can be closed completely.

(13) Upstream of the inlet 42 of the gear pump 10, an incoming valve 65 is provided. When the incoming valve 65 is open, the reagents 11, 12 can be fed through the incoming valve 65 to the inlet 42 of the gear pump 10. Downstream of the outlet 44 of the gear pump 10, an outgoing valve 67 is provided.

(14) When the outgoing valve 67 is open, the resultant dispersion 15 can be fed through the outlet 44 of the gear pump 10 and the outgoing valve 67.

(15) Within a process for the production of moulding compounds, in particular for the production of acrylonitrile-butadiene-styrene (ABS), the first reagent 11 and the second reagent 12 are fed to the inlet 42 of the gear pump 10. The gear wheels forward the reagents 11, 12 from the inlet 42 to the outlet 44.

(16) While the outgoing valve 67 is closed and the incoming valve 65 is closed and the loop valve 35 is open, the reagents 11, 12 are pressed from the outlet 44 into the loop conduit 29. From the loop conduit 29 the reagents 11, 12 are then pressed back to the inlet 42.

(17) Within such a loop through the loop conduit 29 and passing the gear wheels, a partition of the reagents 11, 12 is dispersed to a dispersion 15. Within every new loop, some more of the reagents 11, 12 are dispersed to the dispersion 15. The resultant dispersion 15 also travels around within the loop conduit 29 and passing the gear wheels. Thereby, the resultant dispersion 15 is homogenized.

(18) After a certain number of loops within the loop conduit 29, the reagents 11, 12 are dispersed, at least almost, completely. That means, only the dispersion 15 that is also homogenized, then travels around within the loop conduit 29, forwarded by the gear wheels.

(19) Then, the outgoing valve 67 is opened and the loop valve 35 is closed, while the incoming valve 65 remains closed. The dispersion 15 is then pressed through the outlet 44 and through the outgoing valve 67.

(20) When the dispersion 15 has left the outgoing valve 67, the outgoing valve 67 is closed and the loop valve 35 is opened again. Then, the incoming valve 65 is opened. While the incoming valve 65 is open, the first reagent 11 and the second reagent 12 are fed to the inlet 42 of the gear pump 10, again, and the gear wheels forward the reagents 11, 12 from the inlet 42 to the outlet 44. When a sufficient amount of reagents 11, 12 is present within the loop conduit 29, the incoming valve 65 is closed.

(21) Within an alternative, continuous process for the production of moulding compounds, in particular for the production of acrylonitrile-butadiene-styrene (ABS), the incoming valve 65 and the outgoing valve 67 are open. The loop valve 35 is adjusted to a state in between of the closed state and the open state. The incoming valve 65, the outgoing valve 67 and the loop valve 35 remain in said positions during the production process. The first reagent 11 and the second reagent 12 are fed to the inlet 42 of the gear pump 10, and the gear wheels forward the reagents 11, 12 from the inlet 42 to the outlet 44.

(22) Within said alternative, continuous process, a partition of the reagents 11, 12 is dispersed to a dispersion 15 when passing the gear wheels. A part of the reagents 11, 12 and the dispersion 15 are pressed from the outlet 44 into the loop conduit 29 and back to the inlet 42. Said part of the reagents 11, 12 and the dispersion 15 hence travel around within the loop conduit 29 in a loop, whereby the reagents 11, 12 are dispersed to the dispersion 15 and the resultant dispersion 15 is homogenized. A part of the resultant dispersion 15 is pressed towards the outlet 44. By means of the position of the loop valve 35 defining the cross sectional area of the loop conduit 29, the ratio of reagents 11, 12 and dispersion 15 pressed through the outlet 44 towards the outgoing valve 67 can be adjusted.

(23) Subsequently, further processing, in particular dewatering, of the resultant dispersion 15 then takes place to give moulding compounds, in particular to provide acrylonitrile-butadiene-styrene copolymer compositions (ABS).

(24) In FIG. 2 a schematic drawing of a second embodiment of a system for the production of moulding compounds, in particular for the production of acrylonitrile-butadiene-styrene (ABS), is shown.

(25) The system further comprises a mixing vessel 50. The mixing vessel 50 has a beater 52 which is drivable by an electric motor 62. Downstream of the mixing vessel 50 and upstream of the inlet 42 of the gear pump 10 there is arranged the incoming valve 65. Downstream of the outlet 44 of the gear pump 10 there is arranged the outgoing valve 67. The system also comprises a loop conduit 29. The loop conduit 29 connects the outlet 44 to inlet 42.

(26) Within a process for the production of moulding compounds, in particular for the production of acrylonitrile-butadiene-styrene (ABS), using the system according to FIG. 2, the first reagent 11 and the second reagent 12 are fed to the mixing vessel 50. Additionally, a solvent, for example EB (ethylbenzene), can be added to the reagents 11, 12. Within the mixing vessel 50, by a rotation of the beater 52, a premixing of the reagents 11, 12 proceeds to form a premix. The resultant premix is then fed through the incoming valve 65 to the inlet 42 of the gear pump 10.

(27) Within the gear pump 10 and the loop conduit 29, the reagents 11, 12 are dispersed to the dispersion 15 within several loops, and thereby, the resultant dispersion 15 is homogenized, as described above. The resultant dispersion 15 is then delivered from outlet 44 of the gear pump 10 through the outgoing valve 67, as described above.

(28) Subsequently, further processing, in particular dewatering, of the resultant dispersion 15 then takes place to give moulding compounds, in particular to give acrylonitrile-butadiene-styrene (ABS), as described above.

(29) In FIG. 3 a schematic drawing of a third embodiment of a system for the production of moulding compounds, in particular for the production of acrylonitrile-butadiene-styrene (ABS), is shown.

(30) The system comprises a mixing vessel 50, like the second embodiment. The mixing vessel 50 has a beater 52 which is drivable by an electric motor 62. Downstream of the mixing vessel 50 and upstream of the inlet 42 of the gear pump 10 there is arranged the incoming valve 65. Downstream of the outlet 44 of the gear pump 10 there is arranged the outgoing valve 67. The system also comprises a loop conduit 29. The loop conduit 29 connects the outlet 44 to mixing vessel 50.

(31) Within a process for the production of moulding compounds, in particular for the production of acrylonitrile-butadiene-styrene (ABS), using the system according to FIG. 3, the first reagent 11 and the second reagent 12 are fed to the mixing vessel 50. Additionally, a solvent, for example EB (ethylbenzene), can be added to the reagents 11, 12. Within the mixing vessel 50, by a rotation of the beater 52, a premixing of the reagents 11, 12 proceeds to form a premix. The resultant premix is then fed through the incoming valve 65 to the inlet 42 of the gear pump 10.

(32) Within the gear pump 10, the reagents 11, 12 are partially dispersed to the dispersion 15. The reagents 11, 12 and the dispersion 15 are fed through the loop conduit 29 back to the mixing vessel 50. Within several loops, the reagents 11, 12 are dispersed to the dispersion 15, and the resultant dispersion 15 is homogenized, as described above. The resultant dispersion 15 is then delivered from outlet 44 of the gear pump 10 through the outgoing valve 67, as described above.

(33) Subsequently, further processing, in particular dewatering, of the resultant dispersion 15 then takes place to give moulding compounds, in particular to give ABS-compositions, as described above.

LIST OF REFERENCE SIGNS

(34) 10 gear pump 11 first reagent 12 second reagent 15 dispersion 29 loop conduit 35 loop valve 42 inlet 44 outlet 50 mixing vessel 52 beater 62 electric motor 65 incoming valve 67 outgoing valve