Fabrication of compound semiconductor structures
10529562 ยท 2020-01-07
Assignee
Inventors
- Daniele Caimi (BESENBUEREN, CH)
- Lukas Czornomaz (ZURICH, CH)
- Jean Fompeyrine (Waedenswil, CH)
- Emanuele Uccelli (Rueschlikon, CH)
Cpc classification
International classification
Abstract
A semiconductor substrate, comprising a first semiconductor material, is provided and an insulating layer is formed thereon; an opening is formed in the insulating layer. Thereby, a seed surface of the substrate is exposed. The opening has sidewalls and a bottom and the bottom corresponds to the seed surface of the substrate. A cavity structure is formed above the insulating layer, including the opening and a lateral growth channel extending laterally over the substrate. A matching array is grown on the seed surface of the substrate, including at least a first semiconductor matching structure comprising a second semiconductor material and a second semiconductor matching structure comprising a third semiconductor material. The compound semiconductor structure comprising a fourth semiconductor material is grown on a seed surface of the second matching structure. The first through fourth semiconductor materials are different from each other. Corresponding semiconductor structures are also included.
Claims
1. A method for fabricating a compound semiconductor structure, the method comprising: providing a semiconductor substrate comprising a first semiconductor material; forming an insulating layer on the semiconductor substrate; forming an opening in the insulating layer, thereby exposing a seed surface of the substrate, the opening having sidewalls and a bottom, wherein the bottom corresponds to the seed surface of the substrate; forming a cavity structure above the insulating layer, the cavity structure comprising the opening and a lateral growth channel extending laterally over the substrate; growing a matching array on the seed surface of the substrate, the matching array comprising at least a first matching structure comprising a second semiconductor material and a second matching structure comprising a third semiconductor material; growing the compound semiconductor structure comprising a fourth semiconductor material on a seed surface of the matching array; wherein the first, the second, the third and the fourth semiconductor material are different from each other; further comprising providing a geometrical constraint in the growth channel to reduce in plane crystalline defects, wherein the geometrical constraint is an in-plane necking of the growth channel in a plane of a top view of the semiconductor structure.
2. A method for fabricating a compound semiconductor structure, the method comprising: providing a semiconductor substrate comprising a first semiconductor material; forming an insulating layer on the semiconductor substrate; forming an opening in the insulating layer, thereby exposing a seed surface of the substrate, the opening having sidewalls and a bottom, wherein the bottom corresponds to the seed surface of the substrate; forming a cavity structure above the insulating layer, the cavity structure comprising the opening and a lateral growth channel extending laterally over the substrate; growing a matching array on the seed surface of the substrate, the matching array comprising at least a first matching structure comprising a second semiconductor material and a second matching structure comprising a third semiconductor material; growing the compound semiconductor structure comprising a fourth semiconductor material on a seed surface of the matching array; wherein the first, the second, the third and the fourth semiconductor material are different from each other; further comprising providing a geometrical constraint in the growth channel to reduce in plane crystalline defects, wherein the geometrical constraint is a change of the in-plane direction of the growth channel in a plane of a top view of the semiconductor structure.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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DETAILED DESCRIPTION
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(30) On the substrate 110 an insulating layer 111 is provided. The insulating layer 111 may be embodied e.g. as a dielectric layer. The insulating layer 111 can be formed by known methods, as for example thermal oxidation, chemical vapor deposition (CVD), plasma enhanced CVD (PECVD), atomic layer deposition, chemical solution deposition, MOCVD, evaporation, sputtering and other deposition processes. Examples of such dielectric material include, but are not limited to: SiO2, Si3N4, Al2O3, AlON, Ta2O5, TiO2, La2O3, SrTiO3, LaAlO3, ZrO2, Y2O3, Gd2O3, MgO, MgNO, Hf-based materials and combinations including multilayers thereof.
(31) The thicknesses of the substrate 110 and the insulating layer 111 can be any suitable thicknesses.
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(36) According to embodiments the material of the cavity layer 130 is selected to have a low sticking coefficient, and hence low nucleation probability, for the semiconductor material to be grown in the cavity structure.
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(43) The first matching structure 150 and the second matching structure 151 form a matching array.
(44) The seed surfaces 157 of the second semiconductor matching structure 151 form according to this embodiment a seed surface of the matching array.
(45) In general, the first, the second, the third and the fourth semiconductor material are different from each other.
(46) The growth of the first semiconductor matching structure, the second semiconductor matching structure and the compound semiconductor structure may be performed in particular by selective epitaxy in any suitable deposition system. For example, metal organic chemical vapor deposition (MOCVD), atmospheric pressure CVD, low or reduced pressure CVD, ultra-high vacuum CVD, molecular beam epitaxy (MBE) or atomic layer deposition (ALD) techniques can be employed.
(47) In general the first matching structure 150 and the second matching structure 151 are designed to solve a growth mismatch between the first and the fourth semiconductor material in a stepwise approach. For this, the first matching structure 150 may be embodied to provide a first matching level between the first semiconductor material of the substrate 110 and the second semiconductor material of the first matching structure 150. Furthermore, the second matching structure 150 may be embodied to provide a second matching level between the second semiconductor material of the first matching structure 150 and the third semiconductor material of the second matching structure 151. Finally the compound semiconductor structure 152 may be embodied to provide a third matching level between the third semiconductor material of the second matching structure 151 and the fourth semiconductor material of the compound semiconductor structure 153. The first, the second and the third matching level can be used to address a plurality of matching parameters in a sequential way.
(48) According to an embodiment the matching levels may be defined by matching parameters. According to a preferred embodiment the first, the second and the third matching level may be defined by three matching parameters. As first matching parameter a lattice match of the lattice constants of two adjacent materials may be used. As second matching parameter a structural match of the crystal structure of two adjacent materials may be used. Finally, as third matching parameter a chemical similarity match may be used.
(49) According to embodiments of the invention chemical similarity refers to the similarity of semiconductor materials with respect to a predefined set of functional qualities of the semiconductor materials. The predefined set of functional qualities may comprise in particular the interdiffusion characteristics of two adjacent semiconductor materials. In this respect according to embodiments of the invention two semiconductor materials are considered chemically similar if there is no or hardly any diffusion between the two semiconductor materials. Interdiffusion may refer in particular to the dopant characteristics of two semiconductor materials. Hence according to embodiments of the invention two semiconductor materials are considered chemically similar if they are not dopants to each other. Furthermore, according to embodiments group III-V compound semiconductor materials may generally be considered chemically similar to each other, while group III-V compound semiconductor materials may be considered chemically non similar to group IV materials.
(50) According to embodiments of the invention two semiconductor materials are considered as lattice matched if the difference between the lattice constants is less than 25 pm, preferably less 10 pm, more preferably less than 5 pm and most preferably less than 3 pm.
(51) According to embodiments of the invention two semiconductor materials are considered as structurally matched if they have the same crystal structure, e.g. if they both have a diamond crystal structure or both a zinc blende crystal structure.
(52) In order to gradually adapt the matching level, the third matching level may be higher than the second matching level and the second matching level may be higher than the first matching level. According to embodiments the first, the second and the third matching level may provide an improved match in at least one of the three matching parameters.
(53) In the following a preferred embodiment will be explained in more detail. According to this embodiment the first semiconductor material of the substrate 110 is silicon and the second semiconductor material of the adjacent first matching structure 150 is GaP. This combination SiGaP provides a match in one of the three matching parameters described above, namely a match in the lattice constant. Si has a lattice constant of 0.543 nm at 300 K and GaP a lattice constant of 0.545 at 300 K. Hence the difference in the lattice constant is only in the order of 2 pm which can be considered as a lattice match as explained above. Si has a diamond cubic crystal structure while GaP has a zinc blende crystal structure. Accordingly both are mismatched concerning the second lattice parameter. Also chemically they are different, in particular in view of their interdiffusion characteristics. More particularly, GaP is a dopant to Si and hence Ga and P atoms diffuse into the Si. Hence the third matching parameter concerning chemical similarity is also no match.
(54) According to this embodiment the third semiconductor material of the second matching structure is InP. The combination GaP-InP provides a match in two of the three matching parameters described above, namely a structural match in the crystal structure and a chemical similarity match. InP has a lattice constant of 0.587 nm at 300 K which differs from the lattice constant 0.545 of GaP by 32 pm which is above the highest threshold of 25 pm as defined above. Hence this may be considered as a lattice mismatch. Both GaP and InP have a zinc blende crystal structure, hence there is a structural match and accordingly a match in the second matching parameter. Finally InP and GaP are chemically similar and hence there is a match in the third matching parameter. More particularly, both are III-V compound binary materials and are non-dopant to each other.
(55) Finally the fourth semiconductor material of the compound semiconductor structure is InGaAs. InGaAs has a lattice constant of 0.587 nm at 300 K and is hence lattice matched to InP. Furthermore, InGaAs has a zinc blende crystal structure and is hence structurally matched to InP. Finally, InGaAs is chemically similar to InP. The latter is based on the fact that InP and InGaAs are both III-V compound materials and non-dopant to each other.
(56) Hence there is a match in all three matching parameters.
(57) According to another preferred embodiment the first semiconductor material of the substrate is Si, the second semiconductor materials is Ge, the third semiconductor material is GaAs and the fourth semiconductor material is InGaAs.
(58) According to this embodiment the first matching level provides a structural match as Si and Ge both have a diamond crystal structure. The lattice constant of Ge is 0.566 nm at 300 K and hence differs from the lattice constant 0.543 by 0.23 pm. This is still lower than the highest threshold of 0.25 pm as mentioned above. Hence according to some embodiment this may be considered as a lattice match while according to other embodiment this may be considered as a lattice mismatch. Finally, Si and Ge may be considered chemically similar. Hence according to this embodiment the first matching level provides a match in two or three of the matching parameters depending on the threshold chosen for a lattice match. The second matching level provides a structural mismatch as GaAs has a zinc blende structure. GaAs has a lattice constant of 0.565 nm at 300 K and hence there is an excellent lattice match between Ge and GaAs. Chemically Ge and GaAs may be considered non similar as Ga and As are dopants for Ge. Hence the second matching level provides a match in one matching parameter. But importantly it provides an excellent match in the parameter that was different or a moderate match respectively in the first matching level, namely the lattice constant. In this respect, the second matching level provides an improved match in the first matching parameter, namely in the lattice constant. Finally the third matching level provides a structural match as InGaAs and GaAs have both a zinc blende structure. Furthermore, they may be considered chemically similar as they are non-dopants to each other. The lattice constants (0.565 vs. 0.587) differ by app. 22 pm. This is still lower than the highest threshold of 25 pm according to the definition provided above and can hence be still considered as a lattice match according to embodiments of the invention. But importantly the difference in lattice constants between InGaAs and GaP (22 pm) is significantly lower than the initial difference of 44 pm between Si and InGaAs.
(59) According to another preferred embodiment the first semiconductor material of the substrate is Si, the second semiconductor materials is GaSb, the third semiconductor material is GaAsSb and the fourth semiconductor material is InGaAs.
(60) According to this embodiment the first matching level provides a structural mismatch as Si has a diamond crystal structure while GaSb has a zinc blende structure. The lattice constant of GaSb is with 0.609 mismatched to the lattice constant 0.54 of Si. In addition, Si and GaSb may be considered chemically non similar as Ga and Sb are dopants for Si. Hence according to this embodiment the first matching level provides no match in the three above mentioned matching parameters. However, the lattice constant of GaSb differs substantially less (0. 22 pm) from the target lattice constant of InGaAs than the lattice constant of the initial Si (44 pm). In this respect an improvement in the first lattice parameter has been made. The second matching level provides a structural match as GaSb and GaAsSb have both a zinc blende structure. The lattice constant of GaAsSb (0.587 nm at 300 K) differs to the constant 0.609 of GaSb by app. 22 pm. As this is still lower than the highest threshold of 25 pm according to the definition provided above it can hence be still considered as a lattice match according to embodiments of the invention. Chemically GaAsSb and GaSb may be considered similar to each other as they are non-dopants to each other. Hence the second matching level may be considered as providing already a match in three of the three matching parameters, wherein in particular the matching parameter lattice constant offers still room for improvement. Finally the third matching level provides a structural match as InGaAs and GaAsSb have both a zinc blende structure. Furthermore, they may be considered chemically similar as they are non-dopants to each other. In terms of lattice constants (0.587 for both) they provide an excellent match. Hence the third matching level also provides a match in three of the three matching parameters. Notably, the match of the first matching parameter lattice constant has improved over the second matching level and accordingly also the degree of matching has improved over the second level in view of the better match of the lattice constants.
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(78) The fin structure 2510 may be e.g. used to fabricate FIN FETs.
(79) The width w.sub.1 of the first compound semiconductor structures 2210 in the growth direction x (corresponding to the fins 2520) and the width w.sub.2 of the second compound semiconductor structures 2220 in the growth direction x can be controlled via the time of the epitaxial growth.
(80) The fourth and/or the fifth semiconductor materials of the compound semiconductor structures may be generally any material suitable for epitaxial growth. According to preferred embodiments the fourth and/or fifth semiconductor materials may be a group III-V compound semiconductor material. The group III-V material could be a binary material such, as for example, Gallium Arsenide (GaAs) or Gallium Antimonide (GaSb). The group III-V material could also be a tertiary material such as, for example, Indium Gallium Arsenide (InGaAs) or Indium Gallium Antimonide (InGaSb). According to other embodiments group II-VI semiconductor compounds, mixed II-VI compounds, and IV-VI compounds may be used. According to another preferred embodiment In.sub.xGa.sub.1-xAs where x=0 to 1 may be used. According to other embodiments further alloyed combinations of (In, Ga) and (As, Sb, P) may be used. Further examples include gallium aluminum arsenide (GaAlAs), indium phosphide (InP), cadmium sulfide (CdS), cadmium mercury telluride (CdHgTe), zinc selenide (ZnSe), zinc sulfur selenide (ZnSSe), lead selenide (PbSe), lead teluride (PbTe), lead sulfide selenide (PbSSe) and the like.
(81) According to embodiments the fourth and the fifth semiconductor material are chosen to be such to have a good etching selectivity to facilitate an efficient and reliable etching of the second compound semiconductor structures 2220. According to embodiments the first compound semiconductor structures 2210 comprises InGaAs as fourth semiconductor material and the second compound semiconductor structures 2220 comprise InP as fifth semiconductor material.
(82) While illustrative examples are given above, it will be appreciated that the basic fabrication steps described above can be used to produce semiconductor structures of other materials, shapes and sizes. Materials and processing techniques can be selected as appropriate for a given embodiment, and suitable choices will be readily apparent to those skilled in the art.
(83) While particular examples have been described above, numerous other embodiments can be envisaged. The seed surfaces for growing the semiconductor structures may be preferably crystalline seed surfaces, but may according to other embodiments also be provided by amorphous surfaces. If the seed has a well-defined crystalline orientation and if the crystal structure of the seed is a reasonable match to that of the growing crystal (for example a III-V compound semiconductor), the growing crystal can adapt this orientation. If the seed is amorphous or has an undefined crystal orientation, the growing crystal will be single crystalline but its crystal orientation will be random.
(84) By appropriate shaping of the sacrificial structure in fabrication processes embodying the invention, cavity structures and corresponding cavities can be formed with any desired shapes and cross-sectional dimensions. Furthermore, the cross-section may be varied along the length of the cavity structures if desired. For example, cavity structures can be formed with curves, bends, corners, junctions and branches.
(85) The disclosed semiconductor structures and circuits can be part of a semiconductor chip. The resulting integrated circuit chips can be distributed by the fabricator in raw wafer form (that is, as a single wafer that has multiple unpackaged chips), as a bare die, or in a packaged form. In the latter case the chip is mounted in a single chip package (such as a plastic carrier, with leads that are affixed to a motherboard or other higher level carrier) or in a multichip package (such as a ceramic carrier that has either or both surface interconnections or buried interconnections). In any case the chip may be integrated with other chips, discrete circuit elements, and/or other signal processing devices as part of either an intermediate product, such as a motherboard, or an end product. The end product can be any product that includes integrated circuit chips, ranging from toys and other low-end applications to advanced computer products having a display, a keyboard or other input devices, and a central processor.
(86) Embodiments of the present invention described and illustrated herein have been dedicated to use in semiconductor devices such as integrated circuits. However, embodiments of the present invention are not limited as such. Other embodiments of the present invention contemplate a temperature measurement device that could be a standalone device, such as one that is placed on the skin of a human and used to take temperature measurements of the human. As such, this type of device may be a relatively inexpensive and high volume type of device which is used once and then discarded. Also, other embodiments of the present invention contemplate a temperature measurement device that may be integrated into a process control system for various types of industry, for example, some type of manufacturing process in which it is desired to measure the temperature of a part being manufactured and/or of the machines utilized in the manufacture of the parts.
(87) The following definitions and abbreviations are to be used for the interpretation of the claims and the specification. As used herein, the terms comprises, comprising, includes, including, has, having, contains or containing, or any other variation thereof, are intended to cover a non-exclusive inclusion. For example, a composition, a mixture, process, method, article, or apparatus that comprises a list of elements is not necessarily limited to only those elements but can include other elements not expressly listed or inherent to such composition, mixture, process, method, article, or apparatus.
(88) As used herein, the articles a and an preceding an element or component are intended to be nonrestrictive regarding the number of instances (i.e., occurrences) of the element or component. Therefore, a or an should be read to include one or at least one, and the singular word form of the element or component also includes the plural unless the number is obviously meant to be singular.
(89) As used herein, the terms invention or present invention are non-limiting terms and not intended to refer to any single aspect of the particular invention but encompass all possible aspects as described in the specification and the claims.
(90) As used herein, the term about modifying the quantity of an ingredient, component, or reactant of the invention employed refers to variation in the numerical quantity that can occur, for example, through typical measuring and liquid handling procedures used for making concentrates or solutions. Furthermore, variation can occur from inadvertent error in measuring procedures, differences in the manufacture, source, or purity of the ingredients employed to make the compositions or carry out the methods, and the like. In one aspect, the term about means within 10% of the reported numerical value. In another aspect, the term about means within 5% of the reported numerical value. Yet, in another aspect, the term about means within 10, 9, 8, 7, 6, 5, 4, 3, 2, or 1% of the reported numerical value.
(91) The descriptions of the various embodiments of the present invention have been presented for purposes of illustration, but are not intended to be exhaustive or limited to the embodiments disclosed. Many modifications and variations will be apparent to those of ordinary skill in the art without departing from the scope and spirit of the described embodiments. The terminology used herein was chosen to best explain the principles of the embodiments, the practical application or technical improvement over technologies found in the marketplace, or to enable others of ordinary skill in the art to understand the embodiments disclosed herein.