Method for producing nanoheterostructured permanent magnet

Abstract

A method for producing a nanoheterostructured permanent magnet includes a first step of preparing a raw material solution by dissolving, in a solvent, (1) a block copolymer comprising polymer block components that are immiscible but linked to each other, (2) a first inorganic precursor which is one of a hard magnetic material precursor and a soft magnetic material precursor, and (3) a second inorganic precursor which is the other of the hard magnetic material precursor and the soft magnetic material precursor, and a second step including a phase-separation treatment for forming a nanophase-separated, a conversion treatment for converting the hard magnetic material precursor and the soft magnetic material precursor to a hard magnetic material and a soft magnetic material, respectively, and a removal treatment for removing the block copolymer from the nanophase-separated structure.

Claims

1. A method for producing a nanoheterostructured permanent magnet, comprising: a first step of preparing a raw material solution by dissolving, in a solvent, a block copolymer comprising at least a first polymer block component and a second polymer block component which are immiscible but linked to each other, a first inorganic precursor which is one of a hard magnetic material precursor and a soft magnetic material precursor, and a second inorganic precursor which is the other of the hard magnetic material precursor and the soft magnetic material precursor; and a second step including a phase-separation treatment for forming a nanophase-separated structure in which at least a first polymer phase comprising the first polymer block component with the first inorganic precursor introduced thereinto and a second polymer phase comprising the second polymer block component with the second inorganic precursor introduced thereinto are regularly arranged by self-assembly, a conversion treatment for converting the hard magnetic material precursor and the soft magnetic material precursor to a hard magnetic material and a soft magnetic material, respectively, and a removal treatment for removing the block copolymer from the nanophase-separated structure, to thereby obtain a nanoheterostructured permanent magnet comprising the hard magnetic material and the soft magnetic material.

2. The method for producing a nanoheterostructured permanent magnet according to claim 1, wherein a solubility parameter difference between the first inorganic precursor and the first polymer block component is 2 (cal/cm.sup.3).sup.1/2 or less, and a solubility parameter difference between the second inorganic precursor and the second polymer block component is 2 (cal/cm.sup.3).sup.1/2 or less.

3. The method for producing a nanoheterostructured permanent magnet according to claim 2, wherein a solubility parameter difference between the first polymer block component and the first inorganic precursor is smaller than a solubility parameter difference between the first polymer block component and the second inorganic precursor.

4. The method for producing a nanoheterostructured permanent magnet according to claim 2, wherein a solubility parameter difference between the second polymer block component and the second inorganic precursor is smaller than a solubility parameter difference between the second polymer block component and the first inorganic precursor.

5. The method for producing a nanoheterostructured permanent magnet according to claim 2, wherein the block copolymer comprises at least one first polymer block component and at least one second polymer block component which are linked to each other, the first polymer block component being selected from the group consisting of a polystyrene component, a polyisoprene component, and a polybutadiene component, the second polymer block component being selected from the group consisting of a poly(methyl methacrylate) component, a poly(ethylene oxide) component, a polyvinylpyridine component, and a poly(acrylic acid) component, the first inorganic precursor is at least one of organometallic compounds and organometalloidal compounds having at least one structure selected from the group consisting of a phenyl group, long hydrocarbon chains having 5 or more carbon atoms, a cyclooctatetraene ring, a cyclopentadienyl ring, and an amino group, and the second inorganic precursor is at least one selected from the group consisting of salts of metals or metalloids, metal- or metalloid-containing alkoxides having 1 to 4 carbon atoms, and metal or metalloid acetylacetonate complexes.

6. The method for producing a nanoheterostructured permanent magnet according claim 2, wherein a molecular weight of a polymer block component constituting a polymer phase into which the soft magnetic material precursor is introduced and a molecular weight ratio between the polymer block component constituting the polymer phase into which the soft magnetic material precursor is introduced and a polymer block component constituting a polymer phase into which the hard magnetic material precursor is introduced are adjusted such that a volume of part of a region comprising the soft magnetic material is controlled to 50% by volume or more of a total volume of the soft magnetic material, the part satisfying a condition that a distance from an interface with the hard magnetic material is 10 nm or less.

7. The method for producing a nanoheterostructured permanent magnet according to claim 1, wherein a solubility parameter difference between the first polymer block component and the first inorganic precursor is smaller than a solubility parameter difference between the first polymer block component and the second inorganic precursor.

8. The method for producing a nanoheterostructured permanent magnet according to claim 1, wherein a solubility parameter difference between the second polymer block component and the second inorganic precursor is smaller than a solubility parameter difference between the second polymer block component and the first inorganic precursor.

9. The method for producing a nanoheterostructured permanent magnet according to claim 1, wherein the block copolymer comprises at least one first polymer block component and at least one second polymer block component which are linked to each other, the first polymer block component being selected from the group consisting of a polystyrene component, a polyisoprene component, and a polybutadiene component, the second polymer block component being selected from the group consisting of a poly(methyl methacrylate) component, a poly(ethylene oxide) component, a polyvinylpyridine component, and a poly(acrylic acid) component, the first inorganic precursor is at least one of organometallic compounds and organometalloidal compounds having at least one structure selected from the group consisting of a phenyl group, long hydrocarbon chains having 5 or more carbon atoms, a cyclooctatetraene ring, a cyclopentadienyl ring, and an amino group, and the second inorganic precursor is at least one selected from the group consisting of salts of metals or metalloids, metal- or metalloid-containing alkoxides having 1 to 4 carbon atoms, and metal or metalloid acetylacetonate complexes.

10. The method for producing a nanoheterostructured permanent magnet according claim 1, wherein a molecular weight of a polymer block component constituting a polymer phase into which the soft magnetic material precursor is introduced and a molecular weight ratio between the polymer block component constituting the polymer phase into which the soft magnetic material precursor is introduced and a polymer block component constituting a polymer phase into which the hard magnetic material precursor is introduced are adjusted such that a volume of part of a region comprising the soft magnetic material is controlled to 50% by volume or more of a total volume of the soft magnetic material, the part satisfying a condition that a distance from an interface with the hard magnetic material is 10 nm or less.

Description

BRIEF DESCRIPTION OF DRAWINGS

(1) FIG. 1 is a schematic diagram illustrating nanophase-separated structures generated from A-B type block copolymers.

(2) FIG. 2 is a transmission electron microphotograph of a nanoheterostructured permanent magnet obtained in Example 1.

(3) FIG. 3 is a transmission electron microphotograph of a nanoheterostructured permanent magnet obtained in Example 2.

DESCRIPTION OF EMBODIMENTS

(4) Hereinafter, the present invention will be described in detail on the basis of preferred embodiments thereof.

(5) First, a nanoheterostructured permanent magnet of the present invention is described. The nanoheterostructured permanent magnet of the present invention comprises a hard magnetic material and a soft magnetic material of which one inorganic component is a matrix, and of which the other inorganic component is three-dimensionally and periodically arranged in the matrix, in a shape selected from the group consisting of a spherical shape, a columnar shape, and a gyroid shape, the nanoheterostructured permanent magnet having a three-dimensional periodic structure whose average value of one unit length of a repeated structure is 1 nm to 100 nm (more preferably 1 nm to 50 nm, and particularly preferably 1 to 30 nm).

(6) The nanoheterostructured permanent magnet of the present invention has a structure that has not been formed by conventional production methods. It is possible to obtain those having a nanoheterostructure in which the arrangement, composition, structure scale, and the like of various combinations of the hard magnetic material and the soft magnetic material are controlled in various ways. Therefore, the nanoheterostructured permanent magnet of the present invention exhibits a flux pinning effect because of the magnetic exchange interaction between the hard magnetic material and the soft magnetic material, and achieves remarkable improvements in interface increasing effect, nanosize effect, durability, and the like upon conventional nanostructured permanent magnets. Consequently, the nanoheterostructured permanent magnet of the present invention has both the high coercive force of the hard magnetic material and the high saturation magnetization of the soft magnetic material.

(7) In addition, in the nanoheterostructured permanent magnet of the present invention, a volume of part of a region comprising the soft magnetic material preferably accounts for 50% by volume or more of the total volume of the soft magnetic material, the part satisfying a condition that a distance from an interface with the hard magnetic material is 10 nm or less. If the volume of the part of the soft magnetic material satisfying the above-described condition is less than the lower limit, part of the soft magnetic material where the magnetic exchange interaction does not take place increases, so that the coercive force tends to decrease.

(8) As the hard magnetic material constituting the nanoheterostructured permanent magnet of the present invention, any known hard magnetic material can be used, as long as it has a high coercive force. Preferred examples thereof include ferrite-based magnets such as BaFe.sub.12O.sub.19, SrFe.sub.12O.sub.19, BaFe.sub.18O.sub.27, and SrFe.sub.18O.sub.27, rare earth-based magnets such as SmCo.sub.5, Pr.sub.2Fe.sub.14B, Nd.sub.2Fe.sub.14B, Dy.sub.2Fe.sub.14B, Sm(Fe.sub.11Ti), Y(Fe.sub.11Ti), Sm.sub.2Co.sub.17, Er.sub.2Co.sub.17, Y.sub.2Co.sub.17, and Sm.sub.2Fe.sub.17N.sub.3, and noble metal-based magnets such as FePt and FePd. One of these hard magnetic materials may be used alone, or two or more thereof may be used in combination.

(9) Meanwhile, as the soft magnetic material constituting the nanoheterostructured permanent magnet of the present invention, any known soft magnetic material can be used as long as it has a low coercive force and a high magnetic permeability. Preferred are iron, cobalt, iron-cobalt alloys (such as Permendur), iron-nickel alloys (such as permalloy), iron-noble metal alloys (such as Fe.sub.3Pt), silicon steel, Sendust, and soft ferrite. One of these soft magnetic materials may be used alone, or two or more thereof may be used in combination.

(10) Next, a method for producing a nanoheterostructured permanent magnet of the present invention is described. The method for producing a nanoheterostructured permanent magnet of the present invention comprises:

(11) a first step of preparing a raw material solution by dissolving, in a solvent, a block copolymer comprising at least a first polymer block component and a second polymer block component which are immiscible but linked to each other, a first inorganic precursor which is one of a hard magnetic material precursor and a soft magnetic material precursor, and a second inorganic precursor which is the other of the hard magnetic material precursor and the soft magnetic material precursor; and

(12) a second step including a phase-separation treatment for forming a nanophase-separated structure in which at least a first polymer phase comprising the first polymer block component with the first inorganic precursor introduced thereinto and a second polymer phase comprising the second polymer block component with the second inorganic precursor introduced thereinto are regularly arranged by self-assembly, a conversion treatment for converting the hard magnetic material precursor and the soft magnetic material precursor to a hard magnetic material and a soft magnetic material, respectively, and a removal treatment for removing the block copolymer from the nanophase-separated structure, to thereby obtain a nanoheterostructured permanent magnet comprising the hard magnetic material and the soft magnetic material. Hereinafter, each of the steps is described.
First Step: Raw Material Solution Preparation Step

(13) This step is a step of preparing a raw material solution by dissolving, in a solvent, a block copolymer described below and inorganic precursors described below.

(14) The block copolymer used in the present invention comprises at least a first polymer block component and a second polymer block component which are linked to each other. Specific examples of the block copolymer include A-B type and A-B-A type block copolymers having a structure such as -(aa . . . aa)-(bb . . . bb)- in which a polymer block component A (first polymer block component) having a repeating unit a and a polymer block component B (second polymer block component) having a repeating unit b are linked end to end. Moreover, the block copolymer may be of a star type in which at least one polymer block component extends radially from a center, or of a type in which another polymer component is branched from the main chain of the block copolymer.

(15) The kinds of the polymer block components constituting the block copolymer used in the present invention are not particularly limited, as long as the polymer block components are immiscible with each other. Thus, the block copolymer used in the present invention preferably comprises polymer block components having different polarities. Specific examples of such a block copolymer include polystyrene-poly(methyl methacrylate) (PS-b-PMMA), polystyrene-poly(ethylene oxide) (PS-b-PEO), polystyrene-polyvinylpyridine (PS-b-PVP), polystyrene-poly(ferrocenyldimethylsilane) (PS-b-PFS), polyisoprene-poly(ethylene oxide) (PI-b-PEO), polybutadiene-poly(ethylene oxide) (PB-b-PEO), polyethylethylene-poly(ethylene oxide) (PEE-b-PEO), polybutadiene-polyvinylpyridine (PB-b-PVP), polyisoprene-poly(methyl methacrylate) (PI-b-PMMA), polystyrene-poly(acrylic acid) (PS-b-PAA), polybutadiene-poly(methyl methacrylate) (PB-b-PMMA), and the like. In particular, PS-b-PVP, PS-b-PEO, PS-b-PAA, and the like are preferable from the viewpoint that precursors are more likely to be introduced into the respective polymer block components. This is because if the polymer block components greatly differ from each other in polarity, precursors which greatly differ from each other in polarity can also be used for the introduction.

(16) The molecular weights of the block copolymer and the polymer block components constituting the block copolymer can be selected as appropriate in accordance with the structure scale (the size and distance of spheres, columns, layers, or the like) and the arrangement of a nanoheterostructured permanent magnet to be produced. For example, by adjusting the molecular weight of the polymer block component constituting the polymer phase into which the soft magnetic material precursor of the nanophase-separated structure is introduced among the polymer block components constituting the block copolymer, the volume of the predetermined part of the soft magnetic material can be controlled to a desired ratio. By increasing the molecular weight of the polymer block component constituting the polymer phase into which the soft magnetic material precursor is introduced, the ratio of the volume of the predetermined part of the soft magnetic material can be increased. In addition, by adjusting the molecular weight ratio between the polymer block component constituting the polymer phase into which the soft magnetic material precursor is introduced and the polymer block component constituting the polymer phase into which the hard magnetic material precursor is introduced, the volume of the predetermined part of the soft magnetic material can be controlled to a desired ratio. By relatively increasing the molecular weight of the polymer block component constituting the polymer phase into which the soft magnetic material precursor is introduced, the ratio of the volume of the predetermined part of the soft magnetic material can be increased. Note that the number average molecular weight of each of the polymer block components is preferably 100 to 10,000,000 (more preferably 1,000 to 1,000,000). It is also preferable to use a block copolymer which is easily decomposed by a heat treatment (calcination) or light irradiation to be described later or a block copolymer which is easily removed with a solvent.

(17) The hard magnetic material precursor and the soft magnetic material precursor used in the present invention are not particularly limited, as long as these are inorganic precursors capable of forming the above-described hard magnetic material and soft magnetic material, respectively, by the conversion treatment to be described later. Specifically, preferred are salts of a metal or metalloid constituting the hard magnetic material and the soft magnetic material (for example, carbonates, nitrates, phosphates, sulfates, acetates, chlorides, organic acid salts (such as acrylates)), alkoxides having 1 to 4 carbon atoms and containing the metal or the metalloid (for example, methoxides, ethoxides, propoxides, and butoxides), complexes of the metal or the metalloid (for example, acetylacetonate complexes), and organometallic compounds or organometalloidal compounds containing the metal or the metalloid (for example, those having at least one structure selected from the group consisting of a phenyl group, long hydrocarbon chains having 5 or more carbon atoms, a cyclooctatetraene ring, a cyclopentadienyl ring, and an amino group). One kind or two or more kinds of such hard magnetic material precursors and one kind or two or more kinds of such soft magnetic material precursors are selected as appropriate for use, in accordance with the combination of the hard magnetic material and the soft magnetic material constituting the desired nanoheterostructured permanent magnet, so that the precursors satisfy the above-described various conditions.

(18) The solvent used in the present invention is not particularly limited, as long as the solvent is capable of dissolving the block copolymer and the first and second inorganic precursors to be used. Examples of the solvent include acetone, tetrahydrofuran (THF), toluene, propylene glycol monomethyl ether acetate (PGMEA), propylene glycol monomethyl ether (PGME), chloroform, benzene, and the like. One of these solvents may be used alone, or two or more thereof may be used as a mixture.

(19) Note that, in the present description, to dissolve means a phenomenon that a substance (solute) is dissolved in a solvent to form a homogeneous mixture (solution), and includes cases where after dissolving, at least part of the solute becomes ions, where the solute is not dissociated into ions, but exists as molecules, and where the solute exists as associated molecules or ions, and other cases.

(20) In the present invention, the first polymer block component is used in combination with the first inorganic precursor, which is one of the hard magnetic material precursor and the soft magnetic material precursor, and the second polymer block component is used in combination with the second inorganic precursor, which is the other of the precursors. Moreover, it is preferable to use a first inorganic precursor having a solubility parameter different from that of the first polymer block component by 2 (cal/cm.sup.3).sup.1/2 or less in combination with a second inorganic precursor having a solubility parameter different from that of the second polymer block component by 2 (cal/cm.sup.3).sup.1/2 or less. By using the first inorganic precursor and the second inorganic precursor satisfying such conditions in combination, in the step of forming the nanophase-separated structure described later, a nanophase-separated structure is formed with achievement of self-assembly of the block copolymer, while the first inorganic precursor and the second inorganic precursor are sufficiently introduced into the first polymer block component and the second polymer block component, respectively. Thereby, the inorganic precursors are arranged with a three-dimensional nanoscale periodicity.

(21) A solubility parameter difference between the first polymer block component and the first inorganic precursor used in the present invention is preferably smaller than a solubility parameter difference between the first polymer block component and the second inorganic precursor. Meanwhile, a solubility parameter difference between the second polymer block component and the second inorganic precursor is preferably smaller than a solubility parameter difference between the second polymer block component and the first inorganic precursor. Moreover, it is more preferable to satisfy both the conditions.

(22) Moreover, the first inorganic precursor used in the present invention preferably has a solubility parameter different from that of the second polymer block component by more than 2 (cal/cm.sup.3).sup.1/2. Meanwhile, the second inorganic precursor preferably has a solubility parameter different from that of the first polymer block component by more than 2 (cal/cm.sup.3).sup.1/2. Furthermore, it is more preferable to satisfy both the conditions.

(23) By using the first inorganic precursor and the second inorganic precursor satisfying such conditions in combination, a part of the second inorganic precursor and a part of the first inorganic precursor tend to be more surely prevented from being introduced as impurities into the first polymer block component and the second polymer block component, respectively, in the step of forming the nanophase-separated structure described later. Moreover, the purity of the inorganic component constituting the matrix and/or the purity of the inorganic component arranged in the matrix in a nanoheterostructured permanent magnet to be obtained tend to be more improved.

(24) Preferred combinations of the first and second polymer block components and the first and second inorganic precursors satisfying such conditions are those in which the first polymer block component is at least one low-polarity polymer block component selected from the group consisting of a polystyrene component, a polyisoprene component, and a polybutadiene component, the second polymer block component is at least one high-polarity polymer block component selected from the group consisting of a poly(methyl methacrylate) component, a poly(ethylene oxide) component, a polyvinylpyridine component, and a poly(acrylic acid) component, the first inorganic precursor is at least one low-polarity inorganic precursor selected from the group consisting of the above-described organometallic compounds and the above-described organometalloidal compounds, and the second inorganic precursor is at least one high-polarity inorganic precursor selected from the group consisting of the above-described salts of metals or metalloids, the above-described metal- or metalloid-containing alkoxides having 1 to 4 carbon atoms, and the above-described of metal or metalloid acetylacetonate complexes.

(25) In addition, preferably, at least one (more preferably both) of the first inorganic precursor and the second inorganic precursor has a solubility parameter different from that of the solvent used by 2 (cal/cm.sup.3).sup.1/2 or less. By using the first inorganic precursor and/or the second inorganic precursor satisfying such a condition, the inorganic precursor tends to be more surely dissolved in the solvent, and the inorganic precursor tends to be more surely introduced into the polymer block component in the step of forming the nanophase-separated structure described later.

(26) Moreover, the ratios of the solutes (the block copolymer, the first inorganic precursor, and the second inorganic precursor) in the obtained raw material solution are not particularly limited. When a total amount of the raw material solution is taken as 100% by mass, the total amount of the solutes is preferably around 0.1 to 30% by mass and more preferably 0.5 to 10% by mass. Further, by adjusting the amounts of the first and second inorganic precursors used relative to the block copolymer, the amount of each inorganic precursor introduced into the corresponding polymer block component is adjusted, so that the volume of the predetermined part of the soft magnetic material in the obtained nanoheterostructured permanent magnet can be controlled to a desired ratio. For example, by increasing the amount of the inorganic precursor introduced into the polymer block component constituting the polymer phase into which the soft magnetic material precursor is introduced, the ratio of the volume of the predetermined part of the soft magnetic material can be increased.

(27) Second Step: Nanoheterostructured Permanent Magnet Formation Step

(28) This step is a step including a phase-separation treatment, a conversion treatment, and a removal treatment, which are to be described in detail below, to thereby prepare a nanoheterostructured permanent magnet comprising a hard magnetic material and a soft magnetic material.

(29) First, the raw material solution prepared in the first step contains the block copolymer, the hard magnetic material precursor, and the soft magnetic material precursor. In the present invention, it is preferable to use the first polymer block component in combination with the first inorganic precursor which is one of the hard magnetic material precursor and the soft magnetic material precursor, and to use the second polymer block component in combination with the second inorganic precursor which is the other of the precursors. Moreover, it is further preferable to use a first inorganic precursor having a solubility parameter different from that of the first polymer block component by 2 (cal/cm.sup.3).sup.1/2 or less in combination with a second inorganic precursor having a solubility parameter different from that of the second polymer block component by 2 (cal/cm.sup.3).sup.1/2 or less. Accordingly, the first inorganic precursor and the second inorganic precursor exist in such a state that the first inorganic precursor and the second inorganic precursor are sufficiently introduced into the first polymer block component and the second polymer block component, respectively. Hence, by the phase-separation treatment for forming a nanophase-separated structure by self-assembly of the block copolymer, a first polymer phase comprising the first polymer block component with the first inorganic precursor introduced thereinto and a second polymer phase comprising the second polymer block component with the second inorganic precursor introduced thereinto are regularly arranged, and the inorganic precursors are arranged with a three-dimensional nanoscale periodicity.

(30) Such a phase-separation treatment is not particularly limited. By carrying out a heat treatment at or above a glass transition temperature of the block copolymer used, self-assembly of the block copolymer is achieved, and the phase-separated structure is obtained.

(31) Next, in the present invention, the nanophase-separated structure formed by the phase-separation treatment is subjected to the conversion treatment for converting the hard magnetic material precursor and the soft magnetic material precursor to a hard magnetic material and a soft magnetic material, respectively; and the removal treatment for removing the block copolymer from the nanophase-separated structure. The hard magnetic material precursor and the soft magnetic material precursor are converted to the hard magnetic material and the soft magnetic material, respectively, by such a conversion treatment, and the block copolymer is removed by such a removal treatment. Thereby, a nanoheterostructured permanent magnet of the present invention is obtained which comprises a hard magnetic material and a soft magnetic material of which one inorganic component is a matrix, and of which the other inorganic component is arranged with a three-dimensional specific nanoscale periodicity in the matrix in such a shape as a spherical shape, a columnar shape, a gyroid shape, or a lamellar structure, in accordance with the type (shape) of the nanophase-separated structure.

(32) Such a conversion treatment may be a step of heating at or above a temperature at which the inorganic precursors are converted to the inorganic components for conversion to the inorganic components, or a step of subjecting the inorganic precursors to hydrolysis and dehydration condensation for conversion to the inorganic components.

(33) Meanwhile, the removal treatment may be a step of decomposing the block copolymer by a heat treatment (calcination) at or above a temperature at which the block copolymer is decomposed, a step of removing the block copolymer by dissolving the block copolymer in a solvent, or a step of decomposing the block copolymer by light irradiation such as ultraviolet ray irradiation.

(34) Further, in the second step of the present invention, if the raw material solution prepared in the first step is subjected to a heat treatment (calcination) at or above a temperature at which the block copolymer is decomposed, the phase-separation treatment, the conversion treatment, and the removal treatment can be conducted at once in a single heat treatment. In order to complete the phase-separation treatment, the conversion treatment, and the removal treatment by only one heat treatment in this manner, the heat treatment is carried out preferably at 300 to 1200 C. (more preferably 400 to 900 C.) for approximately 0.1 to 50 hours, although the conditions vary depending on the kinds of the block copolymer and the inorganic precursors to be used.

(35) Such a heat treatment may be carried out in an inert gas atmosphere (for example, nitrogen gas or the like), an oxidizing gas atmosphere (for example, air or the like), or a reducing gas atmosphere (for example, hydrogen or the like). When the inorganic precursors are converted to the inorganic components and the block copolymer is removed in an inert gas atmosphere, the three-dimensional nanoscale periodic structure tends to be kept more surely. Meanwhile, when the inorganic precursors are converted to the inorganic components in an oxidizing gas atmosphere, a permanent magnet including a hard magnetic material and a soft magnetic material each comprising an oxide of a metal or a metalloid can be obtained. Further, when the inorganic precursors are converted to the inorganic components in a reducing gas atmosphere, a permanent magnet including a hard magnetic material and a soft magnetic material each comprising a metal or a metalloid can be obtained. The conditions of such a heat treatment in an inert gas atmosphere, an oxidizing gas atmosphere, or a reducing gas atmosphere are not particularly limited. The treatment is preferably carried out at 300 to 1200 C. (more preferably 400 to 900 C.) for approximately 0.1 to 50 hours.

(36) After the first step, the second step may be performed on the raw material solution introduced into a heat treatment container, or the second step may be performed after the raw material solution is applied onto a surface of a substrate, in the method for producing a nanoheterostructured permanent magnet of the present invention. By the latter method, a film-shaped nanoheterostructured permanent magnet can be formed directly on the surface of the substrate. The kind of the substrate used is not particularly limited, but may be selected as appropriate depending on the application of the nanoheterostructured permanent magnet to be obtained. Moreover, brush painting, a spray method, a dipping method, a spin method, a curtain flow method, or the like is used as a method for applying the raw material solution.

EXAMPLES

(37) Hereinafter, the present invention will be described more specifically on the basis of Examples and Comparative Examples. However, the present invention is not limited to Examples below.

Example 1

(38) A raw material solution was obtained by dissolving, in 10 mL of toluene, 0.1 g of a polystyrene-b-poly(4-vinylpyridine) (PS-b-P4VP, the number average molecular weight of the PS component: 5010.sup.3, the number average molecular weight of the P4VP component: 1310.sup.3) as a block copolymer, 0.039 g of iron(III) chloride (FeCl.sub.3) and 0.123 g of chloroplatinic(IV) acid (H.sub.2[PtCl.sub.6]) as an FePt precursor (an Fe precursor and a Pt precursor), which was a hard magnetic material precursor, and 0.174 g of iron(III) diphenylpropanedionate (Fe(OC(Ph)=CHC(O)Ph).sub.3) as an Fe precursor, which was a soft magnetic material precursor.

(39) Next, the obtained raw material solution was placed in a heat treatment container, and subjected to a heat treatment in argon at 700 C. for 6 hours. Thus, an inorganic structure (0.8 cm0.8 cm2 m) was obtained.

(40) The obtained inorganic structure was observed with a transmission electron microscope (TEM). As shown in FIG. 2, a nanoheterostructure was confirmed in which FePt (platinum-iron alloy), which was a hard magnetic material, was three-dimensionally and periodically arranged in a spherical shape in an Fe (iron) matrix, which was a soft magnetic material. In addition, the volume of part of the region comprising the soft magnetic material (Fe), the part satisfying the condition that the distance from the interface with the hard magnetic material (FePt) was 10 nm or less, accounted for 91% by volume of the total volume of the soft magnetic material (Fe).

(41) Further, a small-angle X-ray diffraction pattern of the obtained inorganic structure was measured with a small-angle X-ray diffractometer (manufactured by Rigaku Corporation, product name: NANO-Viewer). The distance (d) of the periodic structure was 16.1 nm, and a diffraction peak pattern characteristic of a spherical structure (i.e., the ratio of magnitudes (q) of the diffraction spectra at peak positions) was confirmed.

(42) Moreover, a magnetization curve of the obtained inorganic structure was measured with a vibrating sample magnetometer (manufactured by TOEI INDUSTRY CO., LTD., product name: VSM-3S-15) in the range up to 20 kOe at room temperature, and the maximum energy product was determined. The maximum energy product was higher than that of an FePt single-phase permanent magnet by 25%.

Example 2

(43) An inorganic structure (0.8 cm0.8 cm2 m) was fabricated in the same manner as in Example 1, except that 0.1 g of a PS-b-P4VP whose PS component had a number average molecular weight of 4010.sup.3 and whose P4VP component had a number average molecular weight of 1810.sup.3 was used as a block copolymer, and that 0.039 g of iron(III) chloride (FeCl.sub.3) and 0.073 g of palladium acetylacetonate (Pd(acac).sub.2), which was an FePd precursor (an Fe precursor and a Pd precursor), were used as a hard magnetic material precursor.

(44) The obtained inorganic structure was observed with a transmission electron microscope (TEM) in the same manner as in Example 1. As shown in FIG. 3, a nanoheterostructure was confirmed in which FePd (palladium-iron alloy), which was a hard magnetic material, was three-dimensionally and periodically arranged in a columnar shape in an Fe (iron) matrix, which was a soft magnetic material. In addition, the volume of part of the region comprising the soft magnetic material (Fe), the part satisfying the condition that the distance from the interface with the hard magnetic material (FePd) was 10 nm or less, accounted for 88% by volume of the total volume of the soft magnetic material (Fe).

(45) In addition, a small-angle X-ray diffraction pattern of the obtained inorganic structure was measured in the same manner as in Example 1. The distance (d) of the periodic structure was 18.9 nm, and a diffraction peak pattern characteristics of a columnar structure (the ratio of magnitudes (q) of the diffraction spectra at the peak positions) was confirmed.

(46) Moreover, the maximum energy product of the obtained inorganic structure was determined in the same manner as in Example 1. The maximum energy product was higher than that of a FePd single-phase permanent magnet by 19%.

Example 3

(47) A raw material solution was obtained by dissolving, in 10 mL of tetrahydrofuran (THF, solubility parameter: 9.1 (cal/cm.sup.3).sup.1/2), 0.1 g of a polystyrene-b-poly(4-vinylpyridine) (PS-b-P4VP, the number average molecular weight of the PS component: 1310.sup.3, the solubility parameter of the PS component: 9.1 (cal/cm.sup.3).sup.1/2, the number average molecular weight of the P4VP component: 5010.sup.3, and the solubility parameter of the P4VP component: 12.0 (cal/cm.sup.3).sup.1/2) as a block copolymer, 0.042 g of neodymium acetylacetonate (Nd(acac).sub.3, solubility parameter: 9.0 (cal/cm.sup.3).sup.1/2) and 0.214 g of iron acetylacetonate (Fe(acac).sub.3, solubility parameter: 9.0 (cal/cm.sup.3).sup.1/2) as an Nd.sub.2Fe.sub.14B precursor (an Nd precursor and an Fe precursor), which was a hard magnetic material precursor, and 0.154 g of iron pyrrolidinedithiocarbamate (FePDC, solubility parameter: 11.4 (cal/cm.sup.3).sup.1/2) as an Fe precursor, which was a soft magnetic material precursor.

(48) Next, the obtained raw material solution was placed in a heat treatment container together with 0.024 g of boric acid and 1.54 g of calcium hydride, and subjected to a heat treatment under vacuum at 700 C. for 6 hours, followed by washing with acetic acid and acetone. Thus, an inorganic structure (0.8 cm0.8 cm2 m) was obtained.

(49) The obtained inorganic structure was observed with a transmission electron microscope (TEM) in the same manner as in Example 1. A nanoheterostructure was confirmed in which Fe (iron), which was the soft magnetic material, was three-dimensionally and periodically arranged in a spherical shape in an Nd.sub.2Fe.sub.14B matrix, which was the hard magnetic material. In addition, the volume of part of the region comprising the soft magnetic material (Fe), the part satisfying the condition that the distance from the interface with the hard magnetic material (Nd.sub.2Fe.sub.14B) was 10 nm or less, accounted for 94% by volume of the total volume of the soft magnetic material (Fe).

(50) In addition, a small-angle X-ray diffraction pattern of the obtained inorganic structure was measured in the same manner as in Example 1. The distance (d) of the periodic structure was 18.2 nm, and a diffraction peak pattern characteristic of a spherical structure (the ratio of magnitudes (q) of the diffraction spectra at the peak positions) was confirmed.

(51) Moreover, the maximum energy product of the obtained inorganic structure was determined in the same manner as in Example 1. The maximum energy product was higher than that of an Nd.sub.2Fe.sub.14B single-phase permanent magnet by 14%.

Example 4

(52) A raw material solution was obtained by dissolving, in 10 mL of tetrahydrofuran (THF, solubility parameter: 9.1 (cal/cm.sup.3).sup.1/2), 0.1 g of a polystyrene-b-poly(4-vinylpyridine) (PS-b-P4VP, the number average molecular weight of the PS component: 1810.sup.3, the solubility parameter of the PS component: 9.1 (cal/cm.sup.3).sup.1/2, the number average molecular weight of the P4VP component: 4010.sup.3, the solubility parameter of the P4VP component: 12.0 (cal/cm.sup.3).sup.1/2) as a block copolymer, 0.042 g of samarium acetylacetonate (Sm(acac).sub.3, solubility parameter: 9.0 (cal/cm.sup.3).sup.1/2) and 0.084 g of cobalt acetylacetonate (Co(acac).sub.3, solubility parameter: 8.8 (cal/cm.sup.3).sup.1/2) as an SmCo.sub.5 precursor (an Sm precursor and a Co precursor), which was a hard magnetic material precursor, and 0.154 g of iron pyrrolidinedithiocarbamate (FePDC, solubility parameter: 11.4 (cal/cm.sup.3).sup.1/2) as an Fe precursor, which was a soft magnetic material precursor.

(53) Next, the obtained raw material solution was placed in a heat treatment container together with 1.40 g of calcium hydride, and subjected to a heat treatment under vacuum at 700 C. for 6 hours, followed by washing with acetic acid and acetone. Thus, an inorganic structure (0.8 cm0.8 cm2 m) was obtained.

(54) The obtained inorganic structure was observed with a transmission electron microscope (TEM) in the same manner as in Example 1. A nanoheterostructure was confirmed in which Fe (iron), which was a soft magnetic material, was three-dimensionally and periodically arranged in a columnar shape in an SmCo.sub.5 matrix, which was a hard magnetic material. In addition, the volume of part of the region comprising the soft magnetic material (Fe), the part satisfying the condition that the distance from the interface with the hard magnetic material (SmCo.sub.5) was 10 nm or less, accounted for 92% by volume of the total volume of the soft magnetic material (Fe).

(55) In addition, a small-angle X-ray diffraction pattern of the obtained inorganic structure was measured in the same manner as in Example 1. The distance (d) of the periodic structure was 17.9 nm, and a diffraction peak pattern characteristics of a columnar structure (the ratio of magnitudes (q) of the diffraction spectra at the peak positions) was confirmed.

(56) Moreover, the maximum energy product of the obtained inorganic structure was determined in the same manner as in Example 1. The maximum energy product was higher than that of an SmCo.sub.5 single-phase permanent magnet by 11%.

Example 5

(57) An inorganic structure (0.8 cm0.8 cm2 m) was fabricated in the same manner as in Example 1, except that 0.066 g of iron acetylacetonate (Fe(acac).sub.3, solubility parameter: 9.0 (cal/cm.sup.3).sup.1/2) and 0.064 g of platinum acetylacetonate (Pt(acac).sub.2, solubility parameter: 9.0 (cal/cm.sup.3).sup.1/2) which were an FePt precursor (an Fe precursor and a Pt precursor), were used as a hard magnetic material precursor, 0.141 g of iron pyrrolidinedithiocarbamate (FePDC, solubility parameter: 11.4 (cal/cm.sup.3).sup.1/2), which was an Fe precursor, was used as a soft magnetic material precursor, and 10 mL of tetrahydrofuran (THF, solubility parameter: 9.1 (cal/cm.sup.3).sup.1/2) was used instead of toluene. Note that the PS component of the block copolymer, PS-b-P4VP, had a solubility parameter of 9.1 (cal/cm.sup.3).sup.1/2, and the P4VP component thereof had a solubility parameter of 12.0 (cal/cm.sup.3).sup.1/2.

(58) The obtained inorganic structure was observed with a transmission electron microscope (TEM) in the same manner as in Example 1. A nanoheterostructure was confirmed in which FePt (platinum-iron alloy), which was a hard magnetic material, was three-dimensionally and periodically arranged in a spherical shape in an Fe (iron) matrix, which was a soft magnetic material. In addition, the volume of part of the region comprising the soft magnetic material (Fe), the part satisfying the condition that the distance from the interface with the hard magnetic material (FePt) was 10 nm or less, accounted for 94% by volume of the total volume of the soft magnetic material (Fe).

(59) In addition, a small-angle X-ray diffraction pattern of the obtained inorganic structure was measured in the same manner as in Example 1. The distance (d) of the periodic structure was 17.3 nm, and a diffraction peak pattern characteristic of a spherical structure (the ratio of magnitudes (q) of the diffraction spectra at the peak positions) was confirmed.

(60) Moreover, the maximum energy product of the obtained inorganic structure was determined in the same manner as in Example 1. The maximum energy product was higher than that of an FePt single-phase permanent magnet by 28%.

INDUSTRIAL APPLICABILITY

(61) As described above, the present invention makes it possible to obtain a permanent magnet having a nanoheterostructure comprising a hard magnetic material and a soft magnetic material of which one inorganic component is a matrix, and of which the other inorganic component is three-dimensionally and periodically arranged in a predetermined shape on a predetermined nanoscale in the matrix.

(62) The nanoheterostructured permanent magnet of the present invention has a structure that has not been formed by conventional production methods. It is possible to obtain nanoheterostructures in which the arrangement, composition, structure scale, and the like of various combinations of the hard magnetic material and the soft magnetic material are controlled in various ways.

(63) The permanent magnet having such a nanoheterostructure exhibits a flux pinning effect because of the magnetic exchange interaction between the hard magnetic material and the soft magnetic material, and achieves remarkable improvements in interface increasing effect, nanosize effect, durability, and the like upon conventional nanostructured permanent magnets. Consequently, the permanent magnet has both the high coercive force of the hard magnetic material and the high saturation magnetization of the soft magnetic material. Hence, the nanoheterostructured permanent magnet of the present invention is useful as a permanent magnet for motors, power generators, coils for various sensors, cap magnets, and the like.