NEW COSMETIC COMPOSITIONS

Abstract

New cosmetic compositions and their use, in particular, as a shampoo or a cleanser. The compositions are in powder form substantially free of water. The compositions are composed of constituents and ingredients that are natural or of natural origin, non-allergenic, healthy, and free of preservatives. Also, a device including the novel compositions.

Claims

1.-38. (canceled)

39. A combination consisting of the following 5 constituents: a powder adhesion agent, mannitol, α-glucan oligosaccharide, at least one oil, and at least one surfactant, said combination being in powder form, in which the mass percentage of water is between 0 and 10% relative to the total mass of the combination, said adhesion agent, said mannitol, said α-glucan oligosaccharide, and said at least one surfactant being in powder form, said at least one oil being in particular in powder form, in particular in which the density of the powder is comprised from 0.35 to 0.55 g/ml, in particular from 0.4 to 0.5 g/ml.

40. The combination according to claim 39, free of mannitol.

41. The combination according to claim 39, in which: the powder adhesion agent is chosen from: corn starch, acacia powder, maltodextrin powder, apple extract powder, tapioca powder, rice powder, rice bran extract, and arrowroot powder or a mixture of these, and/or in which the at least one oil is chosen from: jojoba oil, sweet almond oil, bitter almond oil, Argan oil, sesame oil, camellia oil, safflower oil, moringa oil, Castor oil, coconut oil, apricot oil, linseed oil, pomegranate oil, grapeseed oil, prickly pear oils, marula oil, evening primrose oil, avocado oil, raspberry oil, borage oil, olive oil, neem oil, sunflower oil, walnut or hazelnut oil, amla oil, plum oil, coffee oil, hemp oil, a vanilla macerate, an oil powder, and a fermented oil, or a mixture of these, and/or in which the surfactant is a surfactant chosen from: lauryl glucoside, decyl glucoside, caprylyl/capryl glucoside, coco-glucoside, hexyl glucoside, sodium cocoyl glutamate, disodium cocoyl glutamate, sodium stearoyl glutamate, sodium lauroyl glutamate, sodium myristoyl glutamate, coco-betaine, cocamidopropyl betaine, disodium cocoamphodiacetate, sodium arganamphoacetate, sodium babassuamphoacetate, sodium cocoabutteramphoacetate, sodium cottonseedamphoacetate, sodium sheabutteramphoacetate, sodium mangoamphoacetate, sodium olivamphoacetate, sodium ricebranamphoacetate, sodium sweetalmondamphoacetate, sodium sunflowerseedamphoacetate, potassium cocoate, potassium palmate, potassium laurate, potassium olivate, sodium coco-sulfate, sodium cocoamphoacetate, disodium coco-glucoside citrate, sodium coco-glucoside tartrate, sodium lauroamphoacetate, cocoyl methyl glucamide, capryloyl/caproyl methyl glucamide, lauroyl/myristoyl methyl glucamide, ammonium lauryl sulfate, ammonium coco-sulfate, magnesium lauryl sulfate, sodium C12-18 alkyl sulfate, zinc coco-sulfate, sodium cocoyl alaninate, sodium lauryl sulfate, sodium cetearyl sulfate, sodium cocoyl isethionate, sodium methyl oleoyl taurate, sodium methyl cocoyl taurate, cocamide MEA, cocamide MIPA, sodium C14-16 olefin sulfonate, sodium lauryl sulfoacetate, sodium lauroyl sarcosinate, sodium laureth sulfate, ammonium laureth sulfate, cocamidopropyl hydroxysultaine, disodium laureth sulfosuccinate, disodium lauryl sulfosuccinate, sodium myreth sulfate, laureth-5 carboxylic acid, and saponin, in particular, in which the surfactant is an anionic surfactant chosen in particular from: sodium cocoyl glutamate, and sodium cocoyl isethionate, or a mixture of these.

42. The combination according to claim 39, in which: the total quantity of powder adhesion agent is comprised from 5 to 85%, in particular from 5 to 15%, or from 70 to 85%, in percentage by weight relative to the total weight of the combination. and/or in which the total quantity of mannitol is comprised from 5 to 20%, in particular from 5 to 15% in percentage by weight relative to the total weight of the combination, and/or in which the total quantity of α-glucan oligosaccharide is comprised from 0.5 and 2%, in particular approximately 1% in percentage by weight relative to the weight total of the combination, and/or in which the total quantity of oil is comprised from 1 to 50%, in particular from 1 to 10%, in particular from 2 to 8% in percentage by weight with respect to the total weight of the combination, and/or in which the total quantity of surfactant is comprised from 1 and 80%, in particular from 2 to 20%, or from 40 to 80% in percentage by weight relative to the total weight of the combination.

43. The combination according to claim 39, said combination being in the form: of a shampoo, said shampoo comprising in particular: two surfactants in a total amount comprised from 40 to 80%, in particular from 70 to 80%, as a percentage by weight relative to the total weight of the composition, and a powder adhesion agent, in an amount comprised from 5 to 15% in percentage by weight relative to the total weight of the composition, or of a cleaner, said cleaner comprising in particular: a surfactant in an amount comprised from 2 to 20%, in particular from 5 to 10% by weight percentage relative to the total weight of the composition, and a powder adhesion agent, in an amount of 70 to 85% in percentage by weight relative to the total weight of the composition.

44. A cosmetic composition, comprising a combination according to claim 39, in a cosmetically acceptable medium, said composition being in the form of a powder, in which the mass percentage of water is comprised from 0 to 10% relative to the total mass of the composition, in particular in which the density of the powder is comprised from 0.35 to 0.55 g/ml, in particular from 0.4 to 0.5 g/ml.

45. A cosmetic composition, comprising a combination according to claim 40, in a cosmetically acceptable medium, said composition being in the form of a powder, in which the mass percentage of water is comprised from 0 to 10% relative to the total mass of the composition, wherein said composition further comprises a pigment or piroctone olamine, in particular in which the density of the powder is comprised from 0.35 to 0.55 g/ml, in particular from 0.4 to 0.5 g/ml.

46. The cosmetic composition according to claim 44, said combination being present at a rate of 70 to 100%, in particular 85 to 100% in percentage by weight relative to the total weight of the composition.

47. The cosmetic composition according to claim 44, in which the total quantity of powder adhesion agent is comprised from 3.5 to 85%, in particular from 3.5 to 15%, or from 50 to 85%, as a percentage by weight relative to the total weight of the composition, and/or in which the total quantity of mannitol is comprised from 3.5 to 20%, in particular from 8 to 15%, as a percentage by weight relative to the total weight of the composition, and/or in which the total quantity of α-glucan oligosaccharide is comprised from 0.35 to 2%, in particular approximately 1%, as a percentage by weight relative to the total weight of the composition, and/or in which the total quantity of oil is comprised from 0.7 to 50% in percentage by weight relative to the total weight of the composition, and/or in which the total amount of surfactant is comprised from 0.7 to 80%, in particular comprised from 1.4 to 20%, or comprised from 30 to 80% as a percentage by weight relative to the total weight of the composition.

48. The cosmetic composition according to claim 44, in which the composition also comprises at least one ingredient, in particular an active principle, in particular chosen from: flower acid, Zinc PCA, a pigment, the coal, an antioxidant, in particular vitamin C, or one of its derivatives, powdered tea, including matcha green tea, fermented tea, powdered kombucha tea, centella asiatica, or madecassoside, sugars, in particular xylitol, rhamnose, or fructooligosaccharides, the aloe vera, a protein, in particular pea protein, soy protein, wheat protein, or rice protein, sweet almond milk, or one or more of its components, in particular prunus dulcis, rice syrup or acacia fibre, a perfume, in particular an apricot almond perfume, ghassoul, white clay, especially kaolin, sodium hyaluronate, hyaluronic acid, lactic acid, vanilla macerate, maltodextrin, bamboo powder, spirulina, phycocyanin, fermented mushrooms, guarana, caffeine, acerola, chamomile, Ayurvedic powders, vitamins, in particular vitamin B3, or vitamin B5, glycosphingolipids and glycolipids, exopolysaccharides, and postbiotics, in particular lactobacillus ferment, pyroctolamine, piroctone olamine, an extract of camellia seeds, corn flower extract, chamomile flower extract, or a mixture of these, said at least one ingredient is in particular solid at room temperature.

49. The cosmetic composition according to claim 44, said composition being in the form: of a shampoo, said shampoo comprising in particular: two surfactants in a total amount comprised from 30 to 80%, in particular from 50 to 80% as a percentage by weight relative to the total weight of the composition, and a powder adhesion agent, in an amount comprised from 3.5 to 15% in percentage by weight relative to the total weight of the composition, or of a cleaner, said cleaner comprising in particular: a surfactant at a rate of 1.4 to 20% in percentage by weight relative to the total weight of the composition, and a powder adhesion agent, in an amount comprised from 50 to 85%, in particular from 70 to 85% in percentage by weight relative to the total weight of the composition.

50. The cosmetic composition according to claim 44, in which said composition comprises, in percentage by weight relative to the total weight of the composition: a powder adhesion agent, in particular corn starch, at a rate of 8 to 11%, and mannitol at a rate of 9 to 11%, α-glucan oligosaccharide, at a rate of 0.5 to 1.5%, Argan oil, at a rate of 3 to 5%, sodium cocoyl glutamate at a rate of 25 to 35%, sodium cocoyl isethionate at a rate of 35 to 45%, aloe vera at a rate of 0.5 to 1%, pea protein at 2 to 3%, and apricot almond flavor at a rate of 1 to 3%, said composition being in particular a shampoo.

51. The cosmetic composition according to claim 44, in which said composition comprises, in percentage by weight relative to the total weight of the composition: a powder adhesion agent, in particular corn starch, at a rate of 10 to 12%, mannitol at a rate of 9 to 10%, α-glucan oligosaccharide, at a rate of 0.5 to 1.5%, sweet almond milk, at a rate of 6 to 7%, sodium cocoyl glutamate at a rate of 25 to 35%, and sodium cocoyl isethionate at a rate of 35 to 45%, said composition being in particular a shampoo.

52. The cosmetic composition according to claim 44, in which said composition comprises, in percentage by weight relative to the total weight of the composition: a powder adhesion agent, in particular corn starch, at a rate of 8 to 11%, mannitol at a rate of 7 to 9%, α-glucan oligosaccharide, at a rate of 0.5 to 1.5%, Ghassoul, at a rate of 4 to 6%, sodium cocoyl glutamate at a rate of 25 to 35%, sodium cocoyl isethionate at a rate of 35 to 45%, bamboo powder at a rate of 2 to 4%, jojoba oil at a rate of 1 to 3%, and herbal and tea perfume at a rate of 1 to 3%, said composition being in particular a shampoo.

53. The cosmetic composition according to claim 45, in which said composition comprises, in percentage by weight relative to the total weight of the composition: sodium cocoyl glutamate at a rate of 25 to 35%, sodium cocoyl isethionate at a rate of 35 to 45%, a powder adhesion agent, in particular corn starch, α-glucan oligosaccharide, at a rate of 0.5 to 1.5%, sunflower oil, chamomile flower extract, piroctone olamine flower acid, and herbal and tea fragrance, said composition being in particular a shampoo.

54. The cosmetic composition according to claim 45, in which said composition comprises, in percentage by weight relative to the total weight of the composition: sodium cocoyl glutamate at a rate of 25 to 35%, sodium cocoyl isethionate at a rate of 35 to 45%, a powder adhesion agent, in particular corn starch, α-glucan oligosaccharide, at a rate of 0.5 to 1.5%, argan oil, rice protein, pea protein, benzene sulfonic acid 2-[(9,10-dihydro-4-hydroxy-9,10-dioxo-1-anthracenyl) amino]-5-methyl sodium monosalt, erythrol, and herbal and tea fragrance, said composition being in particular a shampoo.

55. The cosmetic composition according to claim 44, in which said composition comprises, in percentage by weight relative to the total weight of the composition: a powder adhesion agent, in particular corn starch, at a rate of 75 to 79%, mannitol at a rate of 12 to 14%, α-glucan oligosaccharide, at a rate of 0.5 to 1.5%, sodium cocoyl glutamate at a rate of 4 to 6%, sesame oil at a rate of 0.5 to 2%, jojoba oil at a rate of 0.5 to 2%, zinc PCA at a rate of 0.5 to 2%, and coal at a rate of 0.5 to 2%, said composition being in particular a cleanser.

56. The cosmetic composition according to claim 44, in which said composition comprises, in percentage by weight relative to the total weight of the composition: a powder adhesion agent, in particular corn starch, at a rate of 72 to 76%, mannitol at a rate of 9 to 11%, α-glucan oligosaccharide, at a rate of 0.5 to 1.5%, sodium cocoyl glutamate at a rate of 4 to 6%, sweet almond oil at a rate of 2 to 4%, ascorbyl glucoside at a rate of 2 to 4%, jojoba oil at a rate of 2 to 4%, and flower acid at a rate of 1 to 3%, said composition being in particular a cleanser.

57. The cosmetic composition according to claim 44, in which said composition comprises, in percentage by weight relative to the total weight of the composition: a powder adhesion agent, in particular corn starch, at a rate of 65 to 75%, mannitol at a rate of 14 to 16%, α-glucan oligosaccharide, at a rate of 0.5 to 1.5%, sodium cocoyl glutamate at a rate of 4 to 6%, safflower oil at a rate of 2 to 4%, jojoba oil at a rate of 2 to 4%, and spirulina at a rate of 2 to 4%, said composition being in particular a cleanser.

58. The cosmetic composition according to claim 44, in which said composition comprises, in percentage by weight relative to the total weight of the composition: a powder adhesion agent, in particular corn starch, at a rate of 70 to 76%, mannitol at a rate of 13 to 17%, α-glucan oligosaccharide, at a rate of 0.5 to 1.5%, sodium cocoyl glutamate at a rate of 4 to 6%, safflower oil at a rate of 1 to 3%, argan oil at a rate of 1 to 3%, and hemp oil at a rate of 1 to 3%. said composition being in particular a cleanser.

Description

EXAMPLES

Example a General Procedure for the Manufacture of the Compositions

[0305] The different ingredients are weighed and added one by one in a mixer. The powders are added first and the vegetable oil and perfume are added second. The ingredients are mixed for 10 seconds twice and then packaged.

Example B Powder Density Measurement Procedure

[0306] A 250 ml test tube was weighed empty to give its weight M0 in grams. A volume V of the powder, ranging from 240 to 250 ml, is versed into the test tube using a funnel. The test tube is weighed again to give the weight M1 in grams.

[0307] The density ρ of the powder, expressed in g/ml, is calculated according to the following formula 1:

ρ=(M1−M0)/V  formula 1

Example C pH Measurement Procedure

[0308] The composition is weighed and diluted in water to obtain an aqueous solution of the composition at 10% by weight. The pH is then measured at room temperature, using a pH meter.

Example D General Procedure for Cleaning Sensory Tests on a Panel of Experts

[0309] Sensory tests were carried out on a panel of experts.

[0310] The powder cleanser was used like a regular facial cleanser. It was used as follows: [0311] 1) Wet the face [0312] 2) Sprinkle 1 teaspoon of the powder cleanser into your hand [0313] 3) Add a few drops of water to make it foam in your hands [0314] 4) Apply cleanser to face and massage to remove makeup and impurities [0315] 5) Rinse with water

[0316] The performance of the cleaner is evaluated according to: [0317] its foaming power in contact with water [0318] its make-up removing power [0319] its rinsability

Example E General Procedure for Shampoo Tests on a Panel of Experts

[0320] Sensory tests were carried out on a panel of experts.

[0321] The powder shampoo was used on wet hair like a classic shampoo. It was used as follows: [0322] 1) Wet her hair and hands [0323] 2) Sprinkle 1 to 2 teaspoons of shampoo powder into hand depending on length of hair and add water if needed [0324] 3) Apply shampoo to hair [0325] 4) Massage hair and scalp [0326] 5) Rinse with water

[0327] The performance of the shampoo is evaluated according to: [0328] its foaming power [0329] its cleansing power [0330] its detangling power [0331] its rinsability [0332] its ease of combing

Example 1 Ghassoul Shampoo

[0333] The shampoo composition of Table 1, comprising Ghassoul, was manufactured according to the general procedure of Example A.

TABLE-US-00001 TABLE 1 Composition of a Ghassoul shampoo name commercial name INCI name % Corn strach MAISITA 9060 Zea Mays (Corn) Starch 9 Mannitol Beauté by Roquette ® PO260 Mannitol 8 Sodium cocoyl AMISOFT ® CS 11 SODIUM COCOYL 30 glutamate GLUTAMATE Sodium cocoyl PUREACT I-80P SODIUM COCOYL 40 iséthionate ISETHIONATE Ghassoul GHASSOUL Morrocan Lava Clay 5 Bamboo powder Greensil Bambusa Arundinacea Stem 3 Extract alpha-Glucan BIOECOLIA ® α-glucan oligosaccharide 1 oligosaccharide Jojoba oil Jojoba Oil CP Org SIMMONDSIA CHINENSIS 2 SEED OIL Herb & Tea fragrance HERBES & THE 2 NATFLOR 2 RT4693 TOTAL 100

[0334] The composition is in the form of a white powder, the density of which, measured according to the procedure of Example B, is 0.42 g/ml.

[0335] The pH, measured according to the procedure of Example C, is 5.85.

[0336] Sensory Tests

[0337] The shampoo was evaluated according to the procedure of Example E: [0338] foaming power: Foam formation is rapid. The foam is abundant, light and pleasant to the touch. [0339] washing power: The hair is clean after washing. [0340] detangling power: The hair is easy to detangle. [0341] rinsability: The shampoo rinses out very quickly. [0342] ease of combing: The hair is easy to detangle when combing.

Example 2 Ghassoul Shampoo

[0343] The shampoo composition of Table 2, comprising Ghassoul, was manufactured according to the general procedure of Example A.

TABLE-US-00002 TABLE 2 Composition of a Ghassoul shampoo name INCI name % Corn starch Zea mays (corn) starch 8 Mannitol Mannitol 8 Sodium cocoyl glutamate Sodium cocoyl glutamate 30 Sodium cocoyl iséthionate Sodium cocoyl isethionate 40 Ghassoul Maroccan lava clay 5 L-Arginin L-Arginine 1 Bbamboo powder Bambusa arundinacea stem 3 powder Jojoba oil Simmondsia chinensis seed oil 2 alpha-Glucan oligosaccharide α-glucan oligosaccharide 1 Herb & tea fragrance fragrance 2 Total 100

[0344] The composition is in the form of a white powder, the density of which, measured according to the procedure of Example B, is 0.43 g/ml.

[0345] The pH, measured according to the procedure of Example C, is 5.7.

[0346] Sensory Tests

[0347] The shampoo was evaluated according to the procedure of Example E: [0348] foaming power: Foam formation is rapid. The foam is abundant, light and pleasant to the touch. [0349] washing power: The hair is clean after washing. [0350] detangling power: The hair is easy to detangle. [0351] rinsability: The shampoo rinses out very quickly. [0352] ease of combing: The hair is easy to detangle when combing.

Example 3 Argan Oil Shampoo

[0353] The shampoo composition of Table 3, comprising argan oil, was manufactured according to the general procedure of Example A.

TABLE-US-00003 TABLE 3 Composition of an argan oil shampoo Name commercial name INCI name % Corn starch MAISITA 9060 Zea Mays (Corn) Starch 9.5 Mannitol Beauté by Roquette ® PO260 Mannitol 10 Sodium cocoyl AMISOFT ® CS 11 SODIUM COCOYL 30 glutamate GLUTAMATE Sodium cocoyl PUREACT I-80P SODIUM COCOYL 40 isethionate ISETHIONATE Pea protein Promois WJ-SP Hydrolyzed Pea Protein 2.5 Aloe vera ALOE VERA EXTRAIT SEC Aloe Barbadensis Leaf Juice 1 ATOMISE BIO Powder α-glucan BIOECOLIA ® α-glucan oligosaccharide 1 oligosaccharide Argan oil Deodorized argan oil Argania Spinosa Kernel Oil 4 Almond apricot ABRICOT AMANDE 2 2 fragrance NATFLOR RT4688 TOTAL 100

[0354] The composition is in the form of a white powder, the density of which, measured according to the procedure of Example B, is 0.40 g/ml.

[0355] The pH, measured according to the procedure of Example C, is 5.49.

Example 4 Argan Oil Shampoo

[0356] The shampoo composition of Table 4, comprising argan oil, was manufactured according to the general procedure of Example A.

TABLE-US-00004 TABLE 4 Composition of an argan oil shampoo Name INCI name % Corn starch Zea Mays (Corn) Starch 10 Mannitol Mannitol 10 Sodium cocoyl SODIUM COCOYL GLUTAMATE 30 glutamate Sodium cocoyl SODIUM COCOYL ISETHIONATE 40 isethionate Pea protein Hydrolyzed Pea Protein 2 Aloe vera Aloe Barbadensis Leaf Juice Powder 1 α-glucan α-glucan oligosaccharide 1 oligosaccharide Argan oil Argania Spinosa Kernel Oil 4 fragrance 2 TOTAL 100

[0357] The composition is in the form of a white powder, the density of which, measured according to the procedure of Example B, is 0.34 g/ml.

[0358] The pH, measured according to the procedure of Example C, is 5.8.

[0359] Sensory Tests

[0360] The shampoo was evaluated according to the procedure of Example E: [0361] foaming power: Foam formation is rapid. The foam is abundant, light and pleasant to the touch. [0362] washing power: The hair is clean after washing. [0363] detangling power: The hair is easy to detangle. [0364] rinsability: The shampoo rinses out very quickly. [0365] ease of combing: The hair is easy to detangle when combing.

Example 5 Sweet Almond Milk Shampoo

[0366] The shampoo composition of Table 5, comprising sweet almond milk, was manufactured according to the general procedure of Example A.

TABLE-US-00005 TABLE 5 Composition of a sweet almond milk shampoo name Commercial name INCI name % Corn starch MAISITA 9060 Zea Mays (Corn) Starch 11 Mannitol Beauté by Roquette PO 260 Mannitol 9.5 Sodium cocoyl AMISOFT ® CS 11 SODIUM COCOYL 30 glutamate GLUTAMATE Sodium cocoyl PUREACT I-80P SODIUM COCOYL 40 isethionate ISETHIONATE Sweet almond milk LAIT AMANDE DOUCE BIO Prunus Amygdalus Dulcis 6.5 Protein Oryza Sativa Extract Acacia Senegal Gum Vanilla Planifolia Extract Prunus Amygdalus Dulcis Fruit Extract α-glucan BIOECOLIA ® α-glucan oligosaccharide 1 oligosaccharide Coco milk fragrance LAIT DE COCO 2 NATFLOR 2 RT4683 TOTAL 100

[0367] The composition is in the form of a white powder, the density of which, measured according to the procedure of Example B, is 0.48 g/ml.

[0368] The pH, measured according to the procedure of Example C, is 5.84.

Example 6 Sweet Almond Milk Shampoo

[0369] The shampoo composition of Table 6, comprising sweet almond milk, was manufactured according to the general procedure of Example A.

TABLE-US-00006 TABLE 6 Composition of a sweet almond milk shampoo name INCI name % Corn starch Zea mays (corn) starch 11 Mannitol Mannitol 9.5 Sodium cocoyl glutamate Sodium cocoyl glutamate 30 Sodium cocoyl isethionate Sodium cocoyl isethionate 40 Sweet almond milk Lait d'amande douce 4 Hydrolized rice protein Hydrolyzed rice bran protein 2 Kappaphycus alvarezii Kappaphycus alvarezii Extract & 0.5 extract & tara fruit extract Caesalpinia spinosa Fruit Extract α-glucan oligosaccharide α-glucan oligosaccharide 1 fragrance 2 Total 100

[0370] The composition is in the form of a white powder, the density of which, measured according to the procedure of Example B, is 0.44 g/ml.

[0371] The pH, measured according to the procedure of Example C, is 5.7.

[0372] Sensory Tests

[0373] The shampoo was evaluated according to the procedure of Example E: [0374] foaming power: Foam formation is rapid. The foam is abundant, light and pleasant to the touch. [0375] washing power: The hair is clean after washing. [0376] detangling power: The hair is easy to detangle. [0377] rinsability: The shampoo rinses out very quickly. [0378] ease of combing: The hair is easy to detangle when combing.

Example 7 Shampoo with 3 Oils

[0379] The shampoo composition of Table 7, comprising three oils, was made according to the general procedure of Example A.

TABLE-US-00007 TABLE 7 Composition of a shampoo with three oils name Commercial name INCI name % Corn starch MAISITA 9060 Zea Mays (Corn) Starch 6 Mannitol Beauté by Roquette ® PO260 Mannitol 10 Sodium cocoyl AMISOFT ® CS 11 SODIUM COCOYL 30 glutamate GLUTAMATE Sodium cocoyl PUREACT I-80P SODIUM COCOYL 40 iséthionate ISETHIONATE Aloe vera ALOE VERA EXTRAIT SEC Aloe Barbadensis Leaf Juice 5 ATOMISE BIO Powder α-glucan BIOECOLIA ® α-glucan oligosaccharide 1 oligosaccharide Moringa seed oil ORGANIC REFINED Moringa Oleifera Seed Oil 2 MORINGA OIL Jojoba oil Jojoba Oil CP Org SIMMONDSIA CHINENSIS 2 SEED OIL Argan oil Huile d'argan désodorisée Argania Spinosa Kernel Oil 2 ABRICOT AMANDE 2 2 NATFLOR RT4688 TOTAL 100

[0380] The composition is in the form of a white powder.

[0381] The pH, measured according to the procedure of Example C, is 5.71.

Example 8 Charcoal Cleaner

[0382] The cleaning composition of Table 8, including charcoal, was made according to the general procedure of Example A.

TABLE-US-00008 TABLE 8 Composition of a charcoal cleaner Name Commercial name INCI name % Corn starch MAISITA 9060 Zea Mays (Corn) Starch 77 Mannitol Beauté by Roquette ® PO260 Mannitol 13 Jojoba oil Jojoba Oil CP Org SIMMONDSIA CHINENSIS 1 SEED OIL Sesame oil HUILE VIERGE DE Sesamum Indicum Seed Oil 1 SESAME BIO Coal powder CHARBON VEGETAL Charcoal Powder 1 POUDRE Zinc salt of ZINCIDONE ® Zinc PCA 1 pyrrolidone carboxylic acid α-glucan BIOECOLIA ® α-glucan oligosaccharide 1 oligosaccharide Sodium cocoyl AMISOFT ® CS 11 Sodium Cocoyl Glutamate 5 glutamate TOTAL 100

[0383] The composition is in the form of a white powder, the density of which, measured according to the procedure of Example B, is 0.4 g/ml.

[0384] The pH, measured according to the procedure of Example C, is 5.3.

Example 9 Charcoal Cleaner

[0385] The cleaning composition in Table 9, including coal, was made according to the general procedure of Example A.

TABLE-US-00009 name INCI name % arrowroot powder Maranta Arundinacea Root Powder 77 Mannitol Mannitol 13 Jojoba oil SIMMONDSIA CHINENSIS SEED OIL 1 Sesame oil Sesamum Indicum Seed Oil 1 Coal powder coal Powder 1 Zinc salt of Zinc PCA 1 pyrrolidone carboxylic acid α-glucan α-glucan oligosaccharide 1 oligosaccharide Sodium cocoyl Sodium Cocoyl Glutamate 5 glutamate TOTAL 100

[0386] The composition is in the form of a white powder, the density of which, measured according to the procedure of Example B, is 0.39 g/ml.

[0387] The pH, measured according to the procedure of Example C, is 5.7.

[0388] Sensory Tests

[0389] The cleaner was evaluated according to the procedure of Example D: [0390] foaming power: In contact with water, the cleanser foams slightly and becomes creamy. [0391] make-up removing power: The cleanser cleanses the skin and removes make-up. However, it needs to be combined with an eye make-up remover to perfect eye make-up removal when the eyes are made up. [0392] rinsability: The cleanser rinses off easily and leaves a feeling of softness on the skin after use.

Example 10 Flower Acid Cleanser

[0393] The cleaning composition in Table 10, including coal, was made according to the general procedure of Example A.

TABLE-US-00010 TABLE 10 Composition of a flower acid cleanser name Commercial name INCI name % Corn starch MAISITA 9060 Zea Mays (Corn) Starch 74 Mannitol Beauté by Roquette ® PO260 Mannitol 10 Jojoba oil Jojoba Oil CP Org SIMMONDSIA CHINENSIS 3 SEED OIL Sweet almond oil HUILE D'AMANDE DOUCE Prunus Amygdalus Dulcis 3 VIERGE BIO (Sweet Almond) Oil Ascorbyl Glucoside AA2G Ascorbyl Glucoside 2 Flower acid ACIDE DE FLEURS ROUGES Hibiscus Sabdariffa Flower 2 EXTRAIT SEC Extract, Maltodextrin α-glucan BIOECOLIA ® α-glucan oligosaccharide 1 oligosaccharide Sodium cocoyl AMISOFT ® CS 11 Sodium Cocoyl Glutamate 5 glutamate TOTAL 100

[0394] The composition is in the form of a white powder, the density of which, measured according to the procedure of Example B, is 0.41 g/ml.

[0395] The pH, measured according to the procedure of Example C, is 4.82.

Example 11 Flower Acid Cleanser

[0396] The cleaning composition in Table 11, including coal, was made according to the general procedure of Example A.

TABLE-US-00011 TABLE 11 Composition of a flower acid cleanser name INCI name % Arrowroot Powder Maranta Arundinacea Root 74 Powder Mannitol Mannitol 10 Jojoba oil SIMMONDSIA CHINENSIS SEED 3 OIL Sweet almond oil Prunus Amygdalus Dulcis (Sweet 3 Almond) Oil Ascorbyl Glucoside Ascorbyl Glucoside 2 Flower acid Hibiscus Sabdariffa Flower 2 Extract, Maltodextrin α-glucan α-glucan oligosaccharide 1 oligosaccharide Sodium cocoyl Sodium Cocoyl Glutamate 5 glutamate TOTAL 100

[0397] The composition is in the form of a white powder, the density of which, measured according to the procedure of Example B, is 0.40 g/ml.

[0398] The pH, measured according to the procedure of Example C, is 5.

[0399] Sensory Tests

[0400] The cleaner was evaluated according to the procedure of Example D: [0401] foaming power: In contact with water, the cleanser foams slightly and becomes creamy. [0402] make-up removing power: The cleanser cleanses the skin and removes make-up. However, it needs to be combined with an eye make-up remover to perfect eye make-up removal when the eyes are made up. [0403] rinsability: The cleanser rinses off easily and leaves a feeling of softness on the skin after use.

Example 12 Tri-Oil Cleanser

[0404] The cleaning composition in Table 12, including oils, was made according to the general procedure of Example A.

TABLE-US-00012 TABLE 12 Composition of a three-oil cleanser name Commercial name INCI name Corn starch MAISITA 9060 Zea Mays (Corn) Starch 73 Mannitol Beauté by Roquette ® PO260 Mannitol 15 Oil starch Huile d'argan désodorisée Argania Spinosa Kernel Oil 2 Virgin Safflower Oil Huile Vierge de Carthame Bio Carthamus Tinctorius Seed Oil 2 Hemp oil Organic Hemp Oil Cannabis Sativa Seed Oil 2 α-glucan BIOECOLIA ® α-glucan oligosaccharide 1 oligosaccharide Sodium cocoyl AMISOFT ® CS 11 Sodium Cocoyl Glutamate 5 glutamate TOTAL 100

[0405] The composition is in the form of a white powder, the density of which, measured according to the procedure of Example B, is 0.5 g/ml.

[0406] The pH, measured according to the procedure of Example C, is 5.5.

Example 13 Matcha Green Tea Cleanser

[0407] The cleaning composition in Table 13, including matcha green tea, was made according to the general procedure of Example A.

TABLE-US-00013 name INCI name % arrowroot powder Maranta Arundinacea Root 74 Powder Mannitol Mannitol 12 Jojoba oil SIMMONDSIA CHINENSIS 3 SEED OIL camellia oil Camellia Oleifera Seed Oil 3 Matcha green tea Camellia Sinensis Leaf Extract 2 α-glucan α-glucan oligosaccharide 1 oligosaccharide Sodium cocoyl Sodium Cocoyl Glutamate 5 glutamate TOTAL 100

[0408] The composition is in the form of a white powder, the density of which, measured according to the procedure of Example B, is 0.43 g/ml.

[0409] The pH, measured according to the procedure of Example C, is 5.4.

[0410] Sensory Tests

[0411] The cleaner was evaluated according to the procedure of Example D: [0412] foaming power: In contact with water, the cleanser foams slightly and becomes creamy. [0413] make-up removing power: The cleanser cleanses the skin and removes make-up. However, it needs to be combined with an eye make-up remover to perfect eye make-up removal when the eyes are made up. [0414] rinsability: The cleanser rinses off easily and leaves a feeling of softness on the skin after use.

Example 14 Spirulina Cleanser

[0415] The cleansing composition in Table 14, including spirulina, was made according to the general procedure of Example A.

TABLE-US-00014 TABLE 14 Composition of a spirulina cleanser name Commercial name INCI name % arrowroot powder Maranta Arundinacea 70 Root Powder Mannitol Mannitol 15 Jojoba oil SIMMONDSIA 3 CHINENSIS SEED OIL Safflower Oil Carthamus Tinctorius 3 Seed Oil Spirulina Spirulina Platensis 3 Extract α-glucan BIOECOLIA ® α-glucan 1 oligosaccharide oligosaccharide Sodium cocoyl Sodium Cocoyl 5 glutamate Glutamate TOTAL 100

[0416] The composition is in the form of a white powder, the density of which, measured according to the procedure of Example B, is 0.4 g/ml.

[0417] The pH, measured according to the procedure of Example C, is 5.7.

[0418] Sensory Tests

[0419] The cleaner was evaluated according to the procedure of Example D: [0420] foaming power: In contact with water, the cleanser foams slightly and becomes creamy. [0421] make-up removing power: The cleanser cleanses the skin and removes make-up. However, it needs to be combined with an eye make-up remover to perfect eye make-up removal when the eyes are made up. [0422] rinsability: The cleanser rinses off easily and leaves a feeling of softness on the skin after use.

Example 15 Anti-Dandruff Shampoo

[0423] The shampoo composition of Table 15 was manufactured according to the general procedure of Example A.

TABLE-US-00015 TABLE 15 Composition of an anti-dandruff shampoo name Commercial name INCI name % Sodium cocoyl Pureact I-80P Sodium cocoyl 40 isethionate isethionate Sodium cocoyl Amisoft CS 11 Sodium Cocoyl 30 glutamate Glutamate Corn starch Maisita 9060 Zea Mays (Corn) 17 Starch Sunflower oil HUILE DE HELIANTHUS 4 TOURNESOL ANNUS SEED OIL DESODO BIO Chamomile Chamomile Maltodextrin, 2 flower extract Herbasec ® Chamomilla Recutita Flower Extract α-glucan Bioecolia ® α-glucan 3 oligosaccharide oligosaccharide piroctone olamine Kopirox Piroctone Olamine 1 Flower acid ACIDES DE HIBISCUS 1 FLEURS SABDARIFFA ROUGES FLOWER EXTRACT, EXTRAIT MALTODEXTRIN SEC (001233) herb & tea 2 fragrance TOTAL 100

Example 16 Shampoo for Blonde Hair

[0424] The shampoo composition of Table 16 was manufactured according to the general procedure of Example A.

TABLE-US-00016 TABLE 16 Composition of a shampoo for blond hair name Commercial name INCI name % Sodium cocoyl Sodium cocoyl 40 isethionate isethionate Sodium cocoyl Sodium cocoyl 30 glutamate glutamate Erythriol Erylite ® Erythriol 8 Corn starch Zea Mays (Corn) 10.5 Starch Argan oil 5 Pea protein 1.5 Rice protein 1.5 herb & tea 2 fragrance α-glucan Bioecolia ® α-glucan 1 oligosaccharide oligosaccharide Unicert violet K7025-J CI 60730 0.5 Total 100

Example 17 Tests for Evaluating the Clinical Tolerance of Two Shampoos

[0425] The following shampoos have been tested in a test to assess the clinical and dermatological tolerance and acceptability of a cosmetic product after use over a period of 21 days under normal conditions of use. [0426] Almond milk shampoo according to example 5, on 21 volunteers [0427] Argan oil shampoo according to example 3, on 22 volunteers

[0428] The tests were carried out by IDEA Clinic, France.

[0429] Instructions Selected for the Study

[0430] Use the shampoo according to your usual routine: [0431] Shake well before use; [0432] Apply in the shower, thoroughly wet your hair and hands; [0433] Pour ½ teaspoon of shampoo powder into your hand depending on the length of your hair; [0434] Add water to your hands to lather; [0435] Apply to hair and lather like a classic shampoo; [0436] Rinse well with water.

[0437] The volunteers evaluated the product for its properties after use over a period of 21 days. The study was monocentric, open and comparative between D21 and D1.

[0438] Results—Discussion

[0439] No clinical signs of intolerance were observed for the two shampoos.

[0440] Almond Milk Shampoo [0441] Items relating to the efficacy of the product (positive responses≥75%, threshold of statistical significance for 21 volunteers analysed) [0442] The product is gentle on the hair as well as the scalp (85.71%) [0443] The product is suitable for your hair type (76.19%) [0444] The product gently cleanses the hair (90.48%) [0445] The product protects hair and scalp (85.71%) [0446] The hair is light (76.19%) [0447] The hair is supple (85.71%) [0448] The hair is soft and silky (80.95%) [0449] The hair is hydrated (85.71%) [0450] The hair is nourished (85.71%) [0451] The foam is melting (85.71%) [0452] The product is easy to rinse off (90.48%) [0453] The product rinses out more easily than a conventional shampoo (80.95%)

[0454] Under the conditions of the study, the product exhibited: [0455] excellent dermatological tolerance, according to the scale adopted, on oily scalp and on normal and fine hair [0456] good cosmetic acceptability, with 76% favorable opinions.

[0457] Argan Oil Shampoo [0458] Items relating to the efficacy of the product (positive responses≥75%, threshold of statistical significance for 22 volunteers analysed) [0459] The product is easy to rinse off (90.91%) [0460] The product rinses out more quickly than a classic shampoo (77.27%) [0461] The product is gentle on the hair and the scalp (81.82%) [0462] The hair is light (77.27%) [0463] My color is preserved (77.27%) [0464] The scalp itches less (87.50%)

[0465] Under the conditions of the study, the product exhibited: [0466] excellent dermatological tolerance, according to the scale adopted, on dry and colored hair and on the scalp; [0467] good cosmetic acceptability, with 64% favorable opinions.

Example 18 Clinical Tolerance Evaluation Tests of Three Cleansers

[0468] The following cleansers have been tested in a test to assess clinical and dermatological tolerance and acceptability of a cosmetic product after use over a period of 21 days under normal conditions of use. [0469] The coal cleaner according to example 8, on 23 volunteers [0470] The hibiscus flower acid cleanser according to example 10, on 22 volunteers [0471] The three-oil cleanser according to example 12, on 23 volunteers

[0472] The tests were carried out by IDEA Clinic, France.

[0473] Instructions Selected for the Study

[0474] Once a day, preferably in the evening: [0475] shake the cleaner before use, [0476] pour ½ teaspoon of product into the hand, [0477] add water and lather between your hands, [0478] apply to the face, massaging in circular movements to cleanse it well and rinse well with water.

[0479] The volunteers evaluated the product for its properties after use over a period of 21 days. The study was monocentric, open and comparative between D21 and D1.

[0480] Results—Discussion

[0481] No clinical signs of intolerance were observed for the two shampoos.

[0482] Coal Cleaner [0483] Items relating to the efficacy of the product (positive responses≥75%, threshold of statistical significance for 23 volunteers analysed) [0484] The product perfectly cleanses the skin (95.65%) [0485] The product is pleasant to use (100%) [0486] The product is easy to apply (95.65%) [0487] The product is easy to rinse off (100%) [0488] The skin is soft (95.65%) [0489] The skin is clearer (95.65%) [0490] The product removes impurities (95.65%) [0491] The skin is clean and healthy (95.65%) [0492] The product improves the overall appearance and condition of the skin (95.65%) [0493] The product reduces the feeling of tightness and provides a feeling of comfort (95.65%) [0494] The skin is purified (95.65%) [0495] Pores appear tightened (95.65%) [0496] The product reduces imperfections (86.96%) [0497] The product is gentle on the skin (95.65%) [0498] The skin is less shiny (95.65%) [0499] The product limits excess of sebum (95.65%) [0500] The product matifies the skin (95.65%) [0501] The skin is protected from external aggressions (95.65%) [0502] The skin does not feel tight (100%) [0503] The skin is perfectly cleansed (95.65%) [0504] The product is suitable for your skin type (95.65%) [0505] Your impression of the product is good (95.65%)

[0506] Under the conditions of the study, the product exhibited: [0507] excellent dermatological tolerance, according to the scale adopted, on oily facial skin; [0508] and very good cosmetic acceptability, with 96% favorable opinions.

[0509] Hibiscus Flower Acid Cleanser [0510] Items relating to the efficacy of the product (positive responses≥75%, threshold of statistical significance for 22 volunteers analysed) [0511] The product perfectly cleanses the skin (100%) [0512] The product is pleasant to use (95.45%) [0513] The product is easy to apply (95.45%) [0514] The product is easy to rinse off (100%) [0515] The skin is soft (100%) [0516] The skin is clearer (100%) [0517] The product removes impurities (100%) [0518] The skin is clean and healthy (100%) [0519] The product improves the overall appearance and condition of the skin (100%) [0520] The product reduces the feeling of tightness and provides a feeling of comfort (100%) [0521] The skin does not feel tight (100%) [0522] The product is suitable for your skin type (100%) [0523] The complexion is brighter (100%) [0524] Pores appear tightened (100%) [0525] The skin is smooth (100%) [0526] The product is gentle on the skin (100%) [0527] The skin is protected from external aggressions (100%) [0528] The complexion is even (100%) [0529] The skin is perfectly cleansed (100%) [0530] Your impression of the product is good (100%)

[0531] Under the conditions of the study, the product exhibited: [0532] excellent dermatological tolerance, according to the scale adopted, on normal facial skin; [0533] excellent cosmetic acceptability, with 100% favorable opinions.

[0534] Triple Oil Cleanser [0535] Items relating to the efficacy of the product (positive responses≥75%, threshold of statistical significance for 23 volunteers analysed) [0536] The product perfectly cleanses the skin (100%) [0537] The product is pleasant to use (100%) [0538] The product is easy to apply (100%) [0539] The product is easy to rinse off (100%) [0540] The skin is soft (100%) [0541] The skin is clearer (100%) [0542] The product removes impurities (100%) [0543] The skin is clean and healthy (100%) [0544] The product improves the overall appearance and condition of the skin (100%) [0545] The product reduces the feeling of tightness and provides a feeling of comfort (100%) [0546] The product does not dry out the skin (100%) [0547] The product is suitable for your skin type (100%) [0548] The skin is nourished (100%) [0549] The skin is smooth (100%) [0550] The skin does not feel tight (100%) [0551] The product is gentle on the skin (100%) [0552] The skin is protected from external aggressions (100%) [0553] The skin is perfectly cleansed (100%) [0554] Your impression on the product is good 100%)

[0555] Under the conditions of the study, the product exhibited: [0556] excellent dermatological tolerance, according to the scale adopted, on normal or dry facial skin; [0557] and excellent cosmetic acceptability, with 100% favorable opinions.